CN103834164B - A kind of automotive plastic parts nano raw material modified nylon 66 material - Google Patents
A kind of automotive plastic parts nano raw material modified nylon 66 material Download PDFInfo
- Publication number
- CN103834164B CN103834164B CN201310587831.9A CN201310587831A CN103834164B CN 103834164 B CN103834164 B CN 103834164B CN 201310587831 A CN201310587831 A CN 201310587831A CN 103834164 B CN103834164 B CN 103834164B
- Authority
- CN
- China
- Prior art keywords
- raw material
- nano
- nylon
- automotive plastic
- nylon66 fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 29
- 229920002302 Nylon 6,6 Polymers 0.000 title claims abstract description 23
- 239000002994 raw material Substances 0.000 title claims abstract description 21
- 239000004033 plastic Substances 0.000 title claims abstract description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000835 fiber Substances 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011449 brick Substances 0.000 claims abstract description 9
- 239000002893 slag Substances 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims abstract description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000007822 coupling agent Substances 0.000 claims abstract description 7
- 238000006735 epoxidation reaction Methods 0.000 claims abstract description 7
- -1 polyoxyethylene Polymers 0.000 claims abstract description 7
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002545 silicone oil Polymers 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 244000223014 Syzygium aromaticum Species 0.000 claims description 3
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229910052624 sepiolite Inorganic materials 0.000 claims description 3
- 235000019355 sepiolite Nutrition 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010455 vermiculite Substances 0.000 claims description 3
- 229910052902 vermiculite Inorganic materials 0.000 claims description 3
- 235000019354 vermiculite Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 4
- 238000012986 modification Methods 0.000 abstract description 3
- 230000004048 modification Effects 0.000 abstract description 3
- 230000035939 shock Effects 0.000 abstract description 3
- 239000002932 luster Substances 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
Abstract
The invention belongs to polymeric material field, being specifically related to a kind of automotive plastic parts nano raw material modified nylon 66 material, does this material comprise the raw material of following weight part: nylon66 fiber? 100, nylon 6? 12-15, tributyl acetylcitrate 5-8, polyoxyethylene glycol 3-4, nano titanium oxide 10-12, titanate coupling agent TMC-TTS? 1-2, epoxidation tri-glyceride 6-9, propylene glycol phenylate 3-4, dimethyl silicone oil 0.5-1, nano brick ground-slag 10-12, auxiliary agent 12-15; Present invention incorporates the advantage of the raw material such as nylon66 fiber, nylon 6, and utilize the raw material such as nano titanium oxide, nano brick ground-slag to carry out modification to material, make it have good processing characteristics and mechanical property, the material hardness of preparation is high, pliable and tough wear-resisting, good luster, heat-proof aging, shock-resistant, long service life, can be widely used in and make all kinds of automotive plastic part.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of automotive plastic parts nano raw material modified nylon 66 material and preparation method thereof.
Background technology
Along with the development of automobile industry, people are to the comfortableness of automobile, security, aesthetic property, the requirement of the use propertieies such as energy saving is more and more higher, and improve orthodox car material, it is the fundamental way improving vehicle operation performance, macromolecular automobile plastic material has many outstanding advantages than orthodox car material, quality is light, mechanical property is superior, easy machine-shaping, material can reuse, also there is remarkable attractive, decorative effect, but also there are some shortcomings in these macromolecular materials, such as rigidity is poor, easy burning, non-refractory low temperature aging etc., therefore, in order to improve the performance of conventional polymer material, widen materials'use scope, need to improve original automotive plastic formula, modification is carried out to material, each position of automobile can be widely used in.
Summary of the invention
The object of the invention is to, a kind of automotive plastic parts nano raw material modified nylon 66 material is provided, improves the performance of conventional nylon 66 material, it is made to possess excellent mechanical property, can adapt to specific environment for use, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of automotive plastic parts nano raw material modified nylon 66 material, it is characterized in that, material of the present invention is made up of the raw material of following weight part: nylon66 fiber 100, nylon 612-15, tributyl acetylcitrate 5-8, polyoxyethylene glycol 3-4, nano titanium oxide 10-12, titanate coupling agent TMC-TTS1-2, epoxidation tri-glyceride 6-9, propylene glycol phenylate 3-4, dimethyl silicone oil 0.5-1, nano brick ground-slag 10-12, auxiliary agent 12-15.
Described auxiliary agent is made up of the raw material of following weight part: clay 300-320, sepiolite powder 3-4, vermiculite power 1-2,1,6 hexanediyl ester 14-16, montmorillonite powder 2-3, sodium carbonate 3-4, Sodium Silicofluoride 4-5, Silver Nitrate 1-2, vanadium diboride 2.1-2.4, Syzygium aromaticum stem oil 1-2, brown alundum powder 1-2, silane resin acceptor kh-550 1-2; Clay is put into calcining furnace to calcine 3-4 hour at 710-740 DEG C by preparation method, and cooling, puts into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, clean with clear water and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
Described a kind of automotive plastic parts nano raw material modified nylon 66 material, its preparation method is: by nylon66 fiber, nylon 6, tributyl acetylcitrate, nano titanium oxide mixing, be heated to 250-280 DEG C, to nylon66 fiber melting, stir 5-8 minute, add titanate coupling agent TMC-TTS, nano brick ground-slag, epoxidation tri-glyceride again, stir 4-5 minute, finally add other remaining component, stir after 5-8 minute, send into twin screw extruder extruding pelletization, to obtain final product.
Present invention incorporates the advantage of the raw material such as nylon66 fiber, nylon 6, and utilize the raw material such as nano titanium oxide, nano brick ground-slag to carry out modification to material, make it have good processing characteristics and mechanical property, the material hardness of preparation is high, pliable and tough wear-resisting, good luster, heat-proof aging, shock-resistant, long service life, can meet specific environment for use condition, market application foreground is wide.
Embodiment
Embodiment
The present embodiment material is made up of the raw material of following weight part: nylon66 fiber 100, nylon 615, tributyl acetylcitrate 8, polyoxyethylene glycol 4, nano titanium oxide 12, titanate coupling agent TMC-TTS2, epoxidation tri-glyceride 8, propylene glycol phenylate 4, dimethyl silicone oil 1, nano brick ground-slag 12, auxiliary agent 15.
Described auxiliary agent is made up of the raw material of following weight part: clay 300, sepiolite powder 3, vermiculite power 1,1,6 hexanediyl ester 14, montmorillonite powder 3, sodium carbonate 3, Sodium Silicofluoride 5, Silver Nitrate 1, vanadium diboride 2.1, Syzygium aromaticum stem oil 1, brown alundum powder 2, silane resin acceptor kh-550 1; Clay is put into calcining furnace to calcine 4 hours at 740 DEG C by preparation method, cooling, puts into 12% hydrochloric acid soln and soaks 2 hours, filter and take out, and clean with clear water and dry, be ground into 400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
Described a kind of automotive plastic parts nano raw material modified nylon 66 material, its preparation method is: by nylon66 fiber, nylon 6, tributyl acetylcitrate, nano titanium oxide mixing, be heated to 280 DEG C, to nylon66 fiber melting, stir 8 minutes, add titanate coupling agent TMC-TTS, nano brick ground-slag, epoxidation tri-glyceride again, stir 5 minutes, finally add other remaining component, stir after 8 minutes, send into twin screw extruder extruding pelletization, to obtain final product.
The performance test results of material of the present invention is: tensile strength is 108.4MPa, and elongation at break is 42.5%, and flexural strength is 117.5MPa, modulus in flexure 4780MPa, and shock strength is 65.3KJ/m
2, impact embrittlement temperature and reach-40 DEG C, heat-drawn wire (1.82MPa) is 230 DEG C, and after 136 DEG C × 168h hot air aging, stretching strength retentivity 92.6%, elongation at break conservation rate is 91.5%.
Claims (2)
1. an automotive plastic parts nano raw material modified nylon 66 material, it is characterized in that, this material is made up of the raw material of following weight part: nylon66 fiber 100, nylon 612-15, tributyl acetylcitrate 5-8, polyoxyethylene glycol 3-4, nano titanium oxide 10-12, titanate coupling agent TMC-TTS1-2, epoxidation tri-glyceride 6-9, propylene glycol phenylate 3-4, dimethyl silicone oil 0.5-1, nano brick ground-slag 10-12, auxiliary agent 12-15;
Described auxiliary agent is made up of the raw material of following weight part: clay 300-320, sepiolite powder 3-4, vermiculite power 1-2,1,6 hexanediyl ester 14-16, montmorillonite powder 2-3, sodium carbonate 3-4, Sodium Silicofluoride 4-5, Silver Nitrate 1-2, vanadium diboride 2.1-2.4, Syzygium aromaticum stem oil 1-2, brown alundum powder 1-2, silane resin acceptor kh-550 1-2; Clay is put into calcining furnace to calcine 3-4 hour at 710-740 DEG C by preparation method, and cooling, puts into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, clean with clear water and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
2. a kind of automotive plastic parts nano raw material modified nylon 66 material as claimed in claim 1, its manufacture craft is: by nylon66 fiber, nylon 6, tributyl acetylcitrate, nano titanium oxide mixing, be heated to 250-280 DEG C, to nylon66 fiber melting, stir 5-8 minute, add titanate coupling agent TMC-TTS, nano brick ground-slag, epoxidation tri-glyceride again, stir 4-5 minute, finally add other remaining component, stir after 5-8 minute, send into twin screw extruder extruding pelletization, to obtain final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310587831.9A CN103834164B (en) | 2013-11-21 | 2013-11-21 | A kind of automotive plastic parts nano raw material modified nylon 66 material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310587831.9A CN103834164B (en) | 2013-11-21 | 2013-11-21 | A kind of automotive plastic parts nano raw material modified nylon 66 material |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103834164A CN103834164A (en) | 2014-06-04 |
CN103834164B true CN103834164B (en) | 2016-03-23 |
Family
ID=50798077
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310587831.9A Active CN103834164B (en) | 2013-11-21 | 2013-11-21 | A kind of automotive plastic parts nano raw material modified nylon 66 material |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103834164B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108178922A (en) * | 2017-12-28 | 2018-06-19 | 南京鸿瑞塑料制品有限公司 | One kind is for super flexible PA6 composite materials of car floor boring cover and preparation method thereof |
CN115139615B (en) * | 2022-08-25 | 2023-06-06 | 河北泰达包装材料有限公司 | Flexible package modified CPP film and production method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101182388A (en) * | 2007-12-11 | 2008-05-21 | 上海金发科技发展有限公司 | High-wearing high-rigidity reinforced nylon 66 complexes and method for making same |
CN101407630A (en) * | 2008-11-21 | 2009-04-15 | 上海锦湖日丽塑料有限公司 | PA / ASA alloy material and preparation thereof |
CN101831172A (en) * | 2010-05-13 | 2010-09-15 | 中山市点石塑胶有限公司 | Carbon fiber reinforced nylon 66 composite material and preparation method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1841824B1 (en) * | 2005-01-27 | 2011-09-28 | Ems-Chemie Ag | Highly viscose thermoplastic polymer-based moulding compounds and the use thereof |
-
2013
- 2013-11-21 CN CN201310587831.9A patent/CN103834164B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101182388A (en) * | 2007-12-11 | 2008-05-21 | 上海金发科技发展有限公司 | High-wearing high-rigidity reinforced nylon 66 complexes and method for making same |
CN101407630A (en) * | 2008-11-21 | 2009-04-15 | 上海锦湖日丽塑料有限公司 | PA / ASA alloy material and preparation thereof |
CN101831172A (en) * | 2010-05-13 | 2010-09-15 | 中山市点石塑胶有限公司 | Carbon fiber reinforced nylon 66 composite material and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN103834164A (en) | 2014-06-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103642212A (en) | Toughening oil-resistant modified nylon material for automobile plastic members | |
CN103642218A (en) | Nanometer potter's clay modified nylon material for automobile plastic members | |
CN103554881A (en) | Anti-bacterial polycarbonate material for water cup shells and preparation method thereof | |
CN103589006B (en) | A kind of high-elastic cold-resistant modification cis-1,4-polybutadiene rubber CABLE MATERIALS | |
CN103642209A (en) | Waterproof temperature-resistant modified nylon material for automobile plastic members | |
CN103642227A (en) | Polyphenylene sulfide modified nylon material for automobile plastic members | |
CN103642229A (en) | Calcium carbonate modified nylon 66 material for automobile plastic members | |
CN103642234A (en) | Anti-ultraviolet modified nylon 66 material for automobile plastic members | |
CN103834164B (en) | A kind of automotive plastic parts nano raw material modified nylon 66 material | |
CN103642210A (en) | ABS modified nylon material for automobile plastic members | |
CN103665841A (en) | Antistatic waterproof modified nylon 12 material for automobile plastic part | |
CN104355624A (en) | Multi-functional ceramic nozzle prepared from fluorite slag and preparation method thereof | |
CN103665840A (en) | Weather-resistant modified nylon 6 material for automobile plastic part | |
CN103665842A (en) | Ultraviolet-proof modified nylon 6 material for automobile plastic parts | |
CN103642230A (en) | Ethylene-propylene-diene monomer modified nylon 66 material for automobile plastic members | |
CN103642208A (en) | Nanometer kaolin modified nylon 6 material for automobile plastic members | |
CN103665858A (en) | Perlite powder modified nylon 66 material for automobile plastic part | |
CN103834165B (en) | A kind of automotive plastic parts ceramics powder modified nylon 66 material | |
CN103642225A (en) | Wear-resistant polyethylene modified nylon 66 material for automobile plastic members | |
CN103554887A (en) | Polycarbonate material for preparing shell of water cup as well as preparation method thereof | |
CN103665861B (en) | The polyolefin modified nylon material of a kind of automotive plastic parts lightweight | |
CN103937213A (en) | Silica powder modified polyphenyl ether material for automobile plastic part | |
CN103642224A (en) | Zeolite powder modified nylon 66 material for automobile plastic members | |
CN103756301B (en) | Halogen-free expansion type flame-proof nylon PA12 combination material for a kind of nylon washer | |
CN103642211A (en) | Anti-ultraviolet modified nylon 12 material for automobile plastic members |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190726 Address after: 434001 No. 9 Xinhua Road, Jingzhou Development Zone, Hubei Province Patentee after: Jingzhou Aokelan Plastic Co., Ltd. Address before: 241000 College of Chemistry and Materials Science, Anhui Normal University, Huajin South Road, Yijiang District, Wuhu City, Anhui Province Patentee before: Anhui Normal University |