CN103725731A - Crystalline dextrose special for sodium gluconate and preparation method of crystalline dextrose - Google Patents
Crystalline dextrose special for sodium gluconate and preparation method of crystalline dextrose Download PDFInfo
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- CN103725731A CN103725731A CN201310742228.3A CN201310742228A CN103725731A CN 103725731 A CN103725731 A CN 103725731A CN 201310742228 A CN201310742228 A CN 201310742228A CN 103725731 A CN103725731 A CN 103725731A
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- temperature
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- crystallization
- liquid glucose
- crystallizer
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- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 title claims abstract description 146
- 239000008121 dextrose Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims description 15
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 title abstract 3
- 229940005574 sodium gluconate Drugs 0.000 title abstract 3
- 235000012207 sodium gluconate Nutrition 0.000 title abstract 3
- 239000000176 sodium gluconate Substances 0.000 title abstract 3
- 238000002425 crystallisation Methods 0.000 claims abstract description 116
- 230000008025 crystallization Effects 0.000 claims abstract description 102
- 238000010926 purge Methods 0.000 claims abstract description 40
- 238000005342 ion exchange Methods 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 35
- 238000001914 filtration Methods 0.000 claims abstract description 24
- 239000007788 liquid Substances 0.000 claims abstract description 24
- 238000001704 evaporation Methods 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 22
- 102000004169 proteins and genes Human genes 0.000 claims description 63
- 108090000623 proteins and genes Proteins 0.000 claims description 63
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 51
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 28
- 238000001816 cooling Methods 0.000 claims description 28
- 239000007787 solid Substances 0.000 claims description 28
- 239000000126 substance Substances 0.000 claims description 28
- 230000008020 evaporation Effects 0.000 claims description 21
- 239000006188 syrup Substances 0.000 claims description 21
- 235000020357 syrup Nutrition 0.000 claims description 21
- 238000002834 transmittance Methods 0.000 claims description 21
- 239000012452 mother liquor Substances 0.000 claims description 16
- 235000013336 milk Nutrition 0.000 claims description 15
- 239000008267 milk Substances 0.000 claims description 15
- 210000004080 milk Anatomy 0.000 claims description 15
- 239000002826 coolant Substances 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 238000002347 injection Methods 0.000 claims description 14
- 239000007924 injection Substances 0.000 claims description 14
- 239000011229 interlayer Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 239000008103 glucose Substances 0.000 claims description 12
- 229920002472 Starch Polymers 0.000 claims description 8
- 235000013305 food Nutrition 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 235000019698 starch Nutrition 0.000 claims description 8
- 239000008107 starch Substances 0.000 claims description 8
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 7
- 229920002261 Corn starch Polymers 0.000 claims description 7
- 102000004190 Enzymes Human genes 0.000 claims description 7
- 108090000790 Enzymes Proteins 0.000 claims description 7
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 claims description 7
- 102000004139 alpha-Amylases Human genes 0.000 claims description 7
- 108090000637 alpha-Amylases Proteins 0.000 claims description 7
- 229940024171 alpha-amylase Drugs 0.000 claims description 7
- 238000004061 bleaching Methods 0.000 claims description 7
- 229910001424 calcium ion Inorganic materials 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- 239000003610 charcoal Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000008120 corn starch Substances 0.000 claims description 7
- 238000005115 demineralization Methods 0.000 claims description 7
- 230000002328 demineralizing effect Effects 0.000 claims description 7
- 230000005611 electricity Effects 0.000 claims description 7
- 229940088598 enzyme Drugs 0.000 claims description 7
- 239000010419 fine particle Substances 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 7
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- 230000003068 static effect Effects 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 238000011033 desalting Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- -1 organic acid salt Chemical class 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Seasonings (AREA)
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CN201310742228.3A CN103725731B (en) | 2013-12-30 | 2013-12-30 | Special crystalline dextrose of Sunmorl N 60S and preparation method thereof |
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CN201310742228.3A CN103725731B (en) | 2013-12-30 | 2013-12-30 | Special crystalline dextrose of Sunmorl N 60S and preparation method thereof |
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CN103725731A true CN103725731A (en) | 2014-04-16 |
CN103725731B CN103725731B (en) | 2015-09-02 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104830918A (en) * | 2015-04-07 | 2015-08-12 | 山东西王糖业有限公司 | Novel production method of sodium gluconate |
CN104928405A (en) * | 2015-05-22 | 2015-09-23 | 山东祥瑞药业有限公司 | Technique for extracting glucose from starch saccharified liquid |
CN105483181A (en) * | 2015-12-28 | 2016-04-13 | 河南飞天农业开发股份有限公司 | Preparation method of high-purity glucose |
CN105821095A (en) * | 2015-09-14 | 2016-08-03 | 呼伦贝尔东北阜丰生物科技有限公司 | Optimization method for crystallization of glucose |
CN110835657A (en) * | 2019-11-15 | 2020-02-25 | 河南飞天农业开发股份有限公司 | Production process of low-oligosaccharide edible glucose |
CN111500794A (en) * | 2020-04-15 | 2020-08-07 | 潍坊盛泰药业有限公司 | Production method of water-containing glucose |
CN112159829A (en) * | 2020-10-29 | 2021-01-01 | 秦皇岛骊骅淀粉股份有限公司 | Glucose production process |
CN114015734A (en) * | 2021-10-31 | 2022-02-08 | 扬州明增生物科技有限公司 | Glucose separation and purification method |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6184003B1 (en) * | 1999-04-02 | 2001-02-06 | Roquette Freres | Process for preparing a crystalline α anhydrous dextrose of high purity |
CN101555508A (en) * | 2009-05-20 | 2009-10-14 | 湖南湘鲁万福农业开发有限公司 | Method for preparing crystalline dextrose by rice |
CN102703547A (en) * | 2012-06-14 | 2012-10-03 | 万福生科(湖南)农业开发股份有限公司 | Method for producing glucose bulk drug for injection by using rice |
-
2013
- 2013-12-30 CN CN201310742228.3A patent/CN103725731B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6184003B1 (en) * | 1999-04-02 | 2001-02-06 | Roquette Freres | Process for preparing a crystalline α anhydrous dextrose of high purity |
CN101555508A (en) * | 2009-05-20 | 2009-10-14 | 湖南湘鲁万福农业开发有限公司 | Method for preparing crystalline dextrose by rice |
CN102703547A (en) * | 2012-06-14 | 2012-10-03 | 万福生科(湖南)农业开发股份有限公司 | Method for producing glucose bulk drug for injection by using rice |
Non-Patent Citations (1)
Title |
---|
赵黎明主编: "《膜分离技术在食品发酵工业中的应用》", 31 July 2011, 北京:中国纺织出版社 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104830918A (en) * | 2015-04-07 | 2015-08-12 | 山东西王糖业有限公司 | Novel production method of sodium gluconate |
CN104928405A (en) * | 2015-05-22 | 2015-09-23 | 山东祥瑞药业有限公司 | Technique for extracting glucose from starch saccharified liquid |
CN105821095A (en) * | 2015-09-14 | 2016-08-03 | 呼伦贝尔东北阜丰生物科技有限公司 | Optimization method for crystallization of glucose |
CN105483181A (en) * | 2015-12-28 | 2016-04-13 | 河南飞天农业开发股份有限公司 | Preparation method of high-purity glucose |
CN110835657A (en) * | 2019-11-15 | 2020-02-25 | 河南飞天农业开发股份有限公司 | Production process of low-oligosaccharide edible glucose |
CN111500794A (en) * | 2020-04-15 | 2020-08-07 | 潍坊盛泰药业有限公司 | Production method of water-containing glucose |
CN112159829A (en) * | 2020-10-29 | 2021-01-01 | 秦皇岛骊骅淀粉股份有限公司 | Glucose production process |
CN114015734A (en) * | 2021-10-31 | 2022-02-08 | 扬州明增生物科技有限公司 | Glucose separation and purification method |
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CN103725731B (en) | 2015-09-02 |
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Denomination of invention: Special crystalline glucose for sodium gluconate and its preparation method Effective date of registration: 20201118 Granted publication date: 20150902 Pledgee: Agricultural Development Bank of China Qixian County branch Pledgor: HENAN FEITIAN AGRICULTURAL DEVELOPMENT Co.,Ltd. Registration number: Y2020990001356 |
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Denomination of invention: Sodium gluconate specific crystalline glucose and its preparation method Effective date of registration: 20230913 Granted publication date: 20150902 Pledgee: Agricultural Development Bank of China Qixian County branch Pledgor: Henan Feitian Biotechnology Co.,Ltd. Registration number: Y2023980056241 |
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