CN103824513B - A kind of temperature becomes vaccine label and preparation method thereof - Google Patents

A kind of temperature becomes vaccine label and preparation method thereof Download PDF

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Publication number
CN103824513B
CN103824513B CN201410075815.6A CN201410075815A CN103824513B CN 103824513 B CN103824513 B CN 103824513B CN 201410075815 A CN201410075815 A CN 201410075815A CN 103824513 B CN103824513 B CN 103824513B
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China
Prior art keywords
temperature
layer
sided
phase
glue material
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Expired - Fee Related
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CN201410075815.6A
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Chinese (zh)
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CN103824513A (en
Inventor
杨秀真
刘永生
郭欣
刘文恒
曾海明
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Shenzhen Nine Stars Printing and Packaging Group Co Ltd
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Shenzhen Nine Stars Printing and Packaging Group Co Ltd
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Priority to CN201410075815.6A priority Critical patent/CN103824513B/en
Priority to PCT/CN2014/073661 priority patent/WO2015131416A1/en
Publication of CN103824513A publication Critical patent/CN103824513A/en
Application granted granted Critical
Publication of CN103824513B publication Critical patent/CN103824513B/en
Expired - Fee Related legal-status Critical Current
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    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F3/0291Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
    • G09F3/0294Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time where the change is not permanent, e.g. labels only readable under a special light, temperature indicating labels and the like

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Adhesive Tapes (AREA)
  • Making Paper Articles (AREA)

Abstract

Become vaccine label the invention discloses a kind of temperature of the information such as title, weight, volume and purposes for being used to indicate vaccine product, it includes:Layer of ink, facial tissue layer, two-sided adhesive layer and the off-style paper layer stacked gradually.Phase-change material bisque is provided between the facial tissue layer and two-sided adhesive layer.The invention also discloses the preparation method that this kind temperature becomes vaccine label.The present invention prepares temperature using the selectable low-temperature phase-change material powder of color and becomes vaccine label, various information is printed with facial tissue, the efficiency far that low temperature of the present invention dusts is higher than the low temperature printing efficiency of prior art, efficiently solves the problem of low low temperature print speed printing speed and slow printed matter drying.In addition, it is not necessary that meeting the special paper of low temperature print request, so that improving the production efficiency that temperature becomes vaccine label, production cost is reduced.

Description

A kind of temperature becomes vaccine label and preparation method thereof
Technical field
The present invention relates to the brief label for information such as the title of marked product, weight, volume and purposes, more particularly to A kind of temperature becomes vaccine label and preparation method thereof.
Background technology
Vaccine label is a kind of brief label for being used to indicate the information such as title, weight, volume and the purposes of vaccine product, It is general to be printed using adhesive sticker paper, it is widely used in the outer packing field of the various vaccine products such as people, animal.In recent years, Researcher attempts to print vaccine label using temperature sensitive ink to monitor validity of the vaccine product in storage and transport Brush, realizes that vaccine label is in different temperatures, shows the effect of different colours, so as to reach that monitoring vaccine product is being stored or transported During defeated, if there is a situation where that possibility that is abnormal and causing failure occurs for refrigerated storage temperature, to facilitate before consumer's use It is confirmed.But, this temperature sensitive ink printed applied to vaccine label, it is necessary to be irreversible temperature sensitive ink, once Print refrigerated storage temperature in the storage or transport of the vaccine label of the ink and be higher than defined critical-temperature (for example, general vaccine production Product take cold storage mode to store and transport, and refrigerated storage temperature is 2~8 DEG C), the color of temperature sensitive ink will occur on the vaccine label Change, the change being changed into from a kind of color between another color, and this color is irreversible, and the color after change will not Original color is become again because the refrigerated storage temperature of the vaccine label is less than critical-temperature again.Meanwhile, it is this to be applied to vaccine label Temperature sensitive ink, belong to bioenzyme activity ink, it is very high to prepare cost, and printing environment temperature have to be lower than its critical-temperature, Belong to low temperature print field, the print speed printing speed and printed matter rate of drying of this low temperature mode of printing are all very low, so as to cause print This temperature of system becomes the production cost height and low production efficiency of vaccine label.
Therefore, a kind of simple, low cost, high efficiency and environment-friendly generation are designed and prepares scheme, phase-change material is utilized Temperature sensitive ink is replaced, a kind of novel warm is developed and becomes vaccine label and preparation method thereof, to monitoring vaccine product in storage, transport ring In section refrigerated storage temperature whether occur exception and facilitate consumer using it is preceding it is carried out confirm it is significant.
The content of the invention
The purpose of the present invention is to be directed to utilize temperature sensitive ink preparation temperature change vaccine label production cost high and low production efficiency The problem of, temperature sensitive ink is replaced using phase-change material, a kind of novel warm is developed and becomes vaccine label and preparation method thereof.
A kind of temperature proposed by the present invention becomes vaccine label, its layer of ink for including stacking gradually, facial tissue layer, two-sided adhesive layer and Off-style paper layer.Phase-change material bisque is provided between the facial tissue layer and two-sided adhesive layer.
Preferably, the phase-change material bisque can for localised spacer be arranged at the facial tissue layer and two-sided adhesive layer it Between, or be continuously located between the facial tissue layer and two-sided adhesive layer.
Described phase-change material bisque is colored low-temperature phase-change material bisque.
Described facial tissue is the paper that weight is 60g~120g/m2.
The present invention also proposes that a kind of temperature becomes the preparation method of vaccine label, and step is as follows:
Step 1, a kind of surface layer of selection are release liners, pair that middle level is two-sided adhesive layer, bottom is release liners or mould release membrance Face glue material;
Step 2, the surface layer release liners for peeling off two-sided glue material, expose the two-sided adhesive layer in middle level;
Step 3, under conditions of 1~7 DEG C of temperature, phase-change material powder is sprayed to the middle level exposed in the two-sided glue material On two-sided adhesive layer;
Step 4, the one side for spraying phase-change material powder in the two-sided glue material, which integrally cover, to be covered one layer and is pre-printed with letter The facial tissue of breath is used as surface layer;
Step 5, the two-sided glue material of the facial tissue covered to set carry out roll-in, then carry out positioning die-cutting to resulting product, i.e., Obtain temperature and become vaccine label.
Preferably, choose after a kind of two-sided glue material, be first die cut the surface layer release liners of two-sided glue material, after cross cutting Surface layer release liners are divided into three parts, peel off intermediate portion;
Phase-change material powder is sprayed on the two-sided adhesive layer in middle level exposed in the two-sided glue material;
The remaining surface layer release liners in two-sided glue material both sides are peeled off, phase-change material powder has been sprayed in the two-sided glue material One side integrally cover and cover the facial tissue that information is pre-printed with described in one layer as surface layer.
It is preferred that, after two-sided glue material is chosen, first the surface layer release liners of two-sided glue material can be die cut, be die cut Back layer release liners are divided into three parts, peel off intermediate portion;
Phase-change material fen-ting position, compartment of terrain are sprayed on the two-sided adhesive layer in middle level exposed in the two-sided glue material;
The remaining surface layer release liners in two-sided glue material both sides are peeled off, phase-change material powder has been sprayed in the two-sided glue material One side integrally cover and cover the facial tissue that information is pre-printed with described in one layer as surface layer.
Described two-sided glue material can be using double two-sided glue materials of paper substrate or paper-two-sided glue material of film base.
The present invention prepares temperature using the optional colored low-temperature phase-change material powder of color and becomes vaccine label, and the label is in temperature Under conditions of the covert critical-temperature (such as 8 DEG C) of phase-change material bisque, its interior phase-change material bisque is solid-state, once should Label local environment temperature is higher than the covert critical-temperature of phase-change material bisque, and its interior phase-change material bisque can then be changed into liquid, Confirm whether occurred during understanding storage or transport before facial tissue, convenient use to the cryogenic product so as to soak, contaminate Temperature anomaly.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) present invention prepares temperature change vaccine label using the low-temperature phase-change material bisque of Color tunable, and facial tissue is advance print The paper brushed, compared with temperature sensitive ink prepares temperature change vaccine label, the efficiency far that low temperature dusts is higher than the effect that low temperature prints Rate, it is possible to resolve the problem of low temperature print speed printing speed is low and printed matter dries slow, improves the production efficiency that temperature becomes vaccine label;
(2) compared with temperature sensitive ink prepares temperature change vaccine label, the cost of low-temperature phase-change material bisque becomes well below temperature The cost of ink, and the special paper of low temperature print request need not be met, common solid matte paper or double copper paper can be used as printing Paper, can effectively reduce the production cost that temperature becomes vaccine label.
Brief description of the drawings
Fig. 1 is the structural representation of present pre-ferred embodiments;
Fig. 2 is intended to for the structural diagrams of the two-sided glue material of preferred embodiment;
Fig. 3 is the cross cutting schematic diagram of the surface layer release liners of the two-sided glue material of preferred embodiment;
Fig. 4 is the stripping schematic diagram of release liners in the middle of the surface layer of the two-sided glue material of preferred embodiment;
Fig. 5 is the positioning of preferred embodiment, is spaced the schematic diagram for spraying phase-change material bisque;
Fig. 6 is the stripping schematic diagram of the remaining release liners in surface layer both sides of the two-sided glue material of preferred embodiment;
Fig. 7 covers schematic diagram for the set of the facial tissue of preferred embodiment;
Fig. 8 becomes the schematic diagram of the positioning die-cutting of vaccine label for the temperature of preferred embodiment.
In figure:1- layer of ink, 2- surface layers, 3- phase-change materials bisque, the two-sided adhesive layers of 4-, 5- off-style paper layers, 6- facial tissue layers.
Embodiment
The present invention is described in detail with reference to the accompanying drawings and examples.
As shown in figure 1, one kind temperature that present pre-ferred embodiments are provided becomes vaccine label, it includes the layer of ink stacked gradually 1st, facial tissue layer 6, two-sided adhesive layer 4 and off-style paper layer 5.Phase-change material bisque 3 is provided between facial tissue layer 6 and two-sided adhesive layer 4. In the present embodiment, phase-change material bisque 3 is arranged between facial tissue layer 6 and two-sided adhesive layer 4 for localised spacer, i.e. phase-change material Also leave two-sided adhesive layer 4 in the periphery of bisque 3.As needed, phase-change material bisque 3 can also continuously be located at facial tissue layer 6 and two-sided Between adhesive layer 4.For convenience of differentiating and observing, phase-change material bisque 3 is colored low-temperature phase-change material bisque, such as from red The low-temperature phase-change material bisque of the colors such as color, blueness or green.Facial tissue 6 is the paper that weight is 60g~120g/m2.
Present invention also offers the preparation method that above-mentioned temperature becomes vaccine label:
Embodiment one:A kind of temperature becomes the preparation method of vaccine label, and implementation steps are as follows:
Step 1, a roll of double paper substrate double faced adhesive tapes (Yongxing adhesive article factory produces, model YX208) of selection, the material includes Three layers, surface layer 2 is release liners, and middle level is two-sided adhesive layer 4, and bottom 5 is release liners, as shown in Figure 2;
Step 2, using label die cutting machine, the surface layer release liners 2 to double paper substrate double faced adhesive tapes are die cut, cross cutting leafing below Type paper 2 is divided into three parts, peels off intermediate portion, as shown in Figure 3,4;
Step 3, under conditions of 3~7 DEG C of temperature, the two-sided adhesive layer in middle level is exposed to double paper substrate double faced adhesive tapes using duster Place, positioned, be spaced spray red low-temperature phase-change material bisque 3 (wide area phase-change material Science and Technology Ltd. produce, Model MG9), as shown in Figure 5;
Step 4, under conditions of 3~7 DEG C of temperature, peel off double remaining surface layer release liners 2 in paper substrate double faced adhesive tape both sides, then Overall set covers one layer of double copper paper 6 (Jing Di Paper Co., Ltd produces, and grammes per square metre is 80g/m2) for being pre-printed with information 1, such as schemes 6th, shown in 7;
Step 5, under conditions of 3~7 DEG C of temperature, double paper substrate double faced adhesive tapes progress roll-in of one layer of double copper paper 6 is covered to set, is made Obtain double copper paper and the bonding of two-sided adhesive layer is firm, then to resulting product progress positioning die-cutting, that is, obtain temperature and become vaccine label, such as Shown in Fig. 8.
Embodiment two:A kind of temperature becomes the preparation method of vaccine label, and implementation steps are as follows:
Step 1, selection one coil paper-film base double faced adhesive tape (Yongxing adhesive article factory produces, model YX320), the material bag Three layers are included, surface layer is release liners 2, middle level is two-sided adhesive layer 4, and bottom is mould release membrance 5, as shown in Figure 2;
Step 2, using label die cutting machine, the surface layer release liners 2 to paper-film base double faced adhesive tape are die cut, be die cut back layer Release liners are divided into three parts, peel off intermediate portion, as shown in Figure 3,4;
Step 3, under conditions of 1~5 DEG C of temperature, it is two-sided gluing to paper-film base double faced adhesive tape exposes middle level using duster The place of layer, is positioned, is spaced low-temperature phase-change material bisque (the wide area phase-change material Science and Technology Ltd. life for spraying blueness Production, model MG9), as shown in Figure 5;
Step 4, under conditions of 1~5 DEG C of temperature, the peeling paper-remaining surface layer release liners 2 in film base double faced adhesive tape both sides, so Overall set covers one layer of solid matte paper (Jing Di Paper Co., Ltd produces, and grammes per square metre is 70g/m2) for being pre-printed with information 1, reference afterwards Fig. 6, shown in 7;
Step 5, under conditions of 1~5 DEG C of temperature, the paper of one layer of solid matte paper-film base double faced adhesive tape is covered to set and carries out roll-in, is made Obtain solid matte paper and the bonding of two-sided adhesive layer is firm, positioning die-cutting then is carried out to resulting product, that is, obtain warm change vaccine label, ginseng Examine shown in Fig. 8.
Required according to different, temperature can also be prepared and becomes vaccine label:
Embodiment three:A kind of temperature becomes the preparation method of vaccine label, and implementation steps are as follows:
Step 1, a roll of double paper substrate double faced adhesive tapes (Yongxing adhesive article factory produces, model YX208) of selection, the material includes Three layers, surface layer is release liners 2, and middle level is two-sided adhesive layer 4, and bottom is release liners 5, with reference to shown in Fig. 2;
Step 2, the surface layer release liners 2 for peeling off two-sided glue material, expose the two-sided adhesive layer in middle level;
Step 3, under conditions of 3~7 DEG C of temperature, phase-change material fen-ting position, the interval of green are sprayed in two-sided glue material , as requested, can also be by the phase-change material powder of green continuously with reference to shown in Fig. 6 on the two-sided adhesive layer in middle level that material exposes Spray on the two-sided adhesive layer in middle level exposed in two-sided glue material;
Step 4, under conditions of 3~7 DEG C of temperature, the one side for spraying phase-change material powder in two-sided glue material, which integrally covers, to be covered One layer is pre-printed with double copper paper 6 of information as surface layer, with reference to shown in Fig. 7;
Step 5, under conditions of 3~7 DEG C of temperature, the two-sided glue material that double copper paper 6 are covered with to set carries out roll-in, then right Resulting product carries out positioning die-cutting, that is, obtains temperature and become vaccine label, with reference to shown in Fig. 8.
The present invention prepares temperature using the optional colored low-temperature phase-change material powder of color and becomes vaccine label, and phase-change material (PCM-Phase Change Material) can be varied with temperature and be changed physical property and can provide the material of latent heat. During changing physical property, phase-change material will absorb or discharge substantial amounts of latent heat.This material is a kind of new energy-conservation The environmental protection carrier of environmental protection.When label prepared by the present invention is in the covert critical-temperature that temperature is less than phase-change material bisque 3 Under conditions of (such as 8 DEG C), its interior phase-change material bisque 3 is solid-state, once the label local environment temperature is higher than phase-change material The covert critical-temperature of bisque 3, its interior phase-change material bisque 3 can then be changed into liquid, so as to soak, contaminate facial tissue, convenient use It is preceding that the cryogenic product is confirmed, whether occur excess temperature during understanding storage or transport abnormal.
Before the exploitation present invention, applicant once using low temperature temperature sensitive ink make can not inversion become vaccine label, run into perhaps Many concrete technical problems, for example, the technique can not solve the problems, such as the drying of high-speed production.Ink setting mode mainly has at present: Three kinds of infra-red drying, ultraviolet drying and volatile dry, it is infrared all to produce substantial amounts of heat with ultraviolet drying process, make low temperature temperature Sensitive ink fails, and is not suitable for irreversible low temperature temperature sensitive ink and dries.And volatile dry process can produce it is substantial amounts of organic molten Agent, in relatively closed low temperature environment, is unfavorable for the healthy of staff, meanwhile, volatile dry generally requires two Collection requirement is can be only achieved more than hour, at low ambient temperatures, drying time requires longer, it is impossible to realize batch production.
Therefore, applicant changes the mode of thinking, the effect that low temperature temperature becomes is realized by the physical property of material, by a large amount of Experiment, final confirmation with phase-change material replace temperature sensitive ink, realize low temperature color changeable effect using the definite melting point of phase-change material. Therefore, the R&D team of the present invention have collected comparing material, meeting batch production requirements for technique for a large amount of different critical temperature Carry out rational procedure planning, while transforming introducing equipment, no less than 300,000 yuan people of project development Master Cost input People's coin, after the time more than half a year, just obtains the creation of the present invention.
After tested present invention can be implemented in the high speed printing under low temperature environment, without considering that material dries problem, it is adapted to wheel Turn equipment high speed, large-scale production, production efficiency is more than 10 times of existing process.Product phase is made with existing temperature sensitive ink Than the discharge of production process organic solvent-free, safety and environmental protection.Compared with existing temperature sensitive ink makes product, production process is without big Drying for amount dries space.
The embodiment of present invention described above, is not intended to limit the scope of the present invention..Any basis Various other corresponding changes and deformation made by the technical concept of the present invention, should be included in the guarantor of the claims in the present invention In the range of shield.

Claims (3)

1. a kind of temperature becomes the preparation method of vaccine label, comprise the following steps:
Step 1, a kind of surface layer of selection are release liners, the double faced adhesive tape that middle level is two-sided adhesive layer, bottom is release liners or mould release membrance Material;
Step 2, the surface layer release liners for peeling off two-sided glue material, expose the two-sided adhesive layer in middle level;
Step 3, under conditions of 1~7 DEG C of temperature, phase-change material powder is sprayed to the middle level exposed in the two-sided glue material two-sided On adhesive layer;
Step 4, under conditions of 1~7 DEG C of temperature, the one side for spraying phase-change material powder in the two-sided glue material, which integrally covers, to be covered One layer is pre-printed with the facial tissue of information as surface layer;
Step 5, under conditions of 1~7 DEG C of temperature, roll-in is carried out to the two-sided glue material of facial tissue that set covers, then to gained system Product carry out positioning die-cutting, that is, obtain temperature and become vaccine label, and the temperature, which becomes vaccine label, includes the layer of ink stacked gradually, facial tissue layer, double Face adhesive layer and off-style paper layer, are provided with phase-change material bisque between the facial tissue layer and two-sided adhesive layer.
2. preparation method as claimed in claim 1, it is characterised in that:
Choose after a kind of two-sided glue material, be first die cut the surface layer release liners of two-sided glue material, be die cut back layer release liners It is divided into three parts, peels off intermediate portion;
Phase-change material fen-ting position, compartment of terrain are sprayed on the two-sided adhesive layer in middle level exposed in the two-sided glue material;
The remaining surface layer release liners in two-sided glue material both sides are peeled off, the one of phase-change material powder is sprayed in the two-sided glue material Face, which integrally covers, covers the facial tissue that information is pre-printed with described in one layer as surface layer.
3. preparation method as claimed in claim 1, it is characterised in that:Described two-sided glue material is the two-sided glue material of double paper substrates Or paper-two-sided glue material of film base.
CN201410075815.6A 2014-03-03 2014-03-03 A kind of temperature becomes vaccine label and preparation method thereof Expired - Fee Related CN103824513B (en)

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PCT/CN2014/073661 WO2015131416A1 (en) 2014-03-03 2014-03-19 Variable temperature vaccine label and preparation method thereof

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CN111105700A (en) * 2020-01-13 2020-05-05 杭州沃朴物联科技有限公司 Color-changing anti-counterfeit label
CN111833719B (en) * 2020-07-06 2021-11-16 深圳市深大极光科技有限公司 Temperature monitoring anti-counterfeit label capable of being signed and preparation method thereof
CN113361672B (en) * 2021-05-25 2022-03-04 天津静华科技发展有限公司 Active label packaging method suitable for cold region
CN114889321A (en) * 2022-06-13 2022-08-12 东莞市恒盛胶袋有限公司 Production device of temperature sensing packaging material and packaging material produced by same

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