CN103771534A - Method and equipment for recycling fluoride in iron-containing compound production - Google Patents
Method and equipment for recycling fluoride in iron-containing compound production Download PDFInfo
- Publication number
- CN103771534A CN103771534A CN201410066435.6A CN201410066435A CN103771534A CN 103771534 A CN103771534 A CN 103771534A CN 201410066435 A CN201410066435 A CN 201410066435A CN 103771534 A CN103771534 A CN 103771534A
- Authority
- CN
- China
- Prior art keywords
- fluorochemical
- product
- solid
- gas
- state
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
The invention relates to the field of fluoride recycling, and particularly relates to a method and equipment for recycling fluoride in iron-containing compound production. The method comprises the following steps of mixing the raw material of Fe-containing oxide with solid-state fluoride to form a mixture; calcining the mixture, wherein the Fe<3+> in the Fe-containing oxide and the F<-> in the fluoride generate a first product FeF3 gas, and the O<2-> in the Fe-containing oxide and the cation in the fluoride generate a second product; introducing water vapor into the first product and enabling reaction to form a gas-solid mixture containing solid-state Fe2O3 and gas-state HF; separating the gas-solid mixture to obtain the first gas phase containing unreacted water vapor and gas-state HF and solid-state Fe2O3; enabling the first gas phase to react with the second product to obtain solid-state fluoride again. According to the method and equipment provided by the invention, the cost is lowered through the recycling of fluoride, and the environmental pollution caused by fluoride is also avoided.
Description
Technical field
The present invention relates to fluorochemical recycling field, the method and apparatus of fluorochemical recycle in producing in particular to a kind of iron containing compounds.
Background technology
Fluorine in fluorine chemical product mainly comes from fluorite, and fluorite is Nonrenewable resources, is a kind of strategic resource simultaneously.Efficiently utilize existing fluorine resource and save existing fluorite resource and become an important directions of fluorine chemical industry Sustainable development.Fluorochemical in use can produce multiple waste now, waste residue fluorine iron perchloride and the fluorine-containing breeze of electrolytic iron production process by-product etc. that such as Neutral ammonium fluoride, ammonium bifluoride produce as etching reagent; Electrolytic process produces the dust such as the gas such as a large amount of hydrofluoric acid and three ferric fluorides and ferric fluoride, Calcium Fluoride (Fluorspan) for another example; Copper metallurgy process adopts fluorite (CaF
2) make fusing assistant, so contain the objectionable impuritiess such as a large amount of Calcium Fluoride (Fluorspan), hydrogen fluoride in flue dust; Magnesium, iron also produce hydrogen fluoride and three ferric fluorides etc. in casting; These fluorochemicals long-term storage or directly emit not only and pollute the environment, and reduced the utilization ratio of these fluorochemicalss.
Summary of the invention
The object of the present invention is to provide the method and apparatus of fluorochemical recycle in a kind of iron containing compounds production, to solve the above problems.
The embodiment of the present invention provides the method for fluorochemical recycle in a kind of iron containing compounds production, comprises the following steps:
(A) raw material containing Fe oxide compound is mixed with solid-state fluorochemical, form mixture;
(B) mixture is calcined, wherein containing the Fe in Fe oxide compound
3+with the F in fluorochemical
-generate the first product FeF
3gas, containing the O in Fe oxide compound
2-generate the second product with the positively charged ion in fluorochemical;
(C) the first product passed into water vapour and reacts, making it to form and contain solid-state Fe
2o
3gas-solid mixture with gaseous state HF;
(D) after being separated, gas-solid mixture obtains the first gas phase and the solid-state Fe that contain unreacted water vapour and gaseous state HF
2o
3;
(E) the first gas phase is reacted with the second product, again obtain solid-state fluorochemical.
Preferably, the reaction conditions of step (E) is to react 1-5h at 100-600 ℃ of temperature.
Preferably, step (E) is specially:
First the first gas phase cooling is obtained to hydrofluoric acid, more mixed to hydrofluoric acid and the second product being incorporated at 100-600 ℃ of temperature reacted to 1-5h, obtain fluorochemical;
Or
First the first gas phase is mixed with the second product, then the first gas phase cooling is obtained to hydrofluoric acid, finally hydrofluoric acid is reacted to 1-5h with the second product at 100-600 ℃ of temperature, obtain fluorochemical.
The condition of preferably, calcining in step (B) for to calcine 1-5h at 600-1300 ℃.
Preferably, the temperature 970-1300 ℃ of reaction in step (C).
Preferably, step (D) is specially:
Gas-solid mixture is cooled to 100-280 ℃ and obtains the first gas phase and the solid-state Fe that contain unreacted water vapour and gaseous state HF after separating
2o
3; Adopt tetrafluoroethylene pipeline transport the first gas phase and mix with the second product.
The embodiment of the present invention also provides the equipment of fluorochemical recycle in a kind of iron containing compounds production, comprising: the first reactor, the second reactor, the 3rd reactor and separator;
The first reactor is for calcining mixture, wherein containing the Fe in Fe oxide compound
3+with the F in fluorochemical
-generate the first product FeF
3gas, containing the O in Fe oxide compound
2-generate the second product with the positively charged ion in fluorochemical;
The second reactor, for the first product is passed into water vapour and reacts, makes it to form and contains solid-state Fe
2o
3gas-solid mixture with gaseous state HF;
First gas phase and the solid-state Fe of separator for obtaining after gas-solid mixture is separated containing unreacted water vapour and gaseous state HF
2o
3;
The 3rd reactor is for reacting the first gas phase again to obtain fluorochemical with the second product.
Preferably, separator is sack cleaner or cyclonic separator.
Preferably, also comprise interchanger, interchanger is for obtaining hydrofluoric acid by the first gas phase cooling.
Preferably, also comprise recirculated water coil pipe, the casing of the 3rd reactor has recirculated water coil pipe, and recirculated water coil pipe is for obtaining hydrofluoric acid by the first gas phase cooling.
The method and apparatus of fluorochemical recycle in a kind of iron containing compounds production that the embodiment of the present invention provides, first after fluorochemical being mixed with ferrous metal mineral and ferrous metal oxide compound, react, generating under high temperature is three ferric fluorides and first reaction product of gaseous state, three of recycling gaseous state is fluoridized molten iron solution and is generated ferric oxide and hydrogen fluoride gas, finally by hydrogen fluoride gas again with the first reaction, again obtain fluorochemical.The method of this recycle fluorochemical, has not only been reduced cost but also has been avoided the pollution of fluorochemical to environment by the iterative cycles utilization to fluorochemical.
Accompanying drawing explanation
The iron containing compounds that Fig. 1-3 show the embodiment of the present invention produce in the process flow sheet of method of fluorochemical recycle;
The iron containing compounds that Fig. 4 shows the embodiment of the present invention produce in the method flow diagram of fluorochemical recycle;
1 first reactor, 2 second reactors, 3 separators, 4 the 3rd reactors, 5 interchanger.
Embodiment
Also by reference to the accompanying drawings the present invention is described in further detail below by specific embodiment.
The embodiment of the present invention provides the method for fluorochemical recycle in a kind of iron containing compounds production, as shown in Figure 4, comprises the following steps:
Step (A): the raw material containing Fe oxide compound is mixed with solid-state fluorochemical, form mixture, wherein the massfraction of solid-state fluorochemical is 20%-80% in mixture, is preferably not more than 7mm, because react more abundant after the less mixing of particle diameter containing the particle diameter of Fe oxide compound.
Preferably, containing the raw material of Fe oxide compound comprise following one or more: Fe
2o
3coarse particles, iron-bearing mineral, contain Fe
2o
3mixture or contain Fe
2o
3waste material etc., wherein contain Fe
2o
3mixture comprise following one or more: the silicate mine of ilmenite, magnetite, rhombohedral iron ore, limonite, spathic iron ore, sulfurous iron ore or iron etc.
Preferably, solid-state fluorochemical comprise following one or more: NaF, NH
4f, NH
4hF
2, CaF
2, AlF
3.
Preferably, be mixed to form in mixture by the raw material containing Fe oxide compound and solid-state fluorochemical, the massfraction of solid-state fluorochemical is preferably 20%-80%.Can make so more Fe participate in reaction, contribute to improve productive rate.
Concrete array mode containing the raw material of Fe oxide compound and solid-state fluorochemical sees the following form 1:
Table 1 is containing kind and the addition of the raw material of Fe oxide compound and solid-state fluorochemical
Step (B), calcines mixture, wherein containing the Fe in Fe oxide compound
3+with the F in fluorochemical
-generate the first product FeF
3gas, containing the O in Fe oxide compound
2-generate the second product with the positively charged ion in fluorochemical;
Due to when temperature is lower than 600 ℃, possibly cannot generate the FeF of gaseous state
3if temperature, higher than 1300 ℃, may generate more by product, therefore preferably the condition of the middle calcining of step (B) for calcining 1-5h at 600-1300 ℃, and the chemical reaction that this step occurs is: MxOynFe
2o
3+ AFz → MxOy+A
2oz+FeF
3(1), specifically the concrete numerical value of this step temperature, time parameter sees the following form 2.
Step (C), passes into the first product water vapour and reacts, and makes it to form to contain solid-state Fe
2o
3with the gas-solid mixture of gaseous state HF, in order better to control Fe
2o
3the particle diameter of product, the therefore temperature 970-1300 ℃ of reaction in step (C) preferably, specifically the concrete numerical value of this step temperature parameter sees the following form 2;
The chemical reaction that this step occurs is: 2FeF
3+ 3H
2o → Fe
2o
3+ 6HF(2)
Step (D), obtains the first gas phase that contains gaseous state HF and contains solid-state Fe after gas-solid mixture is separated
2o
3the first solid phase, by separate after the first gas phase send in the 3rd reactor with polyfluortetraethylene pipe.
Preferably, step (D) is specially: gas-solid mixture is cooled to 100-280 ℃ and obtains the first gas phase and the solid-state Fe that contain unreacted water vapour and gaseous state HF after separating
2o
3; Adopt tetrafluoroethylene pipeline transport the first gas phase and mix with the second product, because HF is that corrosive gases transports with corrosion resistant material tetrafluoroethylene pipeline while therefore transporting, but this material heatproof value is the highest 280 ℃ of left and right, therefore need after gas-solid mixture cooling, to transport with tetrafluoroethylene pipeline.
Step (E), reacts the first gas phase with the second product, again obtain solid-state fluorochemical, by the second product A generating in hydrogen fluoride gas and calcining
2o
zreaction, regenerates fluorochemical AF
z, reaction conditions is preferably under 100-600 ℃ of condition and reacts 1-5 hour.
React and regenerate before fluorochemical with the second product in the first gas phase, need first the first gas phase to be cooled to liquid phase hydrofluoric acid, therefore preferably step (E) is specially: first the first gas phase cooling is obtained to hydrofluoric acid, again mixed to hydrofluoric acid and the second product being incorporated at 100-600 ℃ of temperature reacted to 1-5h, obtain fluorochemical; Or first the first gas phase is mixed with the second product, then the first gas phase cooling is obtained to hydrofluoric acid, finally hydrofluoric acid is reacted to 1-5h with the second product at 100-600 ℃ of temperature, obtain fluorochemical.
The reaction that this step occurs is: A
2o
z+ HF → AF
z+ H
2o (3)
By this step, can realize the recycle of fluorochemical, the concrete data of actual temp, time parameter see the following form 2.
Table 2 step 102,103 and 105 temperature, the concrete numerical value of time parameter
The embodiment of the present invention provides the equipment of a kind of method of fluorochemical recycle in iron containing compounds production, as shown in Figure 1, comprising: the first reactor 1, the second reactor 2, the 3rd reactor 4 and separator 3;
The first reactor 1 is for calcining mixture, wherein containing the Fe in Fe oxide compound
3+generate the first product FeF with the F-in fluorochemical
3gas, containing the O in Fe oxide compound
2 -generate the second product with the positively charged ion in fluorochemical;
Preferably, the first reactor 1 of the embodiment of the present invention is calcining furnace, and calcining furnace quick heating is applicable to gas-solid reaction, but is not limited to calcining furnace, any equipment that can realize this function all can, all within protection scope of the present invention.
The second reactor 2, for the first product is passed into water vapour and reacts, makes it to form and contains solid-state Fe
2o
3gas-solid mixture with gaseous state HF;
First gas phase and the solid-state Fe of separator 3 for obtaining after gas-solid mixture is separated containing unreacted water vapour and gaseous state HF
2o
3;
The 3rd reactor 4 is for reacting the first gas phase again to obtain fluorochemical with the second product.
In iron containing compounds production of the present invention, the equipment of the method for fluorochemical recycle can be realized the recycle of fluorochemical, has not only been reduced cost but also has been avoided the pollution of fluorochemical to environment by the iterative cycles utilization to fluorochemical.
Preferably, separator 3 is sack cleaner or cyclonic separator, and these two kinds of separators belong to common separating device, fully meeting in separation condition situation of the present invention, have the advantages such as cost is lower, easy to use.
Preferably, as shown in Figure 3, also comprise interchanger 5, interchanger 5 is for obtaining hydrofluoric acid by the first gas phase cooling.
Preferably, as shown in Figure 2, also comprise recirculated water coil pipe, the casing of the 3rd reactor has recirculated water coil pipe, and recirculated water coil pipe is for obtaining hydrofluoric acid by the first gas phase cooling.
Next, be described in detail by 4 specific embodiments:
Embodiment 1:
Will be containing Fe
2o
3waste material and CaF
2mix and obtain mixture, Fe
2o
3with CaF
2particle diameter be below 3mm, CaF in gained mixture
2mass percent be 80%.Mixture, the temperature lower calcination of 1150 ℃ of the first reactors 1 hour, is generated to CaO and FeF
3, FeF
3under high temperature, be gaseous state, from solid reactant, overflow.By the FeF overflowing
3introduce in the second reactor, and be hydrolyzed at the temperature of 1250 ℃, generate Fe
2o
3with HF gas.The HF gas that hydrolysis is produced is transported in the 3rd reactor with tetrafluoroethylene pipeline, reacts 2.5 hours at 600 ℃ with reaction product CaO, again obtains CaF
2thereby, realize CaF
2be cycled to repeat utilization.Reaction equation is as follows:
Fe
2O
3+3CaF
2→3CaO+2FeF
3 (4)
2FeF
3+3H
2O→Fe
2O
3+6HF (5)
CaO+2HF→CaF
2+H
2O (6)
Embodiment 2:
By magnetite (Fe
2o
3mSiO
2) and AlF
3mix and obtain mixture, magnetite and AlF
3particle diameter be below 5mm, AlF in gained mixture
3mass percent be 60%.By mixture temperature lower calcination 3 hours of 1300 ℃ in the first reactor, generate Al
2o
3with gaseous state FeF
3and gaseous state SiF
4, by gaseous state SiF
4low ternperature separation process is out hydrolyzed and makes silicon-dioxide and hydrogen fluoride afterwards.By FeF
3from solid reactant, distillation is overflowed.By the FeF overflowing
3introduce in the second reactor, and hydrolysis generates Fe at the temperature of 1300 ℃
2o
3with HF gas.The HF gas that hydrolysis is produced is transported in the 3rd reactor with tetrafluoroethylene pipeline, with reaction product Al
2o
3100 ℃ of reactions 5 hours, again obtain AlF
3thereby, realize AlF
3be cycled to repeat utilization.Reaction equation is as follows:
Fe
2O
3+2AlF
3→Al
2O
3+2FeF
3 (7)
3SiO
2+4AlF
3→3SiF
4+2Al
2O
3 (8)
FeF
3+3H
2O→Fe
2O
3+6HF (9)
Al
2O
3+6HF→2AlF
3+3H
2O (10)
Embodiment 3:
By Fe
2o
3coarse particles and NH
4hF
2mix Fe
2o
3with NH
4hF
2particle diameter be below 7mm, NH in gained mixture
4hF
2mass percent be 40%.By mixture temperature lower calcination 5 hours of 600 ℃ in the first reactor, generate NH
3, H
2o and FeF
3, FeF
3from solid, overflow.By the FeF overflowing
3introduce in the second reactor, and hydrolysis generates Fe at the temperature of 1100 ℃
2o
3with HF gas.The HF gas that hydrolysis is produced is transported in the 3rd reactor with tetrafluoroethylene pipeline, with reaction product NH
3and H
2o, 150 ℃ of reactions 4.5 hours, obtains NH again
4hF
2thereby, realize NH
4hF
2be cycled to repeat utilization.Reaction equation is as follows:
Fe
2O
3+3NH
4HF
2→2FeF
3+3NH
3+3H
2O (11)
FeF
3+3H
2O→Fe
2O
3+6HF (12)
NH
3·H
2O+2HF→NH
4HF
2+H
2O (13)
Embodiment 4:
By limonite and NH
4f mixes, Fe
2o
3with the particle diameter of fluorochemical be below 3mm, NH in gained mixture
4the mass percent of F is 30%.By mixture temperature lower calcination 4.5 hours of 810 ℃ in the first reactor, generate NH
3, H
2o and FeF
3, by FeF
3from solid, distillation is overflowed.By the FeF overflowing
3introduce in the second reactor, and hydrolysis generates Fe at the temperature of 970 ℃
2o
3with HF gas.The HF gas that hydrolysis is produced is transported in the 3rd reactor with tetrafluoroethylene pipeline, with reaction product NH
3and H
2o, 200 ℃ of reactions 1 hour, obtains NH again
4f, thus realize NH
4f is cycled to repeat utilization.Reaction equation is as follows:
Fe
2O
3+6NH
4F→2FeF
3+6NH
3+3H
2O (14)
2FeF
3+3H
2O→Fe
2O
3+6HF (15)
NH
3·H
2O+HF→NH
4F+H
2O (16)
The utilization ratio that the concrete numerical value of the parameters in embodiment 1-4 and the circulation of fluorochemical are reclaimed sees the following form 3:
The concrete numerical value of parameter of the each embodiment of table 3 and the rate of recovery of fluorochemical
The embodiment of the present invention provides a kind of method of efficiently utilizing fluorochemicals, belongs to inorganic fluorine Chemicals production technical field.Utilize F element and metal the first product (M in fluorine-containing material (AFz)
xo
ynFe
2o
3) in close fluorine element Al react, generate another kind of high-purity fluorochemicals, high-purity the first product is made in the hydrolysis that recycles this fluorine-containing material, and the HF finally reaction being generated reacts with the metallic element in fluorine-containing material, change again former fluorine-containing material into, and can return to technical process.High-purity fluorine compound only, as the intermediate product of reaction process, is nonexpendable in theory, thereby has realized the efficient utilization of fluorochemical, and the environmental pollution of avoiding fluorine element to cause.This method is reused fluorochemical, will produce good economic benefit and social benefit.The method processing step is few, and cost is low.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. a method for fluorochemical recycle in iron containing compounds production, is characterized in that, comprises the following steps:
(A) raw material containing Fe oxide compound is mixed with solid-state fluorochemical, form mixture;
(B) described mixture is calcined, wherein said containing the Fe in Fe oxide compound
3+with the F in described fluorochemical
-generate the first product FeF
3gas, described containing the O in Fe oxide compound
2-generate the second product with the positively charged ion in described fluorochemical;
(C) described the first product passed into water vapour and reacts, making it to form and contain solid-state Fe
2o
3gas-solid mixture with gaseous state HF;
(D) after being separated, described gas-solid mixture obtains the first gas phase and the solid-state Fe that contain unreacted water vapour and gaseous state HF
2o
3;
(E) described the first gas phase is reacted with described the second product, again obtain described solid-state fluorochemical.
2. the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 1, is characterized in that, the reaction conditions of described step (E) is to react 1-5h at 100-600 ℃ of temperature.
3. the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 1, is characterized in that, described step (E) is specially:
First described the first gas phase cooling is obtained to hydrofluoric acid, more mixed to described hydrofluoric acid and described the second product being incorporated at 100-600 ℃ of temperature reacted to 1-5h, obtain described fluorochemical;
Or
First described the first gas phase is mixed with described the second product, more described the first gas phase cooling is obtained to hydrofluoric acid, finally described hydrofluoric acid is reacted to 1-5h with described the second product at 100-600 ℃ of temperature, obtain described fluorochemical.
4. the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 1, is characterized in that, in described step (B), the condition of calcining for to calcine 1-5h at 600-1300 ℃.
5. the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 1, is characterized in that the temperature 970-1300 ℃ of reaction in described step (C).
6. the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 1, is characterized in that, described step (D) is specially:
Described gas-solid mixture is cooled to 100-280 ℃ and obtains the first gas phase and the solid-state Fe that contain unreacted water vapour and gaseous state HF after separating
2o
3; Adopt tetrafluoroethylene pipeline transport point state the first gas phase and mix with the second product.
7. the equipment of the method for fluorochemical recycle in a kind of iron containing compounds production as claimed in claim 1, is characterized in that, comprising: the first reactor, the second reactor, the 3rd reactor and separator;
Described the first reactor is for described mixture is calcined, wherein said containing the Fe in Fe oxide compound
3+with the F in described fluorochemical
-generate the first product FeF
3gas, described containing the O in Fe oxide compound
2-generate the second product with the positively charged ion in described fluorochemical;
Described the second reactor, for described the first product is passed into water vapour and reacts, makes it to form and contains solid-state Fe
2o
3gas-solid mixture with gaseous state HF;
First gas phase and the solid-state Fe of described separator for obtaining after described gas-solid mixture is separated containing unreacted water vapour and gaseous state HF
2o
3;
Described the 3rd reactor is for reacting described the first gas phase again to obtain described fluorochemical with described the second product.
8. the equipment of the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 7, is characterized in that, described separator is sack cleaner or cyclonic separator.
9. the equipment of the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 7, is characterized in that, also comprises interchanger, and described interchanger is for obtaining hydrofluoric acid by described the first gas phase cooling.
10. the equipment of the method for fluorochemical recycle in a kind of iron containing compounds production according to claim 7, it is characterized in that, also comprise recirculated water coil pipe, the casing of described the 3rd reactor has recirculated water coil pipe, and described recirculated water coil pipe is for obtaining hydrofluoric acid by described the first gas phase cooling.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410066435.6A CN103771534B (en) | 2014-02-26 | 2014-02-26 | Method and equipment for recycling fluoride in iron-containing compound production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410066435.6A CN103771534B (en) | 2014-02-26 | 2014-02-26 | Method and equipment for recycling fluoride in iron-containing compound production |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103771534A true CN103771534A (en) | 2014-05-07 |
CN103771534B CN103771534B (en) | 2015-06-03 |
Family
ID=50564372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410066435.6A Active CN103771534B (en) | 2014-02-26 | 2014-02-26 | Method and equipment for recycling fluoride in iron-containing compound production |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103771534B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111989413A (en) * | 2017-07-11 | 2020-11-24 | 泰尼尔项目管理有限公司 | Method for processing titanomagnetite ore material |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2167784A (en) * | 1936-01-13 | 1939-08-01 | Sherwin Williams Co | Method of treating iron fluoride |
JPS5815039A (en) * | 1981-07-16 | 1983-01-28 | Nishimura Watanabe Chiyuushiyutsu Kenkyusho:Kk | Production of high purity iron oxide |
EP0319857A1 (en) * | 1987-12-04 | 1989-06-14 | Nkk Corporation | Method for producing titanium fluoride |
CN1714043A (en) * | 2002-10-28 | 2005-12-28 | 铂知识产权有限合伙公司 | Method for producing metal fluoride materials |
CN102826616A (en) * | 2012-09-13 | 2012-12-19 | 广东电网公司电力科学研究院 | Ferric fluoride nano material and preparation method thereof |
CN102945961A (en) * | 2012-12-05 | 2013-02-27 | 吉林大学 | Preparation method of high-performance positive FeF3 composite material for lithium ion batteries |
CN103165888A (en) * | 2013-03-02 | 2013-06-19 | 合肥国轩高科动力能源股份公司 | Preparation method of ferric three fluoride (FeF3) nanorod with embedded lithium activity |
-
2014
- 2014-02-26 CN CN201410066435.6A patent/CN103771534B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2167784A (en) * | 1936-01-13 | 1939-08-01 | Sherwin Williams Co | Method of treating iron fluoride |
JPS5815039A (en) * | 1981-07-16 | 1983-01-28 | Nishimura Watanabe Chiyuushiyutsu Kenkyusho:Kk | Production of high purity iron oxide |
EP0319857A1 (en) * | 1987-12-04 | 1989-06-14 | Nkk Corporation | Method for producing titanium fluoride |
CN1714043A (en) * | 2002-10-28 | 2005-12-28 | 铂知识产权有限合伙公司 | Method for producing metal fluoride materials |
CN102826616A (en) * | 2012-09-13 | 2012-12-19 | 广东电网公司电力科学研究院 | Ferric fluoride nano material and preparation method thereof |
CN102945961A (en) * | 2012-12-05 | 2013-02-27 | 吉林大学 | Preparation method of high-performance positive FeF3 composite material for lithium ion batteries |
CN103165888A (en) * | 2013-03-02 | 2013-06-19 | 合肥国轩高科动力能源股份公司 | Preparation method of ferric three fluoride (FeF3) nanorod with embedded lithium activity |
Non-Patent Citations (3)
Title |
---|
ADHYAPAK ET AL.: "REACTION OF AMMONIUM HYDEOGEN FLUORIDE WITH OXIDES OF IRON IN SOLID STATE", 《SYNTH.REACT.INORG.MET.-ORG.CHEM》 * |
J.M JUNEJA ET AL.: "Preparation of anhydrous FeF3 by solid state reaction of iron oxide with ammonium hydrogen fluoride", 《INDIAN JOURNAL OF ENGINEERING & MATERIALS SCIENCES》 * |
SEUNG-TAEK MYUNG ET AL.: "Iron trifluoride synthesized via evaporation method and its application to rechargeable lithium batteries", 《JOURNAL OF POWER SOURCES》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111989413A (en) * | 2017-07-11 | 2020-11-24 | 泰尼尔项目管理有限公司 | Method for processing titanomagnetite ore material |
Also Published As
Publication number | Publication date |
---|---|
CN103771534B (en) | 2015-06-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103738968B (en) | The method of recycle fluorochemical in the process preparing silicon-containing compound | |
Innocenzi et al. | Yttrium recovery from primary and secondary sources: A review of main hydrometallurgical processes | |
CN106276801B (en) | A kind of production equipment and process of anhydrous hydrogen fluoride | |
US20180056344A1 (en) | Method of utilizing construction and demolition waste | |
CN102259838B (en) | Method for continuously preparing hydrogen fluoride by using rotary reaction furnace | |
CN104271504A (en) | The method and system for production of silicon and devicies | |
CN104004919A (en) | Environment-friendly recycling process of waste residues in electrolytic manganese production | |
CN103771534B (en) | Method and equipment for recycling fluoride in iron-containing compound production | |
CN105369042B (en) | Method for extracting rare earths from fluoride system rare earth molten salt electrolysis slag | |
CN106978531A (en) | The method that soda acid joint decomposes mixed rare earth concentrate | |
CN107604385B (en) | The preparation method of magnesium-rare earth alloy electrolysis raw material | |
CN103787403B (en) | A kind of method containing fluorochemical recycle in gallium compound production | |
CN103936044B (en) | Prepare efficient circulation in the process of aluminum contained compound and utilize the method for fluorochemical | |
CN103708550B (en) | The preparation method of Zirconium tetrafluoride | |
CN103818955B (en) | Method and apparatus for cyclic utilization of fluoride in production of titanium-containing compound | |
CN103787412B (en) | The method and apparatus that in a kind of zirconium-containing compound production, fluoride recycles | |
CN1051057C (en) | Preparation of anhydrous magnesium chloride-containing melts from hydrated magnesium chloride and production of magnesium metal | |
CN111534701A (en) | Method for efficiently recovering valuable elements from rare earth molten salt electrolytic slag | |
CN100494059C (en) | Method of coproducing anhydrous potassium pentaborate by boric acid factory self-producing boric acid | |
CN109179487A (en) | A method of utilizing waste acid treatment germanium mud | |
CN113005285B (en) | Process for producing brown corundum by using red mud | |
CN103708533B (en) | One prepares nanometer Ga 2o 3the method of powder | |
CN110482601A (en) | It is a kind of to produce TiO with rutile ore2The method of powder | |
CN110422878A (en) | One kind preparing anatase titanium dioxide TiO by ammonium titanium fluoride2The method of powder | |
CN102001628B (en) | Method for preparing hydrogen fluoride by taking ammonium bisulfate and fluorine ammonium salt as raw materials |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhang Lin Inventor after: Liu Rui Inventor after: Shi Chunhua Inventor after: Gong Longjiang Inventor before: Yang Xianjin Inventor before: Zhang Lin Inventor before: Liu Rui Inventor before: Shi Chunhua Inventor before: Gong Longjiang |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |