CN103710953A - Fabric with infrared management characteristic and preparation method thereof - Google Patents
Fabric with infrared management characteristic and preparation method thereof Download PDFInfo
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- CN103710953A CN103710953A CN201210378067.XA CN201210378067A CN103710953A CN 103710953 A CN103710953 A CN 103710953A CN 201210378067 A CN201210378067 A CN 201210378067A CN 103710953 A CN103710953 A CN 103710953A
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Abstract
The invention relates to fabric with an infrared management characteristic and a preparation method thereof. The invention provides a novel functional fabric design method. The key to the novel functional fabric design method is that thermal insulation property adjustment of the fabric is achieved by designing a fabric surface structure and modifying infrared radiation characteristics of the fabric surface through utilization of a functional material. A fabric infrared management characteristic concept is also provided. The objective of the invention is to provide a feasible technology and a finishing scheme to achieve the goal that the fabric has two different infrared radiation characteristics, so as to achieve different infrared management functions. The preparation method includes 1) when starting from yarn: steps of subjecting a portion of yarn and fiber to infrared reinforcement treatment, designing the fabric structure and weaving, baking the fabric and washing the fabric with water to obtain a final product; and 2) when starting from the fabric: steps of subjecting the two surfaces of the fabric to infrared radiation differentiation finishing, baking the fabric and washing the fabric with water to obtain a final product.
Description
Technical field
The present invention relates to a kind of Design & preparation method of functional textile.The method, by fabric specifically being arranged or selects to have the yarn of specific function or yarn being carried out to specific finishing functions, designs different fabric structures simultaneously and has different infrared signatures to reach the fabric two sides of making.
Technical background
No matter directly or indirectly, the sun provides the needed energy for tellurian all life.The high sun being suspended in sky, its surface temperature, up to 6000 ℃, is launched the electromagnetic wave of a plurality of frequency ranges incessantly, comprising ultraviolet, visible ray and infrared ray.Correspond to the gross energy that the sun arrives the earth, ultraviolet band accounts for 6.8% gross energy (0.5%UVB, 6.3%UVA); 38.9% Energy distribution is at visible light wave range; About 54.3% Energy distribution is at infrared band.
Clothes in wearing process ceaselessly the skin of human body contact, affect the wet exchange of heat between human body and environment.In the past few decades, consumer sees by dressing well the requirement of clothes, and being transformed into not only will dress well sees also will wear comfortable.Therefore for physiological effect just being become to considerably important after all clothes dressings.The research first having has shown that the multi-direction transmission characteristic (the aqueous water management characteristic of fabric) of aqueous water in clothes has significant impact to the comfortableness of dressing.The most basic function of clothes is exactly the changes in temperature that regulate us, resists extraneous variations in temperature.
Because behaving, be a homeothermal animal, our body temperature need to maintain in a very narrow region, if surpass this scope, will feel uncomfortable, even dead.The research first having shows, when our skin surface mean temperature is at 33 ℃ to 35 ℃ and while there is no sweat on its surface, we can feel comfortably cool conventionally.Human body and environment carry out heat exchange and conventionally in following three kinds of modes, carry out: convection current, conduction and radiation.Conduction mode is to realize by the interaction in short distance between molecule or electronics; Also there is certain conduction with mixing in the mechanical flow that convection current combines fluid simultaneously; When heat energy transmits in the mode of radiation, be to realize at infrared spectrum with electromagnetic form.First there is research to point out the infrared transmission characteristic of fabric and the overall comfort of dressing to have certain relation, and affect the mean temperature of skin.
Therefore being just necessary to develop a kind ofly novel can have to skin surface temperature the functional fabric of certain regulating power.For example, under summer burning sun hot weather, main thermal source comes from the sun that includes outside line frequency range, wants to make people to have nice and cool sensation, and garment material need to can be reflected back the infrared radiation of arrival in environment as much as possible.The sweat of human body surface is delivered to as much as possible to the outer surface of fabric simultaneously, and carries out that volatile zone is walked heat so that wearer's skin keeps nice and cool at outer surface.On the other hand, outdoor main thermal source is human body self in the winter time.Clothes need to be reflected back the infra-red radiation that comes from human body human body to retain heat.For certain some specific purposes, routine military use need to will all be covered the infrared-ray shielding as far as possible of object.
Energy can be with electromagnetic wave, convection current, and these three kinds of modes of radiation are carried out.The radiation mode transmitting with electromagnetic mode is that one group of atom is transmitted in space in the mode of fluctuation, so heat energy just can be propagated and not need medium at vacuum state as solar energy.Infrared ray is to propagate with linear fashion, and its wavelength ratio is wide as seen.
What infrared ray represented is the electromagnetic wave within the scope of certain frequency, starts from the upper limit of visible red, terminates in the emblem ripple that is generally used for communication, wave-length coverage at 1 millimeter to 750 nanometers.Whole infrared band can further be divided into near-infrared again, in infrared, three wave bands of far infrared.
0.076-1.5microns=near-infrared (NIR);
1.5-5.6microns=in infrared (MIR); With
5.6-1000microns=far infrared (FIR).
All objects more than absolute zero all can be continuously outside emitting electromagnetic wave, its wavelength is relevant with the temperature of body surface.The radiation of object is all to exist with ultrared form at ambient temperature, and seldom the form with visible ray occurs.The infra-red radiation dominant wavelength ranges of human body self is at 9 to 10 microns under normal circumstances.
Work as infrared radiation source, for example sunshine includes whole frequency spectrum, and when it arrives fabric face, energy not only comprises the energy IR (I of infrared band
ir) also comprise the energy (I of other wave band
other) (Fig. 1).On the other hand, after cloth specimen absorbs energy, its temperature by continuing, rise and again its two surface emitting go out extra infrared energy.Therefore the infrared light intensity of transmission can be expressed as:
I
t＝I
dt+I
et (1)
Infrared light intensity on reflecting surface can be expressed as simultaneously:
I
r＝I
dr+I
er (2)
In formula: I
dtand I
drthe direct reflection and transmission intensity (W/m of material performance
2).What Iet and Ier represented specimen surface launches light intensity (W/m again
2).
Retrieval according to us to United States Patent (USP) storehouse, relevant heat retention of the fabric can conduct extensive research.Some patented technology, for example, 5,150,476,6,662,389 improve warmth retention property by increasing still air layer to realize. patent 6,662, and 389 have applied for a kind of side that realizes variable thermal property; Patent 6,312,784 more point out to utilize shape-memory material to regulate the warming characteristic of fabric.Patent 6,583,074,5,534,335 instructed a kind of by fabric with metal fibre or change the warming characteristic of fabric by the method for coating; Patent application 20030057750, introduced one make automotive seat nice and cool realize technique; Patent 5,787,525 instructed a kind of with multiply cloth structure and add therein the method for tourmaline to change the infrared signature of fabric.Patent 5,787,525 have instructed at a kind of ceramic powder that adds in shoe-pad to strengthen the product processes of its infrared signature.
The 200710025087.8 1 kinds of heat accumulation thermal wovens that can breathe of patent disclose a kind of heat accumulation thermal woven that can breathe, are provided with on the outer surface drying layer; Inner surface is provided with heat-sink shell.On inner surface to add the mixed solution of the ultra-fine porcelain powder that possesses heat accumulation function to carry out cloth cover in possessing the resin liquid of high breathable moisture permeability, the sweat that fabric is had stop extraneous hardships and human body is distributed is delivered to extraneous function in the mode of water vapour, having avoided forming steam between inside of human body and fabric gathers and causes human body sensory humid, in addition, ultra-fine porcelain powder in inner surface heat-sink shell distributes heat energy by solar infrared heat energy and human body and absorbs on fabric, thereby play, holder temperature compensation is filled and constant effect.99119037.8 have reported a kind of weaving face fabric of three-decker, comprise three-decker, and inside and outside two-layer is woven, and intermediate layer is gasket material; Skin is the woven fabric consisting of combing cotton yarn, and intermediate layer is the gasket material consisting of with nonwoven form polyester low stretch sex pilus, and nexine is to become far infrared yarn and the fabric of woven one-tenth by cotton-polyester blend.Because nexine adopts far-infrared functional sexual health fiber, while therefore wearing next to the skin, can adjust microcirculation in human body, enhance metabolism.Patent 201010130765.9 intelligent temperature-regulation garments relate to a kind of intelligent temperature-regulation garment, comprise fabric and lining, temperature controller and the heating element heater being connected with rechargeable battery, have certain far-infrared physiotherapy effect.Patent 200910031492.X improved structure of breathable heat insulating fabric discloses a kind of improved structure of breathable heat insulating fabric, fabric top layer is the hygroscopic yarn of tool, fabric nexine is that the hygroscopic yarn braiding of the warming febrifacient yarn of tool and tool forms, and the fabric panel structure after fabric top layer and the braiding of fabric nexine is two-sided air layer structure.
According to our result for retrieval, all previous patented technologies all do not have instruction how to revise the infrared characteristic on fabric two sides, make it two sides characteristic different, thereby the difference of utilizing this two sides characteristic realizes the fabric that difference in functionality needs, so method and concept that we propose in this article have its former innovation and novelty.
Summary of the invention
Core of the present invention is to have proposed a kind of new function fabric method for designing, thereby it is the design of fabric face structure at all and utilizes functional material to modify and knit the thermal property that surperficial infrared signature is realized adjusting fabric.This concept of the infrared management characteristic of fabric has been proposed.This concept definition is as follows:
Infra-red radiation management fabric
Fabric two surfaces have specially designed infrared signature, because thereby these specially designed infrared signatures make infrared external reflection and the different transmission characteristic that makes fabric have the ability to make heat energy of transmission capacity on fabric two sides, the particularly radiation capacity of heat transmission is controlled, thereby has influence on the overall heat transfer characteristic of fabric.Such fabric is referred to as infrared management fabric.
This kind fabric is by the characteristic being achieved as follows:
(1) the two different infrared signature in surface
(2) super nice and cool, or
(3) super warm, or
(4) high insulation
For realizing above-mentioned target, in the present invention, infrared management characteristic surface material is mainly divided into two large classes: cool fabric (SCF) and Calefaction type fabric (SWF).
Affect the wear the clothes infrared radiation source of thermal comfort of people and mainly contain two kinds, a kind of is to come from the external high temperature sources such as the sun; Not a kind of is to come from self (Fig. 2).Solar radiation I
0be included in the energy I of infrared band
irwith its wave band energy I
others. under identical air penetrability condition, when radiation luminous energy (comprising visible ray and non-visible light) arrives fabric face, a part will be reflected back toward (I in atmosphere
fre), part energy will be absorbed by fabric and again emit, and strive and will directly penetrate fabric (I for one simultaneously
fte). simultaneously when fabric is through with it, the infrared ray (I that human body self emits
se) partly will be reflected back health (I by fabric
ser), (I partly
set) will be through in fabric entered environment.
In order to make there is nice and cool sensation in the process of dress, fabric is near the side of skin, and being defined as inner surface should have lower transmissivity, and has higher reflectivity at its another side (being defined by outer surface).In this case, the infrared energy that mainly comes from the sun will be reflected back toward environment and makes the temperature rise of fabric inner surface relatively low.
On the other hand, in wearing process, keep warm sensation, its infrared characteristic of fabric is with above-mentioned contrary.Main infrared radiation source is from human body.Therefore the inner surface of fabric need to have higher reflectivity, human-body emitting infrared energy is out reflected back, and have outer surface also to have lower reflection characteristic so that fabric absorbs more infrared energy (Fig. 3).
Therefore by following method, realize the infrared signature of two, fabric modified in the present invention:
1, cool fabric has bright and clean outer surface and soft coarse inner surface;
2, warm-keeping type shell fabric has soft coarse outer surface and bright and clean inner surface;
3, utilize specific technique and auxiliary agent to carry out infrared finishing functions to fabric, yarn or fiber;
4, by given institutional framework, carry out fabric preparation.
Accompanying drawing explanation
Fig. 1 is the transmission of infrared-ray on a fabric cloth;
Fig. 2 is cool fabric structure design diagram;
Fig. 3 is the infrared management fabric structure of warming-type design concept figure;
Fig. 4 is cotton fiber surface SEM pattern photo before processing;
Fig. 5 is cotton fiber surface topography SEM photo after processing;
Fig. 6 is x-ray spectroscopy analyzer analysis result.
The specific embodiment
The object of this invention is to provide a kind of feasible technique and ordering plan and there are two different infrared signatures to realize fabric, to reach different infrared management functions.This comprises the following steps or flow process:
1, by yarn, set out: the infrared enhancing processing → fabric texture of part yarn, fiber and bake → fabric of weaving → fabric wash water → final products;
2, by fabric, set out: fabric two is flushing bake → fabric of the differential arrangement → fabric of external radiation wash water → final products.
Preliminary finish to yarn or fiber, its objective is its infra-red radiation ability of improving, thereby the organizational structure design that coordinates fabric with the yarn that does not have to process and fiber reaches two masks of fabric, has maximized infrared signature difference.
The Main Ingredients and Appearance of knitting infrared signature enhancing formula for fiber, yarn comprises:
(1) infrared reinforcing material 1-300g/L
(2) fiber surface can be modified auxiliary agent 0-100g/L
(3) adhesive 0-50g/L
(4) crosslinking agent 0-50g/L
(5) thickener 0-50g/L
(6) dispersant 0-50g/L
(7) other (water)
In this formula, material used can be any known substance meeting the demands, concrete example is as follows: for infrared enhancing functional material, can be any known but be not limited to known infrared enhancing nano material, can be for example Nano Silver, Zr02, Zn0 and A1203 etc.Conventionally this type of metal inorganic nano material can also provide extra function as anti-ultraviolet or antibacterial.
Dispersant can be fat alcohol ethoxyl compound or fatty acid ethoxy compound or Ethanol Ethoxylation compound etc.Crosslinking agent can be the organic chemistry goods with two or more free hydroxyl groups, such as polyethylene glycol etc.; Adhesive, thickener can be any known chemical productss.It can be hydrophilic finishing auxiliaries that fiber surface can be modified auxiliary agent, also can be hydrophobic type finishing auxiliaries, they can be, but be for example not limited to water imbibition quaternaries cation softener, organosilicon hydrophilic finishing agent, anionic hydrophilic silicone fabric finishing agent, fluorinated polymer, paraffin-slaine water repellent, contains the metal coordination valence solvay-type water repellent of LCFA etc.
Traditional fiber yarn finishing technique is all applicable to this processing.
It is mainly to form different infrared signatures owing to causing unique heat energy transmission characteristic for two surfaces at fabric that fabric of the present invention carries out its object of organizational structure design.Further develop this concept, rear finishing technique also can be applied in the present invention to realize single-sided fabric finishing, thereby realizes the inconsistent of two infrared signatures.The method conventional to single-sided fabric finishing can be, but be not limited to serigraphy, spraying, coating etc.
The fabric that further, multilayer can be had to a Different Red external characteristics is fit together and is formed different infrared management characteristics by compound method.For example smooth fine and closely woven light woven fabric and dark fluffy knit fabric can be carried out compound, thereby form different infra-red radiation heat transfer characteristics.
Further develop this concept, more single-sided fabric finishing technology also may be served new differential function for webbing again.For example such arrangement can be in the inventor's US Patent No. 6806,214, US6, and 454,814B1 and US6,499,338B2 finds detailed explanation and application, and has realized the difference transmission of aqueous water between fabric two surfaces.
In order to carry out performance characterization to preparing resulting function fabric, at this, there is the instrument of two characteristics to use.One is fabric aqueous water management characteristic, and concrete introduction can be referring to inventor's patent US6499338, and this instrument can be for detection of aqueous water multidirectional transmission characteristic between fabric two surfaces.Another instrument is fabric infrared signature measuring instrument (FIRT, China Patent No. ZL200410068752.8).This instrument can be used for measuring the infrared signature of two, fabric.The cardinal principle of this instrument is that the infrared intensity on its two surface will change, and by recording the variation of the infrared intensity on two surfaces, can obtain a series of for describing the index of fabric infrared characteristic when fabric is under a given infrared radiation source radiation.
Example one
Pure-cotton woven fabric carries out infrared signature modification with the method for serigraphy.That wherein infrared functional material adopts is Zn0,10g/L (weight ratio is made by oneself by The Hong Kong Polytechnic University).Then sample after processing roasts for condition in 15 minutes with 90 ℃ of oven dry is 135 ℃, 3 minutes.
Cotton fiber is processed front and rear surfaces pattern as shown in Figure 4, Figure 5.X-ray spectroscopy analyzer (Energy dispersive X-ray spectroscopy (Oxford Link ISIS EDX System)) is used to the composition of fabric surface material after check processing, and its measurement result is as shown in figure six.Measurement result discloses fabric face and contains element zinc and oxygen.
In laboratory with FIRT to before processing with process after sample carry out infrared characteristic measurement, it the results are summarized in table one.
The textile woven infrared signature of table 1 measurement result
From table one, we can find, the measured value before contrast is processed has increased by 40% in starting stage infrared external reflection light intensity (IEDR), and infrared transmission light intensity (IEDT) has only increased by 0.12% and absorb light intensity and reduced by 9.99%.When fabric infra-red radiation reaches after balance, in its infra-red radiation light intensity (IERMS) of reflecting surface of fabric, increased by 17%, and its infra-red radiation light intensity (IEET) of transmission plane has reduced nearly 1%.
Example two
Terylene knitted fabric is coated in nano-functional material STK the surface (STK is by Zhoushan a kind of nano silver antibacterial material that tomorrow, group produced) of fabric with the method for screen printing with the ratio of 25 grams per liters.Then with 90 ℃, dry 10 minutes, 135 ℃ bake 3 minutes.Its infrared signature as shown in Table 2.
Table two polyester knitting thing infrared signature measured value
Contrast process before sample in measurement value, the sample infrared external reflection amount (IEDR) after processing in the starting stage has reduced by 11%, transmission amount (IEDT) increased by 1.6% and uptake increased by 3.32%.When fabric reaches after balance, the average infrared intensity of reflecting surface (IERMS) has reduced 8%..And in transmission plane infrared intensity (IEET), increased by the approximately 8% total radiation intensity in while fabric two sides and increased by 5.39%, the difference of two sides infrared intensity has increased by 13%.
Example three
Utilize the method for coating to carry out finishing functions to cotton ball woll fabric.Functional material is A1
2o
3(MC2R, nano material Co., Ltd will produce by tomorrow) consumption is 40g/L.Then fabric after processing dry 3mins at 100 ℃ bakes 3mins at 140 ℃.That processes is measured and is recorded in table 3 by fabric infrared characteristic tester with untreated fabric.
The cotton ball woll fabric of table 3 infrared characteristic measurement result
Shown in table 3, contrast untreated sample, at starting stage infrared external reflection intensity (IEDR) and intensity in transmission (IEDT), declined respectively 34% and 59%.Absorption intensity has increased by 38%.Arrive steady-state process, the average emitted intensity (IERMS) of reflecting surface increased by 25%. simultaneously its infrared emittances of transmission plane also increased approximately 14%.
Example four
Two layers of cloth of polyester fibre cotton are carried out to finishing functions in the mode of coating.Functional material is that AT0 (Sb adulterate Sn02) (being provided by The Hong Kong Polytechnic University) processes with 20g/L consumption.Then fabric after processing is dry at 100 ℃ bakes 3 minutes in 3 minutes at 140 ℃.That processes is measured and is recorded in table 4 by fabric infrared characteristic tester with untreated fabric.
Table 4 cotton woven infrared characteristic measurement result
Shown in table 4, contrast undressed sample, in the starting stage, infrared external reflection intensity (IEDR) and the intensity in transmission (IEDT) of treated its reflecting surface of sample have reduced respectively 44% and 73.3%.Absorption intensity has increased by 54%.Arrive after balance the average infrared intensity (IERMS) on reflecting surface increased by 98%. and the infrared transmission strength increase on the surface of emission 79%.
Example five
Terylene non-woven fabric is processed finishing functions liquid on the surface of fabric with the method for spraying.The formula of processing is as follows:
(1) the infrared powder of 50g/L A1203 nanometer (MC2R understands that by Zhoushan group provides)
(2) the infrared powder of 30/L Zn0 nanometer (MN6Z, s understands that by Zhoushan group provides)
(3) 30g/L thickener A-1, (Beijing engineering plastics Co., Ltd)
(4) 12g/L adhesive, (printing adhesive, Zhejiang auxiliary chemicals company)
(5) other: water
Nonwoven fabric after processing is dried 5 minutes and at 125 ℃, bakes 3 minutes at 100 ℃.The measurement data record of manager and the rear sample of processing is not in table 5.
Table 5 non-woven infrared measurement characteristics
By table 5, we can find the sample before contrast is processed, sample after processing has strengthened 50% in its infrared external reflection intensity (IEDR) of starting stage, transmission infrared intensity (IEDT) reduced 18% and absorption intensity also reduced 1.4%. and reach balance and close, the infrared intensity of average reflection face (IERMS) has increased by 34%.And the infrared intensity at transmission plane has only increased by 7%.Two sides infrared intensity is poor has reached 26.66%.
Example six
This type of infrared functional fabric can also be processed by the infrared enhancing to part yarn except being realized by afterfinish method, as required the yarn after the infrared processing of this part is utilized to the organizational structure design of fabric, make its major part in the one side of fabric, and not do not process can Different Red external characteristics yarn major part at the another side of fabric, thereby realize the difference of the infrared signature of two, fabric.Thread material is warp thread 100D terylene.Weft yarn 20S cotton jeans yarn and 83.3dex polypropylene fibre.Entering latitude order is: third falls: cotton: the third=1: 1: 1.The final composition of fabric is that cotton 45%, the third falls 25%, and terylene 30% its representation is 100DX (20s+83.3dtex)/55.1ends/cm X90ends/cm.
Warp thread is ordinary polyester, and weft yarn carries out infrared enhancing processing by following technique.
Formula:
(1) 80g/L A1203 (MC2R understands that by Zhoushan group provides)
(2) 30g/L thickener A-1, (Beijing engineering plastics Co., Ltd)
(3) 12g/L adhesive, (printing adhesive, Zhejiang auxiliary chemicals company)
(4) other: water
Processing mode: 100 ℃ of oven dry, 130 ℃ bake 5 minutes.
Example seven
White cotton 60S yarn plain fabric and black polar fleece fabric carry out a subsides mode and carry out compound.When using spring and summer, white cotton fabric, towards the solar time, can be improved infrared albedo reduction radiant heat is delivered to skin surface; If in autumn and winter, on the contrary by black polar fleece in the face of to the sun, increase fabric infrared absorbability to external world.
Example eight
On the basis of example two, in order further to strengthen infrared management effect, further strengthen the difference of fabric two sides structure and how much patterns.After having completed infrared enhancing arrangement, then the one side of terylene fabric is carried out to sanding processing.Traditional roughing process makes reference in this citation.According to the fabric of producing, to the difference of hot delivery request, can carry out sanding processing to the face of fabric or the end, thereby further improve infrared property.
Claims (9)
1. the invention relates to a kind of design and production method that is referred to as infrared management fabric, it is characterized in that two surface red external radiations of fabric are inconsistent in the infrared intensity of its starting stage and equilibrium stage fabric two tables.
2. according to claim 1, the institutional framework of fabric can be knitting, tatting, nonwoven fabric and composite material.
3. according to claim 1, material can be synthetic fiber or natural fabric.
4. according to claim 1, fabric can be single layer structure or sandwich construction.
5. according to claim 1, this type of infrared fabric can carry out different infrared characteristic arrangements by pair warp and weft yarn, then utilize the design of fabric structure to make two surfaces of the different yarn major part minute other places fabric of two groups of infrared characteristics, thereby reach, make the infrared characteristic on fabric two surfaces variant.
6. according to claim 1, the difference of fabric two surperficial infrared signatures can also be by carrying out arranging realization after one side to a certain surface of fabric, and these method for sorting comprise, spraying, silk-screen, coating etc.
7. according to claim 1 and 2, the method can be used for preparing cool fabric, and the characteristic of this type of fabric is that the outer surface of fabric has smooth structure, higher infrared external reflection characteristic, and surface has softness and lower intensity in transmission within it.
8. according to claim 1 and 2, the method also can be used for preparing warm-keeping type shell fabric, and the characteristic of this type of fabric is that the inner surface of fabric has smooth structure, compared with high infrared external reflection characteristic, at its outer surface, has softness and lower intensity in transmission.
9. according to claim 1 and 9, this infrared finishing functions can be mutually compound with other finishing functions.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106364016A (en) * | 2016-08-25 | 2017-02-01 | 浙江鑫涛科技股份有限公司 | Multifunctional shell fabric |
| CN106863957A (en) * | 2015-12-10 | 2017-06-20 | 群天企业有限公司 | Luminous energy fabric |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106863957A (en) * | 2015-12-10 | 2017-06-20 | 群天企业有限公司 | Luminous energy fabric |
| CN106863957B (en) * | 2015-12-10 | 2019-03-01 | 群天企业有限公司 | Luminous energy fabric |
| CN106364016A (en) * | 2016-08-25 | 2017-02-01 | 浙江鑫涛科技股份有限公司 | Multifunctional shell fabric |
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Application publication date: 20140409 |