CN103774423B - A kind of fishing rod manufacture modified carbon fiber - Google Patents
A kind of fishing rod manufacture modified carbon fiber Download PDFInfo
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- CN103774423B CN103774423B CN201410011158.9A CN201410011158A CN103774423B CN 103774423 B CN103774423 B CN 103774423B CN 201410011158 A CN201410011158 A CN 201410011158A CN 103774423 B CN103774423 B CN 103774423B
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Abstract
The invention discloses a kind of fishing rod manufacture modified carbon fiber, the preparation method of described modified carbon fiber is: immersed by carbon fiber in carbon fiber surface modifier and take out after 1-2 hour, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 80-90 DEG C of baking oven 20-22h, take out, cooling, to obtain final product; Obtaining by after the raw material blending of following weight parts of carbon fiber surface modifier: ethylhexyl dihydrogen phosphate 4-5, glycidyl methacrylate 1-2, two ten four carbon alcohols ester 2-3, acetyl triethyl citrate 8-10, crosslinking agent? TAC? 1-2, auxiliary agent 4-5.
Description
Technical field
The present invention relates to fishing tackle field, is exactly a kind of fishing rod manufacture modified carbon fiber.
Background technology
Carbon fiber (carbonfiber), as the term suggests it not only has the intrinsic intrinsic property of material with carbon element, having again the soft machinability of textile fabric concurrently, is fortifying fibre of new generation.Compared with traditional glass fibre (GF), Young's modulus is that they are more than 3 times; It is compared with Kafra fiber (KF-49), and not only Young's modulus is its about 2 times, and insoluble not swollen in organic solvent, acid, alkali, and corrosion resistance is transcendent.Have scholar to be immersed in highly basic NaOH solution in 1981 by PAN base CF, time-out goes more than 30 year, and it still keeps fibre morphology so far.
The manufacturing technique of the fine pole of carbon is the same with glass pole, all impregnated fabric is cut into narrow trapezoidal of a head breadth one to twist on conical punching block core, then rolled tightly from the beginning to the end with clear glass band curl, be placed on again in electric furnace and glue is dried, take out from stove again and horizontal core is exited, remove the glass tape on pole body, through repair, polish, draw paint, assembling after fishing pole.Because the cloth of firm dipped glue is soft, glass tape is rolled up again very tight, pole body is strangled into rugged helical form, instead of carbon fiber cloth or glass-fiber-fabric spirality are rolled into.
Summary of the invention
The object of the present invention is to provide a kind of fishing rod manufacture modified carbon fiber
Above-mentioned purpose is realized by following scheme:
A kind of fishing rod manufacture modified carbon fiber, it is characterized in that: the preparation method of described modified carbon fiber is: carbon fiber is immersed in carbon fiber surface modifier and take out after 1-2 hour, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 80-90 DEG C of baking oven 20-22h, take out, cooling, to obtain final product; Obtaining by after the raw material blending of following weight parts of carbon fiber surface modifier:
Ethylhexyl dihydrogen phosphate 4-5, glycidyl methacrylate 1-2, two ten four carbon alcohols ester 2-3, acetyl triethyl citrate 8-10, crosslinking agent TAC1-2, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: nano-sized carbon 1-2, sldium lauryl sulfate 0.1-0.2, chlorinated paraffin wax 0.2-0.4, methyl-silicone oil 4-5, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2, crosslinking agent TAC1-2, sodium peroxydisulfate 1-2.
Described a kind of fishing rod manufacture modified carbon fiber, is characterized in that: the preparation method of auxiliary agent is by after each raw material blending, under 300-500rpm, after stirring 10-20 minute, to obtain final product at 25-35 DEG C.
Beneficial effect of the present invention is: the carbon fiber modifying method of this method is simple, environmental friendliness.
Detailed description of the invention
A kind of fishing rod manufacture modified carbon fiber, the preparation method of described modified carbon fiber is: immersed by carbon fiber in carbon fiber surface modifier and take out after 1.5 hours, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 90 DEG C of baking oven 20h, take out, cooling, to obtain final product;
Obtaining by after the raw material blending of following weight (kg) of carbon fiber surface modifier:
Ethylhexyl dihydrogen phosphate 5, glycidyl methacrylate 2, two ten four carbon alcohols esters 3, acetyl triethyl citrate 10, crosslinking agent TAC1, auxiliary agent 5;
Auxiliary agent is made up of the raw material of following weight (kg): nano-sized carbon 2, sldium lauryl sulfate 0.2, chlorinated paraffin wax 0.4, methyl-silicone oil 4, ethoxylated dodecyl alcohol 2, potassium permanganate 0.2, crosslinking agent TAC2, sodium peroxydisulfate 1.
Described a kind of fishing rod manufacture modified carbon fiber, the preparation method of auxiliary agent is by after each raw material blending, under 400rpm, stirs after 15 minutes, to obtain final product at 28 DEG C.
The preparation method of fishing rod is:
(1) will the obtained carbon fibre initial rinse fabric of modified carbon fiber be utilized to have cut for subsequent use;
(2) the punching block core brushing mould release toasted after 20 minutes at 65 DEG C, was wound around thereon by the carbon fibre initial rinse fabric cut;
(3) rolled tightly with opp film outside, post-drying, punching block core exits again, and removes the opp film on pole body, after repairing, polish, draw paint, assembling, namely obtain fishing rod.
Prepare the fishing rod of total length 5.3m, test.1000,1500, the weight of 2000g act on the point of fishing rod respectively state under fishing rod is placed in the horizontal plane, thereafter, be center of rotation with fishing rod afterbody the point front end of fishing rod is lifted gradually obliquely from horizontal plane, then, the angle between horizontal plane when weight leaves horizontal plane and fishing rod afterbody is measured.1. described sample is the present embodiment, and 2. described sample is general common carbon fibers fishing rod, and its result as shown in table 1 below.
Table 1
As shown in table 1 with sample 2. compared with, the raising of the present embodiment sample 1. bendability can be found out especially under each different loads.
Claims (2)
1. a fishing rod manufacture modified carbon fiber, it is characterized in that: the preparation method of described modified carbon fiber is: carbon fiber is immersed in carbon fiber surface modifier and take out after 1-2 hour, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 80-90 DEG C of baking oven 20-22h, take out, cooling, to obtain final product; Carbon fiber surface modifier is by obtained after the raw material blending of following weight parts: ethylhexyl dihydrogen phosphate 4-5, glycidyl methacrylate 1-2, two ten four carbon alcohols ester 2-3, acetyl triethyl citrate 8-10, crosslinking agent TAC1-2, auxiliary agent 4-5; Auxiliary agent is made up of the raw material of following weight portion: nano-sized carbon 1-2, sldium lauryl sulfate 0.1-0.2, chlorinated paraffin wax 0.2-0.4, methyl-silicone oil 4-5, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2, crosslinking agent TAC1-2, sodium peroxydisulfate 1-2.
2. a kind of fishing rod manufacture modified carbon fiber according to claim 1, is characterized in that: the preparation method of auxiliary agent is by after each raw material blending, under 300-500rpm, after stirring 10-20 minute, to obtain final product at 25-35 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011158.9A CN103774423B (en) | 2014-01-09 | 2014-01-09 | A kind of fishing rod manufacture modified carbon fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011158.9A CN103774423B (en) | 2014-01-09 | 2014-01-09 | A kind of fishing rod manufacture modified carbon fiber |
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| Publication Number | Publication Date |
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| CN103774423A CN103774423A (en) | 2014-05-07 |
| CN103774423B true CN103774423B (en) | 2015-11-18 |
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| CN201410011158.9A Active CN103774423B (en) | 2014-01-09 | 2014-01-09 | A kind of fishing rod manufacture modified carbon fiber |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106267362A (en) * | 2016-08-31 | 2017-01-04 | 阮丽丽 | A kind of bionical medical composite material and application thereof |
| CN109853234B (en) * | 2019-03-12 | 2022-01-04 | 深圳华力兴新材料股份有限公司 | Method for improving insulating property of carbon fiber, modified carbon fiber and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103451931A (en) * | 2012-06-04 | 2013-12-18 | 金发科技股份有限公司 | Carbon fiber surface modifier, modified carbon fiber, composite material, and preparation methods thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3232169B2 (en) * | 1993-07-12 | 2001-11-26 | 三菱レイヨン株式会社 | Surface modification method for carbon fiber |
| JP4426772B2 (en) * | 2003-04-16 | 2010-03-03 | 三菱レイヨン株式会社 | Carbon fiber manufacturing method |
| JP2005226193A (en) * | 2004-02-13 | 2005-08-25 | Mitsubishi Rayon Co Ltd | Sizing agent for reinforcing fiber, carbon fiber bundle, thermoplastic resin composition and molded product thereof |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103451931A (en) * | 2012-06-04 | 2013-12-18 | 金发科技股份有限公司 | Carbon fiber surface modifier, modified carbon fiber, composite material, and preparation methods thereof |
Non-Patent Citations (1)
| Title |
|---|
| 不同方法表面改性碳纤维对复合摩擦材料性能的影响;李张义等;《润滑与密封》;20130430;第38卷(第4期);第68-71页 * |
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Address after: 242100 Langxi City, Anhui Province Town Development Zone Patentee after: ANHUI GUANTING TECHNOLOGY CO., LTD. Address before: 242100 Langxi City, Anhui Province Town Development Zone Patentee before: LANGXI PROTIME FISHING GEAR MANUFACTURING CO., LTD. |
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Effective date of registration: 20210510 Address after: 214000 Industrial Park, Yangjian Town, Xishan District, Wuxi City, Jiangsu Province Patentee after: Wuxi Xidong New Rural Investment Development Co.,Ltd. Address before: 242100 Cross Town Development Zone, Langxi County, Xuancheng City, Anhui Province Patentee before: ANHUI GUANTING TECHNOLOGY Co.,Ltd. |
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