CN103709888A - Radiation resistant and anti-aging amino resin paint for copper sculptures - Google Patents

Abstract

The invention relates to a paint, and specifically relates to a radiation resistant and anti-aging amino resin paint for copper sculptures. The paint is composed of the following raw materials in parts by weight: 30 to 34 parts of amino resin, 3 to 5 parts of polyethylene wax, 4 to 6 parts of tebuconazole, 1 to 2 parts of ferrocene, 14 to 16 parts of 1,6-hexamethylene diacrylate, 1 to 2 parts of nano alumina, 4 to 5 parts of dipentaerythritol hexaacrylate, 6 to 8 parts of inositol hexaphosphate, 10 to 12 parts of iron oxide red, 6 to 9 parts of dipropylenetriamine, 2 to 3 parts of monobutyl tin oxide, 1 to 2 parts of cross-linking agent TAC, 5 to 6 parts of auxiliary agent, 10 to 12 parts of xylene, and 10 to 12 parts of butyl acetate. The paint has the advantages of high film hardness, good film toughness, bright and long-lasting color and luster, hot resistance, cold resistance, radiation-aging resistance, and simple production technology, and can be used to protect various kinds of copper handicrafts.

Description

The aging copper sculpture of a kind of radioprotective paints with aminoresin

Technical field

The present invention relates to a kind of paint, be specifically related to aminoresin paint and preparation technology thereof for the aging copper sculpture of a kind of radioprotective.

Background technology

Copper sculpture is a class artwork common in daily life, there is higher artistic value and enjoying value, yet, copper sculpture artwork is due to itself material character and the feature of putting environment, easily there is the problems such as oxidation corrosion, affect attractive in appearance and work-ing life, in order to protect bronze, brass or copper ware, often need to varnish with lacquer in sculpture outside, and copper sculpture is had to certain requirement with paint, such as sticking power, weather-proof aging, resistance to sunlight exposure, heatproof etc., therefore, need to improve paint formulation, make the paint that is applicable to different use occasions, increase its artistic value.

Summary of the invention

The object of the invention is to, provide the aging copper sculpture of a kind of radioprotective to paint with aminoresin, to protect sculpture, to achieve these goals, the technical solution used in the present invention is as follows:

The aging copper sculpture of a kind of radioprotective paints with aminoresin, it is characterized in that, material of the present invention is made by the raw material of following weight part: aminoresin 30-34, polyethylene wax 3-5, tebuconazole 4-6, ferrocene 1-2,1,6 hexanediyl ester 14-16, nano-aluminium oxide 1-2, double pentaerythritol methacrylate 4-5, myo-Inositol hexaphosphate 6-8, red iron oxide 10-12, two propylene triamine 6-9, Mono-n-butyltin 2-3, linking agent TAC1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.

Described auxiliary agent is made by the raw material of following weight part: clay 10-12, diatomite 3-4, jade 2-3, sepiolite 2-3, vulkacit D TDM1-2, linking agent TAC2-3, sebacic acid sodium 1-2, alkylphenol polyoxyethylene 4-5, tripoly phosphate sodium STPP 1-2, Vanay 35-40, vanadium diboride 1-2, Tenox PG 1-2, coix seed oil 2-3, l-Epicatechol 1-2; Its preparation method is that clay, diatomite, jade, sepiolite are sent in calcining furnace and calcine 2-3 hour at 700-720 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filter, obtain filter residue, with clear water, clean, dry, grind to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.

The described aging copper sculpture of a kind of radioprotective paints with aminoresin, and its preparation technology is:

(1) tebuconazole, 1,6 hexanediyl ester, nano-aluminium oxide, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 ℃, adds polyethylene wax, double pentaerythritol methacrylate, Mono-n-butyltin, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.

Compared with prior art, copper sculpture provided by the invention is painted possesses following advantage: hardness of paint film is high, good toughness, and bright in color is lasting, heat-resisting cold-resistant, anti-radiation aging, and production technique is relatively simple, can be widely used in all kinds of bronze handicrafts.

Embodiment

Embodiment

The present embodiment paint is made by following weight part raw material: aminoresin 34, polyethylene wax 5, tebuconazole 6, ferrocene 2,1,6 hexanediyl ester 16, nano-aluminium oxide 2, double pentaerythritol methacrylate 5, myo-Inositol hexaphosphate 8, red iron oxide 12, two propylene triamines 8, Mono-n-butyltin 3, linking agent TAC2, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.

Described auxiliary agent is made by the raw material of following weight part: clay 12, diatomite 4, jade 3, sepiolite 3, vulkacit D TDM2, linking agent TAC3, sebacic acid sodium 2, alkylphenol polyoxyethylene 5, tripoly phosphate sodium STPP 2, Vanay 40, vanadium diboride 2, Tenox PG 2, coix seed oil 3, l-Epicatechol 2; Its preparation method is that clay, diatomite, jade, sepiolite are sent in calcining furnace and at 700-720 ℃, calcined 3 hours, then, takes out, send in 15% hydrochloric acid soln and soak 3 hours, filter, obtain filter residue, with clear water, clean, dry, grind to form 500 order powders; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 50 minutes is cooling, grinds to form slurry, obtains.

The described aging copper sculpture of a kind of radioprotective paints with aminoresin, and its preparation technology is:

(1) tebuconazole, 1,6 hexanediyl ester, nano-aluminium oxide, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, react 4 hours;

(2) material of step (1) is cooled to 70-85 ℃, adds polyethylene wax, double pentaerythritol methacrylate, Mono-n-butyltin, stirring reaction 4 hours;

(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, stirring reaction, after 60 minutes, is cooled to room temperature, grinds to form 50 μ m slurries, obtains.

The performance test results of the present invention's paint is:

Above-mentioned test is all followed relevant criterion and is carried out.

Claims (2)

1. the aging copper sculpture of radioprotective paints with aminoresin, it is characterized in that, this paint is made by the raw material of following weight part: aminoresin 30-34, polyethylene wax 3-5, tebuconazole 4-6, ferrocene 1-2,1,6 hexanediyl ester 14-16, nano-aluminium oxide 1-2, double pentaerythritol methacrylate 4-5, myo-Inositol hexaphosphate 6-8, red iron oxide 10-12, two propylene triamine 6-9, Mono-n-butyltin 2-3, linking agent TAC 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12;

Described auxiliary agent is made by the raw material of following weight part: clay 10-12, diatomite 3-4, jade 2-3, sepiolite 2-3, vulkacit D TDM 1-2, linking agent TAC 2-3, sebacic acid sodium 1-2, alkylphenol polyoxyethylene 4-5, tripoly phosphate sodium STPP 1-2, Vanay 35-40, vanadium diboride 1-2, Tenox PG 1-2, coix seed oil 2-3, l-Epicatechol 1-2; Its preparation method is that clay, diatomite, jade, sepiolite are sent in calcining furnace and calcine 2-3 hour at 700-720 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filter, obtain filter residue, with clear water, clean, dry, grind to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.

2. the aging copper sculpture of a kind of radioprotective as claimed in claim 1 paints with aminoresin, and its manufacture craft is:

(1) tebuconazole, 1,6 hexanediyl ester, nano-aluminium oxide, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 ℃, adds polyethylene wax, double pentaerythritol methacrylate, Mono-n-butyltin, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.