CN103833231A - Glass with graphene oxide nickel-phosphorus composite coating and preparation method of glass - Google Patents
Glass with graphene oxide nickel-phosphorus composite coating and preparation method of glass Download PDFInfo
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- CN103833231A CN103833231A CN201410079393.XA CN201410079393A CN103833231A CN 103833231 A CN103833231 A CN 103833231A CN 201410079393 A CN201410079393 A CN 201410079393A CN 103833231 A CN103833231 A CN 103833231A
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Abstract
The invention discloses a piece of glass with a graphene oxide nickel-phosphorus composite coating and a preparation method of the glass. The glass with the graphene oxide nickel-phosphorus composite coating comprises a glass matrix and the graphene oxide nickel-phosphorus composite coating plated on the surface of the glass matrix, wherein the graphene oxide nickel-phosphorus composite coating is prepared by processing the glass matrix by oil removing, defouling, coarsening and activating, then soaking the glass matrix into a graphene oxide nickel-phosphorus chemical plating solution for 20 to 30 minutes, and finally completely cleaning with distilled water and drying; the graphene oxide nickel-phosphorus composite coating can be combined with the glass matrix well and shows high abrasive resistance, corrosion resistance and electric property; the graphene oxide nickel-phosphorus chemical plating solution per liter comprises 0.1 to 1g of graphene oxide, 25 to 35g of nickel sulfate, 25 to 35g of sodium hypophosphite, 15g of sodium acetate, 10 to 15g of phytic acid, 8g of sodium citrate, 10 to 15g of lactic acid, and 0.05g of compound sterilizer.
Description
Technical field
The present invention relates to a kind of glass with graphene oxide nickel-phosphorus composite deposit
and preparation method thereof.
Background technology
Electroless plating refers in the situation that there is no impressed current, utilizes reductive agent that the metal ion in solution is restored, and is deposited on the method for plating piece surface formation coating, and especially for baroque workpiece, the coating surface that utilizes electroless plating to obtain is evenly smooth.Chemical plating coating has surface crystallization densification, and porosity is low, good stability, and hardness, compared with high, is widely used in space flight, electronics, machinery, precision instrument, five metals and chemical industry.In electroless plating process, add other compound or particle, form composite deposite, improve the performance of single chemical plating, be widely used.
In building, industry, scientific research, life, glass is widely used as a kind of base mateiral.Glass transparent is hard, but matter is crisp frangible, particularly ordinary plate glass, and itself does not possess special performance, cannot, in all trades and professions performance effect widely, apply very limited.In order to improve its performance, need to carry out modification and deep processing processing to it.Glass surface electroless plating is common a kind of modified method, and by its surperficial plating, surface attachment layer of metal, is to realize glass surface functionalization, expands the important method in glass applications field.By plating different metallic membranes, can change the performances such as optics, electricity, calorifics, chemistry and the mechanics of glass.Glass surface electroless plating technology is long-standing, is in 12-13 century the earliest, has occurred scribbling the glass of metallic membrane.Occurred again afterwards glass coating silver-colored, aluminium film, along with the development of technology, people's research is more and more deep, has occurred various composite deposites.As glass surface Electroless Plating Ni-Fe-Pr-P alloy layer has good conductivity and good capability of electromagnetic shielding, can be used as electro-conductive material and electrical loss absorption agent and use.But the various binding force of cladding material that obtain are before this lower, thermal shock method is measured bonding force experiment cycle index generally at 8 times; Hardness and wear resistance are generally not high, and its friction weightlessness is conventionally within the scope of 0.13-0.20mg.
Graphene oxide is the growth of Graphene, on the unlimited basal plane extending of two-dimensional space of the monatomic formation of one deck, connect a large amount of oxy radicals, comprise-OH and C-O-C, and in its film source, contain C=O and COOH, bringing into play very important effect improving aspect the over-all propertieies such as the calorifics of material, electricity, mechanics.
But, at present still not about the report of glass with graphene oxide nickel-phosphorus composite deposit.
Graphene oxide is joined in nickel-phosphorus electroless plating solution, add certain complexing agent, stablizer etc. to make graphene oxide nickel-phosphorus electroless plating solution, for surface treated glass surface, obtain having the glass of graphene oxide nickel-phosphorus composite deposit, because coating has good electricity and mechanical property, thereby can make glass be more widely used.
Summary of the invention
One of object of the present invention provides a kind of glass with graphene oxide nickel-phosphorus composite deposit, graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force, graphene oxide nickel-phosphorus composite deposit has very strong wear resistance, the performances such as erosion resistance.
Two of the object of the invention is to provide above-mentioned a kind of glass with graphene oxide nickel-phosphorus composite deposit
preparation method.
Three of object of the present invention is to provide a kind of above-mentioned graphene oxide nickel-phosphor bath used in the glass with graphene oxide nickel-phosphorus composite deposit that is used to form.
technical scheme of the present invention
A glass with graphene oxide nickel-phosphorus composite deposit, comprises glass basis, and being also included in a layer thickness being coated with on the surface of described glass basis is the graphene oxide nickel-phosphorus composite deposit of 4-6 μ m;
Described graphene oxide nickel-phosphorus composite deposit is that the glass basis after oil removing, scrubbing, alligatoring, activation treatment is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min, controls temperature and is 15-20 ℃ and be dried and obtain after distilled water flushing is clean;
Described graphene oxide nickel-phosphorus electroless plating solution, by every liter of calculating, its component and content are as follows:
Graphene oxide 0.5-1g
Single nickel salt 25-30g
Inferior sodium phosphate 25-30g
Sodium acetate 15g
Phytic acid 10-15g
Trisodium Citrate 8g
Lactic acid 10-15g
Stablizer 0.05g
All the other are distilled water;
Adjusting pH with ammoniacal liquor is 4.4-4.6;
Described one package stabilizer is made up of propenyl thiocarbamide, Potassium Iodate and potassiumiodide, calculates in mass ratio propenyl thiocarbamide: Potassium Iodate: potassiumiodide is 1:18:18.
The preparation method of above-mentioned a kind of glass with graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water and dissolved successively, and then adjusting pH with ammoniacal liquor is 4.4-4.6, obtains graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, under room temperature, ultrasonic concussion 15min then soaks 10-15min in 75% ethanol, and distilled water flushing is clean, reaches the object of oil removing scrubbing;
Then, glass basis is placed on and in roughening solution, soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in to 5min in activation solution, sonic oscillation simultaneously, takes out under room temperature and dries, and puts into baking oven, 30min under 165-170 ℃ of condition; Described activation solution, by every liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, and adjusting pH with ammoniacal liquor is 7.0-7.2;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 ℃, the pretreated glass basis of step (2) is put into after graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature and be 15-20 ℃ be dried after, must there is the glass of graphene oxide nickel-phosphorus composite deposit.
Graphene oxide nickel-phosphorus composite deposit obtained above, it is the method for utilizing electroless plating, on the surface of glass basis, there is redox reaction, nickel phosphorus is deposited on glass basis, carry graphene oxide particle deposition simultaneously on nickel-phosphorus coating, thereby obtain graphene oxide nickel-phosphorus composite deposit.
of the present invention usefuleffect
A kind of glass with graphene oxide nickel-phosphorus composite deposit of the present invention, owing to having added and having there is calorifics in graphene oxide nickel-phosphor bath used in its preparation process, electricity, the graphene oxide particle of the over-all propertieies such as mechanics, having of obtaining contains a certain proportion of graphene oxide in graphene oxide nickel-phosphorus composite deposit, thereby improve the surface tissue of coating, there is better bonding force and wear resistance than common coating, better electric property, thereby for the glass future with graphene oxide nickel-phosphorus composite deposit at the applications expanding in the fields such as electronic devices and components prospect.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is further described, but the present invention is not limited in following embodiment.
Various raw materials used in various embodiments of the present invention, if no special instructions, are commercially available.
embodiment 1
A glass with graphene oxide nickel-phosphorus composite deposit, comprises glass basis, and being also included in a layer thickness being coated with on the surface of described glass basis is the graphene oxide nickel-phosphorus composite deposit of 4-6 μ m;
Described graphene oxide nickel-phosphorus composite deposit is that the glass basis after oil removing, scrubbing, alligatoring, activation treatment is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min, controls temperature and is 15-20 ℃ and be dried and obtain after distilled water flushing is clean;
Described graphene oxide nickel-phosphorus electroless plating solution, by every liter of calculating, its component and content are as follows:
Graphene oxide 0.5g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water;
Adjusting pH with ammoniacal liquor is 4.4-4.6;
Described one package stabilizer is made up of propenyl thiocarbamide, Potassium Iodate and potassiumiodide, calculates in mass ratio propenyl thiocarbamide: Potassium Iodate: potassiumiodide is 1:18:18.
The preparation method of above-mentioned a kind of glass with graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water and dissolved successively according to above-mentioned specification of quality, then adjusting pH with ammoniacal liquor is 4.4-4.6, obtains graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, under room temperature, ultrasonic concussion 15min then soaks 10-15min in 75% ethanol, and distilled water flushing reaches the object of oil removing scrubbing;
Then, glass basis is placed on and in roughening solution, soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in to 5min in activation solution, sonic oscillation simultaneously, takes out under room temperature and dries, and puts into baking oven, 30min under 165-170 ℃ of condition; Described activation solution, by every liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, and adjusting pH with ammoniacal liquor is 7.0-7.2;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 ℃, the pretreated glass basis of step (2) is put into after graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature and be 15-20 ℃ be dried after, must there is the glass of graphene oxide nickel-phosphorus composite deposit.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the composite deposite forming, in conjunction with closely, is cellular growth, and surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece to 200 ℃, room temperature water chilling, through 10 circulations, have the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrates that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, adopt MMW-1A friction wear testing machine to measure its wear resisting property, at load 196N, rotating speed is 150r/min, in the situation of fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
embodiment 2
A glass with graphene oxide nickel-phosphorus composite deposit, comprises glass basis, and being also included in a layer thickness being coated with on the surface of described glass basis is the graphene oxide nickel-phosphorus composite deposit of 4-6 μ m;
Described graphene oxide nickel-phosphorus composite deposit is that the glass basis after oil removing, scrubbing, alligatoring, activation treatment is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min, controls temperature and is 15-20 ℃ and be dried and obtain after distilled water flushing is clean;
Described graphene oxide nickel-phosphorus electroless plating solution, by every liter of calculating, its component and content are as follows:
Graphene oxide 1g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water;
Adjusting pH with ammoniacal liquor is 4.4-4.6;
Described one package stabilizer is made up of propenyl thiocarbamide, Potassium Iodate and potassiumiodide, calculates in mass ratio propenyl thiocarbamide: Potassium Iodate: potassiumiodide is 1:18:18.
The preparation method of above-mentioned a kind of glass with graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water and dissolved successively according to above-mentioned specification of quality, then adjusting pH with ammoniacal liquor is 4.4-4.6, obtains graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, under room temperature, ultrasonic concussion 15min then soaks 10-15min in 75% ethanol, and distilled water flushing reaches the object of oil removing scrubbing;
Then, glass basis is placed on and in roughening solution, soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in to 5min in activation solution, sonic oscillation simultaneously, takes out under room temperature and dries, and puts into baking oven, 30min under 165-170 ℃ of condition; Described activation solution, by every liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, and adjusting pH with ammoniacal liquor is 7.0-7.2;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 ℃, the pretreated glass basis of step (2) is put into after graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature and be 15-20 ℃ be dried after, must there is the glass of graphene oxide nickel-phosphorus composite deposit.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the composite deposite forming, in conjunction with closely, is cellular growth, and surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece to 200 ℃, room temperature water chilling, through 10 circulations, have the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrates that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, adopt MMW-1A friction wear testing machine to measure its wear resisting property, at load 196N, rotating speed is 150r/min, in the situation of fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
embodiment 3
A glass with graphene oxide nickel-phosphorus composite deposit, comprises glass basis, and being also included in a layer thickness being coated with on the surface of described glass basis is the graphene oxide nickel-phosphorus composite deposit of 4-6 μ m;
Described graphene oxide nickel-phosphorus composite deposit is that the glass basis after oil removing, scrubbing, alligatoring, activation treatment is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min, controls temperature and is 15-20 ℃ and be dried and obtain after distilled water flushing is clean;
Described graphene oxide nickel-phosphorus electroless plating solution, by every liter of calculating, its component and content are as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 15g
Stablizer 0.05g
All the other are distilled water;
Adjusting pH with ammoniacal liquor is 4.4-4.6;
Described one package stabilizer is made up of propenyl thiocarbamide, Potassium Iodate and potassiumiodide, calculates in mass ratio propenyl thiocarbamide: Potassium Iodate: potassiumiodide is 1:18:18.
The preparation method of above-mentioned a kind of glass with graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water and dissolved successively according to above-mentioned specification of quality, then adjusting pH with ammoniacal liquor is 4.4-4.6, obtains graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, under room temperature, ultrasonic concussion 15min then soaks 10-15min in 75% ethanol, and distilled water flushing reaches the object of oil removing scrubbing;
Then, glass basis is placed on and in roughening solution, soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in to 5min in activation solution, sonic oscillation simultaneously, takes out under room temperature and dries, and puts into baking oven, 30min under 165-170 ℃ of condition; Described activation solution, by every liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, and adjusting pH with ammoniacal liquor is 7.0-7.2;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 ℃, the pretreated glass basis of step (2) is put into after graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature and be 15-20 ℃ be dried after, must there is the glass of graphene oxide nickel-phosphorus composite deposit.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the composite deposite forming, in conjunction with closely, is cellular growth, and surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece to 200 ℃, room temperature water chilling, through 10 circulations, have the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrates that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, adopt MMW-1A friction wear testing machine to measure its wear resisting property, at load 196N, rotating speed is 150r/min, in the situation of fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
embodiment 4
A glass with graphene oxide nickel-phosphorus composite deposit, comprises glass basis, and being also included in a layer thickness being coated with on the surface of described glass basis is the graphene oxide nickel-phosphorus composite deposit of 4-6 μ m;
Described graphene oxide nickel-phosphorus composite deposit is that the glass basis after oil removing, scrubbing, alligatoring, activation treatment is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min, controls temperature and is 15-20 ℃ and be dried and obtain after distilled water flushing is clean;
Described graphene oxide nickel-phosphorus electroless plating solution, by every liter of calculating, its component and content are as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 30g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water;
Adjusting pH with ammoniacal liquor is 4.4-4.6;
Described one package stabilizer is made up of propenyl thiocarbamide, Potassium Iodate and potassiumiodide, calculates in mass ratio propenyl thiocarbamide: Potassium Iodate: potassiumiodide is 1:18:18.
The preparation method of above-mentioned a kind of glass with graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water and dissolved successively according to above-mentioned specification of quality, then adjusting pH with ammoniacal liquor is 4.4-4.6, obtains graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, under room temperature, ultrasonic concussion 15min then soaks 10-15min in 75% ethanol, and distilled water flushing reaches the object of oil removing scrubbing;
Then, glass basis is placed on and in roughening solution, soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in to 5min in activation solution, sonic oscillation simultaneously, takes out under room temperature and dries, and puts into baking oven, 30min under 165-170 ℃ of condition; Described activation solution, by every liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, and adjusting pH with ammoniacal liquor is 7.0-7.2;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 ℃, the pretreated glass basis of step (2) is put into after graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature and be 15-20 ℃ be dried after, must there is the glass of graphene oxide nickel-phosphorus composite deposit.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the graphene oxide nickel-phosphorus composite deposit forming, in conjunction with closely, is cellular growth, and surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece to 200 ℃, room temperature water chilling, through 10 circulations, have the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrates that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, adopt MMW-1A friction wear testing machine to measure its wear resisting property, at load 196N, rotating speed is 150r/min, in the situation of fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
Above said content is only the basic explanation of the present invention under conceiving, and according to any equivalent transformation that technical scheme of the present invention is done, all should belong to protection scope of the present invention.
Claims (7)
1. a glass with graphene oxide nickel-phosphorus composite deposit, comprises glass basis, characterized by further comprising the graphene oxide nickel-phosphorus composite deposit that a layer thickness being coated with on the surface of described glass basis is 4-6 μ m;
Described graphene oxide nickel-phosphorus composite deposit is that the glass basis after oil removing, scrubbing, alligatoring, activation treatment is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min, dry obtaining after distilled water flushing is clean;
Described graphene oxide nickel-phosphorus electroless plating solution, by every liter of calculating, its component and content are as follows:
Graphene oxide 0.5-1g
Single nickel salt 25-30g
Inferior sodium phosphate 25-30g
Sodium acetate 15g
Phytic acid 10-15g
Trisodium Citrate 8g
Lactic acid 10-15g
Stablizer 0.05g
All the other are distilled water;
Adjusting pH with ammoniacal liquor is 4.4-4.6;
Described one package stabilizer is made up of propenyl thiocarbamide, Potassium Iodate and potassiumiodide, calculates in mass ratio propenyl thiocarbamide: Potassium Iodate: potassiumiodide is 1:18:18.
2. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, and by every liter of calculating, its component and content are as follows:
Graphene oxide 0.5g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water.
3. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, and by every liter of calculating, its component and content are as follows:
Graphene oxide 1g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water.
4. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, and by every liter of calculating, its component and content are as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 15g
Stablizer 0.05g
All the other are distilled water.
5. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, and by every liter of calculating, its component and content are as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 30g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water.
6. the preparation method of a kind of glass with graphene oxide nickel-phosphorus composite deposit as described in claim as arbitrary in claim 1-5, is characterized in that specifically comprising the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water and dissolved successively, and then adjusting pH with ammoniacal liquor is 4.4-4.6, obtains graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, under room temperature, ultrasonic concussion 15min then soaks 10-15min in 75% ethanol, and distilled water flushing is clean;
Then, glass basis is placed on and in roughening solution, soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in to 5min in activation solution, sonic oscillation simultaneously, takes out under room temperature and dries, and puts into baking oven, 30min under 165-170 ℃ of condition; Described activation solution, by every liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, and adjusting pH with ammoniacal liquor is 7.0-7.2;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 ℃, the pretreated glass basis of step (2) is put into after graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature and be 15-20 ℃ be dried after, must there is the glass of graphene oxide nickel-phosphorus composite deposit.
7. in a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, be used to form the graphene oxide nickel-phosphorus electroless plating solution of graphene oxide nickel-phosphorus composite deposit, it is characterized in that, by every liter of calculating, its component and content are as follows:
Graphene oxide 0.5-1g
Single nickel salt 25-30g
Inferior sodium phosphate 25-30g
Sodium acetate 15g
Phytic acid 10-15g
Trisodium Citrate 8g
Lactic acid 10-15g
Stablizer 0.05g
All the other are distilled water;
Adjusting pH with ammoniacal liquor is 4.4-4.6;
Described one package stabilizer is made up of propenyl thiocarbamide, Potassium Iodate and potassiumiodide, calculates in mass ratio propenyl thiocarbamide: Potassium Iodate: potassiumiodide is 1:18:18.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410079393.XA CN103833231B (en) | 2014-03-06 | 2014-03-06 | A kind of have glass of graphene oxide nickel-phosphorus composite deposit and preparation method thereof |
Applications Claiming Priority (1)
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Cited By (7)
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| CN104726907A (en) * | 2015-03-25 | 2015-06-24 | 西南石油大学 | Nickel-tungsten graphene oxide (GO) composite plating solution, plated film and preparation method thereof |
| CN104947096A (en) * | 2015-06-11 | 2015-09-30 | 南京林业大学 | Preparation method of nickel-phosphorus-graphene oxide composite antibacterial coating |
| CN105369239A (en) * | 2015-11-19 | 2016-03-02 | 上海应用技术学院 | Method for preparing passivation film doped with graphene oxide |
| CN105441911A (en) * | 2015-11-19 | 2016-03-30 | 上海应用技术学院 | Chemical plating solution used for chemically plating Ni-B/GO composite coating on surface of SiCp/Al material and application thereof |
| CN108467033A (en) * | 2018-03-13 | 2018-08-31 | 镇江致达新材料科技有限公司 | A kind of preparation method of bionic laminar nano composite film |
| CN113981424A (en) * | 2021-09-24 | 2022-01-28 | 宁波博威合金材料股份有限公司 | Chemical plating Ni-P-graphene composite coating and preparation method thereof |
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| CN103361637A (en) * | 2013-07-16 | 2013-10-23 | 中南林业科技大学 | Chemical nickel-plating graphene preparation method |
| CN103556136A (en) * | 2013-08-26 | 2014-02-05 | 上海应用技术学院 | Graphene-nickel-phosphorus chemical plating liquid, and preparation method and application thereof |
| CN103556138A (en) * | 2013-11-07 | 2014-02-05 | 杭州广荣科技有限公司 | Compound chemical nickel-phosphorus plating solution containing graphene and plating process |
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| CN103556136A (en) * | 2013-08-26 | 2014-02-05 | 上海应用技术学院 | Graphene-nickel-phosphorus chemical plating liquid, and preparation method and application thereof |
| CN103556138A (en) * | 2013-11-07 | 2014-02-05 | 杭州广荣科技有限公司 | Compound chemical nickel-phosphorus plating solution containing graphene and plating process |
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| CN104726907A (en) * | 2015-03-25 | 2015-06-24 | 西南石油大学 | Nickel-tungsten graphene oxide (GO) composite plating solution, plated film and preparation method thereof |
| CN104947096A (en) * | 2015-06-11 | 2015-09-30 | 南京林业大学 | Preparation method of nickel-phosphorus-graphene oxide composite antibacterial coating |
| CN104947096B (en) * | 2015-06-11 | 2017-07-18 | 南京林业大学 | A kind of preparation method of nickel phosphorus oxidation graphene composite antibacterial coating |
| CN105369239A (en) * | 2015-11-19 | 2016-03-02 | 上海应用技术学院 | Method for preparing passivation film doped with graphene oxide |
| CN105441911A (en) * | 2015-11-19 | 2016-03-30 | 上海应用技术学院 | Chemical plating solution used for chemically plating Ni-B/GO composite coating on surface of SiCp/Al material and application thereof |
| CN105369239B (en) * | 2015-11-19 | 2017-12-05 | 上海应用技术学院 | A kind of preparation method of graphene oxide doped passivating film |
| CN108467033A (en) * | 2018-03-13 | 2018-08-31 | 镇江致达新材料科技有限公司 | A kind of preparation method of bionic laminar nano composite film |
| CN113981424A (en) * | 2021-09-24 | 2022-01-28 | 宁波博威合金材料股份有限公司 | Chemical plating Ni-P-graphene composite coating and preparation method thereof |
| CN113981424B (en) * | 2021-09-24 | 2023-09-12 | 宁波博威合金材料股份有限公司 | Chemical plating Ni-P-graphene composite coating and preparation method thereof |
| CN114772947A (en) * | 2022-05-07 | 2022-07-22 | 洪泽县港宏玻璃瓶制造有限公司 | Corrosion-resistant perfume glass bottle and preparation method thereof |
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