CN103700892B - Maitenance-free colloid lead-acid accumulator is efficiently internalized into charge technology - Google Patents

Maitenance-free colloid lead-acid accumulator is efficiently internalized into charge technology Download PDF

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Publication number
CN103700892B
CN103700892B CN201310719065.7A CN201310719065A CN103700892B CN 103700892 B CN103700892 B CN 103700892B CN 201310719065 A CN201310719065 A CN 201310719065A CN 103700892 B CN103700892 B CN 103700892B
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Prior art keywords
charging
maitenance
acid accumulator
time
free colloid
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CN201310719065.7A
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CN103700892A (en
Inventor
任建成
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YANGZHOU YONGDA POWER Co Ltd
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YANGZHOU YONGDA POWER Co Ltd
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H01M10/446—Initial charging measures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Charge And Discharge Circuits For Batteries Or The Like (AREA)

Abstract

The invention discloses a kind of maitenance-free colloid lead-acid accumulator and be efficiently internalized into charge technology, comprise the steps: to leave standstill, in added battery standing 60min; 0.1～1.5I10 current charges, 10～60min for charging for the first time; Charging for the second time, electric current is by descending 0.5～1.0I10, the 30～45h that charges that is down in three stages within the scope of 2.5～1.5I10; Discharge for the first time with 2.5～2.0I10 current discharge, 1～2h; Charging for the third time, electric current is down to 0.5～1.0I10, the 10～15h that charges by descending point three or four-stage within the scope of 2.5～1.5I10. Maitenance-free colloid lead-acid accumulator disclosed by the invention is efficiently internalized into charge technology, improved lead-acid accumulator and be internalized into the production efficiency of production; Solve the larger problem of internal formation process occupied ground, and the consumption of a large amount of cooling waters, battery production energy consumption reduced.

Description

Maitenance-free colloid lead-acid accumulator is efficiently internalized into charge technology
Technical field
The present invention relates to a kind of battery production technology, particularly solve the problems such as to be internalized into the charging interval long, and efficiency is low,Realize the large-scale production of internal formation process, provide a kind of maitenance-free colloid lead-acid accumulator to be efficiently internalized into charge technology.
Background technology
Maitenance-free colloid lead-acid accumulator chemical synthesis technology changes into (pole plate changes into) and is internalized into (battery outside being roughly divided at presentChange into), be current general charge technology and change into outward, and the benefit charging interval that ripe pole plate is assembled into after battery also need48h～72h; But internal formation process is also not general, changes into the time long yet simultaneously, conventionally the time more than 120h, and inChemical synthesis technology occupied ground is larger, and the consumption of a large amount of cooling waters, and battery production energy consumption is large, has increased enterprise's production cost.
Summary of the invention
It is long to the object of the invention is to solve the maitenance-free colloid container formation process for lead acid storage battery time, and production efficiency is low,Take plant area larger, the problems such as energy consumption height, provide a kind of maitenance-free colloid lead-acid accumulator to be efficiently internalized into and to fillGalvanic process.
The present invention is internalized into the adjustment of battery formation charging pattern mainly for maitenance-free colloid lead-acid accumulator.
The technical solution adopted in the present invention is: provide a kind of maitenance-free colloid lead-acid accumulator to be efficiently internalized into chargingTechnique, comprises the steps:
1) leave standstill, in added maitenance-free colloid lead-acid accumulator standing 60min;
2) charging for the first time, by 0.1～1.5I10 current charges, the charging interval is 10～60min;
3) charging for the second time, electric current is entered by the descending 0.5～1.0I10 that is down in three stages within the scope of 2.5～1.5I10Row charging, the charging interval is 30～45h;
4) electric discharge for the first time, with 2.5～2.0I10 current discharge, be 1～2h discharge time;
5) charging for the third time, electric current by descending point three or four-stage within the scope of 2.5～1.5I10 be down to 0.5～1.0I10 charges, and the charging interval is 10～15h;
As preferably, the whole process operation time≤60h of described internal formation process, the time of being internalized into be controlled at 60h withIn, improve production efficiency.
As preferably, in the whole process of described internal formation process, maitenance-free colloid lead-acid accumulator temperature must not exceed 60DEG C, ensure the safety in maitenance-free colloid lead-acid accumulator charge and discharge process.
As preferably, the total charge volume of described internal formation process maitenance-free colloid lead-acid accumulator is in 7 of accumulator capacityTo 9 times, the battery capacity of maitenance-free colloid lead-acid accumulator can be maximized.
As preferably, in the whole process of described internal formation process, charging voltage must not be higher than 16.5V, and discharge voltage must notLower than 12V.
The invention has the beneficial effects as follows,
1,, by maitenance-free colloid lead-acid accumulator being internalized into the adjustment of battery formation charging pattern, be internalized into time controlIn 60h, thereby improve maitenance-free colloid lead-acid accumulator and be internalized into the production efficiency of production.
2, to be internalized into the time shorter for maitenance-free colloid lead-acid accumulator, solved maitenance-free colloid lead-acid accumulator and be internalized intoThe problem that technique occupied ground is larger, and the consumption of a large amount of cooling waters, reduced battery production energy consumption, thereby reduced enterpriseProduction cost.
Detailed description of the invention
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the present invention is further detailed explanation. BelowEmbodiment is only for technical scheme of the present invention is more clearly described, and can not limit the scope of the invention with this.
Specific embodiments of the invention 1 are,
Step Charging current Time Temperature Voltage
Leave standstill - ＜60min - -
Charging 0.1～1.5I10 10～60min ≤60℃ ≤16.5V
Charging 2.5I10 10h ≤60℃ ≤16.5V
Charging 2.0I10 8h20min ≤60℃ ≤16.5V
Charging 1.5I10 4h ≤60℃ ≤16.5V
Charging 0.5～1.0I10 7h40min ≤60℃ ≤16.5V
Electric discharge 2.5～2.0I10 1～2h ≤60℃ ≥12V
Charging 2.5I10 4h ≤60℃ ≤16.5V
Charging 2.0I10 2h40min ≤60℃ ≤16.5V
Charging 1.5I10 2h ≤60℃ ≤16.5V
Charging 0.5～1.0I10 1h20min ≤60℃ ≤16.5V
Finish - - - -
Specific embodiments of the invention 2 are,
Step Charging current Time Temperature Voltage
Leave standstill - ＜60min - -
Charging 0.1～1.5I10 10～60min ≤60℃ ≤16.5V
Charging 2.5I10 15h40min ≤60℃ ≤16.5V
Charging 2.0I10 10h ≤60℃ ≤16.5V
Charging 1.5I10 8h ≤60℃ ≤16.5V
Charging 0.5～1.0I10 11h20min ≤60℃ ≤16.5V
Electric discharge 2.5～2.0I10 1～2h ≤60℃ ≥12V
Charging 2.5I10 5h40min ≤60℃ ≤16.5V
Charging 2.0I10 3h ≤60℃ ≤16.5V
Charging 1.5I10 2h20min ≤60℃ ≤16.5V
Charging 0.5～1.0I10 4h ≤60℃ ≤16.5V
Finish - - - -
Specific embodiments of the invention 3 are,
Step Charging current Time Temperature Voltage
Leave standstill - ＜60min - -
Charging 0.1～1.5I10 10～60min ≤60℃ ≤16.5V
Charging 2.5I10 12h ≤60℃ ≤16.5V
Charging 2.0I10 10h ≤60℃ ≤16.5V
Charging 1.5I10 6h20min ≤60℃ ≤16.5V
Charging 0.5～1.0I10 8h10min ≤60℃ ≤16.5V
Electric discharge 2.5～2.0I10 1～2h ≤60℃ ≥12V
Charging 2.5I10 4h ≤60℃ ≤16.5V
Charging 2.0I10 2h40min ≤60℃ ≤16.5V
Charging 1.5I10 3h30min ≤60℃ ≤16.5V
Charging 0.5～1.0I10 2h20min ≤60℃ ≤16.5V
Finish - - - -
Specific embodiments of the invention 4 are,
Step Charging current Time Temperature Voltage
Leave standstill - ＜60min - -
Charging 0.1～1.5I10 10～60min ≤60℃ ≤16.5V
Charging 2.5I10 10h ≤60℃ ≤16.5V
Charging 2.0I10 8h20min ≤60℃ ≤16.5V
Charging 1.5I10 4h ≤60℃ ≤16.5V
Charging 0.5～1.0I10 7h40min ≤60℃ ≤16.5V
Electric discharge 2.5～2.0I10 1～2h ≤60℃ ≥12V
Charging 2.5I10 3h ≤60℃ ≤16.5V
Charging 2.0I10 1h20min ≤60℃ ≤16.5V
Charging 1.5I10 2h ≤60℃ ≤16.5V
Charging 1.0I10 1h40min ≤60℃ ≤16.5V
Charging 0.5～1.0I10 2h ≤60℃ ≤16.5V
Finish - - - -
Specific embodiments of the invention 5 are,
Step Charging current Time Temperature Voltage
Leave standstill - ＜60min - -
Charging 0.1～1.5I10 10～60min ≤60℃ ≤16.5V
Charging 2.5I10 15h40min ≤60℃ ≤16.5V
Charging 2.0I10 10h ≤60℃ ≤16.5V
Charging 1.5I10 8h ≤60℃ ≤16.5V
Charging 0.5～1.0I10 11h20min ≤60℃ ≤16.5V 3 -->
Electric discharge 2.5～2.0I10 1～2h ≤60℃ ≥12V
Charging 2.5I10 4h ≤60℃ ≤16.5V
Charging 2.0I10 3h20min ≤60℃ ≤16.5V
Charging 1.5I10 2h ≤60℃ ≤16.5V
Charging 1.0I10 1h40min ≤60℃ ≤16.5V
Charging 0.5～1.0I10 4h ≤60℃ ≤16.5V
Finish - - - -
Specific embodiments of the invention 6 are,
Step Charging current Time Temperature Voltage
Leave standstill - ＜60min - -
Charging 0.1～1.5I10 10～60min ≤60℃ ≤16.5V
Charging 2.5I10 12h ≤60℃ ≤16.5V
Charging 2.0I10 10h ≤60℃ ≤16.5V
Charging 1.5I10 6h20min ≤60℃ ≤16.5V
Charging 0.5～1.0I10 8h10min ≤60℃ ≤16.5V
Electric discharge 2.5～2.0I10 1～2h ≤60℃ ≥12V
Charging 2.5I10 4h ≤60℃ ≤16.5V
Charging 2.0I10 2h10min ≤60℃ ≤16.5V
Charging 1.5I10 2h ≤60℃ ≤16.5V
Charging 1.0I10 1h20min ≤60℃ ≤16.5V
Charging 0.5～1.0I10 3h ≤60℃ ≤16.5V
Finish - - - -
As preferably, the whole process operation time≤60h of internal formation process, the time of being internalized into is controlled in 60h, carriesHigh production efficiency.
As preferably, in the whole process of internal formation process, maitenance-free colloid lead-acid accumulator temperature must not exceed 60 DEG C,Ensure the safety in maitenance-free colloid lead-acid accumulator charge and discharge process.
As preferably, the total charge volume of internal formation process maitenance-free colloid lead-acid accumulator is 7 to 9 of accumulator capacityDoubly, the battery capacity of maitenance-free colloid lead-acid accumulator can be maximized.
As preferably, in the whole process of internal formation process, charging voltage must not be higher than 16.5V, and discharge voltage must not be lower than12V
Be noted that the above embodiment is explanation to technical solution of the present invention and unrestricted, affiliated technology neckOther amendments that are equal to replacement or make according to prior art of territory those of ordinary skill, as long as do not exceed the technology of the present invention sideThe thinking of case and scope, within all should being included in interest field of the presently claimed invention.

Claims (5)

1. maitenance-free colloid lead-acid accumulator is efficiently internalized into charge technology, it is characterized in that: comprise the steps:
1) leave standstill, in added maitenance-free colloid lead-acid accumulator standing 60min;
2) charging for the first time, by 0.1～1.5I10 current charges, the charging interval is 10～60min;
3) charging for the second time, electric current is undertaken by the descending 0.5～1.0I10 that is down in three stages within the scope of 2.5～1.5I10Charging, the charging interval is 30～45h;
4) electric discharge for the first time, with 2.5～2.0I10 current discharge, be 1～2h discharge time;
5) charging for the third time, electric current is down to 0.5～1.0I by descending point three or four-stage within the scope of 2.5～1.5I1010 charge, and the charging interval is 10～15h.
2. maitenance-free colloid lead-acid accumulator according to claim 1 is efficiently internalized into charge technology, it is characterized in that: instituteState the whole process operation time≤60h of internal formation process.
3. maitenance-free colloid lead-acid accumulator according to claim 1 is efficiently internalized into charge technology, it is characterized in that: instituteState maitenance-free colloid lead-acid accumulator temperature in the whole process of internal formation process and must not exceed 60 DEG C.
4. maitenance-free colloid lead-acid accumulator according to claim 1 is efficiently internalized into charge technology, it is characterized in that: instituteState 7 to 9 times in accumulator capacity of the total charge volume of internal formation process maitenance-free colloid lead-acid accumulator.
5. maitenance-free colloid lead-acid accumulator according to claim 1 is efficiently internalized into charge technology, it is characterized in that: instituteState that in the whole process of internal formation process, charging voltage must not be higher than 16.5V, discharge voltage must not be lower than 12V.
CN201310719065.7A 2013-12-23 2013-12-23 Maitenance-free colloid lead-acid accumulator is efficiently internalized into charge technology Active CN103700892B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1564366A (en) * 2003-09-11 2005-01-12 陈刚 Internal chemical synthetic process for colloidal battery
CN101673844A (en) * 2009-10-21 2010-03-17 风帆股份有限公司 Container formation method of valve-regulated lead-acid battery
CN101877425A (en) * 2010-06-25 2010-11-03 湖南丰日电源电气股份有限公司 Pulse container formation method for high-capacity lead-acid battery
CN102244301A (en) * 2011-05-26 2011-11-16 江苏永达电源股份有限公司 Container formation process for lead acid storage battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1564366A (en) * 2003-09-11 2005-01-12 陈刚 Internal chemical synthetic process for colloidal battery
CN101673844A (en) * 2009-10-21 2010-03-17 风帆股份有限公司 Container formation method of valve-regulated lead-acid battery
CN101877425A (en) * 2010-06-25 2010-11-03 湖南丰日电源电气股份有限公司 Pulse container formation method for high-capacity lead-acid battery
CN102244301A (en) * 2011-05-26 2011-11-16 江苏永达电源股份有限公司 Container formation process for lead acid storage battery

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Denomination of invention: Efficient internalization charging process for maintenance free colloidal Lead acid battery

Effective date of registration: 20230712

Granted publication date: 20160511

Pledgee: Jiangsu Gaoyou Rural Commercial Bank Co.,Ltd.

Pledgor: YANGZHOU YONGDA POWER Co.,Ltd.

Registration number: Y2023320000372