CN103756562A - Fluorine-containing organosilicone stone antifouling agent and preparation method thereof - Google Patents
Fluorine-containing organosilicone stone antifouling agent and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a fluorine-containing organosilicone stone antifouling agent and a preparation method thereof. The fluorine-containing organosilicone stone antifouling agent is prepared from the following raw materials in parts by weight: 90-130 parts of petroleum ether, 20-35 parts of silicon resin, 10-30 parts of fluorosilicone oil, 5-10 parts of dispersion wetting agent, 3-10 parts of defoamer, 1-5 parts of preservative, 1-5 parts of silane coupling agent, 10-25 parts of film forming additive, 1-5 parts of pigments and fillers and 2-7 parts of thickener. The fluorine-containing organosilicone stone antifouling agent has the beneficial effects that compared with the traditional antifouling agent, the fluorine-containing organosilicone stone antifouling agent has the advantages of good water and oil prevention performance and permeability; and by adopting the fluorine-containing organosilicone stone antifouling agent, the soiling resistance of stones is improved, and the fluorine-containing organosilicone stone antifouling agent is simple in manufacturing, can be directly used without dilution and is convenient to use.
Description
Technical field
The present invention relates to a kind of stain control agent, particularly a kind of fluorine-containing organic silicon stone anti-fouling agent and preparation method thereof.
Background technology
Stone material has beautiful attractive in appearance, the firm and durable of color, the material advantage such as be easy to get as a kind of building and ornament materials.Therefore, stone material all extensively and is generally used on the exterior wall of the various devices from the rock cave in ancient times, stone bridge, pinnacle to the modern times and various cliff painting, statue, wall quarter, monument and buildings and ground etc.Yet these material of construction were used after several years, at stone surface, there will be pathology and stone material itself can be subject to various invasives and pollute, stone surface there will be water spots, greasy dirt, tells the phenomenons such as yellow thus.The generation of these phenomenons is because this type of material has micropore, easily absorbs corrosive gases in atmosphere, moisture and pollutent.And these phenomenons can cause its decorative effect, and to causing great effect its work-ing life.In order to prevent the pathology of stone material, there is the antifouling and maintenance technology of stone surface at home and abroad.At present, the surface soiling agent waterproof on market, grease proofing and antifouling property is poor.
Summary of the invention
The object of the present invention is to provide a kind of fluorine-containing organic silicon stone anti-fouling agent for stone protector, there is waterproof, grease proofing and raising stone material wearing quality.
In order to realize foregoing invention object, the invention provides a kind of fluorine-containing organic silicon stone anti-fouling agent, described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 90-130 weight part, fluorine silicon resin 20-35 weight part, fluorosilicon oil 10-30 weight part, dispersion wetting agent 5-10 weight part, defoamer 3-10 weight part, sanitas 1-5 weight part, silane coupling agent 1-5 weight part, film coalescence aid 10-25 weight part, color stuffing 1-5 weight part and thickening material 2-7 weight part.
Described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 90-115 weight part, fluorine silicon resin 25-35 weight part, fluorosilicon oil 10-21 weight part, dispersion wetting agent 5-8 weight part, defoamer 3-7 weight part, sanitas 1-3 weight part, silane coupling agent 1-3 weight part, film coalescence aid 10-17 weight part, color stuffing 1-3 weight part and thickening material 2-5 weight part.
Described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 106-130 weight part, fluorine silicon resin 20-31 weight part, fluorosilicon oil 17-30 weight part, dispersion wetting agent 7-10 weight part, defoamer 5-10 weight part, sanitas 2-5 weight part, silane coupling agent 2-5 weight part, film coalescence aid 15-25 weight part, color stuffing 2-5 weight part and thickening material 3-7 weight part.
Described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 105-125 weight part, fluorine silicon resin 23-31 weight part, fluorosilicon oil 15-25 weight part, dispersion wetting agent 6-9 weight part, defoamer 4-8 weight part, sanitas 2-4 weight part, silane coupling agent 2-4 weight part, film coalescence aid 13-21 weight part, color stuffing 2-4 weight part and thickening material 3-6 weight part.
Described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 116 weight parts, fluorine silicon resin 27 weight parts, fluorosilicon oil 21 weight parts, dispersion wetting agent 8 weight parts, defoamer 6 weight parts, sanitas 3 weight parts, silane coupling agent 3 weight parts, film coalescence aid 17 weight parts, color stuffing 3 weight parts and thickening material 4 weight parts.
Described stain control agent preferably also comprises oxysuccinic acid and beeswax; Described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 90-130 weight part, fluorine silicon resin 20-35 weight part, oxysuccinic acid 5-12 weight part, fluorosilicon oil 10-30 weight part, beeswax 3-7 weight part, dispersion wetting agent 5-10 weight part, defoamer 3-10 weight part, sanitas 1-5 weight part, silane coupling agent 1-5 weight part, film coalescence aid 10-25 weight part, color stuffing 1-5 weight part and thickening material 2-7 weight part.
Described stain control agent is preferably comprised of the raw material of following ratio of weight and number: sherwood oil 112 weight parts, fluorine silicon resin 27 weight parts, oxysuccinic acid 8 weight parts, fluorosilicon oil 23 weight parts, beeswax 5 weight parts, dispersion wetting agent 7 weight parts, defoamer 5 weight parts, sanitas 3 weight parts, silane coupling agent 3 weight parts, film coalescence aid 16 weight parts, color stuffing 3 weight parts and thickening material 5 weight parts.
Described fluorosilicon oil for take alkyl acrylic 12 heptyl esters and alkyl acryloxy propyl trimethoxy silicane as main raw material synthetic fluorosilicon oil, wherein, alkyl is methyl, ethyl or propyl group; The boiling point of described sherwood oil is 60-90 ℃.
Described dispersion wetting agent is phosphoric acid, silicate, how joins one or more in polyvalent alcohol-many ethyleneimines segmented copolymer, sodium oleate and sulfonate in; Wherein, the weight percent of described phosphoric acid is 0% ~ 10%, 10% ~ 30% or 40% ~ 100%, and the weight percent of described silicate is 0% ~ 35%, 40% ~ 65%, 70% ~ 100%; Described many weight percents of joining polyvalent alcohol-many ethyleneimines segmented copolymer in are 0% ~ 10%, 20% ~ 35% or 40% ~ 100%; The weight percent of described sodium oleate is 0% ~ 10%, 10% ~ 30% or 40% ~ 100%; The weight percent of described sulfonate is 0% ~ 20%, 20% ~ 35% or 45% ~ 100%, and the weight percent summation of five kinds of described compositions is 100%; Be preferably: described dispersion wetting agent is joined polyvalent alcohol-many ethyleneimines segmented copolymer, 10% ~ 30% sodium oleate and 0% ~ 20% sulfonate by 10% ~ 30% phosphoric acid, 0% ~ 35% silicate, more than 20% ~ 35% in and formed, and the weight percent summation of five kinds of described compositions is 100%; Most preferably, described dispersion wetting agent is joined polyvalent alcohol-many ethyleneimines segmented copolymer, 21% sodium oleate and 17% sulfonate by 15% phosphoric acid, 15% silicate, more than 32% in and is formed,
Described defoamer is one or more in HT-606, HT-610 and NXZ; Wherein, the weight percent of described HT-606 is 0% ~ 10%, 15% ~ 35% or 40% ~ 100%, the weight percent of described HT-610 is 0% ~ 10%, 10% ~ 30% or 35% ~ 100%, the weight percent of described NXZ is 0% ~ 30%, 35% ~ 60% or 60% ~ 100%, and the weight percent summation of three kinds of described compositions is 100%; Be preferably: described defoamer is comprised of 15% ~ 35%HT-606,10% ~ 30%HT-610 and 35% ~ 60%NXZ, the weight percent summation of three kinds of described compositions is 100%; Most preferably be: described defoamer is comprised of 30%HT-606,10%HT-610 and 60%NXZ.
Described sanitas is one or more in sodium rice silver, zinc oxide and magnesium oxide; Wherein, the weight percent of described nanometer silver is 0% ~ 20%, 25% ~ 65% or 70% ~ 100%, the weight percent of described zinc oxide is 0% ~ 10%, 10% ~ 30% or 40% ~ 100%, described magnesian weight percent is 0% ~ 20%, 20% ~ 35% or 45% ~ 100%, and the weight percent summation of three kinds of described compositions is 100%; Be preferably: described sanitas is comprised of 25% ~ 65% sodium rice silver, 10% ~ 30% zinc oxide and 20% ~ 45% magnesium oxide, and the weight percent summation of three kinds of described compositions is 100%; Most preferably be: the magnesium oxide that the sodium rice silver that described sanitas is 52% by weight percent, the zinc oxide that weight percent is 19% and weight percent are 29% forms.
Described silane coupling agent is one or more in methacryloxy Trimethoxy silane, γ-isocyanic ester propyl-triethoxysilicane and γ-mercaptopropyl trimethoxysilane; Wherein, the weight percent of described methacryloxy Trimethoxy silane is 0%-20%, 20%-45% or 50%-100%; The weight percent of described γ-isocyanic ester propyl-triethoxysilicane is 0%-10%, 10%-25% or 40%-100%; The weight percent of described γ-mercaptopropyl trimethoxysilane is 0%-30%, 35%-45% or 50%-100%, and the weight percent summation of three kinds of described compositions is 100%; Be preferably: described silane coupling agent is comprised of 20%-45% methacryloxy Trimethoxy silane, 10%-25% γ-isocyanic ester propyl-triethoxysilicane and 35%-45% γ-mercaptopropyl trimethoxysilane, and the weight percent summation of three kinds of described compositions is 100%; Most preferably be: described silane coupling agent is comprised of 41% methacryloxy Trimethoxy silane, 21% γ-isocyanic ester propyl-triethoxysilicane and 38 γ-mercaptopropyl trimethoxysilane.
Described film coalescence aid is one or more in epoxy soybean oil, clorafin, adjacent benzene dicaprylate and adjacent benzene dibutyrate; Wherein, the weight percent of described epoxy soybean oil is 0%-15%, 15%-35% or 40%-100%, the weight percent of described clorafin is 0%-10%, 10%-40% or 45%-100%, the weight percent of described adjacent benzene dicaprylate is 0%-10%, 15%-30%, 30%-50% or 55%-100% and adjacent benzene dibutyrate 0%-20%, 25%-45% or 50%-100%, and the weight percent summation of four kinds of described compositions is 100%; Be preferably: described film coalescence aid is comprised of 10%-40% epoxy soybean oil, 10%-40% clorafin, the adjacent benzene dicaprylate of 15%-30% and the adjacent benzene dibutyrate of 25%-45%, and the weight percent summation of four kinds of described compositions is 100%; Most preferably be: described film coalescence aid is comprised of 35% epoxy soybean oil, 12% clorafin, 18% adjacent benzene dicaprylate and 35% adjacent benzene dibutyrate.
Described thickening material is one or both during sodium-chlor and carboxylic hydroxyl fiber are received; The weight percent of described sodium-chlor is 0%-30%, 35%-55% or 60%-100%, and the weight percent that described carboxylic hydroxyl fiber is received is 0-40,40-65 or 70%-100%, and the weight percent summation of two kinds of described compositions is 100%; Be preferably: described thickening material is received and formed by 35%-55% sodium-chlor and 40%-65% carboxylic hydroxyl fiber, and the weight percent summation of two kinds of described compositions is 100%; Most preferably be: described thickening material is received and formed by 51% sodium-chlor and 49% carboxylic hydroxyl fiber
Described color stuffing is nano titanium oxide.
In order better to realize foregoing invention object, the invention provides a kind of preparation method of fluorine-containing organic silicon stone anti-fouling agent, described preparation method is: at room temperature, according to ratio of weight and number, take all raw materials, fully mix and can obtain stain control agent.
The beneficial effect that the technical scheme that the embodiment of the present invention provides is brought is: compare with traditional stain control agent, stain control agent of the present invention has advantages of waterproof, grease proofing and good penetrability, has improved the resistance to soiling of stone material, and makes simple, directly use without dilution, easy to use.
Embodiment
Embodiment 1
The embodiment of the present invention provides a kind of fluorine-containing organic silicon stone anti-fouling agent, and stain control agent is comprised of the raw material of following parts by weight: sherwood oil 112 weight parts, fluorine silicon resin 27 weight parts, oxysuccinic acid 8 weight parts, fluorosilicon oil 23 weight parts, beeswax 5 weight parts, dispersion wetting agent 7 weight parts, defoamer 5 weight parts, sanitas 3 weight parts, silane coupling agent 3 weight parts, film coalescence aid 16 weight parts, color stuffing 3 weight parts and thickening material 5 weight parts.
Wherein, fluorosilicon oil is the synthetic fluorosilicon oil of main raw material for take methacrylic acid 12 heptyl esters and methacryloxypropyl trimethoxy silane; The boiling point of sherwood oil is 80 ℃.
Disperse wetting agent to be grouped into by the one-tenth of following weight percent: phosphatase 11 5%, silicate 15%, how to join polyvalent alcohol-many ethyleneimines segmented copolymer 32%, sodium oleate 21% and sulfonate 17% in; Defoamer is grouped into by the one-tenth of following weight percent: 30%HT-606,10%HT-610 and 60%NXZ.
Sanitas is grouped into by the one-tenth of following weight percent: sodium rice silver 52%, zinc oxide 19% and magnesium oxide 29%.
Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane 41%, γ-isocyanic ester propyl-triethoxysilicane 21% and γ-mercaptopropyl trimethoxysilane 38%.
Film coalescence aid is grouped into by the one-tenth of following weight percent: epoxy soybean oil 35%, clorafin 12%, adjacent benzene dicaprylate 18% and adjacent benzene dibutyrate 35%.
Thickening material is grouped into by the one-tenth of following weight percent: sodium-chlor 51% and carboxylic hydroxyl fiber receive 49%.
Color stuffing is nano titanium oxide.
The embodiment of the present invention provides a kind of preparation method of fluorine-containing organic silicon stone anti-fouling agent to be: at room temperature, according to ratio of weight and number, take all raw materials, fully mix and can obtain stain control agent.
Embodiment 2
The embodiment of the present invention provides a kind of fluorine-containing organic silicon stone anti-fouling agent, and the raw material of the ratio of weight and number of described stain control agent forms: sherwood oil 116 weight parts, fluorine silicon resin 27 weight parts, fluorosilicon oil 21 weight parts, dispersion wetting agent 8 weight parts, defoamer 6 weight parts, sanitas 3 weight parts, silane coupling agent 3 weight parts, film coalescence aid 17 weight parts, color stuffing 3 weight parts and thickening material 4 weight parts.
Wherein, fluorosilicon oil is the synthetic fluorosilicon oil of main raw material for take methacrylic acid 12 heptyl esters and methacryloxypropyl trimethoxy silane; The boiling point of sherwood oil is 70 ℃.
Disperse wetting agent to be grouped into by the one-tenth of following weight percent: phosphatase 11 1%, silicate 18%, how to join polyvalent alcohol-many ethyleneimines segmented copolymer 21%, sodium oleate 27% and sulfonate 23% in; Defoamer is grouped into by the one-tenth of following weight percent: 20%HT-606,50%HT-610 and 20%NXZ.
Sanitas is grouped into by the one-tenth of following weight percent: sodium rice silver 27%, zinc oxide 59% and magnesium oxide 14%.
Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane 35%, γ-isocyanic ester propyl-triethoxysilicane 15% and γ-mercaptopropyl trimethoxysilane 50%.
Film coalescence aid is grouped into by the one-tenth of following weight percent: epoxy soybean oil 15%, clorafin 29%, adjacent benzene dicaprylate 26% and adjacent benzene dibutyrate 30%.
Thickening material is grouped into by the one-tenth of following weight percent: sodium-chlor 39% and carboxylic hydroxyl fiber receive 61%.
Color stuffing is nano titanium oxide.
The embodiment of the present invention provides a kind of preparation method of fluorine-containing organic silicon stone anti-fouling agent to be: at room temperature, according to ratio of weight and number, take all raw materials, fully mix and can obtain stain control agent.
Embodiment 3
The embodiment of the present invention provides a kind of fluorine-containing organic silicon stone anti-fouling agent, and stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 102 weight parts, fluorine silicon resin 30 weight parts, fluorosilicon oil 16 weight parts, dispersion wetting agent 6 weight parts, defoamer 5 weight parts, sanitas 2 weight parts, silane coupling agent 2 weight parts, film coalescence aid 13 weight parts, color stuffing 2 weight parts and thickening material 3 weight parts.
Wherein, fluorosilicon oil is the synthetic fluorosilicon oil of main raw material for take methacrylic acid 12 heptyl esters and methacryloxypropyl trimethoxy silane; The boiling point of sherwood oil is 90 ℃.
Disperse wetting agent to be grouped into by the one-tenth of following weight percent: phosphoric acid 21%, silicate 19%, sodium oleate 34% and sulfonate 26%.
Defoamer is grouped into by the one-tenth of following weight percent: 20%HT-606 and 80%NXZ.
Sanitas is grouped into by the one-tenth of following weight percent: sodium rice silver 51% and zinc oxide 49%.
Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane 35%, γ-isocyanic ester propyl-triethoxysilicane 15% and γ-mercaptopropyl trimethoxysilane 50%.
Film coalescence aid is grouped into by the one-tenth of following weight percent: epoxy soybean oil 24%, adjacent benzene dicaprylate 41% and adjacent benzene dibutyrate 35%.
Thickening material is grouped into by the one-tenth of following weight percent: sodium-chlor 49% and carboxylic hydroxyl fiber receive 51%.
Color stuffing is nano titanium oxide.
The embodiment of the present invention provides a kind of preparation method of fluorine-containing organic silicon stone anti-fouling agent to be: at room temperature, according to ratio of weight and number, take all raw materials, fully mix and can obtain stain control agent.
Embodiment 4
The embodiment of the present invention provides a kind of fluorine-containing organic silicon stone anti-fouling agent, and stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 118 weight parts, fluorine silicon resin 26 weight parts, fluorosilicon oil 23 weight parts, dispersion wetting agent 8 weight parts, defoamer 7 weight parts, sanitas 4 weight parts, silane coupling agent 4 weight parts, film coalescence aid 19 weight parts, color stuffing 4 weight parts and thickening material 5 weight parts.
Wherein, fluorosilicon oil is the synthetic fluorosilicon oil of main raw material for take methacrylic acid 12 heptyl esters and methacryloxypropyl trimethoxy silane; The boiling point of sherwood oil is 85 ℃.
Disperse wetting agent to be grouped into by the one-tenth of following weight percent: silicate 22%, how to join polyvalent alcohol-many ethyleneimines segmented copolymer 26% and sodium oleate 52% in; Defoamer is grouped into by the one-tenth of following weight percent: 64%HT-606 and 36%HT-610.
Sanitas is grouped into by the one-tenth of following weight percent: zinc oxide 53% and magnesium oxide 47%.
Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane 25% and γ-mercaptopropyl trimethoxysilane 75%.
Film coalescence aid is grouped into by the one-tenth of following weight percent: epoxy soybean oil 27%, clorafin 34% and adjacent benzene dicaprylate 39%.
Thickening material is that carboxylic hydroxyl fiber is received.
Color stuffing is nano titanium oxide.
The embodiment of the present invention provides a kind of preparation method of fluorine-containing organic silicon stone anti-fouling agent to be: at room temperature, according to ratio of weight and number, take all raw materials, fully mix and can obtain stain control agent.
Embodiment 5
The embodiment of the present invention provides a kind of fluorine-containing organic silicon stone anti-fouling agent, and stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 90 weight parts, fluorine silicon resin 35 weight parts, oxysuccinic acid 12 weight parts, fluorosilicon oil 30 weight parts, beeswax 7 weight parts, dispersion wetting agent 10 weight parts, defoamer 9 weight parts, sanitas 4 weight parts, silane coupling agent 4 weight parts, film coalescence aid 19 weight parts, color stuffing 3 weight parts and thickening material 4 weight parts.
Wherein, fluorosilicon oil is the synthetic fluorosilicon oil of main raw material for take methacrylic acid 12 heptyl esters and methacryloxypropyl trimethoxy silane; The boiling point of sherwood oil is 90 ℃.
Disperse wetting agent to be grouped into by the one-tenth of following weight percent: silicate 34%, sodium oleate 39% and sulfonate 27%.
Defoamer is grouped into by the one-tenth of following weight percent: 43%HT-610 and 57%NXZ.
Sanitas is grouped into by the one-tenth of following weight percent: sodium rice silver 44% and magnesium oxide 56%.
Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane 35% and γ-isocyanic ester propyl-triethoxysilicane 65%.
Film coalescence aid is grouped into by the one-tenth of following weight percent: epoxy soybean oil 21%, clorafin 37% and adjacent benzene dibutyrate 42%.
Thickening material is grouped into by the one-tenth of following weight percent: sodium-chlor 47% and carboxylic hydroxyl fiber receive 53%.
Color stuffing is nano titanium oxide.
The embodiment of the present invention provides a kind of preparation method of fluorine-containing organic silicon stone anti-fouling agent to be: at room temperature, according to ratio of weight and number, take all raw materials, fully mix and can obtain stain control agent.
Simultaneous test
1, test materials
Stain control agent (embodiment group 1-5) for examination stain control agent: embodiment of the present invention 1-5; Fluorine-containing organic silicon siloxane compound (control group 1); Tradition stain control agent (control group 2).Wherein, the fluorine-containing organic silicon siloxane compound of control group 1 is for being 201110001005.2 according to application number, and application publication number is the stain control agent of the content production of specification sheets embodiment 2 in CN 102585232 A patent documentations.
For trying stone material: select rostone as supplying examination stone material; Every group of identical test of stain control agent selects identical rostone to test.
2, test method
By being coated in respectively rostone surface after the stain control agent of embodiment of the present invention 1-5, the dilution of fluorine-containing organic silicon siloxane compound and after the dilution of traditional stain control agent, all apply twice rear placement after 7-10 days, stone surface is tested.Wherein, OCA video optics contact angle instrument test for water contact angle is tested contact angle with 0.5ml water droplet on sample; Quanta200 type scanning electron microscope test for perviousness, first cuts the stone material sample after applying, then section is carried out to testing permeability; Didirtresistance drops in respectively stone surface with soy sauce and coffee, after soy sauce and coffee are dry, places one day, with clear water washing, then uses microscopic examination, according to dirt revolution mark, antipollution standard is divided into Three Estate: fine, good, poor.Before each test, all adopt identical stone material, test result is as shown in table 1.
Table 1: use respectively the antifouling property of the stone material of product of the present invention and conventional products to detect synopsis:
| Group | Water contact angle | Anti-coffee pollutes | Anti-soy sauce pollutes | Grease proofness | Perviousness |
| Embodiment group 1 | 142 | Fine | Fine | Fine | 2.4 mm |
| Embodiment group 2 | 141 | Fine | Fine | Fine | 2.3 mm |
| Embodiment group 3 | 139 | Fine | Fine | Fine | 2.3 mm |
| Embodiment group 4 | 139 | Fine | Fine | Fine | 2.1 mm |
| Embodiment group 5 | 141 | Fine | Fine | Fine | 2.3 mm |
| Control group 1 | 120 | Good | Good | Fine | 1.8mm |
| Control group 2 | 100 | Poor | Poor | Poor | 1mm |
Data from table 1: use the stain control agent of embodiment of the present invention 1-5 to be coated on artificial slabstone, each test parameter is all better than conventional products assay, the stone protectant of embodiment of the present invention 1-5 has good anti-fouling effect to stone material, has improved the wearing quality of stone material; Compare with the stain control agent of control group 1, stain control agent of the present invention is all better than the stain control agent of control group 1 in water contact angle, the pollution of anti-coffee, the pollution of anti-soy sauce and perviousness, and stain control agent preparation of the present invention is simple, easy to use, does not need to dilute direct use before use.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. a fluorine-containing organic silicon stone anti-fouling agent, it is characterized in that, described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 90-130 weight part, fluorine silicon resin 20-35 weight part, fluorosilicon oil 10-30 weight part, dispersion wetting agent 5-10 weight part, defoamer 3-10 weight part, sanitas 1-5 weight part, silane coupling agent 1-5 weight part, film coalescence aid 10-25 weight part, color stuffing 1-5 weight part and thickening material 2-7 weight part.
2. fluorine-containing organic silicon stone anti-fouling agent according to claim 1, it is characterized in that, described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 90-115 weight part, fluorine silicon resin 25-35 weight part, fluorosilicon oil 10-21 weight part, dispersion wetting agent 5-8 weight part, defoamer 3-7 weight part, sanitas 1-3 weight part, silane coupling agent 1-3 weight part, film coalescence aid 10-17 weight part, color stuffing 1-3 weight part and thickening material 2-5 weight part.
3. fluorine-containing organic silicon stone anti-fouling agent according to claim 1 and 2, it is characterized in that, described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 106-130 weight part, fluorine silicon resin 20-31 weight part, fluorosilicon oil 17-30 weight part, dispersion wetting agent 7-10 weight part, defoamer 5-10 weight part, sanitas 2-5 weight part, silane coupling agent 2-5 weight part, film coalescence aid 15-25 weight part, color stuffing 2-5 weight part and thickening material 3-7 weight part.
4. according to the fluorine-containing organic silicon stone anti-fouling agent described in claim 1-3 any one, it is characterized in that, described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 105-125 weight part, fluorine silicon resin 23-31 weight part, fluorosilicon oil 15-25 weight part, dispersion wetting agent 6-9 weight part, defoamer 4-8 weight part, sanitas 2-4 weight part, silane coupling agent 2-4 weight part, film coalescence aid 13-21 weight part, color stuffing 2-4 weight part and thickening material 3-6 weight part.
5. according to the fluorine-containing organic silicon stone anti-fouling agent described in claim 1-4 any one, it is characterized in that, described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 116 weight parts, fluorine silicon resin 27 weight parts, fluorosilicon oil 21 weight parts, dispersion wetting agent 8 weight parts, defoamer 6 weight parts, sanitas 3 weight parts, silane coupling agent 3 weight parts, film coalescence aid 17 weight parts, color stuffing 3 weight parts and thickening material 4 weight parts.
6. according to the fluorine-containing organic silicon stone anti-fouling agent described in claim 1-5 any one, it is characterized in that, described stain control agent also comprises oxysuccinic acid and beeswax; Described stain control agent is comprised of the raw material of following ratio of weight and number: sherwood oil 90-130 weight part, fluorine silicon resin 20-35 weight part, oxysuccinic acid 5-12 weight part, fluorosilicon oil 10-30 weight part, beeswax 3-7 weight part, dispersion wetting agent 5-10 weight part, defoamer 3-10 weight part, sanitas 1-5 weight part, silane coupling agent 1-5 weight part, film coalescence aid 10-25 weight part, color stuffing 1-5 weight part and thickening material 2-7 weight part.
7. according to the fluorine-containing organic silicon stone anti-fouling agent described in claim 1-6 any one, it is characterized in that, described dispersion wetting agent is phosphoric acid, silicate, how joins one or more in polyvalent alcohol-many ethyleneimines segmented copolymer, sodium oleate and sulfonate in; Described defoamer is one or more in HT-606, HT-610 and NXZ.
8. according to the fluorine-containing organic silicon stone anti-fouling agent described in claim 1-7 any one, it is characterized in that, described sanitas is one or more in sodium rice silver, zinc oxide and magnesium oxide.
9. according to the fluorine-containing organic silicon stone anti-fouling agent described in claim 1-8 any one, it is characterized in that, described silane coupling agent is one or more in methacryloxy Trimethoxy silane, γ-isocyanic ester propyl-triethoxysilicane and γ-mercaptopropyl trimethoxysilane; Described film coalescence aid is one or more in epoxy soybean oil, clorafin, adjacent benzene dicaprylate and adjacent benzene dibutyrate; Described thickening material is one or both during sodium-chlor and carboxylic hydroxyl fiber are received; Described color stuffing is nano titanium oxide.
10. a preparation method for the fluorine-containing organic silicon stone anti-fouling agent as described in claim 1-9 any one, is characterized in that, described preparation method is: at room temperature, according to ratio of weight and number, take all raw materials, fully mix and can obtain stain control agent.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410031729.5A CN103756562B (en) | 2014-01-23 | 2014-01-23 | A kind of fluorine-containing organic silicon stone anti-fouling agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410031729.5A CN103756562B (en) | 2014-01-23 | 2014-01-23 | A kind of fluorine-containing organic silicon stone anti-fouling agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103756562A true CN103756562A (en) | 2014-04-30 |
| CN103756562B CN103756562B (en) | 2016-12-07 |
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| CN108300284A (en) * | 2017-08-23 | 2018-07-20 | 宁波千玉琉璃制品股份有限公司 | A kind of waterproof and oilproof coating |
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| CN107778939A (en) * | 2017-10-27 | 2018-03-09 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
| CN107778939B (en) * | 2017-10-27 | 2019-09-24 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
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