CN103694562B - Automotive upholstery is with exempting from spraying scratch resistance PP composite material and preparation method thereof - Google Patents
Automotive upholstery is with exempting from spraying scratch resistance PP composite material and preparation method thereof Download PDFInfo
- Publication number
- CN103694562B CN103694562B CN201310670823.0A CN201310670823A CN103694562B CN 103694562 B CN103694562 B CN 103694562B CN 201310670823 A CN201310670823 A CN 201310670823A CN 103694562 B CN103694562 B CN 103694562B
- Authority
- CN
- China
- Prior art keywords
- polypropylene
- exempting
- rev
- scratch resistance
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005507 spraying Methods 0.000 title claims abstract description 20
- 239000002131 composite material Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000002184 metal Substances 0.000 claims abstract description 26
- 239000004743 Polypropylene Substances 0.000 claims abstract description 25
- -1 polypropylene Polymers 0.000 claims abstract description 14
- 229920001155 polypropylene Polymers 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 229920001971 elastomer Polymers 0.000 claims abstract description 8
- 239000000806 elastomer Substances 0.000 claims abstract description 7
- 238000007790 scraping Methods 0.000 claims abstract description 7
- 230000003078 antioxidant Effects 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 239000004611 light stabiliser Substances 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 15
- 239000004411 aluminium Substances 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011159 matrix material Substances 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- YVKMMZAFUFUAAX-UHFFFAOYSA-N aluminum;tetrahydrate Chemical compound O.O.O.O.[Al] YVKMMZAFUFUAAX-UHFFFAOYSA-N 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 2
- 239000000049 pigment Substances 0.000 abstract description 30
- 230000000694 effects Effects 0.000 abstract description 22
- 238000003672 processing method Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 239000007921 spray Substances 0.000 description 6
- 229920000178 Acrylic resin Polymers 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 150000004645 aluminates Chemical group 0.000 description 2
- SMYKVLBUSSNXMV-UHFFFAOYSA-J aluminum;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-J 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000011218 segmentation Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- HBGPNLPABVUVKZ-POTXQNELSA-N (1R,3aS,4S,5aR,5bR,7R,7aR,11aR,11bR,13aS,13bR)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1H-cyclopenta[a]chrysen-9-one Chemical group C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N (Z)-docos-13-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L Calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- UYTPUPDQBNUYGX-UHFFFAOYSA-N Guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N Oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000003678 scratch resistant Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Abstract
The invention discloses a kind of automotive upholstery with exempting from spraying scratch resistance PP composite material, it is made up of polypropylene, elastomer, Pulvis Talci, compatilizer, metallic pigments, metal pigment surfaces inorganic agent, scraping-resistant agent, antioxidant, light stabilizer, the invention also discloses the aforementioned processing method meeting material, use formula and the preparation method of the present invention, metal effect is good, can effectively reduce spraying current mark.
Description
Technical field
The invention mainly relates to exempt from the manufacturing technology of spray coating polypropylene composite, be specifically related to a kind of automotive upholstery and use
Exempt from spray scratch resistance PP composite material and preparation method thereof, belong to the technical field of modification of polymer composite.
Background technology
" low-carbon environment-friendly, energy-saving and emission-reduction " are one of important issue of 12 planning.For automaker, from setting
The meter development phase will consider to use the material of environmental protection, be not only enterprise product upgrading and the needs of technological innovation, and
Embody social responsibility of enterprises.For the direction lightweight of development of automobile, comfortableization, safe, material manufacturer actively pushes away
The solution made new advances, and exempt from the solution of high-quality and the low cost balance spraying the application Ze Shi automobile main frame maker proposition of resin
One of scheme.
In the past, automotive trim ornament materials generally uses means that plastic basis material carries out spraying paint to reach the merit that interior trim is attractive in appearance
Energy.Main cause is that incrustation paint is possible not only to protect resin base material, but also can realize the surface such as Gao Guang, dumb light effect
Really, and weathering, the function such as scratch-resistant.But spraying coating process also brings along some problems.First it is the complexity of flow process, is molded hair
After blank, needing to increase the basic links such as transport, pretreatment, application, transport, part lacquer spraying technique needs priming paint, finish paint, and UV is solid
Change the multiple tracks production processes such as paint.Next to that the defect that each product produces is due to the most spray coated thermosetting varniss, it is impossible to easily
Stripping, cause finally reclaiming difficulty, pollute environment.It is that car inside gadget uses expendable thermosetting varniss also to full again
The requirement of foot ELV decree brings challenge.Finally, make to paint the cost so that whole part and typically double even two
Times.
Along with material and the development of mould process, exempt to spray the new trend becoming interior trim application.Chinese invention patent
CN102942742A application disclose a kind of have high glaze, metal or pearly-lustre flicker effect exempt from spraying PP material and preparation
Method, this patent uses the effect pigment such as metallic aluminium powder and pearl essence, it is not necessary to spraying directly injection can obtain good Gao Guang
Pool and pearly-lustre flash, and metal sprays paint effect, possesses good appearance, has saved cost, avoid simultaneously compared with lacquer spraying technique
Goods use during depainting problem.Chinese invention patent CN102585365A application disclose one have paint glossy
Metal-like exempts from polypropene composition and the preparation method thereof of spraying, and this patent, with the use of flake aluminum and color and luster brightener, makes material
Material has that good paint is glossy and metal-like, and its appearance is close with effect of spraying paint.Chinese invention patent
CN102516700A application disclose a kind of improve outward appearance exempt from spraying aesthetic resin and preparation method thereof, this patent of invention is first
Metallic pigments are prepared as master batch form, and make it have magnetic, the affine of aluminium powder pigment and plastic basis material can be effectively improved
Property, alleviate current mark and weld bond that the aesthetic resin containing aluminium powder pigment occurs in injection or extrusion, meanwhile, enhance system
The metal effect of part.
These current researchs mainly there is also following deficiency: 1. conventional twin-screw extrusion is complete to metallic pigments microstructure
Whole property is destroyed relatively big, affects final metal effect；2. metallic pigments and the resin base compatibility are poor, and difficulties in dispersion causes current mark to be asked
Topic is difficult to solve.
Summary of the invention
It is contemplated that solve the problems referred to above to a certain extent, provide at a kind of coml application.
To this end, first goal of the invention of the present invention is that the defect overcoming prior art provides the vapour that a kind of metal effect is good
Car inside gadget exempt from spray scratch resistance PP composite material.
Second goal of the invention of the present invention be to provide the automotive upholstery that a kind of metal effect is good exempt from spray scratch resistance
The preparation method of PP composite material.
For realizing first goal of the invention of the present invention, the present invention adopts the following technical scheme that, a kind of automotive upholstery is with exempting from
Spraying scratch resistance PP composite material, is made up of by mass percentage following components:
The present invention improves the polarity of polypropylene matrix resin by maleic anhydride, metal pigment surfaces processes two means,
Improve metallic pigments and the compatibility of matrix resin and the dispersibility in matrix resin, on the one hand decrease metallic pigments
Usage amount, reduces cost, on the other hand efficiently solves the injection problem such as current mark, weld bond.
Specifically, described metallic pigments are silver dollar matrix shape metallic aluminium powder.Silver dollar type flake aluminum has rule relatively
Laminated structure, the ratio producing direct reflection is high, thus has more preferable metal effect.
Described metallic aluminium powder is silver dollar shape type.
Described metal pigment surfaces inorganic agent is Aluminate.Specifically, described Aluminate is aluminic acid trimethyl.Aluminic acid
In trimethyl structure, aluminium element part and metallic aluminium powder have the good compatibility, and trimethyl part then has with acrylic resin
The good compatibility, thus improve the compatibility between metallic aluminium powder and polypropylene matrix resin.
Described Pulvis Talci mean diameter is 1-20um.
Described compatilizer is maleic anhydride inoculated polypropylene.
Described elastomer is one or both the mixture in EP rubbers, ethylene-octene copolymer.
Described acrylic resin is HOPP, second the third block copolymerization polypropylene or the mixture of two kinds of resins.
Described scraping-resistant agent is the mixing of one or more in silicone powder, silicone master batch, oleamide, erucyl amide
Thing.
For realizing second goal of the invention of the present invention, the present invention adopts the following technical scheme that, one prepares any of the above-described institute
State automotive upholstery with exempting from spraying scratch resistance PP composite material, it is characterised in that comprise the following steps:
S1. raw material is weighed by said ratio；
S2. by acrylic resin, elastomer, Pulvis Talci 800-1500 rev/min of lower mixed at high speed 5-10 minute, then
Add antioxidant, light stabilizer, scraping-resistant agent, compatilizer in 800-1500 rev/min of lower mixed at high speed 5-10 minute, mixed at high speed
The temperature of machine controls, at 55-65 DEG C, to obtain 1# premix material；
S3. by metallic pigments, metal pigment surfaces inorganic agent 200-500 rev/min of lower mixed on low speed 5-10 minute, mixed
The temperature of conjunction machine controls, at 45-55 DEG C, to obtain 2# premix material；
S4. 1# premix material being added from twin-screw extrusion owner's spout, melt extrude pelletize, each section of temperature of extruder sets
It is set to 200 DEG C, 210 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 210 DEG C, head temperature 220 DEG C, screw rod
Rotating speed is 300-600 rev/min；
S5. 2# premix material being added from the side spout of double screw extruder, side spout is arranged on the 4th of extruder
Section cylinder, side feeding frequency is 2-10HZ.
The present invention by by metallic pigments premix material side feeding segmentation addition by the way of, reduce screw rod shearing to metal
The destructiveness of pigment microstructure, improves service efficiency and the effect of metallic pigments.
The invention has the beneficial effects as follows, (1) present invention improves the polarity of polypropylene matrix resin, metal pigment surfaces processes
Two means, improve metallic pigments and the compatibility of matrix resin and the dispersibility in matrix resin, on the one hand decrease
The usage amount of metallic pigments, reduces cost, on the other hand efficiently solves the injection problem such as current mark, weld bond.(2) present invention adopts
Metallic aluminium powder surface is processed with Aluminate so that it is and by the compatibility between the polypropylene matrix resin of maleic anhydride modified mistake
It is greatly improved.In Aluminate structure, aluminium element and metallic aluminium powder have the good compatibility, and ester group structure then has with maleic anhydride
There is the good compatibility.(3) present invention by by metallic pigments premix material side feeding segmentation addition by the way of, reduce screw rod
Shear the destructiveness to metallic pigments microstructure, improve service efficiency and the effect of metallic pigments.
Detailed description of the invention
Below by embodiment, the present invention is described in detail, but does not limits the invention.
Preparation method is as follows:
The first step, weighs each raw material by weight percent；
Second step, by acrylic resin, elastomer, Pulvis Talci 800-1500 rev/min of lower mixed at high speed 5-10 minute,
It is subsequently adding antioxidant, light stabilizer, scraping-resistant agent, compatilizer 800-1500 rev/min of lower mixed at high speed 5-10 minute, at a high speed
The temperature of mixer controls, at 55-65 DEG C, to obtain 1# premix material；
3rd step, divides metallic pigments, metal pigment surfaces inorganic agent 200-500 rev/min of lower mixed on low speed 5-10
Clock, the temperature of mixer controls, at 45-55 DEG C, to obtain 2# premix material；
4th step, adds 1# premix material from twin-screw extrusion owner's spout, melt extrudes pelletize, each section of temperature of extruder
Degree is set as 200 DEG C, 210 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 210 DEG C, head temperature 220 DEG C,
Screw speed is 300-600 rev/min；
5th step, adds 2# premix material from the side spout of double screw extruder, and side spout is arranged on extruder
4th section of cylinder, side feeding frequency is 2-10HZ.
Method made above is applicable to embodiment 1-7, comparative example 2-5.
The preparation method of comparative example 1 is:
The first step, weighs each raw material by weight percent；
Second step, by acrylic resin, elastomer, Pulvis Talci 800-1500 rev/min of lower mixed at high speed 5-10 minute,
It is subsequently adding antioxidant, light stabilizer, scraping-resistant agent, compatilizer 800-1500 rev/min of lower mixed at high speed 5-10 minute, at a high speed
The temperature of mixer controls, at 55-65 DEG C, to obtain 1# premix material；
3rd step, divides metallic pigments, metal pigment surfaces inorganic agent 200-500 rev/min of lower mixed on low speed 5-10
Clock, the temperature of mixer controls, at 45-55 DEG C, to obtain 2# premix material；
4th step, adds 1# and 2# premix material from twin-screw extrusion owner's spout simultaneously, melt extrudes pelletize, extrusion
Each section of temperature of machine is set as 200 DEG C, 210 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 210 DEG C, head temperature
Spending 220 DEG C, screw speed is 300-600 rev/min；
The most talcous mean diameter is 1-20um.
GB/T17037 standard injected sample pressed by the model of evaluation result, evaluates the metal effect of model, the current mark order of severity
And anti-scratch performance.Metal effect and the current mark order of severity take artificial visual assessment method, and metal effect presses quality degree from 0-
10 points, the best score of metal effect is the highest, selects at least 5 people to evaluate, makes even and divide equally.The current mark order of severity is divided slight, general, tight
Weight Three Estate, selects at least 5 people to evaluate.Anti-scratch performance presses GMW14688 standard testing.
As can be seen from the above table, not having compatilizer in embodiment 1, metal effect is general, and current mark is serious；Embodiment 7
The non-surface of metallic pigments processes, and metal effect is general, and current mark is serious；Side feeding manner do not taked by comparative example 1 metallic pigments, gold
Belong to poor effect.Comparative example 2,3,4,5 is respectively adopted bisphenol A type epoxy resin, SAN-GMA, calcium stearate, silane coupler pair
Metallic aluminium powder Treatment of Metal Surface, metal effect is general, and current mark is serious, and its effect is not so good as at the aluminic acid trimethyl that the present invention uses
Reason agent.
Claims (3)
1. automotive upholstery is with exempting from a spraying scratch resistance PP composite material, is made up of by mass percentage following components:
Polypropylene 71.06%
Elastomer POE 10%
Pulvis Talci 10%
Compatilizer 5%
Silver dollar matrix shape metallic aluminium powder 2%
Aluminic acid trimethyl metal conditioner 0.04%
Silicone powder scraping-resistant agent 1.5%
Antioxidant 0.2%
Light stabilizer 0.2%
Wherein, described Pulvis Talci mean diameter is 1-20 μm；
The preparation method of above-mentioned composite is:
S1. raw material is weighed by said ratio；
S2. by polypropylene, elastomer POE, Pulvis Talci 800-1500 rev/min of lower mixed at high speed 5-10 minute, it is subsequently adding
Antioxidant, light stabilizer, silicone powder scraping-resistant agent, compatilizer are 800-1500 rev/min of lower mixed at high speed 5-10 minute, the most mixed
The temperature of conjunction machine controls, at 55-65 DEG C, to obtain 1# premix material；
S3. silver dollar matrix shape metallic aluminium powder, aluminic acid trimethyl metal conditioner are mixed at 200-500 rev/min of lower low speed
Closing 5-10 minute, the temperature of mixer controls, at 45-55 DEG C, to obtain 2# premix material；
S4. 1# premix material being added from twin-screw extrusion owner's spout, melt extrude pelletize, each section of temperature of extruder sets
Being 200 DEG C, 210 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 210 DEG C, head temperature 220 DEG C, screw rod turns
Speed is 300-600 rev/min；
S5. 2# premix material being added from the side spout of double screw extruder, side spout is arranged on the 4th section of cylinder of extruder
Body, side feeding frequency is 2-10Hz.
Automotive upholstery the most according to claim 1 is with exempting from spraying scratch resistance PP composite material, it is characterised in that described
Compatilizer be maleic anhydride inoculated polypropylene.
Automotive upholstery the most according to claim 1 is with exempting from spraying scratch resistance PP composite material, it is characterised in that described
Polypropylene be HOPP, second the third block copolymerization polypropylene or the mixture of two kinds of resins.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310670823.0A CN103694562B (en) | 2013-12-10 | Automotive upholstery is with exempting from spraying scratch resistance PP composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310670823.0A CN103694562B (en) | 2013-12-10 | Automotive upholstery is with exempting from spraying scratch resistance PP composite material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103694562A CN103694562A (en) | 2014-04-02 |
| CN103694562B true CN103694562B (en) | 2016-11-30 |
Family
ID=
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787162A (en) * | 2009-11-12 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Aesthetical resin capable of eliminating injection-molding weld lines and preparation method thereof |
| CN102206407A (en) * | 2011-04-21 | 2011-10-05 | 上海锦湖日丽塑料有限公司 | Biodegradable free-spraying aesthetic resin and preparation method thereof |
| CN102372904A (en) * | 2010-08-13 | 2012-03-14 | 上海锦湖日丽塑料有限公司 | Preparation method for aesthetic resin for improving affinity of aluminum powder pigment |
| CN102382371A (en) * | 2010-12-14 | 2012-03-21 | 重庆文理学院 | Automobile interior trim part material and preparation method thereof |
| CN102464857A (en) * | 2010-11-15 | 2012-05-23 | 上海锦湖日丽塑料有限公司 | Extrusion grade aesthetical resin possessing metal color effect and its preparation method |
| CN102585365A (en) * | 2012-02-16 | 2012-07-18 | 金发科技股份有限公司 | Coating-free polypropylene composition with paint brightness and metal texture and preparation method thereof |
| CN102627827A (en) * | 2012-03-19 | 2012-08-08 | 上海锦湖日丽塑料有限公司 | Aesthetic resin composition having metal appearance and preparation method thereof |
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787162A (en) * | 2009-11-12 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Aesthetical resin capable of eliminating injection-molding weld lines and preparation method thereof |
| CN102372904A (en) * | 2010-08-13 | 2012-03-14 | 上海锦湖日丽塑料有限公司 | Preparation method for aesthetic resin for improving affinity of aluminum powder pigment |
| CN102464857A (en) * | 2010-11-15 | 2012-05-23 | 上海锦湖日丽塑料有限公司 | Extrusion grade aesthetical resin possessing metal color effect and its preparation method |
| CN102382371A (en) * | 2010-12-14 | 2012-03-21 | 重庆文理学院 | Automobile interior trim part material and preparation method thereof |
| CN102206407A (en) * | 2011-04-21 | 2011-10-05 | 上海锦湖日丽塑料有限公司 | Biodegradable free-spraying aesthetic resin and preparation method thereof |
| CN102585365A (en) * | 2012-02-16 | 2012-07-18 | 金发科技股份有限公司 | Coating-free polypropylene composition with paint brightness and metal texture and preparation method thereof |
| CN102627827A (en) * | 2012-03-19 | 2012-08-08 | 上海锦湖日丽塑料有限公司 | Aesthetic resin composition having metal appearance and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 不同加工工艺对ABS金属闪光效果影响的研究;王斌等;《工程塑料应用》;20101010;第38卷(第10期);第1.1、2.1节及图1 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3789456B1 (en) | Polyamide resin composition having high metal texture and preparation method of polyamide resin composition | |
| CN103910941B (en) | A kind of polypropene composition exempting from spraying aesthetic effect and preparation method and application | |
| CN104693602A (en) | High-flowability high-glossiness no-surface-defect colored metallic-pearl-effect spraying-free polypropylene automobile material and preparation method thereof | |
| CN105419205B (en) | A kind of high glaze exempts from the PMMA/ASA alloy resin composition and preparation method thereof of spraying | |
| CN103910937A (en) | Scratch-resistant high-gloss spraying-free polypropylene composition with aesthetic effect as well as preparation method and application of composition | |
| CN101781424B (en) | Formula of non-painted automobile bumper with metal luster and production process thereof | |
| CN113416372B (en) | Spraying-free metallic high-gloss high-weather-resistance PMMA/ASA alloy material and preparation method thereof | |
| CN106084493A (en) | A kind of metal-like for automobile exterior trimming parts exempts from spray coating polypropylene composite and preparation method thereof | |
| CN106916445A (en) | One kind exempts from spraying transparent glass fiber reinforced nylon resin material and preparation method thereof | |
| CN106589768B (en) | The PC/ABS for improving injection molding filamentary silver problem exempts to spray resin combination and preparation method thereof | |
| CN108102506A (en) | Bonding Pearlescent powder paint and preparation method thereof | |
| CN107011614A (en) | A kind of bumper metal-like exempts from spray coating polypropylene composite and preparation method thereof | |
| CN107778750A (en) | A kind of weather-proof intermingling material with high brightness metal-like of damage resistant | |
| CN109705515A (en) | One kind is exempted to spray scratch-resistant dumb light ABS resin and preparation method thereof | |
| CN111690209A (en) | High-fluidity scratch-resistant spraying-free metallic silver modified polypropylene material for vehicles | |
| CN109735001A (en) | A kind of high glaze exempts from spraying, scratch resistance polypropylene material and preparation method thereof | |
| CN111363248A (en) | Spraying-free polypropylene composite material for automobile bumper decoration strip and preparation method thereof | |
| CN108976693A (en) | A kind of marbling Masterbatch and its application method suitable for ABS | |
| CN108623920A (en) | A kind of bumper polypropylene alloy and preparation method thereof for exempting from spraying pearl effect | |
| CN104804354A (en) | Spraying-free weather-proof metal texture ASA composite and preparation method thereof | |
| CN103554669B (en) | A kind of exempting from the glossy argentine texture of paint sprays modified polypropylene material | |
| CN109503922B (en) | Preparation method of pigment functional master batch, product and application thereof | |
| CN101906263A (en) | Automobile copper-gold hammer artistic coating and preparation method thereof | |
| CN101781422B (en) | Formula of non-painted automobile spoiler with metal luster and production process thereof | |
| CN105802116A (en) | Spraying-free high-metal-gloss transparent ABS material and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151102 Address after: Conghua City Ao town Guangzhou city Guangdong province 510945 Longtan Jubao Industrial Zone Applicant after: Guangzhou Super-Dragon Engineering plastic Co., Ltd. Address before: Conghua City Ao town Guangzhou city Guangdong province 510945 Longtan Jubao Industrial Zone Applicant before: Guangzhou Super-Dragon Engineering plastic Co., Ltd. Applicant before: Super-Dragon New Material Technology Co., Ltd. |
|
| CB02 | Change of applicant information |
Address after: Conghua City Ao town Guangzhou city Guangdong province 510945 Longtan Jubao Industrial Zone Applicant after: GUANGZHOU SUPER-DRAGON ENGINEERING PLASTICS CO., LTD. Address before: Conghua City Ao town Guangzhou city Guangdong province 510945 Longtan Jubao Industrial Zone Applicant before: Guangzhou Super-Dragon Engineering plastic Co., Ltd. |
|
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Spraying-free scrape-resistant polypropylene composite material for automobile interior trim parts and preparation method thereof Effective date of registration: 20190530 Granted publication date: 20161130 Pledgee: Conghua Branch of Guangzhou Bank Co., Ltd. Pledgor: GUANGZHOU SUPER-DRAGON ENGINEERING PLASTICS CO., LTD. Registration number: 2019440000196 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200821 Granted publication date: 20161130 Pledgee: Conghua Branch of Guangzhou Bank Co.,Ltd. Pledgor: GUANGZHOU SUPER-DRAGON ENGINEERING PLASTICS Co.,Ltd. Registration number: 2019440000196 |