CN103805294A - High-energy and environment-friendly renewable clean fuel and preparation method thereof - Google Patents
High-energy and environment-friendly renewable clean fuel and preparation method thereof Download PDFInfo
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- CN103805294A CN103805294A CN201210454714.0A CN201210454714A CN103805294A CN 103805294 A CN103805294 A CN 103805294A CN 201210454714 A CN201210454714 A CN 201210454714A CN 103805294 A CN103805294 A CN 103805294A
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Abstract
The invention discloses high-energy and environment-friendly renewable clean fuel and a preparation method thereof, and belongs to the technical field of a new energy source fuel. The high-energy and environment-friendly renewable clean fuel is prepared from the following raw materials by mass percent: 65.43% of methanol, 30.5% of auxiliary material, 3.3% of denaturing agent, 0.57% of dissolving-assisting and pungent-increasing additive, and 0.2% of dispersant. The high-energy and environment-friendly renewable clean fuel produced by the method disclosed by the invention has the significant progresses that 1, the traditional fuel can be fully and comprehensively replaced, and the realistic problem of crisis of global energy can be solved; 2, the high-energy and environment-friendly renewable clean fuel is wide in raw material range, and free of emission of three wastes in the production process; 2, the high-energy and environment-friendly renewable clean fuel is broad in applicable range, and the operating requirements of kinds of fields such as industries and the like can be met; 4, the consumption is lower than that of the traditional fuel under the same condition, the environmental index is that over 80% of emission is reduced in comparison with the traditional fuel, and energy conservation and emission reduction are really achieved; 5, the high-energy and environment-friendly renewable clean fuel is high in cost performance, and the price of the product does not change along with fluctuation of the international crude oil price, and is stable; and 6, the high-energy and environment-friendly renewable clean fuel is high in safety performance.
Description
Technical field
The present invention relates to new forms of energy fuel technology field, specifically, relate to a kind of high-capacity environment-protecting regenerated clean fuel and preparation method thereof.
Background technology
In recent years, once support 20th century human civilization high speed developments, occurred unprecedented crisis take oil, coal and Sweet natural gas as main fossil energy.Traditional fossil fuel belongs to the one-time consumption energy, is Nonrenewable resources, and its storage capacity is in continuous minimizing.Along with petering out of fossil energy, it is more expensive that its price also can become gradually, can not meet the normal Sustainable development of the mankind.More seriously, scientific research discovery, the carbon dioxide that fossil energy produces afterwards in use is discharged in atmosphere, produce Greenhouse effect, cause artificially Global warming, have a strong impact on human lives, caused extensive concern and the thinking of people to Future Social Development power resources.
Now, the energy strategy of many countries has an obvious policy guidance---encourages to tap a new source of energy, this is the high due to pressure of traditional energy product price (except the eventuality) such as oil on world market, is also the desirability of human kind sustainable development.Therefore, new energy development likely becomes following most important Economic Growth Engine, becomes the new economic pillar that has creativity and wealth ability most.
At present, the amount of funds surge of new forms of energy is invested in the whole world.There is a kind of common recognition just worldwide to form: only in new energy technology revolution, to go before, just likely in following economic pattern, occupy superiority.Especially be subject to the impact of financial crisis; global economy presents under the background of the serious situation of keeping falling; there is expert to think to the development and utilization of new forms of energy the new round hot spot for competition that is world economy after global financial crisis; the development of the improvement to traditional energy and new energy technology and product; will expedite the emergence of a huge market, New Energy Industry will become the individual important breakthrough mouth that has that countries in the world tap new sources of economic growth.
In addition, along with social progress and economic fast development, the continuous propelling of industrialization, urbanization process, resource environment problem manifests day by day on the impact that promotes people's life and social economy and increase.Research and development utilize resource environment, have now become current the focus of world attention for improving environment for human survival.China is maximum in the world developing country, and populous, large to the demand of the energy, it is particularly outstanding that resource environment problem seems.
Find from consulted correlation technique data, mostly adopt physical combination both at home and abroad at present in the exploitation of regeneration clean energy technology, fail all the time to break through qualitative change, thereby reach, to meet the use of every profession and trade required.In earlier stage, domestic initiation existing two more than ten years history the new forms of energy take alcohol radical as representative, because of its calorific value with temperature is low can not meet conventional required grade for the self-defect that uses, fail so far popularize and do not accepted by market.And the germ theory that the relevant expert in countries in the world proposes in new forms of energy (be still at present theory seek in), but also come out without any pilot sample so far.In addition, on market, also there is mixing a certain proportion of diesel oil with the product of alcohol oil name in methyl alcohol, ethanol, still do not had yet the breakthrough of matter, can not expand equally use range, can not meet every profession and trade demand.
Summary of the invention
One of object of the present invention is to provide a kind of high-capacity environment-protecting regenerated clean fuel.
For addressing the above problem, the technical solution adopted in the present invention is:
A kind of high-capacity environment-protecting regenerated clean fuel, is characterized in that: be made up of following raw material and formula: methyl alcohol 65.43%, auxiliary material 30.5%, denaturing agent 3.3%, hydrotropy increase pungent auxiliary agent 0.57%, dispersion agent 0.2%;
Described auxiliary material adopts vegetables oil, methyl alcohol, catalyzer formulated according to weight ratio 81.4: 15.2: 1.1; Described denaturing agent adopts cerous nitrate, methyl phosphamide formulated according to the ratio of 1: 3; Described hydrotropy increases pungent auxiliary agent and adopts isopropylcarbinol formulated according to the ratio of 1: 4 in, benzene; Described dispersion agent adopts iron pentacarbonyl, carbonyl hydrochlorate, SODIUM PHOSPHATE, MONOBASIC formulated according to the ratio of 1: 2.3: 3.
Described catalyzer adopts iron trichloride, potassium hydroxide formulated according to the ratio of 1: 1.32.
The concentration of described methyl alcohol is less than 75%.
Another object of the present invention is to provide the preparation method of above-mentioned a kind of high-capacity environment-protecting regenerated clean fuel, comprises the steps:
1, adopt vegetables oil, methyl alcohol and catalyzer according to 81.4: 15.2: 1.1 preparation auxiliary materials of weight ratio, vegetables oil, methyl alcohol and catalyzer are put into constant temperature still and stir three hours, temperature is controlled at 69 ℃-87 ℃, and pH value is controlled between 6-8;
Adopt cerous nitrate, methyl phosphamide, according to the ratio preparation denaturing agent of 1: 3;
Employing isopropylcarbinol is pressed, benzene, increases pungent auxiliary agent according to the ratio preparation hydrotropy of 1: 4;
Adopt iron pentacarbonyl, carbonyl hydrochlorate and SODIUM PHOSPHATE, MONOBASIC, according to the ratio preparation dispersion agent of 1: 2.3: 3;
2, the formula that increases pungent auxiliary agent 0.57%, dispersion agent 0.2% according to methyl alcohol 65.43%, auxiliary material 30.5%, denaturing agent 3.3%, hydrotropy has weighed various raw material for standby;
3, first load weighted step 2 methyl alcohol is injected to reactor, then add load weighted denaturing agent in reactor, stir after 10 minutes, leave standstill 10 minutes; Again load weighted auxiliary material is added in reactor, stir 20 minutes; Again load weighted hydrotropy is increased to pungent auxiliary agent and add in reactor, stir 15 minutes; Finally, load weighted dispersion agent is joined in reactor, stir after 30 minutes, leave standstill 35 minutes, make high-capacity environment-protecting regenerated clean fuel finished product.
Catalyzer described in step 1 adopts iron trichloride, potassium hydroxide formulated according to the ratio of 1: 1.32;
The concentration of methyl alcohol described in step 2 is less than 75%.
Compared with prior art, the high-capacity environment-protecting regenerated clean fuel that adopts formula of the present invention and method to produce, has following significant progress: 1, can substitute traditional fuel fully, all sidedly, can solve the realistic problem of global energy anxiety; 2, raw material drawing scope is wide, production process three-waste free discharge; 3, the scope of application is very extensive, can meet industrial each field service requirements, has broken through the bottleneck that in the past can be directly used in the fields such as Industrial Boiler, smelting furnace, forging, baking without any new forms of energy; 4, under equal conditions consumption is lower than traditional fuel, and environmental protection index reduces discharge more than 80% than traditional fuel, really realizes energy-saving and emission-reduction, effectively improves people's living environment, improves people's quality of life; 5, have high performance-price ratio, product price does not change with the fluctuation of International Crude Oil, price steadiness; 6, safety performance is high, as accidental ignition, meets water and produces fire-retardant integument at its table, plays fire extinguishing function.
Below in conjunction with embodiment, the present invention will be further described.
Embodiment
High-capacity environment-protecting regenerated clean fuel of the present invention, is made up of following raw material and formula: concentration is less than 75% methyl alcohol 65.43%, auxiliary material 30.5%, denaturing agent 3.3%, hydrotropy and increases pungent auxiliary agent 0.57%, dispersion agent 0.2%.
Described auxiliary material adopts vegetables oil, methyl alcohol, catalyzer formulated according to weight ratio 81.4: 15.2: 1.1, and described catalyzer adopts iron trichloride, potassium hydroxide formulated according to the ratio of 1: 1.32.
Described denaturing agent adopts cerous nitrate, methyl phosphamide formulated according to the ratio of 1: 3.
Described hydrotropy increases pungent auxiliary agent and adopts isopropylcarbinol formulated according to the ratio of 1: 4 in, benzene.
Described dispersion agent adopts iron pentacarbonyl, carbonyl hydrochlorate, SODIUM PHOSPHATE, MONOBASIC formulated according to the ratio of 1: 2.3: 3.
The preparation method of high-capacity environment-protecting regenerated clean fuel of the present invention, comprises the steps:
1, adopt vegetables oil, methyl alcohol and catalyzer according to 81.4: 15.2: 1.1 preparation auxiliary materials of weight ratio, vegetables oil, methyl alcohol and catalyzer are put into constant temperature still and stir three hours, temperature is controlled at 69 ℃-87 ℃, and pH value is controlled between 6-8; Described catalyzer employing iron trichloride, potassium hydroxide are formulated according to the ratio of 1: 1.32;
Adopt cerous nitrate, methyl phosphamide, according to the ratio preparation denaturing agent of 1: 3;
Employing isopropylcarbinol is pressed, benzene, increases pungent auxiliary agent according to the ratio preparation hydrotropy of 1: 4;
Adopt iron pentacarbonyl, carbonyl hydrochlorate and SODIUM PHOSPHATE, MONOBASIC, according to the ratio preparation dispersion agent of 1: 2.3: 3;
2, the formula that increases pungent auxiliary agent 0.57%, dispersion agent 0.2% according to methyl alcohol 65.43%, auxiliary material 30.5%, denaturing agent 3.3%, hydrotropy has weighed various raw material for standby; The concentration of described methyl alcohol is less than 75%.
3, first load weighted step 2 methyl alcohol is injected to reactor, then add load weighted denaturing agent in reactor, stir after 10 minutes, leave standstill 10 minutes; Again load weighted auxiliary material is added in reactor, stir 20 minutes; Again load weighted hydrotropy is increased to pungent auxiliary agent and add in reactor, stir 15 minutes; Finally, load weighted dispersion agent is joined in reactor, stir after 30 minutes, leave standstill 35 minutes, make high-capacity environment-protecting regenerated clean fuel finished product.
Claims (6)
1. a high-capacity environment-protecting regenerated clean fuel, is characterized in that: be made up of following raw material and formula: methyl alcohol 65.43%, auxiliary material 30.5%, denaturing agent 3.3%, hydrotropy increase pungent auxiliary agent 0.57%, dispersion agent 0.2%;
Described auxiliary material adopts vegetables oil, methyl alcohol, catalyzer formulated according to weight ratio 81.4: 15.2: 1.1; Described denaturing agent adopts cerous nitrate, methyl phosphamide formulated according to the ratio of 1: 3; Described hydrotropy increases pungent auxiliary agent and adopts isopropylcarbinol formulated according to the ratio of 1: 4 in, benzene; Described dispersion agent adopts iron pentacarbonyl, carbonyl hydrochlorate, SODIUM PHOSPHATE, MONOBASIC formulated according to the ratio of 1: 2.3: 3.
2. high-capacity environment-protecting regenerated clean fuel as claimed in claim 1, is characterized in that: described catalyzer adopts iron trichloride, potassium hydroxide formulated according to the ratio of 1: 1.32.
3. high-capacity environment-protecting regenerated clean fuel as claimed in claim 1, is characterized in that: the concentration of described methyl alcohol is less than 75%.
4. the preparation method of high-capacity environment-protecting regenerated clean fuel as claimed in claim 1, is characterized in that: comprise the steps:
(1) adopt vegetables oil, methyl alcohol and catalyzer according to 81.4: 15.2: 1.1 preparation auxiliary materials of weight ratio, vegetables oil, methyl alcohol and catalyzer are put into constant temperature still and stir three hours, temperature is controlled at 69 ℃-87 ℃, and pH value is controlled between 6-8;
Adopt cerous nitrate, methyl phosphamide, according to the ratio preparation denaturing agent of 1: 3;
Employing isopropylcarbinol is pressed, benzene, increases pungent auxiliary agent according to the ratio preparation hydrotropy of 1: 4;
Adopt iron pentacarbonyl, carbonyl hydrochlorate and SODIUM PHOSPHATE, MONOBASIC, according to the ratio preparation dispersion agent of 1: 2.3: 3;
(2) formula that increases pungent auxiliary agent 0.57%, dispersion agent 0.2% according to methyl alcohol 65.43%, auxiliary material 30.5%, denaturing agent 3.3%, hydrotropy has weighed various raw material for standby;
(3) first load weighted step (2) methyl alcohol is injected to reactor, then add load weighted denaturing agent in reactor, stir after 10 minutes, leave standstill 10 minutes; Again load weighted auxiliary material is added in reactor, stir 20 minutes; Again load weighted hydrotropy is increased to pungent auxiliary agent and add in reactor, stir 15 minutes; Finally, load weighted dispersion agent is joined in reactor, stir after 30 minutes, leave standstill 35 minutes, make high-capacity environment-protecting regenerated clean fuel finished product.
5. the preparation method of high-capacity environment-protecting regenerated clean fuel according to claim 4, is characterized in that: the catalyzer described in step (1) adopts iron trichloride, potassium hydroxide formulated according to the ratio of 1: 1.32.
6. the preparation method of high-capacity environment-protecting regenerated clean fuel according to claim 4, is characterized in that: described in step (2), the concentration of methyl alcohol is less than 75%.
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| CN201210454714.0A CN103805294B (en) | 2012-11-06 | 2012-11-06 | A kind of high-capacity environment-protecting regenerated clean fuel and preparation method thereof |
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| CN201210454714.0A CN103805294B (en) | 2012-11-06 | 2012-11-06 | A kind of high-capacity environment-protecting regenerated clean fuel and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109929599A (en) * | 2019-04-15 | 2019-06-25 | 长沙而道新能源科技有限公司 | A kind of environment friendly biological new energy fuel and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1364856A (en) * | 2001-11-30 | 2002-08-21 | 向胜树 | Methanol gasoline for vehicle |
| CN101045887A (en) * | 2006-03-30 | 2007-10-03 | 阚立健 | Synthesized clean gasoline |
| JP2008031257A (en) * | 2006-07-27 | 2008-02-14 | Asahi Kasei Corp | Method for producing diesel engine fuel |
| KR20100136874A (en) * | 2009-06-19 | 2010-12-29 | 박해영 | Energy efficiency and energy-saving micro-emulsified biological petrol and diesel oil mixed fuel and additive with seawater, and animal and plant oil and ethanol |
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2012
- 2012-11-06 CN CN201210454714.0A patent/CN103805294B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1364856A (en) * | 2001-11-30 | 2002-08-21 | 向胜树 | Methanol gasoline for vehicle |
| CN101045887A (en) * | 2006-03-30 | 2007-10-03 | 阚立健 | Synthesized clean gasoline |
| JP2008031257A (en) * | 2006-07-27 | 2008-02-14 | Asahi Kasei Corp | Method for producing diesel engine fuel |
| KR20100136874A (en) * | 2009-06-19 | 2010-12-29 | 박해영 | Energy efficiency and energy-saving micro-emulsified biological petrol and diesel oil mixed fuel and additive with seawater, and animal and plant oil and ethanol |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109929599A (en) * | 2019-04-15 | 2019-06-25 | 长沙而道新能源科技有限公司 | A kind of environment friendly biological new energy fuel and preparation method thereof |
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