CN103814937A - Insecticide composition - Google Patents
Insecticide composition Download PDFInfo
- Publication number
- CN103814937A CN103814937A CN201410049037.3A CN201410049037A CN103814937A CN 103814937 A CN103814937 A CN 103814937A CN 201410049037 A CN201410049037 A CN 201410049037A CN 103814937 A CN103814937 A CN 103814937A
- Authority
- CN
- China
- Prior art keywords
- active ingredient
- pyridine
- afidopyropen
- cycloxaprid
- piperazine worm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000002917 insecticide Substances 0.000 title description 6
- LRZWFURXIMFONG-HRSIRGMGSA-N afidopyropen Chemical compound C([C@@]1(C)[C@H]2[C@]([C@H]3[C@@H](O)C=4C(=O)OC(=CC=4O[C@]3(C)[C@@H](O)C2)C=2C=NC=CC=2)(C)CC[C@@H]1OC(=O)C1CC1)OC(=O)C1CC1 LRZWFURXIMFONG-HRSIRGMGSA-N 0.000 claims abstract description 56
- 241000238631 Hexapoda Species 0.000 claims abstract description 48
- NDHXMRFNYMNBKO-PWSUYJOCSA-N chembl2227757 Chemical compound [O-][N+](=O)C([C@H]1CC[C@H](O1)N1CC2)=C1N2CC1=CC=C(Cl)N=C1 NDHXMRFNYMNBKO-PWSUYJOCSA-N 0.000 claims abstract description 48
- 239000004480 active ingredient Substances 0.000 claims abstract description 29
- 241001414989 Thysanoptera Species 0.000 claims abstract description 4
- 230000003405 preventing effect Effects 0.000 claims abstract description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 132
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 132
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 66
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 56
- 239000004593 Epoxy Substances 0.000 claims description 39
- 230000000361 pesticidal effect Effects 0.000 claims description 18
- 241000607479 Yersinia pestis Species 0.000 claims description 9
- 239000000375 suspending agent Substances 0.000 claims description 7
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- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
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- 229940056881 imidacloprid Drugs 0.000 description 3
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- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
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- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
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- 231100000614 poison Toxicity 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
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- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- YYFLDZZDOUDZQM-UHFFFAOYSA-N 3-[1-[[4-(3-phenylquinolin-2-yl)phenyl]methyl]piperidin-4-yl]-1h-benzimidazol-2-one Chemical compound O=C1NC2=CC=CC=C2N1C(CC1)CCN1CC(C=C1)=CC=C1C1=NC2=CC=CC=C2C=C1C1=CC=CC=C1 YYFLDZZDOUDZQM-UHFFFAOYSA-N 0.000 description 1
- NDCQPJCNZBQYAO-UHFFFAOYSA-N 4-[[3-[3-benzoyl-8-(trifluoromethyl)quinolin-4-yl]phenoxy]methyl]benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1COC1=CC=CC(C=2C3=CC=CC(=C3N=CC=2C(=O)C=2C=CC=CC=2)C(F)(F)F)=C1 NDCQPJCNZBQYAO-UHFFFAOYSA-N 0.000 description 1
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- 239000005995 Aluminium silicate Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
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- 239000000205 acacia gum Substances 0.000 description 1
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- 239000002671 adjuvant Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
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- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition. The composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A adopts afidopyropen; the active ingredient B is selected from one of paichongding, cycloxaprid and cycolxylidin; the weight ratio of the active ingredient A to the active ingredient B is (1:80) to (80:1). The pesticide composition is used for controlling and preventing various injurious insects, such as plant hoppers and thrips, has an excellent synergistic interaction effect, and can improve the controlling and preventing effect, and reduce the usage amount of pesticide and the use cost of farmers.
Description
Technical field
The invention belongs to agricultural insecticide field, relate to particularly Pesticidal combination and application thereof that a class contains afidopyropen.
Background technology
Afidopyropen (test code number ME5343) is a kind of novel pesticide of Japanese Meiji Pharmaceutial Ltd. and the joint research exploitation of Japanese Kitasato Kenkyusho (JP) 9-1, Shirokane 5-chome, Minato-ku, Tokyo 108, Japan.This product is a kind of brand-new structure and has brand-new mechanism of action, can prevent and treat suction type mouthpart insect as aphid, plant hopper, scale insect and leafhopper etc. for vegetables, fruit tree, vine, intertillage crop and ornamental plants etc.
The pyridine of piperazine worm is new and effective, wide spectrum, low toxicity nicotinic insecticide, mode of action uniqueness, and the aixs cylinder that acts on insect nerve conduction is touched acceptor, and block nerves conduction, shows as strong feeding deterrent.There is stronger interior suction conduction, can be absorbed rapidly by crop, rice fulgorid, tea lesser leafhopper etc. are had to good control efficiency.
Cycloxaprid (Cycloxapyrid) is a kind of novel nicotinamide insecticide, is formulated by East China University of Science.This compound has interior suction, stomach toxicity and action of contace poison, can be used for preventing and treating Homoptera, coleopteran pest on crops, without cross resistance, also effective to lepidoptera pest with Imidacloprid, Acetamiprid, epoxy insect quinoline etc.This product using dosage is low, environmentally safe, to beneficial organism without harm or endanger minimum.Aphid to crops such as wheat, cotton, paddy rice, fruit tree, vegetables, aleyrodid, plant hopper, flea beetle, cotton bollworm, diamond-back moth, prodenia litura, armyworm etc. have higher insecticidal activity.
Epoxy insect quinoline (Cycloxylidin) belongs to anabasine insecticide, is formulated by Wuhan Engineering Univ.This compound has interior suction, stomach toxicity and action of contace poison, and structure approaches with Imidacloprid, but active in Imidacloprid, and the sucking pest such as aphid, aleyrodid is had to higher activity.
The technical scheme being used in combination about afidopyropen and the pyridine of piperazine worm or cycloxaprid or epoxy insect quinoline at present has no report.
Summary of the invention
The object of the present invention is to provide a kind of synergistic effect remarkable, control efficiency is good, the Pesticidal combination that drug cost is low and application thereof.
For reaching goal of the invention, the technical solution used in the present invention is:
A Pesticidal combination that contains afidopyropen, the active ingredient of said composition is made up of two kinds of A and B, and active ingredient A is afidopyropen, and active ingredient B is selected from any one in the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline; The mass ratio of active ingredient A and active ingredient B is 80: 1～1: 80, and preferred mass ratio is 40: 1～1: 40.
Pesticidal combination of the present invention also can use with other compound with weeding, bactericidal property, also can mix use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Pesticidal combination of the present invention compared with the existing technology, at least can produce following beneficial effect:
1. in composition, two kinds of active components are composite according to the above ratio has notable synergistic effect afterwards to insect, and the insecticidal effect of mixed composition is significantly improved compared with its single dose, plays good insect protected seedling protecting effect;
2. the mechanism of action difference of two kinds of active ingredients in this Pesticidal combination, the application of composition can delay or overcome the pesticide resistance of insect;
3. there is the Pesticidal combination of synergistic effect, can reduce field dosage, effectively reduce environmental pollution and residue of pesticide, reduce the harm to beneficial organism;
4. composition has the advantages that quick-acting is good and lasting effect is long.
Embodiment
For making object of the present invention, technical scheme and technological merit clearer, below in conjunction with embodiment, content of the present invention is described further, but the present invention is limited to absolutely not these examples.Specific embodiment only, for explaining the present invention, is not intended to limit the present invention.All any modifications of making within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
The embodiment of the present invention provides the Pesticidal combination of a kind of afidopyropen of containing, said composition is made up of active ingredient A and active ingredient B, active ingredient A is afidopyropen, and active ingredient B is selected from any one in the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline; The mass ratio of active ingredient A and active ingredient B is 80: 1～1: 80, and preferred mass ratio is 40: 1～1: 40.
Inventor is by the result of a large amount of biologicall test experiment sievings, after unexpected discovery afidopyropen and the pyridine of piperazine worm or cycloxaprid or epoxy insect quinoline are composite with aforementioned proportion, the suckings pest such as plant hopper, aphid, aleyrodid, thrips are had significant synergies.On the basis of above-mentioned discovery, through composition is carried out to symphyogenetic quantitative analysis, form the present invention, take afidopyropen as a kind of effective ingredient, take the pyridine of piperazine worm or cycloxaprid or epoxy insect quinoline as another effective ingredient, two kinds of compositions complement each other, and synergy, plays excellent synergistic effect.
The Pesticidal combination of the embodiment of the present invention can be according to the crop of required control, environmental condition of living in, prevent and treat the various factors such as method, cost accounting, active ingredient is processed into together with carrier (filler) to acceptable any one formulation in pesticides application with auxiliary agent, preferred dosage form is granule, microcapsule suspending agent, microemulsion, suspending agent, aqueous emulsion, wetting powder, water dispersible granules or ultra low volume liquids.Adjuvant used, carrier and process technology adopt known component.In above-mentioned various formulations, the gross mass percentage composition of afidopyropen and the pyridine of piperazine worm or cycloxaprid or epoxy insect quinoline is 0.5%～85%, for example, in the time that the quality percentage composition of afidopyropen and the pyridine of piperazine worm is respectively 20% and 4%, total content is 24%; In the time that the quality percentage composition of afidopyropen and cycloxaprid is respectively 10% and 5%, total content is 15%, shown in the following example of value of concrete gross mass percentage composition.
In order to make object of the present invention, technical scheme and advantage clearer, the present invention further describes by following specific experiment example.If no special instructions, the ratio (comprising percentage) of below mentioning is all mass ratio.
One, preparation processing formulation Example
Embodiment 1:40%afidopyropen piperazine worm pyridine suspending agent (afidopyropen: piperazine worm pyridine=1: 1)
Make wherein afidopyropen20g, piperazine worm pyridine 20g according to common process, sodium lignin sulfonate (dispersant) 4g, ethylene glycol (antifreeze) 4g, bentonite (thickener) 3g, organic silicone (defoamer) 3g, deionized water is mended to 100g.
In the present embodiment, the part by weight of afidopyropen and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to cycloxaprid, epoxy insect quinoline forms new embodiment.
Embodiment 2:60%afidopyropen paichongding water dispersible granule (afidopyropen: piperazine worm pyridine=1: 5)
Make according to common process, afidopyropen10g, piperazine worm pyridine 50g, Negel (dispersant) 5g, sodium lignin sulfonate (dispersant) 7g, lauryl sodium sulfate (wetting agent) 2g, ammonium sulfate (disintegrant) 5g, precipitated calcium carbonate (filler) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 5～80%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to cycloxaprid, epoxy insect quinoline forms new embodiment.
Embodiment 3:55%afidopyropen piperazine worm pyridine wetting powder (afidopyropen: piperazine worm pyridine=10: 1)
Afidopyropen50g, piperazine worm pyridine 5g, lauryl sodium sulfate (wetting agent) 2g, sodium lignin sulfonate (dispersant) 3g, NN0 (dispersant) 5g, kaolin complements to 100g.
In the present embodiment, the part by weight of afidopyropen and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 5～85%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to cycloxaprid, epoxy insect quinoline forms new embodiment.
Embodiment 4:12%afidopyropen piperazine worm pyridine microemulsion (afidopyropen: piperazine worm pyridine=1: 5)
Make according to common process, afidopyropen2g, piperazine worm pyridine 10g, 1-METHYLPYRROLIDONE (cosolvent) 10g, calcium dodecyl benzene sulfonate (emulsifier) 8g, phenethyl phenol polyethenoxy ether (emulsifier) 7g, triphen ethyl-phenol polyoxyethylene (emulsifier) 5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to cycloxaprid, epoxy insect quinoline forms new embodiment.
Embodiment 5:10%afidopyropen cycloxaprid micro-capsule suspension (afidopyropen: cycloxaprid=1: 1)
Afidopyropen5g, cycloxaprid 5g, cyclohexanone (solvent) 1g, polyisocyanates (curing agent) 0.4g, ethylene glycol (solvent) 0.4g, gum Arabic (thickener) 1g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and cycloxaprid can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Cycloxaprid can also be replaced to the pyridine of piperazine worm, epoxy insect quinoline forms new embodiment.
Embodiment 6:15%afidopyropen cycloxaprid emulsion in water (afidopyropen: cycloxaprid=1: 2)
Afidopyropen5g, cycloxaprid 10g, calcium dodecyl benzene sulfonate (emulsifier) 2.1g, phenethyl phenol polyethenoxy ether (emulsifier) 1.5g, cyclohexanone (solvent) 10.1g, toluene (solvent) 10.2g, xanthans (thickener) 0.5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and cycloxaprid can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Cycloxaprid can also be replaced to the pyridine of piperazine worm, epoxy insect quinoline forms new embodiment.
Embodiment 7:8.2%afidopyropen piperazine worm pyridine granule (afidopyropen: piperazine worm pyridine=40: 1)
Afidopyropen8g, piperazine worm pyridine 0.2g, dioctyl sodium sulphosuccinate 1g, wood is moulded sodium sulfonate 2g, vinyl alcohol-vinyl alkyl ethers copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of afidopyropen and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 0.5～85%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to cycloxaprid, epoxy insect quinoline forms new embodiment.
Embodiment 8:12%afidopyropen piperazine worm pyridine ultra low volume liquids (afidopyropen: piperazine worm pyridine=1: 5)
Afidopyropen2g, piperazine worm pyridine 10g, 1-METHYLPYRROLIDONE 10g, DMF 15g, n-octyl alcohol 2g, dodecyl sodium sulfonate calcium 2g, OPEO 3g, C10 aromatic hydrocarbons complements to 100g.
In the present embodiment, the part by weight of afidopyropen and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to cycloxaprid, epoxy insect quinoline forms new embodiment.
Embodiment 9:4.1%afidopyropen piperazine worm pyridine granule (afidopyropen: piperazine worm pyridine=1: 40)
Afidopyropen0.1g, piperazine worm pyridine 4g, dioctyl sodium sulphosuccinate 1g, wood is moulded sodium sulfonate 2g, vinyl alcohol-vinyl alkyl ethers copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of afidopyropen and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 0.5～85%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to cycloxaprid, epoxy insect quinoline forms new embodiment.
Two, biological activity determination and test of pesticide effectiveness example
The combination of active principles of different agricultural chemicals is made to agricultural chemicals, is effectively and the efficiently mode of one of the upper resistant insect of current development novel pesticide and control agricultural.The agricultural chemicals of different cultivars shows three kinds of type of action: summation action, synergistic effect and antagonism after mixing conventionally.But be specially which kind of effect, unpredictable, only have by lot of experiments and could determine.
Inventor is by a large amount of screening tests, find that afidopyropen and the pyridine of piperazine worm or cycloxaprid or the combination of epoxy insect quinoline have obvious synergistic function to the sucking pest such as plant hopper, thrips, thus, the embodiment of the present invention also provides the application of above-mentioned Pesticidal combination suckings pest such as control Brown Planthopper, Frankliniella occidentalis.Control efficiency is not only the simple addition of two kinds of medicaments, is specifically illustrated with following biologicall test example.
One) the composite joint toxicity measuring to Brown Planthopper of biologicall test example: afidopyropen and the pyridine of piperazine worm or cycloxaprid or epoxy insect quinoline
For examination object: Brown Planthopper (Nilaparvata lugens (Stdl)), resource environment institute of Agricultural University Of South China Pesticide Science be the sensitive population providing, and use pot rice indoor culture, picking consistent 3 age nymph be used for test.
Test method: with reference to farm-chemical indoor determination test rule insecticidal n Y/T1154.11-2008, adopt rice stem infusion process.
Mode of application is judged co-toxicity coefficient (CTC) method that adopts.The computing formula of co-toxicity coefficient is as follows:
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) × 100
The percentage composition of B in percentage composition+B medicament ATI × mixture of A in theoretical toxicity index (TTI)=A medicament ATI × mixture
Co-toxicity coefficient (CTC)=[the theoretical toxicity index of mixture actual measurement toxicity index (ATI)/mixture (TTI)] × 100
When CTC≤80, composition performance is for antagonism, and as 80 < CTC < 120, composition performance is for summation action, and when CTC >=120, composition performance is synergistic effect.
Result of the test: afidopyropen and the pyridine of piperazine worm, afidopyropen and cycloxaprid, afidopyropen and epoxy insect quinoline, the composite rear joint toxicity measuring to Brown Planthopper the results are shown in Table 1-3 respectively.
Table 1afidopyropen and piperazine worm pyridine different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| afidopyropen | 0.24 | 100.00 | ? | ? |
| The pyridine of piperazine worm | 0.87 | 27.59 | ? | ? |
| Afidopyropen80: piperazine worm pyridine 1 | 0.19 | 126.32 | 99.11 | 127.46 |
| Afidopyropen40: piperazine worm pyridine 1 | 0.11 | 218.18 | 98.23 | 222.10 |
| Afidopyropen20: piperazine worm pyridine 1 | 0.13 | 184.62 | 96.55 | 191.21 |
| Afidopyropen10: piperazine worm pyridine 1 | 0.10 | 240.00 | 93.42 | 256.91 |
| Afidopyropen5: piperazine worm pyridine 1 | 0.12 | 200.00 | 87.93 | 227.45 |
| Afidopyropen1: piperazine worm pyridine 1 | 0.20 | 120.00 | 63.79 | 188.11 |
| Afidopyropen1: piperazine worm pyridine 5 | 0.28 | 85.71 | 39.66 | 216.15 |
| Afidopyropen1: piperazine worm pyridine 10 | 0.34 | 70.59 | 34.17 | 206.58 |
| Afidopyropen1: piperazine worm pyridine 20 | 0.39 | 61.54 | 31.03 | 198.29 |
| Afidopyropen1: piperazine worm pyridine 40 | 0.43 | 55.81 | 29.35 | 190.15 |
| Afidopyropen1: piperazine worm pyridine 80 | 0.68 | 35.29 | 28.48 | 123.93 |
The result of table 1 co-toxicity test shows, afidopyropen and the pyridine of piperazine worm composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 2afidopyropen and cycloxaprid different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| afidopyropen | 0.27 | 100.00 | ? | ? |
| Cycloxaprid | 1.23 | 21.95 | ? | ? |
| Afidopyropen80: cycloxaprid 1 | 0.20 | 135.00 | 99.04 | 136.31 |
| Afidopyropen40: cycloxaprid 1 | 0.14 | 192.86 | 98.10 | 196.60 |
| Afidopyropen20: cycloxaprid 1 | 0.15 | 180.00 | 96.28 | 186.95 |
| Afidopyropen10: cycloxaprid 1 | 0.13 | 207.69 | 92.90 | 223.55 |
| Afidopyropen5: cycloxaprid 1 | 0.16 | 168.75 | 86.99 | 193.98 |
| Afidopyropen1: cycloxaprid 1 | 0.22 | 122.73 | 60.98 | 201.27 |
| Afidopyropen1: cycloxaprid 5 | 0.41 | 65.85 | 34.96 | 188.37 |
| Afidopyropen1: cycloxaprid 10 | 0.49 | 55.10 | 29.05 | 189.70 |
| Afidopyropen1: cycloxaprid 20 | 0.53 | 50.94 | 25.67 | 198.47 |
| Afidopyropen1: cycloxaprid 40 | 0.47 | 57.45 | 23.85 | 240.82 |
| Afidopyropen1: cycloxaprid 80 | 0.91 | 29.67 | 22.91 | 129.48 |
The result of table 2 co-toxicity test shows, afidopyropen and cycloxaprid composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 3afidopyropen and epoxy insect quinoline different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| afidopyropen | 0.21 | 100.00 | ? | ? |
| Epoxy insect quinoline | 2.69 | 7.81 | ? | ? |
| Afi dopyropen80: epoxy insect quinoline 1 | 0.15 | 140.00 | 98.86 | 141.61 |
| Afidopyropen40: epoxy insect quinoline 1 | 0.11 | 190.91 | 97.75 | 195.30 |
| Afidopyropen20: epoxy insect quinoline 1 | 0.12 | 175.00 | 95.61 | 183.04 |
| Afidopyropen10: epoxy insect quinoline 1 | 0.08 | 262.50 | 91.62 | 286.51 |
| Afidopyropen5: epoxy insect quinoline 1 | 0.13 | 161.54 | 84.63 | 190.87 |
| Afidopyropen1: epoxy insect quinoline 1 | 0.17 | 123.53 | 53.90 | 229.17 |
| Afidopyropen1: epoxy insect quinoline 5 | 0.42 | 50.00 | 23.17 | 215.78 |
| Afidopyropen1: epoxy insect quinoline 10 | 0.65 | 32.31 | 16.19 | 199.58 |
| Afi dopyropen1: epoxy insect quinoline 20 | 0.91 | 23.08 | 12.20 | 189.20 |
| Afidopyropen1: epoxy insect quinoline 40 | 1.05 | 20.00 | 10.06 | 198.90 |
| Afidopyropen1: epoxy insect quinoline 80 | 1.69 | 12.43 | 8.94 | 138.92 |
The result of table 3 co-toxicity test shows, afidopyropen and epoxy insect quinoline composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Two) field medicine effect test example
1, the control efficiency to Brown Planthopper
Tested in August, 2013 and carry out at Wugang City of Hunan Province one paddy field, test adopts knapsack sprayer to carry out the method for full field even spraying, the paddy rice growth of choosing is basically identical, be in tillering stage, that a situation arises is basically identical for plant hopper, investigation insect population radix before medicine, and 1d, 7d, 15d check the borer population of living after medicine.From table 4, data can draw, the composite rear various formulation synergistic effects of afidopyropen and the pyridine of piperazine worm or cycloxaprid or epoxy insect quinoline are obvious; 1d after dispenser, 7d and 15d, each compound drug to the control efficiency of brown planthopper also significantly better than single dose.
Table 4 is prevented and treated the field control effect of Brown Planthopper
| Medicament | Using dosage (g or | 1d preventive effect % | 7d preventive effect % | 15d preventive effect % |
| ? | mL/667m 2) | ? | ? | ? |
| 10%afidopyropen suspending agent | 15mL | 75.89 | 87.53 | 70.24 |
| 25% cycloxaprid wettable powder | 15g | 73.87 | 80.21 | 61.52 |
| 10% epoxy insect quinoline wetting powder | 30g | 70.57 | 79.54 | 67.94 |
| 10% piperazine worm pyridine suspending agent | 30g | 69.38 | 78.39 | 60.35 |
| Embodiment 1 | 15mL | 70.94 | 91.28 | 80.47 |
| Embodiment 2 | 10g | 75.69 | 99.87 | 87.54 |
| Embodiment 3 | 10g | 71.28 | 97.64 | 81.56 |
| Embodiment 4 | 15mL | 68.34 | 90.17 | 78.69 |
| Embodiment 5 | 15mL | 65.79 | 90.48 | 82.47 |
| Embodiment 6 | 15mL | 76.98 | 98.65 | 79.24 |
| Embodiment 7 | 15g | 72.15 | 95.36 | 74.58 |
| Embodiment 8 | 60mL | 73.56 | 96.87 | 80.51 |
| Embodiment 9 | 15g | 67.58 | 90.45 | 70.26 |
| CK | Clear water | / | / | / |
2, the control efficiency to capsicum Frankliniella occidentalis
Tested in April, 2013 and carry out in Li Nong food market, Huidong County of Guangdong Province, test adopts knapsack sprayer to carry out the method for full field even spraying, the experimental field capsicum of choosing is in the Sheng phase of yielding positive results, plant strain growth is basically identical, Frankliniella occidentalis occurs heavier, and it is basically identical to distribute, investigation insect population radix before medicine, and 1d, 3d, 7d check the borer population of living after medicine.From table 5, data can draw, the composite rear various formulation synergistic effects of afidopyropen and the pyridine of piperazine worm or cycloxaprid or epoxy insect quinoline are obvious; 1d after dispenser, 3d and 7d, each compound drug to the control efficiency of Frankliniella occidentalis also significantly better than single dose.
Table 5 is prevented and treated the field control effect of capsicum Frankliniella occidentalis
From afidopyropen and the pyridine of piperazine worm or cycloxaprid or the composite field efficacy to Brown Planthopper, capsicum Frankliniella occidentalis of epoxy insect quinoline, each compound drug control efficiency, significantly better than single dose, illustrates the composite synergistic effect that has; Lasting period extends, and can reduce dosage and spraying times, delays pest resistance to insecticide and produces, and can reduce cost accounting simultaneously.
These are only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (7)
1. a Pesticidal combination, is characterized in that: the active ingredient of said composition is made up of two kinds of A and B, and active ingredient A is afidopyropen, and active ingredient B is selected from any one in the pyridine of piperazine worm, epoxy insect quinoline, cycloxaprid; Wherein the mass ratio of active ingredient A and active ingredient B is 80: 1～1: 80.
2. Pesticidal combination according to claim 1, is characterized in that, the mass ratio of described active ingredient A and active ingredient B is 40: 1～1: 40.
3. Pesticidal combination according to claim 1 and 2, is characterized in that the active ingredient of said composition and auxiliary composition are mixed with the preparation that is applicable to agricultural use.
4. Pesticidal combination according to claim 3, is characterized in that, the preparation of described applicable agricultural use is granule, microcapsule suspending agent, microemulsion, aqueous emulsion, suspending agent, wetting powder, water dispersible granules, ultra low volume liquids.
5. Pesticidal combination according to claim 4, is characterized in that, active ingredient A and the active ingredient B gross mass percentage composition in each preparation is 0.5%～85%.
6. described in claim 1 to 5, Pesticidal combination is used for preventing and treating the application of paddy rice, fruit tree, vegetable crop sucking pest aspect.
7. the application of Pesticidal combination according to claim 6, is characterized in that, described sucking pest is plant hopper, thrips.
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