CN1037743A - Technique of silico-manganese steel enamel - Google Patents
Technique of silico-manganese steel enamel Download PDFInfo
- Publication number
- CN1037743A CN1037743A CN88103025A CN88103025A CN1037743A CN 1037743 A CN1037743 A CN 1037743A CN 88103025 A CN88103025 A CN 88103025A CN 88103025 A CN88103025 A CN 88103025A CN 1037743 A CN1037743 A CN 1037743A
- Authority
- CN
- China
- Prior art keywords
- coat
- enamel
- ground
- coat enamel
- blank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of can be used for the silicon manganese steel is the enamel manufacturing process of blank.New ground-coat enamel and cover-coat enamel prescription have been adopted in the technology; The vertical flow coat of dipping or cast is warded off method; And adopt shredder that the porcelain facing after burning till is ground, burnt till again at last.The enamel product that adopts the present invention to produce has good resistance to acids and bases and wear resistance and higher precision, good adherence is arranged between enamel and the steel billet, but widespread use is the various industrial enamels of product with silicon manganese steel and soft steel.
Description
The present invention relates to the prescription of enamelled manufacturing process and enamel.
Existing enamel manufacturing process and enamel only are applicable to soft steel to be the enamel blank.But the intensity of these steel is relatively poor usually, and in many industrial products, the silicon manganese steel that the normal intensity of using is higher and the adhesion property of existing enamel are very poor.For the blank of tubulose or column, bad with existing dipping enamelling method application of slip effect, tend to occur the uppity phenomenon of uneven distribution or thickness, and when blank is heavier, also can't operate.And these products are generally to adherence, wear resistance, erosion resistance and having relatively high expectations of degree of making and precision slightly, so it is the qualified enamelware of blank that prior art can not be made with the silicon manganese steel.
Purpose of the present invention, be to adopt a kind of new enamel manufacturing process and enamel prescription, enamel is not only had with the soft steel blank also have the adherence good, and make the enamel product have well acidproof, alkali resistance, wear resistance and slightly degree of making and precision with the silicon manganese steel blank.
Specific embodiment of the present invention is:
The first, the silicon manganese steel blank of selecting for use is warded off pre-treatment.
Purpose by this process is the machining stress that will remove the greasy dirt on blank surface, zone of oxidation and elimination blank.
The second, the flow coat that hangs down is warded off method or the vertical flow coat of cast is warded off method application of slip ground-coat enamel slurry with flooding, and after the drying, burns till.
The flow coat method of warding off of hanging down dipping all immerses blank in the glaze slip exactly, with anchor clamps blank is vertically proposed, and treats till the glaze slip stop.This method is suitable for the blank of application of slip all styles of, and the outer wall of tubular blank especially should be wiped this part glaze slip off with rubber after the position seals of the application of slip or the application of slip not needing before the application of slip.
The vertical flow coat method of warding off of cast is the inwall that is used for application of slip tubular blank, make blank upright during the application of slip, a spheroid or a piston that has transmission rod is put into blank, mention to slight distance on blank with transmission rod, pour into a certain amount of glaze slip from above, allow spheroid or piston at the uniform velocity glide, glaze slip on the uniform cloth flow to till the stop glaze slip vertically downward in the blank.The elastic sphere that this kind method is adopted or the size of piston are should be in the internal diameter of blank consistent or be close.
The 3rd, ward off method or the cast flow coat that hangs down and ward off method application of slip cover-coat enamel slurry with the dipping flow coat that hangs down, drying, burn till after, repeat again a cover-coat enamel slurry the application of slip, dry, burn till.
Application of slip method in this process is identical with the application of slip method of ground-coat enamel slurry.
The 4th, after the longitude that porcelain facing is ground to drawing regulation with shredder requires, reburn into finished product.
Enamelware after burning till is because the enamel coating surface ratio is more coarse, variable thickness, thereby often do not reach desired precision, with shredder porcelain facing is ground to claimed accuracy after, burn till again, can meet the requirements of precision.
The ground-coat enamel slurry that is adopted in the above-mentioned technology is to introduce the mill addition grinding by the ground-coat enamel frit to form, and the chemical constitution of ground-coat enamel frit (weight %) is:
SiO
2：44.5-58.4，Ai
2O
3：3.5-9.1，
B
2O
3：11.5-19.0，R
2O：16.0-20.4，
R, expression monovalent base metal.
CaF
2：4.5-11.8，Na
2SiF
6：0.5-3.5，
CoO：0.9-2.7，MnO
2：0.8-5.5，
CuO：0.2-2.8，Fe
2O
3：0.3-3.5，
The composition of mill addition (100 parts umber in glaze piece) is: aluminium sesquioxide: 1.0-3.0
Sodium Nitrite: 0-0.2, borax: 0.5-1.1, soda ash: 0.2-0.7,
Ice crystal: 0.1-0.3, clay: 4.5-8.0, silica powder: 15.0-22.0,
Above-mentioned ground-coat enamel frit is to be cooperated by two kinds, three kinds or four kinds of chemical constitutions and the different ground-coat enamel frit of fusing point to form.
Above-mentioned ground-coat enamel frit can be by first kind of ground-coat enamel frit and second kind of ground-coat enamel frit with 70: 30-50: 50 ratio cooperates and forms.
First kind chemical constitution (weight %) is:
SiO
2：49.0-62.0，Ai
2O
3：5.0-10.0，
CaF
2：6.0-13.0，B
2O
3：10.0-16.0，
R
2O：18.0-21.0，Na
2SiF
6：1.0-5.0，
R: expression monovalent base metal.
MnO
2：0.7-5.0，CoO：1.0-3.0;
Second kind chemical constitution (weight %) is:
SiO
2：40.0-50.0，Ai
2O
3：2.0-7.0，
MnO
2：1.0-6.0，B
2O
3：15.0-22.0，
R
2O：14.0-19.0，Fe
2O
3：1.0-7.0，
R: expression monovalent base metal.
CaF
2：3.0-9.0，CuO：0.5-5.5，
CoO：0.8-2.0。
The cover-coat enamel that adopted in above-mentioned technology slurry can be that cover-coat enamel frit by following chemical constitution (weight %) grinds and forms:
SiO
2：62.0-69.0，Ai
2O
3：2.0-5.0，
Na
2O：6.0-11.0，B
2O
3：2.0-6.0，
ZrO
2：0.8-6.0，Na
2SiF
6：1.0-4.0，
TiO
2：5.0-9.0，K
2O：0-3.0，
Li
2O：0.5-5.0，CoO：0.5-2.0，
MnO
2：0.3-1.5，CaO：0-3.0。
The cover-coat enamel that adopted in above-mentioned technology slurry also can be that cover-coat enamel frit by following chemical constitution (weight %) grinds and forms:
SiO
2：63.0-68.0，Ai
2O
3：9.0-13.0，
Na
2O：3.0-8.0，MnO
2：0-3.0，
TiO
2：1.0-6.0，B
2O
3：1.0-5.0，
ZrO
2：0.5-5.5，CaO：1.0-5.0，
K
2O：2.0-7.0，CoO：0.6-2.7，
Li
2O：1.5-6.5，P
2O
5：0-1.5，
Na
2SiF
6：1.0-6.0。
Because the present invention has adopted a kind of new enamel manufacturing process, used in the technology to be adapted at ground-coat enamel and the cover-coat enamel prescription that use on the silicon manganese steel surface, thereby the enamel product of manufacturing has the following advantages:
(1). the adhesion property of enamel and blank is good.
(2). stronger corrosion resistance nature is arranged.In the hydrochloric acid soln of concentration 20%, under 100 ℃ the condition, corroded 4 hours, below the weight loss 0.091mg/cm; In 1% caustic soda soln, under 100 ℃ the condition, corroded weight loss 0.036mg/cm 4 hours
2Below.
(3). hardness height, Mo Shi 7-8.
(4). slightly degree of making is good, Ra:0.40-0.100.
(5). wear resisting property is strong, and wear-resistant index is at 0.040mg/cm
2Below the min.
(6). the precision height guarantees that working accuracy is 0.07-0.14.
It is the various industrial enamels of blank that the present invention can be widely used in soft steel, silicon manganese steel, especially is the industrial enamel of blank with the 27SiMn steel.
Embodiment:
Get the raw material of following composition (weight %): fluorite: 6.66, feldspar: 25.28, SODIUMNITRATE: 6.24, manganese oxide: 1.05, cobalt oxide: 1.05, borax: 25.77, quartz: 22.77, soda ash: 8.91, sodium silicofluoride: 1.59.Behind the accurately also abundant mixing of weighing, add in the smelting furnace, under 1200-1300 ℃ temperature, found into first kind of ground-coat enamel frit.Its chemical constitution (weight %) is:
SiO
2：51.0，Ai
2O
3：6.0，Na
2SiF
6：2.0，CaF
2：7.0，
B
2O
3: 12.0, MnO
2: 1.0, CoO:2.0, R
2O:19.0, R: expression monovalent base metal.
Get the raw material of following composition (weight %): fluorite: 4.40, feldspar: 13.80, SODIUMNITRATE: 5.10, cupric oxide: 1.20, ferric oxide: 1.50, cobalt oxide: 1.50, manganese oxide: 3.90, soda ash: 5.50, borax: 40.30, quartz: 22.80.Behind the accurately also abundant mixing of weighing, add in the smelting furnace, under 1200-1300 ℃ temperature, found into second kind of ground-coat enamel frit.Its chemical constitution (weight %) is:
SiO
2：44.00，Ai
2O
3：3.50，CaF
2：5.00，MnO
2：4.00，
B
2O
3：20.00，Fe
2O
3：2.00，CuO：1.70，CoO：1.80，
R
2O:18.00, R: expression monovalent base metal.
Get first kind of ground-coat enamel frit and second kind of ground-coat enamel frit and cooperate, cooperate the chemical constitution (weight %) of back frit to be with 60: 40 ratio:
SiO
2：48.20，Ai
2O
3：5.00，CoO：1.92，CuO：0.68，
MnO
2：2.20，B
2O
3：15.20，CaF
2：6.20，Fe
2O
3：0.80，
NaSiF
6: 1.20, R
2O:18.60, R: expression monovalent base metal.Introduce mill addition (100 parts umber in glaze piece): Sodium Nitrite: 0.15, aluminium sesquioxide: 3, borax: 0.8, soda ash: 0.3, ice crystal: 0.2, silica powder: 17, clay: 5, water: 45.Make the ground-coat enamel slurry through grinding, its grinding rate is the 0.1-0.3g/140 order, and unit weight is at 420-425g/250ml during use, and the stop degree is at 0.03-0.04g/cm
2
Get the raw material of following composition (weight %): feldspar: 12.69, borax: 9.28, SODIUMNITRATE: 4.13, titanium oxide: 5.88, scandium oxide: 0.83, Quilonum Retard: 7.28, cobalt oxide: 0.93, lime carbonate: 2.27, manganese oxide: 0.52, sodium silicofluoride: 1.27, soda ash: 9.20, quartz: 45.72.Behind the accurately also abundant mixing of weighing, add in the smelting furnace, under 1300-1400 ℃ temperature, found into first kind of cover-coat enamel frit, its chemical constitution (weight %) is: SiO
2: 65.00, Ai
2O
3: 2.86, Li
2O:3.53, CoO:1.00, MnO
2: 0.41, Na
2O:10.27, B
2O
3: 4.07, CaO:1.50, TiO
2: 7.10, K
2O:1.76, ZrO
2: 1.00, Na
2SiF
6: 1.50.
Get the raw material of following composition (weight %): feldspar: 47.07, borax: 7.14, SODIUMNITRATE: 1.57, lime carbonate: 3.19, Quilonum Retard: 8.60, sodium silicofluoride: 1.76, titanium oxide: 1.72, zirconium white: 0.86, cobalt oxide: 1.44, manganese oxide: 1.62, quartz: 25.03.Weighing adds in the smelting furnace after accurately and fully mixing an ancient unit of weight, founds into second kind of cover-coat enamel frit under 1300-1400 ℃ temperature.Its chemical constitution (weight %) is:
SiO
2：64.00，Ai
2O
3：10.00，Na
2O：3.58，MnO
2：1.50，B
2O
3：3.00
Li
2O：4.00，TiO
2：2.00，K
2O：5.42，CoO：1.50，CaO：2.00，ZrO
2：1.00，Na
2SiF
6：2.00。
Get first kind of cover-coat enamel frit (or second kind of cover-coat enamel frit), grind to form the cover-coat enamel slurry, its grinding rate is: the 0.1-0.3g/140 order, and unit weight is at 425-430g/250ml during use, and the stop degree is at 0.035-0.05g/cm
2
Behind deployed ground-coat enamel, the cover-coat enamel slurry, get the 27SiMn steel billet spare of a hydraulic prop cylinder body.At first blank is given birth to the pre-treatment of warding off of burning (650-700 ℃), sandblast, cleaning, check; Make blank upright then, an elasticity ball (size of ball is consistent with the blank internal diameter) that has transmission rod is put into blank, mention ball to from blank upper end slight distance with transmission rod, pour into a certain amount of ground-coat enamel slurry, allow ball at the uniform velocity glide from above, glaze slip on the uniform cloth in the blank, glaze slip is flow to till the stop vertically downward, handle with care and send the drying shed oven dry to, move into enamel furnace under 880-910 ℃ temperature, enamel firing 8-15 minute, take out and check that repairing is qualified; With the identical method application of slip cover-coat enamel slurry of application of slip ground-coat enamel slurry, move in the enamel furnace, under 860-900 ℃ temperature enamel firing 7-10 minute, take out check repair after, repeat the application of slip of a cover-coat enamel slurry again, dry, burn till, check repairing; After adding clear water porcelain facing is ground to the desired precision of drawing with shredder at last, put into enamel furnace again, under 860-900 ℃ temperature enamel firing 7-10 minute, promptly obtaining an inwall had enamelled hydraulic prop cylinder body.It guarantees working accuracy 0.07-0.14mm, and roughness Ra is 0.40-0.100.
Claims (8)
1, a kind of enamel manufacturing process, comprise and ward off pre-treatment, application of slip ground-coat enamel slurry, oven dry is burnt till and application of slip cover-coat enamel slurry, oven dry, burn till, the invention is characterized in: at first blank is warded off pre-treatment, hanging down with dipping then, flow coat is warded off method or the vertical flow coat of cast is warded off method application of slip ground-coat enamel slurry, drying, after burning till, hanging down with dipping, flow coat is warded off method or the vertical flow coat of cast is warded off method application of slip cover-coat enamel slurry, drying again, after burning till, repeat application of slip cover-coat enamel slurry again one time, oven dry is burnt till, with shredder porcelain facing is planarized to the accuracy requirement that drawing is stipulated at last, reburns into finished product.
2, according to the described enamel manufacturing process of claim 1, it is characterized in that: the vertical flow coat method of warding off of said dipping is that blank is all immersed in the glaze slip, with anchor clamps blank is vertically proposed, and treats till the glaze slip stop.
3, according to the described enamel manufacturing process of claim 1, it is characterized in that: the vertical flow coat method of warding off of said cast is the inwall that is used in tubular blank, make blank upright during the application of slip, an elastic sphere or a piston that has transmission rod is put into blank, mention to from the upper end slight distance with transmission rod, pour into a certain amount of glaze slip, allow spheroid or piston at the uniform velocity glide from above, glaze slip on the uniform cloth flow to till the stop glaze slip vertically downward in the blank.
4, according to the described enamel manufacturing process of claim 1, it is characterized in that: said ground-coat enamel slurry is to introduce the mill addition grinding by the ground-coat enamel frit to form,
The chemical constitution of ground-coat enamel frit (weight %) is:
SiO
2：44.5-58.4，Ai
2O
3：3.5-9.1，
B
2O
3：11.5-19.0，R
2O：16.0-20.4，
CaF
2：4.5-11.8，Na
2SiF
6：0.5-3.5，
CoO：0.9-2.7，MnO
2：0.8-5.5，
CuO：0.2-2.8，Fe
2O
3：0.3-3.5，
The composition of mill addition (100 parts umber in glaze piece) is: borax: 0.5-1.1, and Sodium Nitrite: 0-0.2, soda ash: 0.2-0.7, ice crystal: 0.1-0.3,
Silica powder: 15.0-22.0, clay: 4.5-8.0, aluminium sesquioxide: 1.0-3.0.
5, according to the described enamel manufacturing process of claim 4, it is characterized in that: said ground-coat enamel frit is to be cooperated by two kinds, three kinds or four kinds of chemical constitutions and the different ground-coat enamel frit of fusing point to form.
6, according to claim 4 or 5 described enamel manufacturing process, it is characterized in that: said ground-coat enamel frit be by first kind of ground-coat enamel frit and second kind of ground-coat enamel frit with 70: 30-50: 50 ratio cooperates and forms, and first kind chemical constitution (weight %) is:
SiO
2：49.0-62.0，Ai
2O
3：5.0-10.0，
B
2O
3：10.0-16.0，R
2O：18.0-21.0，
R, expression monovalent base metal.
CaF
2：6.0-13.0，Na
2SiF
6：1.0-5.0，
CoO：1.0-3.0，MnO
2：0.7-5.0，
Second kind chemical constitution (weight %) is: SiO
2: 40.0-50.0
Ai
2O
3：2.0-7.0，B
2O
3：15.0-22.0
R
2O：14.0-19.0，CaF
3：3.0-9.0，
R, expression monovalent base metal.
CoO：0.8-2.0，MnO
2：1.0-6.0，
CuO：0.5-5.5，Fe
2O
3：1.0-7.0。
7, according to the described enamel manufacturing process of claim 1, it is characterized in that: molten fast grinding of the cover-coat enamel that said cover-coat enamel slurry is a following chemical constitution (weight %) forms,
SiO
2：62.0-69.0，Ai
2O
3：2.0-5.0，
K
2O：0-3.0，Na
2O：6.0-11.0，
B
2O
3：2.0-6.0，ZnO
2：0.8-6.0，
Na
2SiF
6：1.0-4.0，TiO
25.0-9.0，
Li
2O：0.5-5.0，CoO：0.5-2.0，
CaO：0-3.0，MnO
2：0.3-1.5。
8, according to the described enamel manufacturing process of claim 1, it is characterized in that: the cover-coat enamel frit that said cover-coat enamel slurry is a following chemical constitution (weight %) grinds and forms,
SiO
2：63.0-68.0，Ai
2O
3：9.0-13.0，
K
2O：2.0-7.0，Na
2O：3.0-8.0，
B
2O
3：1.0-5.0，ZrO
2：0.5-5.5，
Na
2SiF
6：1.0-6.0，TiO
2：1.0-6.0，
Li
2O：1.5-6.5，P
2O
5：0-1.5，
CaO：1.0-5.0，CoO：0.6-2.7，
MnO
2：0-3.0。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88103025 CN1014724B (en) | 1988-05-21 | 1988-05-21 | Technique of silico-manganese steel enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88103025 CN1014724B (en) | 1988-05-21 | 1988-05-21 | Technique of silico-manganese steel enamel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1037743A true CN1037743A (en) | 1989-12-06 |
| CN1014724B CN1014724B (en) | 1991-11-13 |
Family
ID=4832406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88103025 Expired CN1014724B (en) | 1988-05-21 | 1988-05-21 | Technique of silico-manganese steel enamel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1014724B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089319C (en) * | 1998-12-16 | 2002-08-21 | 中国科学院新疆化学研究所 | Method for copper-contg. ceramic coating of wall of catalytic reactor |
| CN102219382A (en) * | 2011-03-31 | 2011-10-19 | 广东道氏技术股份有限公司 | Frit for full polish and preparation method thereof |
| CN102408196A (en) * | 2010-09-21 | 2012-04-11 | 湖南立发釉彩科技有限公司 | Fish-scaling-resistant enamel glaze for hot-rolled steel plates |
| CN103614725A (en) * | 2013-11-28 | 2014-03-05 | 浙江安吉健丰金属制品有限公司 | Enameling method |
| CN104395686A (en) * | 2012-06-18 | 2015-03-04 | Api施密特-布莱顿两合公司 | Plate heat exchanger |
| CN105755468A (en) * | 2016-02-29 | 2016-07-13 | 广东康业电器有限公司 | Production technology of enamel iron casting |
| CN108409138A (en) * | 2018-04-11 | 2018-08-17 | 东北大学 | The enamel coating and its preparation process of a kind of resistance to sulfuric acid, salt acid dew piont corrosion |
| CN109628931A (en) * | 2019-01-21 | 2019-04-16 | 宁波好物家居用品设计有限公司 | A kind of stainless steel ware and preparation method thereof with enamel coating |
-
1988
- 1988-05-21 CN CN 88103025 patent/CN1014724B/en not_active Expired
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089319C (en) * | 1998-12-16 | 2002-08-21 | 中国科学院新疆化学研究所 | Method for copper-contg. ceramic coating of wall of catalytic reactor |
| CN102408196A (en) * | 2010-09-21 | 2012-04-11 | 湖南立发釉彩科技有限公司 | Fish-scaling-resistant enamel glaze for hot-rolled steel plates |
| CN102408196B (en) * | 2010-09-21 | 2015-01-21 | 湖南立发釉彩科技有限公司 | Fish-scaling-resistant enamel glaze for hot-rolled steel plates |
| CN102219382A (en) * | 2011-03-31 | 2011-10-19 | 广东道氏技术股份有限公司 | Frit for full polish and preparation method thereof |
| CN102219382B (en) * | 2011-03-31 | 2013-06-26 | 广东道氏技术股份有限公司 | Frit for full polish and preparation method thereof |
| CN104395686A (en) * | 2012-06-18 | 2015-03-04 | Api施密特-布莱顿两合公司 | Plate heat exchanger |
| CN103614725A (en) * | 2013-11-28 | 2014-03-05 | 浙江安吉健丰金属制品有限公司 | Enameling method |
| CN103614725B (en) * | 2013-11-28 | 2015-07-29 | 浙江安吉健丰金属制品有限公司 | A kind of enamel method |
| CN105755468A (en) * | 2016-02-29 | 2016-07-13 | 广东康业电器有限公司 | Production technology of enamel iron casting |
| CN108409138A (en) * | 2018-04-11 | 2018-08-17 | 东北大学 | The enamel coating and its preparation process of a kind of resistance to sulfuric acid, salt acid dew piont corrosion |
| CN108409138B (en) * | 2018-04-11 | 2020-09-25 | 东北大学 | Sulfuric acid and hydrochloric acid dew point corrosion resistant enamel coating and preparation process thereof |
| CN109628931A (en) * | 2019-01-21 | 2019-04-16 | 宁波好物家居用品设计有限公司 | A kind of stainless steel ware and preparation method thereof with enamel coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1014724B (en) | 1991-11-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110642521B (en) | High-wear-resistance antifouling microcrystal decorative ceramic thick plate and preparation method thereof | |
| US20210198150A1 (en) | Silky, fine-grained matte ceramic tile and preparation method thereof | |
| CN111056818B (en) | High-transparency polished ceramic thick plate and preparation method thereof | |
| CN107129150A (en) | A kind of high abrasion glaze for glazed tile and preparation method thereof | |
| CN111995382B (en) | Mutton tallow jade ceramic tile and preparation method thereof | |
| CN106431365A (en) | Ultrawhite polished tile and preparation method thereof | |
| CN103601370B (en) | A kind of environmental protection is without the preparation method of acid pollution frosting powder, its preparation method and mat glass | |
| CN108328927B (en) | Ultra-smooth white glaze and preparation method thereof | |
| CN1884212A (en) | High-temperature reparation glaze composition and process for preparing same and application thereof | |
| CN101519276A (en) | Photocatalytic self-cleaning nano-titania porcelain enamel substrate and method for preparing same | |
| CN108423993A (en) | One kind building pottery aerolite glaze and its application process | |
| CN1037743A (en) | Technique of silico-manganese steel enamel | |
| CN112811820A (en) | Microcrystalline glass | |
| CN111792914A (en) | Method for preparing stoneware antique brick from multi-source ceramic solid waste | |
| CN113480298B (en) | Preparation and application method of high-whiteness high-transmittance high-plasticity ceramic blank mud | |
| CN110963791A (en) | Self-releasing glaze inducer, self-releasing glaze ceramic tile and preparation method thereof | |
| CN114292026A (en) | Satin glaze suitable for quick firing and having special crystallization effect and preparation method thereof | |
| CN1281418A (en) | Method for producing building materials similar to natural stone from sintered glasses or sintered glass ceramics | |
| CN105272380B (en) | A kind of preparation method and equipment of dumb light brick | |
| CN1169967A (en) | Low temperature firing acid-alkali resistant enamel and preparation thereof | |
| CN1204627A (en) | Cast-iron porcelain enamel suitable for wet method production and its technology | |
| CN1229445C (en) | Carbon-contg. refratory material antioxidant coating | |
| CN1765816A (en) | Ceramic hand model suitable for acrylonitrile butadiene glove production and its making method | |
| CN108264227A (en) | A kind of manufacturing method of high-strength wearproof corrosion-resistant glassware | |
| CN1681742A (en) | Water-resistant porcelain enamel coatings and method of manufacturing same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |