CN103694512A - Butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material and preparation method thereof - Google Patents
Butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material and preparation method thereof Download PDFInfo
- Publication number
- CN103694512A CN103694512A CN201310631896.9A CN201310631896A CN103694512A CN 103694512 A CN103694512 A CN 103694512A CN 201310631896 A CN201310631896 A CN 201310631896A CN 103694512 A CN103694512 A CN 103694512A
- Authority
- CN
- China
- Prior art keywords
- parts
- mixing
- butadiene
- acrylonitrile rubber
- sealing gasket
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Sealing Material Composition (AREA)
Abstract
The invention discloses a butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material. The butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material is characterized in that the butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material is prepared from the following raw materials in parts by weight: 80-90 parts of butadiene-acrylonitrile rubber, 20-24 parts of fluororubber, 1-2 parts of tetrabenzylthiuramdisulfide, 12-14 parts of silicon dioxide, 2-3 parts of zinc oxide, 3-4 parts of calcium ferrite, 1-2 parts of zinc phosphate, 10-12 parts of barium chromate, 1-2 parts of 2-mercaptobenzimidazole, 1-2 parts of accelerator CZ, 1-2 parts of accelerator M, 30-34 parts of N330 carbon black, 24-28 pars of N550 carbon black, 8-10 parts of epoxy linseed oil and 10-12 parts of modified attapulgite. The processing property of the rubber material is improved due to adding of the modified attapulgite; the environment-friendly accessory ingredients are used to reduce toxic and side effects and environmental pollution; the butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material has reasonable formula, simple process, low cost, and good oil resistance, corrosion resistance and ageing resistance.
Description
Technical field
The present invention relates to rubber composite manufacture field, particularly mixing compound seal cushion material of a kind of paracril viton and preparation method thereof.
Background technology
Gasket is a kind of for the inside such as machinery, equipment, pipeline, the material sealing.The gasket using mostly at present is rubber gasket, be characterized in: high temperature resistant, resistance to ozone, resistance to natural weathering, vacuum-resistant, fuel oil resistance, resistance to lubricating oil, powerful oxidation corrosion resistance agent, resistance to chemical reagents and electrical insulation capability are good, are widely used in national defense industry and civilian industry.The defects such as but existing rubber gasket sealing effectiveness is undesirable, wear resistance is poor, intensity is low, far can not meet actual requirement.Therefore researching and developing a kind of high-performance rubber gasket has become the task of top priority.
Summary of the invention
The object of this invention is to provide mixing compound seal cushion material of a kind of paracril viton and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
The mixing compound seal cushion material of paracril viton, is made by the raw material of following weight part: paracril 80-90, viton 20-24, tetra-benzyl thiram disulfide 1-2, silica 1 2-14, zinc oxide 2-3, calcium ferrite 3-4, zinc phosphate 1-2, baryta yellow 10-12,2-thiol group benzimidazolyl 1-2, accelerant CZ 1-2, captax 1-2, N330 carbon black 30-34, N550 carbon black 24-28, epoxy Toenol 1140 8-10, attapulgite modified 10-12;
The described attapulgite modified raw material by following weight part is made: attapulgite 20-24, clay 10-12, hexamethylene diisocyanate 3-4, tri (propylene glycol) diacrylate 2-3, carborundum powder 9-11, tetrafluoroethylene 3-4, fluorite 6-8, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS 2-3, aluminium hydroxide 8-10, calcium stearate 1-2, Fructus Zanthoxyli oil 1-2; Preparation method puts into attapulgite, clay, fluorite mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
The mixing compound seal cushion material of paracril viton of the present invention, is made by following concrete steps: paracril, tetra-benzyl thiram disulfide are added in Banbury mixer, be heated to 80-90 ℃, mixing 3-5min; Then be warming up to 110-130 ℃, then add silicon-dioxide, zinc oxide, calcium ferrite, zinc phosphate, baryta yellow, 2-thiol group benzimidazolyl, accelerant CZ, mixing 6-8min, then add captax, N330 carbon black to continue mixing 4-6min; Add the mixing 6-8min of all the other remaining components, obtain.
Excellent effect of the present invention is: the present invention adds attapulgite modified, has improved the processing performance of sizing material, uses environment-friendly type Synergist S-421 95, reduces its toxic side effect and the pollution to environment; Composite-material formula of the present invention is reasonable, and technique is simple, and cost is low, has good oil resistant, erosion resistance, ageing resistance.
Embodiment
Below by specific examples, the present invention is described in detail.
The mixing compound seal cushion material of paracril viton, by following weight part (kilogram) raw material make: paracril 80, viton 20, tetra-benzyl thiram disulfide 1, silica 12, zinc oxide 2, calcium ferrite 3, zinc phosphate 1, baryta yellow 10,2-thiol group benzimidazolyl 1, accelerant CZ 1, captax 1, N330 carbon black 30, N550 carbon black 24, epoxy Toenol 1140 8, attapulgite modified 10;
Described attapulgite modified by following weight part (kilogram) raw material make: attapulgite 20, clay 10, hexamethylene diisocyanate 3, tri (propylene glycol) diacrylate 2, carborundum powder 9, tetrafluoroethylene 3, fluorite 6, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS 2, aluminium hydroxide 8, calcium stearate 1, Fructus Zanthoxyli oil 1; Preparation method puts into attapulgite, clay, fluorite mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
The mixing compound seal cushion material of paracril viton of the present invention, is made by following concrete steps: paracril, tetra-benzyl thiram disulfide are added in Banbury mixer, be heated to 80-90 ℃, mixing 3-5min; Then be warming up to 110-130 ℃, then add silicon-dioxide, zinc oxide, calcium ferrite, zinc phosphate, baryta yellow, 2-thiol group benzimidazolyl, accelerant CZ, mixing 6-8min, then add captax, N330 carbon black to continue mixing 4-6min; Add the mixing 6-8min of all the other remaining components, obtain.
By gasket material of the present invention and General Purpose Rubber material physicals, contrast as following table.
Use as can be seen from the table rubber seal cushion material of the present invention, comprehensive comparison is good.
Claims (2)
1. the mixing compound seal cushion material of paracril viton, it is characterized in that, by the raw material of following weight part, made: paracril 80-90, viton 20-24, tetra-benzyl thiram disulfide 1-2, silica 1 2-14, zinc oxide 2-3, calcium ferrite 3-4, zinc phosphate 1-2, baryta yellow 10-12,2-thiol group benzimidazolyl 1-2, accelerant CZ 1-2, captax 1-2, N330 carbon black 30-34, N550 carbon black 24-28, epoxy Toenol 1140 8-10, attapulgite modified 10-12;
The described attapulgite modified raw material by following weight part is made: attapulgite 20-24, clay 10-12, hexamethylene diisocyanate 3-4, tri (propylene glycol) diacrylate 2-3, carborundum powder 9-11, tetrafluoroethylene 3-4, fluorite 6-8, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS 2-3, aluminium hydroxide 8-10, calcium stearate 1-2, Fructus Zanthoxyli oil 1-2; Preparation method puts into attapulgite, clay, fluorite mixing calcining furnace and calcine 3-4 hour at 700-720 ℃, cooling, put into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, with clear water, clean and dry, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
2. the mixing compound seal cushion material of paracril viton according to claim 1, is characterized in that, is made: paracril, tetra-benzyl thiram disulfide are added in Banbury mixer, be heated to 80-90 ℃, mixing 3-5min by following concrete steps; Then be warming up to 110-130 ℃, then add silicon-dioxide, zinc oxide, calcium ferrite, zinc phosphate, baryta yellow, 2-thiol group benzimidazolyl, accelerant CZ, mixing 6-8min, then add captax, N330 carbon black to continue mixing 4-6min; Add the mixing 6-8min of all the other remaining components, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310631896.9A CN103694512A (en) | 2013-11-29 | 2013-11-29 | Butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310631896.9A CN103694512A (en) | 2013-11-29 | 2013-11-29 | Butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103694512A true CN103694512A (en) | 2014-04-02 |
Family
ID=50356189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310631896.9A Pending CN103694512A (en) | 2013-11-29 | 2013-11-29 | Butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103694512A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106256852A (en) * | 2015-06-19 | 2016-12-28 | 镇江耀华密封电器有限公司 | A kind of rubber seal components |
| CN106479004A (en) * | 2016-10-21 | 2017-03-08 | 佛山蓝途科技有限公司 | A kind of aging resistance gasket material and preparation method thereof |
| CN107033408A (en) * | 2016-11-07 | 2017-08-11 | 东莞华南设计创新院 | A kind of auto parts machinery rubber seal |
| CN109369990A (en) * | 2018-10-31 | 2019-02-22 | 江苏伊顿航天材料股份有限公司 | A kind of refractory seals part and preparation method thereof |
| CN111247098A (en) * | 2017-10-27 | 2020-06-05 | 株式会社普利司通 | Silica-based nanomaterials as a substitute for ZnO in rubber compounds and their preparation |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844291A (en) * | 2006-04-30 | 2006-10-11 | 长春蓝天密封技术开发有限公司 | Non-asbestos static sealing materials and products thereof |
| CN102382340A (en) * | 2011-10-27 | 2012-03-21 | 安徽金源流体控制技术有限公司 | Liner rubber material of liner rubber butterfly valve and preparation method thereof |
| CN102995446A (en) * | 2012-10-23 | 2013-03-27 | 合肥市安山涂层织物有限公司 | Attapulgite-modified polyvinyl chloride synthetic leather and manufacturing method thereof |
| CN103102531A (en) * | 2012-12-11 | 2013-05-15 | 芜湖恒坤汽车部件有限公司 | Leather cup rubber for laundry machine and preparation method thereof |
| CN103102528A (en) * | 2012-12-11 | 2013-05-15 | 芜湖恒坤汽车部件有限公司 | High-wear-resistance leather cup rubber material for brake and preparation method thereof |
| CN103146346A (en) * | 2013-03-27 | 2013-06-12 | 中国科学院长春应用化学研究所 | Non-asbestos static seal material and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310631896.9A patent/CN103694512A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844291A (en) * | 2006-04-30 | 2006-10-11 | 长春蓝天密封技术开发有限公司 | Non-asbestos static sealing materials and products thereof |
| CN102382340A (en) * | 2011-10-27 | 2012-03-21 | 安徽金源流体控制技术有限公司 | Liner rubber material of liner rubber butterfly valve and preparation method thereof |
| CN102995446A (en) * | 2012-10-23 | 2013-03-27 | 合肥市安山涂层织物有限公司 | Attapulgite-modified polyvinyl chloride synthetic leather and manufacturing method thereof |
| CN103102531A (en) * | 2012-12-11 | 2013-05-15 | 芜湖恒坤汽车部件有限公司 | Leather cup rubber for laundry machine and preparation method thereof |
| CN103102528A (en) * | 2012-12-11 | 2013-05-15 | 芜湖恒坤汽车部件有限公司 | High-wear-resistance leather cup rubber material for brake and preparation method thereof |
| CN103146346A (en) * | 2013-03-27 | 2013-06-12 | 中国科学院长春应用化学研究所 | Non-asbestos static seal material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 伏芬琪等: "聚合物/凹凸棒土纳米复合材料的研究进展", 《表面技术》 * |
| 陈天虎等: "改性凹凸棒石黏土对低浓度磷的吸附热力学", 《硅酸盐学报》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106256852A (en) * | 2015-06-19 | 2016-12-28 | 镇江耀华密封电器有限公司 | A kind of rubber seal components |
| CN106479004A (en) * | 2016-10-21 | 2017-03-08 | 佛山蓝途科技有限公司 | A kind of aging resistance gasket material and preparation method thereof |
| CN107033408A (en) * | 2016-11-07 | 2017-08-11 | 东莞华南设计创新院 | A kind of auto parts machinery rubber seal |
| CN107033408B (en) * | 2016-11-07 | 2019-03-29 | 东莞华南设计创新院 | A kind of automobile parts rubber seal |
| CN111247098A (en) * | 2017-10-27 | 2020-06-05 | 株式会社普利司通 | Silica-based nanomaterials as a substitute for ZnO in rubber compounds and their preparation |
| CN109369990A (en) * | 2018-10-31 | 2019-02-22 | 江苏伊顿航天材料股份有限公司 | A kind of refractory seals part and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103665499B (en) | A kind of rubber synthesis gasket material and preparation method thereof | |
| CN103694610A (en) | Rubber sealing pad material with wear resistance and sealing performance and preparation method of material | |
| CN103694512A (en) | Butadiene-acrylonitrile rubber and fluororubber composite sealing gasket material and preparation method thereof | |
| CN103665602A (en) | Modified butyl rubber sealing gasket material and preparation method thereof | |
| CN103694517A (en) | Nitrile rubber and ethylene propylene diene rubber compound sealing gasket material and preparation method thereof | |
| CN103709714A (en) | Sealing gasket material prepared by mixing three types of rubber and preparation method of sealing gasket material | |
| CN103665682B (en) | A kind of High-elasticity low-compressive deformation rubber gasket material and preparation method thereof | |
| CN103709531A (en) | Non-toxic and environmental friendly composite rubber mixing sealing gasket material and preparation method thereof | |
| CN103709532A (en) | Modified butyl rubber sealing gasket material and preparation method thereof | |
| CN103665473A (en) | Compounded rubber valve sealing gasket material and preparation method thereof | |
| CN103709533A (en) | Multi-rubber compounded sealing gasket material and preparation method thereof | |
| CN103642071B (en) | A kind of gasket material by multiple compounding rubber and preparation method thereof | |
| CN103694516A (en) | Composite rubber sealing pad material with sealing performance and wear resistance and preparation method of material | |
| CN103694607A (en) | High-strength fluorine rubber gasket material and preparation method thereof | |
| CN103694510A (en) | Attapulgite-modified nitrile rubber sealing pad material and preparation method thereof | |
| CN103613867A (en) | Modified compounded rubber sealing gasket material and preparation method thereof | |
| CN103724741A (en) | Compounded rubber seal pad material and preparation method thereof | |
| CN103665674B (en) | A kind of Rubber gasket material and preparation method thereof | |
| CN103709530A (en) | Durable synthetic rubber sealing gasket material and preparation method thereof | |
| CN103665603A (en) | Modified butyl rubber sealing gasket material and preparation method thereof | |
| CN103709525A (en) | Rubber sealing pad material with good safety sealing performance and preparation method thereof | |
| CN103613892A (en) | Modified compounded rubber sealing gasket material and preparation method thereof | |
| CN103613806A (en) | Novel sealing pad material and preparation method thereof | |
| CN103642095B (en) | Rubber gasket material of a kind of good physical properties and preparation method thereof | |
| CN103665494B (en) | A kind of Composite rubber gasket material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140402 |