CN103708665B - Renewable energy source associating hotting mask coupling sea water desaltination and salt making system - Google Patents

Renewable energy source associating hotting mask coupling sea water desaltination and salt making system Download PDF

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CN103708665B
CN103708665B CN201310677609.8A CN201310677609A CN103708665B CN 103708665 B CN103708665 B CN 103708665B CN 201310677609 A CN201310677609 A CN 201310677609A CN 103708665 B CN103708665 B CN 103708665B
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seawater desalination
low
temperature multi
water
effect
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CN103708665A (en
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李崇超
任显龙
刘娜
李睿
董慧
王新鹏
曾庆才
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Harbin Boiler Co Ltd
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Harbin Boiler Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/138Water desalination using renewable energy
    • Y02A20/141Wind power
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

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Abstract

The present invention relates to a kind of renewable energy source associating hotting mask coupling sea water desaltination and salt making system.Utilizing the renewable energy source such as wind energy and the sun to solve sea water desaltination is research direction, but wind energy has obvious fluctuation and intermittence, therefore wind energy is directly used in the technical limitation that sea water desaltination needs to overcome some necessity.Composition of the present invention comprises: aerogenerator (1), solar heat power generation system, aerogenerator, solar heat power generation system connect and compose associating electric supply installation with wind/light complementation controller (2), described electric supply installation connects remaining electrical storage cell (3), and described electric supply installation connects seawater desalination system, the salt making system be connected with described seawater desalination system and mineralizing device, described electric supply installation and connects civilian electrical equipment (4).The present invention utilizes renewable energy source associating hotting mask coupling seawater desalination system to obtain desalination water and halogen is carried in salt manufacturing.

Description

Renewable energy source associating hotting mask coupling sea water desaltination and salt making system
technical field:
the present invention relates to a kind of renewable energy source associating hotting mask coupling sea water desaltination and salt making system.
background technology:
current desalination technology comparative maturity, but sea water desaltination belongs to the intensive industry of energy consumption, and operation energy consumption height is one of major reason hindering sea water desaltination industry to develop rapidly in China.Current desalination technology mainly uses the conventional energy resources such as electric power and steam, utilizes the renewable energy source such as wind energy and the sun to be do not solve the important means of sea water desaltination high energy consumption.But wind energy has obvious fluctuation and intermittence, therefore wind energy is directly used in the technical limitation that sea water desaltination needs to overcome some necessity.Because meteorological conditions reason solar energy optical-thermal also can exist electricity shortage, be difficult to ensure reliable and stable water supply.
reverse osmosis seawater desalting and low-temperature multi-effect evaporation seawater desalinization are desalination technologies main in the world at present.Reverse osmosis seawater desalting water inlet is comparatively large by the impact of temperature, declines comparatively large in northern China winter low temperature environment water production rate, the steady running of influential system.Low-temperature multi-effect evaporation seawater desalinization device mainly consumes steam, and the general extracted steam from turbine that adopts as the heat source of device, but can affect the generating efficiency of steam turbine, reduces power station whole efficiency.
conventional salt pan efficiency of evaporating brine is low, and climate impact is larger.While hotting mask coupling seawater desalination system produces the fresh water required for us, the concentrated of high power is carried out to residual seawater, if directly discharge will produce long-range impact to surrounding sea areas ecotope.Utilize seawater concentrated solution to carry out evaporating brine and can improve efficiency of evaporating brine greatly, the extraction to the chemical substance such as bromine, Repone K in seawater can also be carried out.
to shortage of fresh water area, especially coastal regional with island, electrical network weak foundation, these areas generally have abundant wind energy, solar energy resources simultaneously, wind energy, sun power are directly used in sea water desaltination, the shortage of fresh water of restriction Economic development can be solved on the one hand, the impact to electrical network that another aspect can avoid wind-powered electricity generation, sun power large-scale grid connection is brought.Utilize concentrated solution also can produce the addition products such as salt, bromine, Repone K simultaneously, by the foundation of this system, energy conservation and eco-friendly Sustainable development can be realized.
summary of the invention:
the object of this invention is to provide a kind of renewable energy source associating hotting mask coupling sea water desaltination and salt making system, solve coastal and area, island fresh water is not enough and electrical network weak foundation, regular seawater desalination energy consumption is high etc. problem; Wind-powered electricity generation and the independent power supply instability problem of sun power; Reverse osmosis seawater desalting to supply water the problems such as poor stability winter; The problems such as strong brine discharge influence ecological environment.Realize the supply of the stable energy of seawater desalination system, reduce sea water desaltination energy consumption, optimize seawater desalination system, productive life fresh water is provided, utilizes strong brine salt manufacturing and carry halogen.
above-mentioned object is realized by following technical scheme:
a kind of renewable energy source associating hotting mask coupling sea water desaltination and salt making system, its composition comprises: aerogenerator, solar heat power generation system, described aerogenerator, described solar heat power generation system connect and compose associating electric supply installation with wind/light complementation controller, described electric supply installation connects remaining electrical storage cell, and described electric supply installation connects seawater desalination system, the salt making system be connected with described seawater desalination system and mineralizing device, described electric supply installation and connects civilian electrical equipment.
described renewable energy source associating hotting mask coupling sea water desaltination and salt making system, described solar heat power generation system comprises solar attachment, described solar attachment is connected with vapour generator, and described vapour generator is connected with steam turbine, and steam turbine is connected with generator.
described renewable energy source associating hotting mask coupling sea water desaltination and salt making system, described seawater desalination system is seawater desalination system by film method, comprise pretreating device, described pretreating device is connected with reverse osmosis equipment, the salt solution outlet pipeline of described reverse osmosis equipment connects salt manufacturing and proposes halogen equipment, the connection of fresh water outlet pipeline connection mineralizing device, and described electric supply installation connects the power device of seawater desalination system.
described renewable energy source associating hotting mask coupling sea water desaltination and salt making system, described seawater desalination system is hot method seawater desalination system, utilize the exhaust steam in solar light-heat power-generation system after the acting of Steam Actuation steam turbine as the thermal source of low-temperature multi-effect evaporation seawater desalinization system, using the condenser of low-temperature multi-effect vaporizer as turbine driven set, the wherein heat air entrance of low-temperature multi-effect vaporizer, is connected to the exhaust steam outlet of steam turbine; The entrance of described steam turbine is connected to the vapour side outlet of described low-temperature multi-effect vapour generator; The water side entrance of described low-temperature multi-effect vapour generator is connected to described low-temperature multi-effect vaporizer head effect condensation-water drain, forms described solar energy thermal-power-generating water circulation system; Described low-temperature multi-effect vaporizer is connected with condenser, and described condenser connects raw material seawater water intake system; First evaporator in low-temperature multi-effect vaporizer in described hot method seawater desalination system is as the condenser of solar heat power generation system, condensate line is connected to the admission port of the low-temperature multi-effect producer in solar heat power generation system, and the fresh water line of evaporative condenser is connected to mineralizing device.
described renewable energy source associating hotting mask coupling sea water desaltination and salt making system, in described low-temperature multi-effect vaporizer, after evaporation of seawater, remaining strong brine is connected with condenser refrigerated sea water pipeline and is connected to the water-in of seawater desalination system by film method; Water inlet pipe in the solid flooding pipe of the low-temperature multi-effect vaporizer of described hot method seawater desalination system and described seawater desalination system by film method all connects the preheating pipeline of described condenser, described condenser inlet pipeline connects raw material seawater water intake system, and the thermal source pipeline of described condenser is connected to the pipeline of the steam of the last evaporator generation of described low-temperature multi-effect vaporizer.
described renewable energy source associating hotting mask coupling sea water desaltination and salt making system, the fresh water line of described low-temperature multi-effect vaporizer and the generation of described seawater desalination system by film method converges, and the pipeline connection after converging enters mineralizing device and obtains qualified tap water.
described renewable energy source associating hotting mask coupling sea water desaltination and salt making system, the strong brine pipeline of described low-temperature multi-effect vaporizer and the generation of seawater desalination system by film method converges, and the pipeline after converging is connected to salt manufacturing or carries halogen equipment.
beneficial effect:
1. the present invention adopts " wind-power electricity generation & solar energy thermal-power-generating complementary system+reverse osmosis & low-temperature multi-effect evaporation seawater desalinization+salt manufacturing " system, wind energy and these renewable energy sources of sun power are utilized to carry out sea water desaltination, overcoming wind energy and sun power by using wind and solar hybrid generating system powers separately by the larger problem of natural environment influence, for reverse osmosis seawater desalination system and other electrical equipments provide stable electric energy; The water quality requirement of the water quality different with the fresh water that Membrane seawater desalination subsystem is produced separately according to low-temperature multi-effect evaporation seawater desalinization and difference water spot, properly distributed treating product water.Low-temperature multi-effect evaporation seawater desalinization produces the relatively high user of water supply water quality requirement, the user that membrane method sea-water-desalination water producing supply water quality requirement is relatively low, obtain qualified tap water after entering mineralizing device after can mixing simultaneously, while improving water quality, also can reduce aftertreatment expense.Utilize the concentrated strong brine salt manufacturing of hotting mask coupling sea water desaltination high power can improve salt manufacturing efficiency, extract bromine and Repone K etc., eliminate strong brine while obtaining valuable product and discharge the impact that ocean environment is caused.
the present invention utilizes the exhaust steam in solar light-heat power-generation system after the acting of Steam Actuation steam turbine as the thermal source of low-temperature multi-effect evaporation seawater desalinization system, using the condenser of low-temperature multi-effect vaporizer as turbine driven set, reduce operation and the cost of investment of power generation system, reduce simultaneously and make water cost;
3. the dense water of low-temperature multi-effect device of the present invention and the mixing of condenser refrigerated sea water, as the water inlet of reverse osmosis seawater desalting, i.e. MED(multiple-effect evaporation)+SWRO(sea-water reverse osmose) PROCESS COUPLING technique, effectively can ensure water production rate requirement when reverse osmosis desalination device runs in the winter time, improve the rate of recovery of whole seawater desalination system simultaneously;
4. the present invention is by utilizing this renewable energy source of wind energy, sun power, carry out the hotting mask coupling sea water desaltination of low-temperature multi-effect evaporation reverse osmosis, the dense water out that low-temperature multi-effect vaporizer produces together is connected to salt manufacturing together with the dense water out to the reverse osmosis equipment in Membrane seawater desalination subsystem or carries halogen equipment and carries out salt manufacturing, extracts bromine and Repone K etc.It is high that this system has utilising efficiency, and operation energy consumption is low, high financial profit, on the advantage of environment without impact.
accompanying drawing illustrates:
accompanying drawing 1 is front view of the present invention.In figure, 1 be aerogenerator, 2 be wind/light complementation controller, 3 for store battery, 4 make a living apply flexibly electric system, 5 be generator, 6 be steam turbine, 7 be vapour generator, 8 be solar energy thermal-power-generating subsystem, 9 be low-temperature multi-effect vaporizer, 10 be condenser, 11 be pretreating device, 12 be reverse osmosis equipment, 13 for salt manufacturing or carry halogen equipment, 14 be mineralizing device, 15 be seawater desalination system by film method for producing the mouth of a river, 16,17 for raw material seawater water intake system.
embodiment:
embodiment 1:
a kind of renewable energy source associating hotting mask coupling sea water desaltination and salt making system, its composition comprises: aerogenerator 1, solar heat power generation system, described aerogenerator, described solar heat power generation system connect and compose associating electric supply installation with wind/light complementation controller 2, described electric supply installation connects remaining electrical storage cell 3, and described electric supply installation connects seawater desalination system, the salt making system be connected with described seawater desalination system and mineralizing device, described electric supply installation and connects civilian electrical equipment 4.
the positive and negative end of store battery is connected to wind/light complementation controller respectively, can be stored in store battery if the electric energy of generation has during affluence; When electric power is not enough, also by battery discharging, can run for equipment through wind/light complementation controller.
embodiment 2:
renewable energy source associating hotting mask coupling sea water desaltination described in embodiment 1 and salt making system, solar heat power generation system 8 comprises solar attachment, described solar attachment is connected with vapour generator, described vapour generator 7 is connected with steam turbine, and steam turbine 6 is connected with generator 5.
the two ends of the heat-conducting medium of solar power system are connected to the two ends of vapour generator respectively, as the thermal source of vapour generator.
embodiment 3:
renewable energy source associating hotting mask coupling sea water desaltination described in embodiment 1 and salt making system, described seawater desalination system is seawater desalination system by film method, comprise pretreating device, described pretreating device is connected with reverse osmosis equipment, the salt solution outlet pipeline of described reverse osmosis equipment connects salt manufacturing and proposes halogen equipment, the connection of fresh water outlet pipeline connection mineralizing device, and described electric supply installation connects the power device of seawater desalination system.
embodiment 4:
renewable energy source associating hotting mask coupling sea water desaltination described in embodiment 1 and salt making system, described seawater desalination system is hot method seawater desalination system, wherein the heat air entrance of low-temperature multi-effect vaporizer, is connected to the exhaust steam outlet of steam turbine; The entrance of described steam turbine is connected to the vapour side outlet of described low-temperature multi-effect vapour generator; The water side entrance of described low-temperature multi-effect vapour generator is connected to described low-temperature multi-effect vaporizer head effect condensation-water drain, forms described solar energy thermal-power-generating water circulation system; Described low-temperature multi-effect vaporizer is connected with condenser, and described condenser connects raw material seawater water intake system; First evaporator in low-temperature multi-effect vaporizer in described hot method seawater desalination system is as the condenser of solar heat power generation system, condensate line is connected to the admission port of the low-temperature multi-effect producer in solar heat power generation system, and the fresh water line of evaporative condenser is connected to mineralizing device.
embodiment 5:
renewable energy source associating hotting mask coupling sea water desaltination described in embodiment 4 and salt making system, in described low-temperature multi-effect vaporizer, after evaporation of seawater, remaining strong brine is connected with condenser refrigerated sea water pipeline, and be connected to the water-in of seawater desalination system by film method, as the part water source of Membrane seawater desalination.; Water inlet pipe in the solid flooding pipe of the low-temperature multi-effect vaporizer of described hot method seawater desalination system and described seawater desalination system by film method all connects the preheating pipeline of described condenser, described condenser inlet pipeline connects raw material seawater water intake system, and the thermal source pipeline of described condenser is connected to the pipeline of the steam of the last evaporator generation of described low-temperature multi-effect vaporizer.
the water intaking pipeline of the former seawater of raw material seawater water intake system is connected to the water side-entrance (as low-temperature receiver) of condenser, after heating, be divided into two portions, and the water side entrance of part access low-temperature multi-effect vaporizer, as the water source of hot method sea water desaltination.Another part is connected to the water-in of seawater desalination system by film method, as another part water source of Membrane seawater desalination.
embodiment 6:
renewable energy source associating hotting mask coupling sea water desaltination described in embodiment 4 or 5 and salt making system, the fresh water line of described low-temperature multi-effect vaporizer and the generation of described seawater desalination system by film method converges, and the pipeline connection after converging enters mineralizing device and obtains qualified tap water.
the steam that in low-temperature multi-effect vaporizer, evaporation of seawater produces is connected to the vapour side entrance of condenser, and as the thermal source of condenser, condensed water converges with water of condensation in low-temperature multi-effect vaporizer, and a part supplies water quality requirement high user.The user that reverse osmosis produced water part supply water quality requirement is relatively low.The low-temperature multi-effect evaporation vaporizer remainder reverse osmosis equipment remainder produced in water and Membrane seawater desalination subsystem produces water and converges, and obtains qualified tap water after mineralizing device, or directly with using it for anything else.
embodiment 7:
renewable energy source associating hotting mask coupling sea water desaltination described in embodiment 4 or 5 and salt making system, the strong brine pipeline of described low-temperature multi-effect vaporizer and the generation of seawater desalination system by film method converges, and the pipeline after converging is connected to salt manufacturing or carries halogen equipment.

Claims (4)

1. a kind of renewable energy source associating hotting mask coupling sea water desaltination and salt making system, its composition comprises: aerogenerator, solar heat power generation system, it is characterized in that: described aerogenerator, described solar heat power generation system connect and compose associating electric supply installation with wind/light complementation controller, described electric supply installation connects remaining electrical storage cell, and described electric supply installation connects seawater desalination system, the salt making system be connected with described seawater desalination system and mineralizing device, described electric supply installation and connects civilian electrical equipment;
described solar heat power generation system comprises solar attachment, and described solar attachment is connected with vapour generator, and described vapour generator is connected with steam turbine, and steam turbine is connected with generator;
described seawater desalination system is seawater desalination system by film method, comprise pretreating device, described pretreating device is connected with reverse osmosis equipment, the salt solution outlet pipeline of described reverse osmosis equipment connects salt manufacturing and proposes halogen equipment, the connection of fresh water outlet pipeline connection mineralizing device, and described electric supply installation connects the power device of seawater desalination system;
described seawater desalination system is hot method seawater desalination system, utilize the exhaust steam in solar light-heat power-generation system after the acting of Steam Actuation steam turbine as the thermal source of low-temperature multi-effect evaporation seawater desalinization system, using the condenser of low-temperature multi-effect vaporizer as turbine driven set, the wherein heat air entrance of low-temperature multi-effect vaporizer, is connected to the exhaust steam outlet of steam turbine; The entrance of described steam turbine is connected to the vapour side outlet of described low-temperature multi-effect vapour generator; The water side entrance of described low-temperature multi-effect vapour generator is connected to described low-temperature multi-effect vaporizer head effect condensation-water drain, forms described solar energy thermal-power-generating water circulation system; Described low-temperature multi-effect vaporizer is connected with condenser, and described condenser connects raw material seawater water intake system; First evaporator in low-temperature multi-effect vaporizer in described hot method seawater desalination system is as the condenser of solar heat power generation system, condensate line is connected to the admission port of the low-temperature multi-effect producer in solar heat power generation system, and the fresh water line of evaporative condenser is connected to mineralizing device.
2. renewable energy source associating hotting mask coupling sea water desaltination according to claim 1 and salt making system, is characterized in that: in described low-temperature multi-effect vaporizer, after evaporation of seawater, remaining strong brine is connected with condenser refrigerated sea water pipeline and is connected to the water-in of seawater desalination system by film method; Water inlet pipe in the solid flooding pipe of the low-temperature multi-effect vaporizer of described hot method seawater desalination system and described seawater desalination system by film method all connects the preheating pipeline of described condenser, described condenser inlet pipeline connects raw material seawater water intake system, and the thermal source pipeline of described condenser is connected to the pipeline of the steam of the last evaporator generation of described low-temperature multi-effect vaporizer.
3. renewable energy source associating hotting mask coupling sea water desaltination according to claim 1 and 2 and salt making system, it is characterized in that: the fresh water line of described low-temperature multi-effect vaporizer and the generation of described seawater desalination system by film method converges, the pipeline connection after converging enters mineralizing device and obtains qualified tap water.
4. renewable energy source associating hotting mask coupling sea water desaltination according to claim 1 or 2 and salt making system, it is characterized in that: the strong brine pipeline of described low-temperature multi-effect vaporizer and the generation of seawater desalination system by film method converges, the pipeline after converging is connected to salt manufacturing or carries halogen equipment.
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