CN103829370B - For reducing additive of Blausure (German) and preparation method and application in cigarette smoke - Google Patents
For reducing additive of Blausure (German) and preparation method and application in cigarette smoke Download PDFInfo
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- CN103829370B CN103829370B CN201210477949.1A CN201210477949A CN103829370B CN 103829370 B CN103829370 B CN 103829370B CN 201210477949 A CN201210477949 A CN 201210477949A CN 103829370 B CN103829370 B CN 103829370B
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Abstract
For reducing additive of Blausure (German) and preparation method and application in cigarette smoke, belong to the tobacco product technical field in light industry field.Including Endoconcha Sepiae, Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae, described Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae are respectively 1～10:100,1～6:100 and 1～6:100 with the weight ratio of Endoconcha Sepiae.The present invention can the most effectively lower the burst size of harmful components Blausure (German) in cigarette mainstream flue gas, can reduce flue gas to the stimulation of human respiratory and damage simultaneously, improve the safety of smoking property of cigarette, and can give Medicated cigarette a kind of specific aromatic style.
Description
Technical field
The invention belongs to the tobacco product technical field in light industry field, relate generally to a kind of reduction for selectivity and roll up
Chinese herbal medicine additive of harmful components Blausure (German) and preparation method and application in cigarette main flume.
Background technology
Blausure (German) is the material of most ciliary toxicity in cigarette smoke, and the Blausure (German) in flue gas is absorbed into rapidly through respiratory tract
Enter body, be combined with high swage cytochrome oxidase and become cyaniding height swage cytochrome oxidase, lose the work of transmission oxygen
With, cause histanoxia to be poisoned.Blausure (German) (HCN) is a kind of high volatile A class violent in toxicity, to human threshold level only l0ppm,
Suck Blausure (German) the most harmful, one of the most important environmental contaminants.Market smoking shows with healthy investigation: Medicated cigarette
The harm of flue gas focuses primarily upon cigarette smoke to the respiratory system of organism and the stimulation of cardiovascular system and damage.
At present, doing numerous studies to how being effectively reduced Blausure (German) burst size in cigarette smoke, having lived as utilized
Property charcoal and the adsorption of silica gel, the crown_interception of ion exchange resin, utilize the gold such as carrier loaded Cu, Co, Ag and Cr (VI)
Belong to the removing effect etc. of ion, but the selectivity that these methods have is the highest, the price that has high, the safety in utilization that has can not be protected
Card, have affect cigarette odor-absorbing, make the aromatic style of Medicated cigarette change, therefore make industrial applications be restricted.Application number
Be 201010594659.6 Chinese patent application disclose a kind of for lowering the Chinese herbal medicine of Blausure (German) in cigarette mainstream flue gas
Additive and preparation method and application, this application uses Chinese herbal medicine additive to remove the Blausure (German) in cigarette smoke,
Not only the removing effect to Blausure (German) is strong, affects the most little on the suction taste of Medicated cigarette.Therefore, research cigarette Chinese herbal medicine adding technique selects
In selecting property reduction cigarette mainstream flue gas, the technology of Blausure (German) burst size is to improving the safety of smoking property of cigarette, reducing cigarette smoke pair
The respiratory system of organism and the stimulation of cardiovascular system and damage, minimizing environmental pollution and give the style of Medicated cigarette sense organ fragrance
Feature is increasingly paid close attention to by people.
Summary of the invention
Present invention aims to defect described above, it is provided that one can the most effectively lower Medicated cigarette
The burst size of harmful components Blausure (German) in main flume, can reduce flue gas to the stimulation of human respiratory and damage simultaneously, carry
The safety of high smoking property of cigarette, and can give a kind of specific aromatic style of Medicated cigarette for reducing adding of Blausure (German) in cigarette smoke
Add agent.
Another object of the present invention is to provide a kind of for reducing the preparation side of the additive of Blausure (German) in cigarette smoke
Method and a kind of for reducing the application of the additive of Blausure (German) in cigarette smoke.
It is an object of the invention to be realized by following method.
One is used for reducing Blausure (German) additive in cigarette smoke, it is characterised in that: include Endoconcha Sepiae, Herba Epimedii, Radix Et Rhizoma Rhei
And Fructus Psoraleae, the weight ratio of described Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae and Endoconcha Sepiae be respectively 1～10:100,1～6:100 and 1～
6:100。
A kind of for reducing the preparation method of the additive of Blausure (German) in cigarette smoke, it is characterised in that to include following step
Rapid:
(1), to take Endoconcha Sepiae and pulverize be 60～100 mesh powder, soaks 24 with KOH or NaOH of 0.5mol/L～1.5mol/L
～48 hours, boil 2～4 hours, with drinkable water rinsing to pH value be 9.7～10.2,60～80 DEG C be dried 4～5 hours, 170
～180 DEG C activate 2～4 hours, cross 60～100 mesh sieves, prepare Endoconcha Sepiae powder；
(2), Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae are taken, the most cataclasm, it is 30%～75% by 6～8 times amount concentration, the ethanol of V/V
Impregnating 24～48 hours, water-bath refluxes 2～3 times, each 2～4 hours, merges reflux extracting liquid, and 1～10 DEG C of cold preservation 22～26 is little
Shi Hou, high speed centrifugation, when centrifugal liquid is concentrated in vacuo to 50 DEG C, relative density is 0.8～1.02g/ml, prepares extract；
(3), by extract obtained for step (2) 5%～10%, W/W mixes with the powder of step (1) gained Endoconcha Sepiae, and 60
DEG C～110 DEG C be dried 2～4 hours, cross 60～100 mesh sieves, prepare extract powder；
(4), with step (3) extract obtained powder as bed material, with the 1%～5% of the extract of step (2) gained, W/W is
Adhesive, makes water content 1%～3%, the granule of W/W by boiling granulating technique, crosses 40～80 mesh sieves, prepare additive；
(5), the boiling granulating condition of described step (4) is: inlet temperature 55 DEG C～75 DEG C, temperature of charge 40 DEG C～45
℃。
The application feature of additive of the present invention comprises the following steps:
(1), described extract be used for adding in cigarette shreds, its addition is 0.3%～1.0%, W/W, preferably addition
It is 0.5%, W/W；
(2), described extract be used for adding in Endoconcha Sepiae, its use total amount be 6.0%～15.0%, W/W, Qi Zhongtian
5%～10% W/W of extract adding agent mixes with the powder of Endoconcha Sepiae, and 1%～5% is the adhesive of boiling granulating technique；Preferably
The total amount used is 10.0%, W/W, and wherein the 7% of the extract of additive mixes with the powder of Endoconcha Sepiae, and 3% is boiling granulating work
The adhesive of skill；
(3), described additive be used for adding in cigarette filter rod and make composite filter, its addition is 10～60mg cig-
1, preferably addition is 30mg cig-1.
The present invention is through Tsing-Hua University, Chinese military medicine academy of science, Zhengzhou Nicotiana tabacum L. academy and the change of Jiangxi College of Traditional Chinese Medicine
Learn detection, control experiment and biological assessment, the Chinese patent application of Application No. 201010594659.6 and the ratio of the present invention
Relatively the results are shown in Table shown in 1, show that there is following beneficial effect:
1, the formula material of additive of the present invention is embodied in the thing that can be used for health product that health ministry is announced
In name of an article list, use safety.
2, in additive of the present invention containing the native chemical composition such as saponin, flavone, anthraquinone and psoralen and Fe,
The lot of trace metallic elements such as Zn, Ca, Mg, can with Blausure (German) generation hydrogen bond, aoxidize, coordinate, the physical and chemical effect such as delay, can be notable
Blausure (German) burst size in ground selectivity reducing cigarette fume, reduction rate is up to 21%～34%, and Application No.
201010594659.6 Chinese patent application compare, average rate of decrease improves 14.16%.
3, containing distilling and volatile active ingredient of Chinese herbs in inventive formulation, mass transfer can be realized in flue gas and turn
Moving, biological assessment shows: compare with compareing cigarette group, and experiment cigarette group can relax and reduce cigarette smoke and organism is breathed system
The stimulation of system and damage.
4, additive stability of the present invention is high, deposits 18 months, and it reduces the efficiency of Blausure (German) in cigarette smoke
Constant.
5, the extract in additive preparation process of the present invention can be directly appended to Medicated cigarette cigarette as a kind of spice
In Si, give Medicated cigarette a kind of distinctive book on Chinese herbal medicine fragrance style and features: fragrant for main body note with herbal and Radix Glycyrrhizae, compound certain
Fruital, fragrant and sweet, baking perfume and cream are fragrant.
6, technique is simple to manufacture, steady quality, with low cost, can be used for industrialized production.
The Chinese patent application of table 1 Application No. 201010594659.6 and the experiment of the present invention and the ratio of testing result
Relatively.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, it should be understood that the scope of the present invention is non-is only limitted to this
The scope of a little embodiments.
Embodiment 1
Weigh Endoconcha Sepiae 10000g, Herba Epimedii 1000g, Radix Et Rhizoma Rhei 600g, Fructus Psoraleae 600g, prepare according to the following steps:
Taking Endoconcha Sepiae and pulverizing is 60 mesh powder, and mixing is soaked 24 hours with the NaOH of 0.5mol/L, boiled 3 hours, uses
Drinkable water rinsing is 9.7 to pH value, drains, and 60 DEG C are dried 4 hours, and 180 DEG C activate 2 hours, cross 60 mesh sieves, prepare Endoconcha Sepiae
Powder.
Take Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae, the most cataclasm, add the alcohol dipping 24 hours that 6 times amount concentration are 30%, water-bath
Refluxing 2 times, each 2 hours, merge reflux extracting liquid, after 10 DEG C of cold preservation 24 hours, high speed centrifugation, centrifugal liquid is concentrated in vacuo to 55
DEG C time relative density be 0.80 g/ml, prepare extract.
Taking Endoconcha Sepiae powder, add the extract of 10%, mixing, 110 DEG C are dried wordizations 2 hours, cross 60 mesh sieves, prepare and add
Add agent powder.Using additive powder as bed material, with the 5% of extract as adhesive, make water content by boiling granulating technique
The granule of 2.1%, boiling granulating condition is set as: inlet temperature 55 DEG C, temperature of charge 45 DEG C, crosses 40 mesh sieves, prepares additive.
Tobacco shred is added to by the 0.8% of prepared extract；Additive sieve takes 40 mesh granules, by 10mg cig-1Make
Binary compound filter candle, cigarette becomes Medicated cigarette, aspirates (smoking capacity 35ml/min) on Filtrona COA200 smoke extractor, uses
1mol/LNaOH solution collects the HCN burst size in main flume, and the HCN collecting liquid with the detection of isonicotinic acid--barbituric acid method contains
Amount, carries out controlled trial with the cigarette that compares being not added with extract and Chinese herbal medicine interpolation, and result shows, compares with compareing cigarette, this
The bright prepared experiment cigarette adding extract and Chinese herbal medicine interpolation can make Blausure (German) (HCN) burst size in main flume reduce
23.73%.The style and features of Medicated cigarette sense organ fragrance: fragrant for main body note with herbal and Radix Glycyrrhizae, compound certain fruital, fragrant and sweet,
Bakee fragrant and cream is fragrant.
Embodiment 2
Weigh Endoconcha Sepiae 10000g, Herba Epimedii 800g, Radix Et Rhizoma Rhei 450g, Fructus Psoraleae 400g, prepare according to the following steps:
Taking Endoconcha Sepiae and pulverizing is 80 mesh powder, and mixing is soaked 36 hours with the NaOH of 1.0mol/L, boiled 2 hours, uses
Drinkable water rinsing is 9.9 to pH value, drains, and 70 DEG C are dried 5 hours, and 175 DEG C activate 3 hours, cross 70 mesh sieves, prepare Endoconcha Sepiae
Powder.
Take Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae, the most cataclasm, add the ethanol of 8 times amount 40%, impregnate 36 hours, water-bath backflow 3
Secondary, each 2 hours, merge reflux extracting liquid, 1 DEG C of cold preservation 22 hours, high speed centrifugation, centrifugal liquid is concentrated in vacuo to when 55 DEG C relative
Density is 1.01g/ml, prepares extract.
Taking Endoconcha Sepiae powder, add the extract of 8%, mixing, 105 DEG C are dried activation 3 hours, cross 70 mesh sieves, prepare and add
Agent powder.Using additive powder as bed material, with the 4% of extract as adhesive, make water content 1.4% by boiling granulating technique
Granule, the material strip part processed that seethes with excitement is: inlet temperature 75 DEG C, temperature of charge 40 DEG C, cross 50 mesh sieves, prepare additive.
Tobacco shred is added to by the 1% of prepared extract；Additive sieve takes 50 mesh granules, by 30 mg cig-1Make two
Unit's composite filter, cigarette becomes Medicated cigarette, aspirates (smoking capacity 35ml/min), use 1mol/ on Filtrona COA200 smoke extractor
LNaOH solution collects the HCN burst size in main flume, with the detection of isonicotinic acid--barbituric acid method collect liquid HCN content,
Carrying out controlled trial with the cigarette that compares being not added with extract and Chinese herbal medicine interpolation, result shows, compares with compareing Medicated cigarette, the present invention
Prepared additive granules can make Blausure (German) (HCN) burst size in main flume reduce by 27.62%.Medicated cigarette sense organ fragrance
Style and features: fragrant for main body note with herbal and Radix Glycyrrhizae, compound certain fruital, fragrant and sweet, baking perfume and cream are fragrant.
Embodiment 3
Weigh Endoconcha Sepiae 10000g, Herba Epimedii 600g, Radix Et Rhizoma Rhei 480g, Fructus Psoraleae 300g, prepare according to the following steps:
Taking Endoconcha Sepiae and pulverizing is 100 mesh powder, and mixing is soaked 48 hours with the NaOH of 1.5mol/L, boiled 4 hours, uses
Drinkable water rinsing to pH value is 10.2,80 DEG C and is dried 4.5 hours, and 180 DEG C activate 4 hours, cross 100 mesh sieves, prepare Endoconcha Sepiae powder
End.
Taking Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae, the most cataclasm, adding 7 times amount concentration is the ethanol of 70%, impregnates 48 hours, water-bath
Refluxing 2 times, secondary 2 hours, merge reflux extracting liquid, 5 DEG C of cold preservation 26 hours, high speed centrifugation, centrifugal liquid is concentrated in vacuo to 55 DEG C
Time relative density be 0.98g/ml, prepare extract.
Take Endoconcha Sepiae powder, add the extract of 7%, mixing, 80 DEG C be dried activation 4 hours, cross 100 mesh sieves, prepare and add
Agent powder.Using additive powder as bed material, with the 3% of extract as adhesive, make water content 1.8% by boiling granulating technique
Granule, boiling granulating condition is: inlet temperature 65 DEG C, temperature of charge 45 DEG C, cross 70 mesh sieves, prepare additive.
Tobacco shred is added to by the 0.5% of prepared extract；Prepared additive sieve is taken 70 mesh granules, by 60
mg·cig-1Making binary compound filter candle, cigarette becomes Medicated cigarette, aspirates (smoking capacity on Filtrona COA200 smoke extractor
35ml/min), collect the HCN burst size in main flume with 1mol/LNaOH solution, receive with the detection of isonicotinic acid--barbituric acid method
Liquid collecting Blausure (German) (HCN) content, carry out controlled trial, result table with being not added with the cigarette that compares that extract and Chinese herbal medicine add
Bright, compare with compareing Medicated cigarette, the additive granules prepared by the present invention can make the Blausure (German) burst size in main flume reduce
39.69%.The style and features of Medicated cigarette sense organ fragrance: fragrant for main body note with herbal and Radix Glycyrrhizae, compound certain fruital, fragrant and sweet,
Bakee fragrant and cream is fragrant.
Embodiment 4
Weigh Endoconcha Sepiae 10000g, Herba Epimedii 400g, Radix Et Rhizoma Rhei 250g, Fructus Psoraleae 200g, prepare according to the following steps:
Taking Endoconcha Sepiae and pulverizing is 100 mesh powder, and mixing is soaked 48 hours with the NaOH of 1.0mol/L, boiled 4 hours, uses
Drinkable water rinsing is 10.0 to pH value, drains, and 75 DEG C are dried 4 hours, and 170 DEG C activate 3 hours, cross 100 mesh sieves, prepare sea Piao
Octopus ocellatus Gray powder.
Take Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae, the most cataclasm, adding 7 times amount concentration is the ethanol of 70%, impregnates 48 hours, water
Bath backflow 2 times, 3 hours for the first time, 2 hours for the second time, merges reflux extracting liquid, 10 DEG C of cold preservation 24 hours, and high speed centrifugation is centrifugal
When liquid is concentrated in vacuo to 55 DEG C, relative density is 1.02g/ml, prepares extract.
Taking Endoconcha Sepiae powder, add the extract of 5%, mixing, 105 DEG C are dried 3 hours, cross 100 mesh sieves, prepare additive
Powder.Using additive powder as bed material, with the 3% of extract as adhesive, make water content 1.3% by boiling granulating technique
Granule, boiling granulating condition is: inlet temperature 65 DEG C, temperature of charge 40 DEG C, crosses 60 mesh sieves, prepares additive.
Tobacco shred is added to by the 0.3% of prepared extract；Herbal fragrance (I) additive sieve takes 60 mesh granules, by 40
mg·cig-1Making binary compound filter candle, cigarette becomes Medicated cigarette, aspirates (smoking capacity on Filtrona COA200 smoke extractor
35ml/min), collect the HCN burst size in main flume with 1mol/LNaOH solution, receive with the detection of isonicotinic acid--barbituric acid method
Liquid collecting Blausure (German) (HCN) content, carry out controlled trial, result table with being not added with the cigarette that compares that extract and Chinese herbal medicine add
Bright, compare with compareing Medicated cigarette, the additive granules prepared by the present invention can make the Blausure (German) burst size in main flume reduce
33.48%.The style and features of Medicated cigarette sense organ fragrance: fragrant for main body note with herbal and Radix Glycyrrhizae, compound certain fruital, fragrant and sweet,
Bakee fragrant and cream is fragrant.
Embodiment 5
Weigh Endoconcha Sepiae 10000g, Herba Epimedii 400g, Radix Et Rhizoma Rhei 250g, Fructus Psoraleae 200g, prepare according to the following steps:
Taking Endoconcha Sepiae and pulverizing is 100 mesh powder, and mixing is soaked 48 hours with the NaOH of 1.0mol/L, boiled 4 hours, uses
Drinkable water rinsing is 10.0 to pH value, drains, and 75 DEG C are dried 4 hours, and 170 DEG C activate 3 hours, cross 100 mesh sieves, prepare sea Piao
Octopus ocellatus Gray powder.
Take Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae, the most cataclasm, adding 7 times amount concentration is 70%(v/v) ethanol, dipping is 48 little
Time, water-bath refluxes 2 times, 2.5 hours for the first time, 2 hours for the second time, merges reflux extracting liquid, 10 DEG C of cold preservation 24 hours, at a high speed from
The heart, when centrifugal liquid is concentrated in vacuo to 55 DEG C, relative density is 1.01g/ml, prepares the extract of additive.
Take Endoconcha Sepiae powder, add 5%(w/w) the extract of additive, mixing, 105 DEG C are dried 3 hours, cross 100 mesh
Sieve, prepares additive powder.Using additive powder as bed material, with the 1%(w/w of the extract of additive) as adhesive, with boiling
Rise granulating process and make water content 1.3%(w/w) granule, boiling granulating condition is: inlet temperature 65 DEG C, temperature of charge 40 DEG C,
Cross 60 mesh sieves, prepare additive.
0.5%(w/w by the extract of prepared additive) add tobacco shred to；Additive sieve takes 60 mesh granules, by 30
mg·cig-1Making binary compound filter candle, cigarette becomes Medicated cigarette, aspirates (smoking capacity on Filtrona COA200 smoke extractor
35ml/min), collect Blausure (German) (HCN) burst size in main flume with 1mol/LNaOH solution, use isonicotinic acid--barbituric acid
Method detection collect liquid Blausure (German) (HCN) content, the cigarette that compares added with the extract being not added with additive and Chinese herbal medicine enters
Row controlled trial, result shows, compares with compareing Medicated cigarette, and the additive granules prepared by the present invention can make the cyanogen in main flume
Change hydrogen (HCN) burst size and reduce by 31.42%.The style and features of Medicated cigarette sense organ fragrance: fragrant for main body note with herbal and Radix Glycyrrhizae,
Compound certain fruital, fragrant and sweet, baking perfume and cream are fragrant.
Test method and result]: extract and the additive of additive prepared in above example are pressed one respectively
Certainty ratio is added in tobacco shred and cigarette filter tip, and presses binary composite tip stick production of cigarettes standard and production of cigarettes standard cigarette rolling
Cigarette, is aspirated on Filtrona COA200 smoke extractor by GB/T5606 and GB/T19609 standard, and presses countries tobacco industry pass
In cigarette mainstream flue gas, mensuration continuous flow method (YC/T253-2008) operation of Blausure (German) (HCN), molten with 1mol/LNaOH
Liquid collects Blausure (German) (HCN) burst size in main flume, with the detection of isonicotinic acid--barbituric acid method collect liquid Blausure (German)
(HCN) content, and compare Medicated cigarette (red double) with the Medicated cigarette not using additive and national standard and carry out controlled trial, result is shown in
Table 2.
The result of the test of Blausure (German) burst size in 2 one kinds of Chinese herbal medicine additive selectivity reducing cigarette main flumes of table.
Test result analysis]
Test result indicate that: 1., compared with blank Medicated cigarette, use the Blausure (German) in its main flume of Medicated cigarette of additive
(HCN) burst size alternative reduces by 23.73%～39.69%, averagely can reduce by 31.19%, and " one is used for lowering with former patent
Chinese herbal medicine additive of Blausure (German) and preparation method and application in cigarette mainstream flue gas " (patent No. 201010594659) compare
Harm reduction effect improves 14.46%.Show this pilot project to utilize the extract of additive add tobacco shred and make additive again
The integrated technology closing cigarette filter tip can the preferably burst size of Blausure (German) in selectivity reducing cigarette main flume.
2. result of the test also shows that the HCN burst size of remaining cigarette auxiliary material and adjuvant of Medicated cigarette is below 0.08%.Negligible
Disregard.
3. used one for reduce volume with institute of radio-medicine to above-mentioned by the radiation of Chinese military medicine academy of science
In cigarette flue gas, additive and the Medicated cigarette thereof of Blausure (German) carry out toxicological experiment evaluation, and result shows: compare with compareing cigarette group, experiment
The cytotoxicity of cigarette group, induction cell oxidative damage, membrane damage, chromogene sudden change and cell transformation capacity are the most obvious
Reduce；The lethal time of animal acute exposure cigarette smoke significantly extends, the immunotoxicity of chronic cigarette smoke, genotoxicity,
Long term toxicity all alleviates, and the hazardness of prompting experiment cigarette group reduces.Result of study, it is also shown that compare with compareing cigarette group, tests cigarette
Group has alleviates and lowers flue gas to the stimulation of organism respiratory system and damage.
4. extract and the additive of the additive of the present invention adds in cigarette shreds as a kind of tobacco aromatics using,
Smoke panel test through expert, conclusion: the extract of the additive of the present invention and additive can give Medicated cigarette a kind of distinctive book on Chinese herbal medicine fragrance wind
Lattice feature: fragrant for main body note with herbal and Radix Glycyrrhizae, compound certain fruital, fragrant and sweet, baking perfume and cream are fragrant.
Claims (3)
1. one kind is used for reducing the additive of Blausure (German) in cigarette smoke, it is characterised in that: include Endoconcha Sepiae, Herba Epimedii, Radix Et Rhizoma Rhei
And Fructus Psoraleae, the weight ratio of described Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae and Endoconcha Sepiae be respectively 1～10:100,1～6:100 and 1～
6:100。
2. one kind is used for reducing the preparation method of the additive of Blausure (German) in cigarette smoke, it is characterised in that: comprise the following steps:
(1), to take Endoconcha Sepiae and pulverize be 60～100 mesh powder, soaks 24～48 with KOH or NaOH of 0.5mol/L～1.5mol/L
Hour, boil 2～4 hours, be 9.7～10.2,60～80 DEG C with drinkable water rinsing to pH value and be dried 4～5 hours, 170～180
DEG C activation 2～4 hours, cross 60～100 mesh sieves, prepare Endoconcha Sepiae powder；
(2), Herba Epimedii, Radix Et Rhizoma Rhei and Fructus Psoraleae are taken, the most cataclasm, it is 30%～75% by 6～8 times amount concentration, the ethanol leaching of V/V
Stain 24～48 hours, water-bath refluxes 2～3 times, each 2～4 hours, merges reflux extracting liquid, 1～10 DEG C of cold preservation 22～26 hours
After, high speed centrifugation, when centrifugal liquid is concentrated in vacuo to 50 DEG C, relative density is 0.8～1.02g/ml, prepares extract；
(3), by extract obtained for step (2) 5%～10%, W/W mixes with the powder of step (1) gained Endoconcha Sepiae, 60 DEG C
～110 DEG C be dried 2～4 hours, cross 60～100 mesh sieves, prepare extract powder；
(4), with step (3) extract obtained powder as bed material, with the 1%～5% of the extract of step (2) gained, W/W is glutinous
Mixture, makes water content 1%～3%, the granule of W/W by boiling granulating technique, crosses 40～80 mesh sieves, prepare additive.
A kind of for reducing the preparation method of the additive of Blausure (German) in cigarette smoke, its feature
It is: the boiling granulating condition of described step (4) is: inlet temperature 55～75 DEG C, temperature of charge 40～45 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210477949.1A CN103829370B (en) | 2012-11-22 | 2012-11-22 | For reducing additive of Blausure (German) and preparation method and application in cigarette smoke |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210477949.1A CN103829370B (en) | 2012-11-22 | 2012-11-22 | For reducing additive of Blausure (German) and preparation method and application in cigarette smoke |
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| CN103829370B true CN103829370B (en) | 2017-01-04 |
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Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0058463A1 (en) * | 1981-02-18 | 1982-08-25 | Gist-Brocades N.V. | Tobacco smoke filter |
| CN1033947C (en) * | 1994-10-11 | 1997-02-05 | 南昌卷烟厂 | Chinese medicinal health cigarette and its prodn. method |
| US8381738B2 (en) * | 2003-12-22 | 2013-02-26 | Philip Morris Usa Inc. | Composite materials and their use in smoking articles |
| CN101263930A (en) * | 2008-01-16 | 2008-09-17 | 江西中烟工业公司 | Manufacturing technology of Chinese medicine health-care cigarette |
| CN102551207B (en) * | 2010-12-17 | 2014-09-10 | 江西中烟工业有限责任公司 | Chinese herbal additive for reducing hydrogen cyanide in main stream smoke of cigarette, preparation method and application thereof |
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