CN103695934A - Emulsion-type derusting antirust liquid and preparation method thereof - Google Patents
Emulsion-type derusting antirust liquid and preparation method thereof Download PDFInfo
- Publication number
- CN103695934A CN103695934A CN201310617533.XA CN201310617533A CN103695934A CN 103695934 A CN103695934 A CN 103695934A CN 201310617533 A CN201310617533 A CN 201310617533A CN 103695934 A CN103695934 A CN 103695934A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- agent
- antirust
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses an emulsion-type derusting antirust liquid which is prepared from the following raw materials in parts by weight: 2-3 parts of potassium dihydrogen phosphate, 10-12 parts of isopropanol, 1-2 parts of zinc oxide, 1-2 parts of thiourea, 4-6 parts of polyisobutene, 1-2 parts of sodium dodecyl benzene sulfonate, 9-12 parts of inositol hexaphosphate, 10-12 parts of dipentaerythritol hexaacrylate, 1-2 parts of a silane coupling agent KH560, 1-2 parts of EDTA disodium, 4-5 parts of an auxiliary agent, and 300 parts of water. The derusting antirust liquid can strongly remove rust on the surface of a metal, at the same time, because of containing resin and the chelating agent, the derusting antirust liquid can form a thin film on the surface of the metal, thereby playing a role of isolating air; besides, because of the resin having an anti-oxidation effect and in addition of containing an antirust agent, the derusting antirust liquid has quite excellent antirust effect; and the antirust film can be immediately removed by water washing, thereby saving manpower.
Description
Technical field
The present invention relates to antirust technology field, relate in particular to a kind of emulsion-type rust-removing and antirusting agent and preparation method thereof.
Background technology
Metallic surface is antirust is the important topic in industrial production, and traditional rust protection liquid, slushing oil have advantage also to have shortcoming.In common aqueous rust preventive, containing a large amount of Sodium Nitrites, there is carinogenicity, be unfavorable for that environmental protection and the person are healthy, and adopt wetting Agent for Printing Inks to extend the life-span of aqueous rust preventive, bring again the disadvantage of touching with one's hand, being covered with dust, and can not be antirust for a long time; Although it is antirust for a long time that general hard film rust preventive oil is applicable to, film forming is also transparent attractive in appearance, and water white resin kind is less, and unstable also easy oxidation discoloration, also needs organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health; General slushing oil is used mineral oil, difficult degradation, and also can bring the problem of oil removing difficulty when antirust for short-term.Therefore, comprehensive study performance is more excellent, and the antirust product being more applicable to for different occasion research is new direction and trend.
Summary of the invention
The object of the present invention is to provide a kind of emulsion-type rust-removing and antirusting agent and preparation method thereof, this rust protection liquid has the feature of rust cleaning, antirust, easy cleaning.
Technical scheme of the present invention is as follows:
An emulsion-type rust-removing and antirusting agent, is characterized in that being made by the raw material of following weight part: potassium primary phosphate 2-3, Virahol 10-12, zinc oxide 1-2, thiocarbamide 1-2, polyisobutene 4-6, Sodium dodecylbenzene sulfonate 1-2, myo-Inositol hexaphosphate 9-12, double pentaerythritol methacrylate 10-12, silane coupling agent KH560 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, water glass 3-4, Resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, peach gum 2-3, ammonium persulphate 1-2, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described emulsion-type rust-removing and antirusting agent, is characterized in that comprising the following steps: water, Sodium dodecylbenzene sulfonate are mixed, be heated to 40-50 ℃; Add Virahol, polyisobutene, myo-Inositol hexaphosphate, double pentaerythritol methacrylate, silane coupling agent KH560, EDETATE SODIUM, continue to be heated to 85-90 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, obtain.
Beneficial effect of the present invention
Rust-removing and antirusting agent of the present invention can brute force be removed the rusty stain on metallic surface, contains resin, sequestrant because of it simultaneously, can form film in metallic surface, plays isolated air, and resin has anti-oxidation effect simultaneously, contains rust-preventive agent in addition, and rust-proof effect is splendid; Anti-rust film washing can be removed, and saves artificial.
Embodiment
An emulsion-type rust-removing and antirusting agent, by following weight part (kilogram) raw material make: potassium primary phosphate 2.5, Virahol 11, zinc oxide 1.5, thiocarbamide 1.5, polyisobutene 5, Sodium dodecylbenzene sulfonate 1.5, myo-Inositol hexaphosphate 11, double pentaerythritol methacrylate 11, silane coupling agent KH560 1.5, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent by following weight part (kilogram) raw material make: polyoxyethylene sorbitan monooleate 2, nano titanium oxide 0.1, catechin 1, ethanol 10, water glass 3, Resorcinol 1, propylene glycol 3, morpholine 2, peach gum 2, ammonium persulphate 1, water 20; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described emulsion-type rust-removing and antirusting agent, comprises the following steps: water, Sodium dodecylbenzene sulfonate are mixed, be heated to 45 ℃; Add Virahol, polyisobutene, myo-Inositol hexaphosphate, double pentaerythritol methacrylate, silane coupling agent KH560, EDETATE SODIUM, continue to be heated to 88 ℃, stir 14 minutes; Add other remaining components, continue to stir 18 minutes, obtain.
The emulsion-type rust-removing and antirusting agent that this embodiment obtains detects by national standard, and humid heat test * (1) is qualified; Salt water immersion test * (1): qualified; Corrosion test * (2): qualified; Rust removability (inferior) < 6.Prepared emulsion-type rust-removing and antirusting agent is brushed on the steel matrix surface of being newly processed into and there is no greasy dirt, be placed in and within indoor 20 days, have no obvious iron mold.
Claims (2)
1. an emulsion-type rust-removing and antirusting agent, is characterized in that being made by the raw material of following weight part: potassium primary phosphate 2-3, Virahol 10-12, zinc oxide 1-2, thiocarbamide 1-2, polyisobutene 4-6, Sodium dodecylbenzene sulfonate 1-2, myo-Inositol hexaphosphate 9-12, double pentaerythritol methacrylate 10-12, silane coupling agent KH560 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300; Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, water glass 3-4, Resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, peach gum 2-3, ammonium persulphate 1-2, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method of emulsion-type rust-removing and antirusting agent according to claim 1, is characterized in that comprising the following steps: water, Sodium dodecylbenzene sulfonate are mixed, be heated to 40-50 ℃; Add Virahol, polyisobutene, myo-Inositol hexaphosphate, double pentaerythritol methacrylate, silane coupling agent KH560, EDETATE SODIUM, continue to be heated to 85-90 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617533.XA CN103695934A (en) | 2013-11-29 | 2013-11-29 | Emulsion-type derusting antirust liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617533.XA CN103695934A (en) | 2013-11-29 | 2013-11-29 | Emulsion-type derusting antirust liquid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103695934A true CN103695934A (en) | 2014-04-02 |
Family
ID=50357592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310617533.XA Pending CN103695934A (en) | 2013-11-29 | 2013-11-29 | Emulsion-type derusting antirust liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103695934A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104005033A (en) * | 2014-05-19 | 2014-08-27 | 刘晓萍 | Anti-corrosion rust remover and preparation method thereof |
| CN105780025A (en) * | 2016-04-20 | 2016-07-20 | 安徽工业大学 | Room temperature low damage pickling solution of 300 series stainless steel tubes and pickling method thereof |
| CN106637272A (en) * | 2017-01-04 | 2017-05-10 | 邯郸学院 | Silverware brightening emulsion and preparation method thereof |
| CN114774004A (en) * | 2022-04-07 | 2022-07-22 | 湖州飞鹿新能源科技有限公司 | Silicon wafer polishing additive, polishing solution, and preparation method and application thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072217A (en) * | 1991-11-11 | 1993-05-19 | 薛志纯 | Conversion rust-resisting liquid |
| EP0972854A2 (en) * | 1998-07-15 | 2000-01-19 | Andritz-Patentverwaltungs-Gesellschaft m.b.H. | Process for pickling stainless steel |
| CN101220479A (en) * | 2007-12-05 | 2008-07-16 | 南宝树脂（中国）有限公司 | Rust-proof rust-cleaning film forming material and preparation thereof |
| WO2009032460A1 (en) * | 2007-08-02 | 2009-03-12 | Advanced Technology Materials, Inc. | Non-fluoride containing composition for the removal of residue from a microelectronic device |
| CN102070941A (en) * | 2010-11-18 | 2011-05-25 | 苏州美亚美建筑涂料有限公司 | Antirusting agent for coating |
| CN102676277A (en) * | 2011-09-06 | 2012-09-19 | 安徽江南机械有限责任公司 | Water soluble antirusting fluid, and preparation method and using method thereof |
| CN102703194A (en) * | 2012-05-28 | 2012-10-03 | 上海福岛化工科技发展有限公司 | Aluminum-magnesium alloy cutting fluid |
| CN103013244A (en) * | 2012-12-07 | 2013-04-03 | 彭美东 | Water-soluble antirust liquid |
| CN103388153A (en) * | 2013-07-26 | 2013-11-13 | 上海金兆节能科技有限公司 | Environment-friendly rustproof cleaning agent |
-
2013
- 2013-11-29 CN CN201310617533.XA patent/CN103695934A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072217A (en) * | 1991-11-11 | 1993-05-19 | 薛志纯 | Conversion rust-resisting liquid |
| EP0972854A2 (en) * | 1998-07-15 | 2000-01-19 | Andritz-Patentverwaltungs-Gesellschaft m.b.H. | Process for pickling stainless steel |
| WO2009032460A1 (en) * | 2007-08-02 | 2009-03-12 | Advanced Technology Materials, Inc. | Non-fluoride containing composition for the removal of residue from a microelectronic device |
| CN101220479A (en) * | 2007-12-05 | 2008-07-16 | 南宝树脂（中国）有限公司 | Rust-proof rust-cleaning film forming material and preparation thereof |
| CN102070941A (en) * | 2010-11-18 | 2011-05-25 | 苏州美亚美建筑涂料有限公司 | Antirusting agent for coating |
| CN102676277A (en) * | 2011-09-06 | 2012-09-19 | 安徽江南机械有限责任公司 | Water soluble antirusting fluid, and preparation method and using method thereof |
| CN102703194A (en) * | 2012-05-28 | 2012-10-03 | 上海福岛化工科技发展有限公司 | Aluminum-magnesium alloy cutting fluid |
| CN103013244A (en) * | 2012-12-07 | 2013-04-03 | 彭美东 | Water-soluble antirust liquid |
| CN103388153A (en) * | 2013-07-26 | 2013-11-13 | 上海金兆节能科技有限公司 | Environment-friendly rustproof cleaning agent |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104005033A (en) * | 2014-05-19 | 2014-08-27 | 刘晓萍 | Anti-corrosion rust remover and preparation method thereof |
| CN105780025A (en) * | 2016-04-20 | 2016-07-20 | 安徽工业大学 | Room temperature low damage pickling solution of 300 series stainless steel tubes and pickling method thereof |
| CN106637272A (en) * | 2017-01-04 | 2017-05-10 | 邯郸学院 | Silverware brightening emulsion and preparation method thereof |
| CN114774004A (en) * | 2022-04-07 | 2022-07-22 | 湖州飞鹿新能源科技有限公司 | Silicon wafer polishing additive, polishing solution, and preparation method and application thereof |
| CN114774004B (en) * | 2022-04-07 | 2023-10-10 | 湖州飞鹿新能源科技有限公司 | Silicon wafer polishing additive, polishing solution and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103882451B (en) | A kind of water base normal temperature rust-removing and antirusting agent and preparation method thereof | |
| CN103695934A (en) | Emulsion-type derusting antirust liquid and preparation method thereof | |
| CN103882439B (en) | A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof | |
| CN103695920A (en) | Water-based metal rustproof liquid and preparation method thereof | |
| CN103882450B (en) | A kind of water base rust-removing and antirusting agent and preparation method thereof | |
| CN103695922A (en) | Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof | |
| CN103695140A (en) | Water-soluble cutting antirust liquid and preparation method thereof | |
| CN103695919B (en) | A kind of metal parts antirust liquid for inner chamber and preparation method thereof | |
| CN103614714B (en) | A kind of steel derusting rust protection liquid and preparation method thereof | |
| CN103710118B (en) | A kind of water base cutting cooling antirust liquid and preparation method thereof | |
| CN103695940A (en) | Water-soluble antioxidant derusting antirust liquid and preparation method thereof | |
| CN103695925A (en) | Water-soluble conversion-type antirust liquid and preparation method thereof | |
| CN103695915A (en) | Emulsion-type antirust liquid and preparation method thereof | |
| CN103695948A (en) | Cast iron derusting antirust liquid and preparation method thereof | |
| CN103882434A (en) | Pollution-free inter-process antirust liquid and preparation method thereof | |
| CN103710709A (en) | Water-based emulsion-type antirust liquid and preparation method thereof | |
| CN103695931A (en) | Water-soluble metal short-term antirust liquid and preparation method thereof | |
| CN103695913A (en) | Water-soluble ferrous metal antirust liquid and preparation method thereof | |
| CN103695936A (en) | Water-based inter-process environment-friendly antirust liquid and preparation method thereof | |
| CN103695921B (en) | A kind of derusting rust-proofing liquid containing alkyd resins and preparation method thereof | |
| CN103695916A (en) | Water-soluble antifouling antirust liquid and preparation method thereof | |
| CN103694857A (en) | Water-based inter-process environment-friendly antirust liquid and preparation method thereof | |
| CN103695141B (en) | A kind of environment protection metal cutting cooling antirust liquid and preparation method thereof | |
| CN103695914A (en) | Water-based precipitation film antirust liquid and preparation method thereof | |
| CN103642288B (en) | A kind of Environment-friendlywater-soluble water-soluble rust protection liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140402 |
|
| RJ01 | Rejection of invention patent application after publication |