CN103725225A - Flame-retardant hot-melt adhesive - Google Patents
Flame-retardant hot-melt adhesive Download PDFInfo
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- CN103725225A CN103725225A CN201310505560.8A CN201310505560A CN103725225A CN 103725225 A CN103725225 A CN 103725225A CN 201310505560 A CN201310505560 A CN 201310505560A CN 103725225 A CN103725225 A CN 103725225A
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Abstract
The invention discloses a flame-retardant hot-melt adhesive. The adhesive is prepared from raw materials in parts by weight as follows: 5-7 parts of octyl phenolic resin 203, 13-15 parts of tertiary butyl phenolic resin 204, 1-2 parts of angelica oil, 0.1-0.3 part of polyisobutyl succinimide, 55-65 parts of Sumitomo SV210 EVA (ethylene vinyl-acetate copolymer), 1-2 parts of antimonous oxide, 1-5 parts of an ultraviolet light absorber UV-P and 1-2 parts of flame-retardant filler. A produced hot-melt adhesive product is excellent in flame-retardant effect, little in fuming, resistant to ultraviolet aging and capable of being widely produced, used as the hot-melt adhesive for automobile interior parts and bonded to composite woven materials.
Description
Technical field
The invention belongs to binding agent field, relate in particular to a kind of flame-retardant hot-melt adhesive.
Background technology
In recent years, the application of the novel materials such as matrix material and plastics on automobile made automobile stick with glue agent and the also sustainable growth of seal gum consumption, and wherein automotive upholstery is the field that tackiness agent consumption increases rapidly.The demand of automotive upholstery hot melt adhesive is more and more.
Summary of the invention
The object of this invention is to provide a kind of flame-retardant hot-melt adhesive.
The present invention adopts following technical scheme to achieve these goals:
A flame-retardant hot-melt adhesive, is characterized in that, it is that raw material by following weight parts makes:
Octyl phenol urea formaldehyde 203 5-7, tert butyl phenolic resin 204 13-15, Radix Angelicae Sinensis oil 1-2, polyisobutenyl succimide 0.1-0.3, SUMITOMO CHEMICAL SV210 EVA 55-65, antimonous oxide 1-2, Ultraviolet Absorber UV-P 1-5, flame-retardant filler 1-2;
Flame-retardant filler is made by the raw material of following weight parts: brucite powder 15-20, neatly stone flour 2-4, siliceous fine sand 8-12, zinc naphthenate 0.2-0.4, calcium lignin sulphonate 0.1-0.2, dioctyl sebacate 1-2, Sodium Fluoride 0.3-0.6, magnesium hydroxide 4-6, aluminium hydroxide 3-5, silicon carbide 0.8-0.9, sepiolite powder 1-2, polypropylene fibre 1-2, alcohol ether glucoside 0.3-0.5;
The preparation method of described flame-retardant filler is: preparation method soaks 8-10 hour by brucite powder, neatly stone flour, siliceous fine sand in clear water, takes out, dry, at 600-700 ℃, calcine 2-3 hour again, take out, hydro-oxidation magnesium, aluminium hydroxide and suitable quantity of water, grind evenly, adding 10-15% sodium hydroxide solution tune pH is 8.5-9.5, ground slurry, to 600-700 order, then adds hydrochloric acid soln and is adjusted to neutrality, dry, mix with surplus stock, ground and mixed evenly and get final product again.
A flame-retardant hot-melt adhesive, is characterized in that:
Preparation process is:
SUMITOMO CHEMICAL SV210EVA, polyisobutenyl succimide are put into blender and mix standbyly, the raw material after mixing is put into kneader, at 180-190 ℃, mediate 5-7 minute, add again surplus stock at 190-200 ℃, mediate after 10-12 minute, obtain.
Beneficial effect of the present invention: the hot melt adhesive product flame retardant effect that the present invention produces is excellent, is fuming few, and anti-ultraviolet aging can widespread production be used as automotive upholstery hot melt adhesive, and compound woven material bonds.
Embodiment
A flame-retardant hot-melt adhesive, it is that raw material by following weight kg makes:
Octyl phenol urea formaldehyde 203 5, tert butyl phenolic resin 204 15, Radix Angelicae Sinensis oil 1, polyisobutenyl succimide 0.3, SUMITOMO CHEMICAL SV210 EVA 65, antimonous oxide 1.3, Ultraviolet Absorber UV-P 1, flame-retardant filler 1;
Flame-retardant filler is made by the raw material of following weight kg: brucite powder 20, neatly stone flour 4, siliceous fine sand 12, zinc naphthenate 0.4, calcium lignin sulphonate 0.2, dioctyl sebacate 1, Sodium Fluoride 0.3, magnesium hydroxide 6, aluminium hydroxide 3, silicon carbide 0.8, sepiolite powder 1, polypropylene fibre 2, alcohol ether glucoside 0.5;
The preparation method of described flame-retardant filler is: preparation method soaks brucite powder, neatly stone flour, siliceous fine sand 10 hours in clear water, takes out, dry, at 700 ℃, calcine 3 hours again, take out, hydro-oxidation magnesium, aluminium hydroxide and suitable quantity of water, grind evenly, adding 10% sodium hydroxide solution tune pH is 9.5, after ground slurry to 600 order, then add hydrochloric acid soln and be adjusted to neutrality, dry, mix with surplus stock, ground and mixed evenly and get final product again.
Described a kind of flame-retardant hot-melt adhesive, preparation process is:
SUMITOMO CHEMICAL SV210 EVA, polyisobutenyl succimide are put into blender and mix standbyly, the raw material after mixing is put into kneader, at 190 ℃, mediates 7 minutes, then adds surplus stock at 200 ℃, mediates after 10 minutes, obtains.
The apparent viscosity of the binding agent of the present embodiment is 4700MPa.s, stripping strength 54N/2.5cm
2, initial bonding strength reaches steel ball No. 5, open hour 39s, and within 24 hours, thermally-stabilised proterties is stable.
Claims (2)
1. a flame-retardant hot-melt adhesive, is characterized in that, it is that raw material by following weight parts makes:
Octyl phenol urea formaldehyde 203 5-7, tert butyl phenolic resin 204 13-15, Radix Angelicae Sinensis oil 1-2, polyisobutenyl succimide 0.1-0.3, SUMITOMO CHEMICAL SV210 EVA 55-65, antimonous oxide 1-2, Ultraviolet Absorber UV-P 1-5, flame-retardant filler 1-2;
Flame-retardant filler is made by the raw material of following weight parts: brucite powder 15-20, neatly stone flour 2-4, siliceous fine sand 8-12, zinc naphthenate 0.2-0.4, calcium lignin sulphonate 0.1-0.2, dioctyl sebacate 1-2, Sodium Fluoride 0.3-0.6, magnesium hydroxide 4-6, aluminium hydroxide 3-5, silicon carbide 0.8-0.9, sepiolite powder 1-2, polypropylene fibre 1-2, alcohol ether glucoside 0.3-0.5;
The preparation method of described flame-retardant filler is: preparation method soaks 8-10 hour by brucite powder, neatly stone flour, siliceous fine sand in clear water, takes out, dry, at 600-700 ℃, calcine 2-3 hour again, take out, hydro-oxidation magnesium, aluminium hydroxide and suitable quantity of water, grind evenly, adding 10-15% sodium hydroxide solution tune pH is 8.5-9.5, ground slurry, to 600-700 order, then adds hydrochloric acid soln and is adjusted to neutrality, dry, mix with surplus stock, ground and mixed evenly and get final product again.
2. a kind of flame-retardant hot-melt adhesive according to claim 1, is characterized in that:
Preparation process is:
SUMITOMO CHEMICAL SV210 EVA, polyisobutenyl succimide are put into blender and mix standbyly, the raw material after mixing is put into kneader, at 180-190 ℃, mediate 5-7 minute, add again surplus stock at 190-200 ℃, mediate after 10-12 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310505560.8A CN103725225A (en) | 2013-10-24 | 2013-10-24 | Flame-retardant hot-melt adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310505560.8A CN103725225A (en) | 2013-10-24 | 2013-10-24 | Flame-retardant hot-melt adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103725225A true CN103725225A (en) | 2014-04-16 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310505560.8A Pending CN103725225A (en) | 2013-10-24 | 2013-10-24 | Flame-retardant hot-melt adhesive |
Country Status (1)
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| CN (1) | CN103725225A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927741A (en) * | 2015-06-17 | 2015-09-23 | 南通和和塑胶新材料有限公司 | Novel flame-retarding hot-melt adhesive film and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997017410A1 (en) * | 1995-11-09 | 1997-05-15 | Raychem Limited | Flame-retarded adhesive composition |
| CN102618211A (en) * | 2012-04-10 | 2012-08-01 | 浙江固特热熔胶有限公司 | Hot melt adhesive used for automotive interiors, and preparation method of hot melt adhesive |
| CN103013390A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special nano-garamite based binder for compounding synthetic leather on automotive upholstery surface |
| CN103013391A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special modified nano expanded vermiculite powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN103013387A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special dioctyl maleate binder for composite woven fabric on surface of automobile interior part |
-
2013
- 2013-10-24 CN CN201310505560.8A patent/CN103725225A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997017410A1 (en) * | 1995-11-09 | 1997-05-15 | Raychem Limited | Flame-retarded adhesive composition |
| CN102618211A (en) * | 2012-04-10 | 2012-08-01 | 浙江固特热熔胶有限公司 | Hot melt adhesive used for automotive interiors, and preparation method of hot melt adhesive |
| CN103013390A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special nano-garamite based binder for compounding synthetic leather on automotive upholstery surface |
| CN103013391A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special modified nano expanded vermiculite powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN103013387A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special dioctyl maleate binder for composite woven fabric on surface of automobile interior part |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927741A (en) * | 2015-06-17 | 2015-09-23 | 南通和和塑胶新材料有限公司 | Novel flame-retarding hot-melt adhesive film and preparation method thereof |
| CN104927741B (en) * | 2015-06-17 | 2017-10-27 | 南通和和塑胶新材料有限公司 | A kind of novel flame-retardant hot melt adhesive film and preparation method thereof |
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Application publication date: 20140416 |
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