CN103681318B - Use the method that the selective oxidation technology of silicon manufactures junction barrier schottky diode - Google Patents

Use the method that the selective oxidation technology of silicon manufactures junction barrier schottky diode Download PDF

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CN103681318B
CN103681318B CN201210345828.1A CN201210345828A CN103681318B CN 103681318 B CN103681318 B CN 103681318B CN 201210345828 A CN201210345828 A CN 201210345828A CN 103681318 B CN103681318 B CN 103681318B
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silicon
layer
region
silicon oxide
optical cement
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CN103681318A (en
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关仕汉
李勇昌
彭顺刚
邹锋
王常毅
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Guilin sizhuanggui Microelectronics Co.,Ltd.
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Strong Guilin Microelectronics Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66083Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices
    • H01L29/6609Diodes
    • H01L29/66143Schottky diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/76Making of isolation regions between components
    • H01L21/762Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
    • H01L21/76202Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using a local oxidation of silicon, e.g. LOCOS, SWAMI, SILO
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • H01L29/872Schottky diodes

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

The method that a kind of selective oxidation technology using silicon of disclosure manufactures junction barrier schottky diode, use LOCOS(local oxidation of silicon) formation of silicon oxide, the range of scatter of the foreign ion injected effectively is confined between LOCOS region of silicon oxide, thus effectively reducing the P region of PN junction or the scope of the n-quadrant laterally diffusion of (horizontal direction), thus decrease the Schottky interface shared by P region or n-quadrant horizontal proliferation, therefore the area of Schottky interface can be fully utilized, effective schottky barrier interface is bent to curved surface thus increasing conductive area simultaneously, compensate the area that special-shaped island takies, thus improve function and the efficiency of the energising of barrier junction Schottky diode forward.

Description

Use the method that the selective oxidation technology of silicon manufactures junction barrier schottky diode
Technical field
The present invention designs diode and manufactures field, is specifically related to a kind of method that selective oxidation technology using silicon manufactures junction barrier schottky diode.
Background technology
Schottky diode is the low-power consumption come out in recent years, big electric current, ultra-speed semiconductor device.Its reverse recovery time extremely short (may diminish to a few nanosecond), forward conduction voltage drop is about 0.4V only, and rectified current can reach several thousand milliamperes.These good characteristics be fast recovery diode incomparable.Schottky diode is to utilize the metal-semiconductor junction principle that metal and semiconductor contact are formed to be made, the metal-semiconductor that is otherwise known as (contact) diode or surface barrier diode.
The Schottky barrier interface that normal schottky diode has between coating metal and silicon layer.This interface can turn on big forward current when forward voltage;And stoping current flowing under reverse voltage conditions, only a small amount of reverse leakage occurs.When reverse biased strengthens, reverse leakage can along with increasing, and this is the natural physical characteristic of Schottky barrier.The problem increased to overcome this reverse leakage to increase along with backward voltage, and a kind of junction barrier schottky diode designed, this junction barrier schottky diode adds the zonule of " P " or " N " type semiconductor ion diffusion of multiple isolation under the Schottky barrier interface of normal schottky diode, and the epitaxial region of these " P " type regions and " N " type forms the epitaxial region of multiple PN junction or " N " type region and " P " type and forms multiple PN junction.When reverse biased strengthens, these PN junctions form one layer of vague and general layer under Schottky barrier interface, the thickness of this vague and general layer can increase along with backward voltage and expand, thus reduces the impact on Schottky barrier interface of the electric field of backward voltage, reaches the purpose that reverse leakage can be greatly lowered.But the shortcoming existing for this barrier Schottky diode is: occupy the area of a part of original Schottky barrier interface owing to adding " P " or " N " type island region;So when forward voltage, it is possible to the area of On current diminishes, so the reduction that forward current also can be relative, thus reduce function and the efficiency of forward conduction electric current.Therefore, how to limit addition " P " or " N " type semiconductor ion scope that laterally (horizontal direction) spreads, effective schottky barrier interface is bent to curved surface thus increasing conductive area simultaneously, compensate the area that special-shaped island takies, be the problem needing in barrier Schottky diode manufacturing process to solve.
Summary of the invention
The technical problem to be solved is to provide a kind of method using selective oxidation technology using silicon to manufacture junction barrier schottky diode, the method can reduce " P " or " N " special-shaped semiconductor ion scope that laterally (horizontal direction) spreads of addition, effective schottky barrier interface is bent to curved surface thus increasing conductive area simultaneously, compensate the area that special-shaped island takies, be effectively improved function and the efficiency of the energising of barrier junction Schottky diode forward.
For solving the problems referred to above, the present invention is achieved by the following scheme:
A kind of method that selective oxidation technology using silicon manufactures junction barrier schottky diode, including crystal generation step and encapsulation step, wherein crystal generation step includes:
(1) at silicon chip substrate overlying lid layer silicon epitaxy layer;
(2) first grow up on silicon epitaxy layer silicon oxide one layer thin, it deposits one layer of silicon nitride again;
(3) forming multiple block optical cement region by photoetching process on silicon nitride layer surface, these block optical cement regions are each independently distributed and cover silicon nitride layer surface;
(4) with dry ecthing method, the silicon nitride etch under the region not having optical cement to cover is fallen, then optical cement is removed clean;
(5) using the silicon oxide that boiler tube sintering process is the two-way growth thick layer of upper and lower surface of silicon oxide in the region not having silicon nitride, now due to the growth that silicon oxide is downward, silicon face becomes the lower prominent curved surface that some are separate;
(6) use phosphoric acid that remaining silicon nitride is removed;
(7) in step (6) gained plane of crystal ion implantation implanting impurity ion, the now region of the wafer surface silicon oxide of (5) described thickness in steps, foreign ion is blocked from entering to silicon face;
(8) by boiler tube sintering process, foreign ion is diffused to below silicon chip surface and form PN junction with lower prominent curved regions;
(9) forming a ring-type optical cement region by photoetching process in the surface of step (8) gained crystal, this ring-type optical cement region is positioned at the edge of plane of crystal and covers plane of crystal;
(10) with dry or wet etch method, the silicon oxide under the region not having optical cement to cover is etched away, then optical cement is removed clean;
(11) in step (10) gained wafer surface Schottky metal, and the Schottky interface of metallic silicon is formed with boiler tube or quick heat treatment method;
(12) in the surface metal-layer of step (11) gained wafer surface evaporation or sputter thick layer, then with photoetching and engraving method, surface metal-layer is carried out separating or independent;
(13) silicon chip substrate is thinned to suitable thickness, and at wafer bottom surface evaporation or sputter metal layer on back.
In above-mentioned steps (2), described silicon oxide is SiO2, described silicon nitride is Si3N4
In above-mentioned steps (2), the thickness of silicon oxide is less than the thickness of silicon nitride.
In above-mentioned steps (8), foreign ion diffusion depth in vertical direction is the degree of depth of prominent curved surface less than or equal under epitaxial layer.
In said method, when using N+ type silicon chip substrate, then the epitaxial layer covered is N-type epitaxial layer, the boron ion that foreign ion is P type injected or the compound ions of boron;Additionally, when using P+ type silicon chip substrate, then the epitaxial layer covered is P-type epitaxial layer, and the ion injected is phosphonium ion or the arsenic ion of N-type.
Compared with prior art, the present invention uses LOCOS(local oxidation of silicon) formation of silicon oxide, the range of scatter of the foreign ion injected effectively is confined between LOCOS region of silicon oxide, thus effectively reducing the P region of PN junction or the scope of the n-quadrant laterally diffusion of (horizontal direction), thus decrease the Schottky interface shared by P region or n-quadrant horizontal proliferation, therefore the area of Schottky interface can be fully utilized, effective schottky barrier interface is bent to curved surface thus increasing conductive area simultaneously, compensate the area that special-shaped island takies, thus improve function and the efficiency of the energising of barrier junction Schottky diode forward.
Accompanying drawing explanation
Fig. 1-Fig. 9 is each obtained crystal structure schematic diagram step by step of crystal generation step described in embodiment 1.
In order to implement, crystal generation step described in 2 is finally obtained obtains crystal structure schematic diagram to Figure 10.
Detailed description of the invention
Embodiment 1:
A kind of method that selective oxidation technology using silicon manufactures junction barrier schottky diode, including crystal generation step and encapsulation step, wherein crystal generation step includes:
(1) at N+ type silicon chip substrate overlying lid layer N-type silicon epitaxy layer.As shown in Figure 1.
(2) first grow up on N-type silicon epitaxy layer silicon oxide one layer thin, it deposits one layer of silicon nitride again;And the thickness of silicon oxide is less than the thickness of silicon nitride.In the present embodiment, described silicon oxide is SiO2, its thickness is about 300 angstroms;Described silicon nitride is Si3N4, its thickness is about 2000 angstroms.
(3) forming multiple block optical cement region on silicon nitride layer surface by photoetching process, distribution that these block optical cement regions are each independent also covers silicon nitride layer surface.As shown in Figure 2.
(4) with dry ecthing method, the silicon nitride etch of (now for not having optical cement covering part) under non-block optical cement region is fallen, then optical cement is removed totally.As shown in Figure 3.
(5) using boiler tube sintering process silicon oxide of upper and lower two-way growth thick layer in non-block optical cement region (now for not having silicon nitride overlay area), its thickness is about 1um.Due to the growth that silicon oxide is downward, silicon lower surface becomes the lower prominent curved surface that some are separate;And due to silicon oxide growth upwards, silicon upper surface becomes the upper prominent curved surface that some are separate.As shown in Figure 4.
(6) use phosphoric acid that remaining silicon nitride is removed.
(7) in the compound ions of step (6) the gained plane of crystal boron ion by ion implantation implanting p-type or boron.Now, the region of the silicon oxide of (5) described thickness in steps due to wafer surface, the compound ions of boron ion or boron is blocked from entering to silicon face, and namely the compound ions of boron ion or boron is limited between lower prominent curved surface.As shown in Figure 5.
(8) by boiler tube sintering process, the compound ions of boron or boron is diffused to below silicon face and form PN junction with lower prominent curved regions.Due to the stop of thick silicon oxide, the compound ions of boron or boron diffusion breadth in the horizontal direction is limit between thick silicon oxide layer.It addition, the diffusion depth that the compound ions of boron or boron is in vertical direction is less than or equal to the degree of depth of sunk area, namely elevation of water residing for the bottommost after the compound ions diffusion of boron or boron is higher than elevation of water residing for the bottommost of thick silicon oxide layer.As shown in Figure 6.
(9) forming a ring-type optical cement region by photoetching process in the surface of step (8) gained crystal, this ring-type optical cement region is positioned at the edge of plane of crystal and covers plane of crystal.As shown in Figure 7.
(10) with dry or wet etch method, the silicon oxide under the region not having optical cement to cover is etched away, then optical cement is removed clean.As shown in Figure 8.
(11) in step (10) gained wafer surface Schottky metal, and the Schottky interface of metallic silicon is formed with boiler tube or quick heat treatment method.As shown in Figure 9.
(12) in the anode surface metal level of step (11) gained wafer surface evaporation or sputter thick layer, then with photoetching and engraving method, anode surface metal level is carried out separating or independent.
(13) silicon chip substrate is thinned to suitable thickness, and at wafer bottom surface evaporation or sputtering cathode metal layer on back.
Embodiment 2:
The N-type of embodiment 1 and P type can be exchanged by the present embodiment 2, and obtain with P+ type substrate, the barrier junction Schottky diode of P-type epitaxial layer and N-type ion implanting, as shown in Figure 10.Namely
A kind of method that selective oxidation technology using silicon manufactures junction barrier schottky diode, including crystal generation step and encapsulation step, wherein crystal generation step includes:
(1) at P+ type silicon chip substrate overlying lid layer P-type silicon epitaxy layer;As shown in Figure 1.
(2) first grow up on P-type silicon epitaxy layer silicon oxide one layer thin, it deposits one layer of silicon nitride again;And the thickness of silicon oxide is less than the thickness of silicon nitride.In the present embodiment, described silicon oxide is SiO2, its thickness is about 300A;Described silicon nitride is Si3N4, its thickness is about 2000A.Above-mentioned 1A=10-4u。
(3) forming multiple block optical cement region on silicon nitride layer surface by photoetching process, distribution that these block optical cement regions are each independent also covers silicon nitride layer surface.
(4) with dry ecthing method, the silicon nitride etch of (now for not having optical cement covering part) under non-block optical cement region is fallen, then optical cement is removed totally.
(5) using boiler tube sintering process silicon oxide of upper and lower two-way growth thick layer in non-block optical cement region (now for not having silicon nitride overlay area), its thickness is about 1um.Due to the growth that silicon oxide is downward, silicon lower surface becomes the lower prominent curved surface that some are separate;And due to silicon oxide growth upwards, silicon upper surface becomes the upper prominent curved surface that some are separate.
(6) use phosphoric acid that remaining silicon nitride is removed.
(7) phosphonium ion or the arsenic ion of N-type is injected in step (6) gained plane of crystal ion implantation.Now, the region of the silicon oxide of (5) described thickness in steps due to wafer surface, phosphonium ion or arsenic ion are blocked from entering to silicon face, and namely phosphonium ion or arsenic ion are limited between lower prominent curved surface.
(8) by boiler tube sintering process, phosphonium ion or arsenic ion are diffused to below silicon face and form PN junction with lower prominent curved regions.Due to the stop of thick silicon oxide, phosphonium ion or arsenic ion diffusion breadth in the horizontal direction is limit between thick silicon oxide layer.It addition, the diffusion depth that phosphonium ion or arsenic ion are in vertical direction is less than or equal to the degree of depth of sunk area, namely elevation of water residing for the bottommost after phosphonium ion or arsenic ion diffusion is higher than elevation of water residing for the bottommost of thick silicon oxide layer.
(9) forming a ring-type optical cement region by photoetching process in the surface of step (8) gained crystal, this ring-type optical cement region is positioned at the edge of plane of crystal and covers plane of crystal.
(10) with dry or wet etch method, the silicon oxide under the region not having optical cement to cover is etched away, then optical cement is removed clean.
(11) in step (10) gained wafer surface Schottky metal, and the Schottky interface of metallic silicon is formed with boiler tube or quick heat treatment method;As shown in Figure 10.
(12) in the cathode surface metal level of step (11) gained wafer surface evaporation or sputter thick layer, then with photoetching and engraving method, cathode surface metal level is carried out separating or independent.
(13) silicon chip substrate is thinned to suitable thickness, and at wafer bottom surface evaporation or sputter anode metal layer on back.

Claims (5)

1. use the method that the selective oxidation technology of silicon manufactures junction barrier schottky diode, including crystal generation step and encapsulation step, it is characterised in that: described crystal generation step includes:
(1) at silicon chip substrate overlying lid layer silicon epitaxy layer;
(2) first grow up on silicon epitaxy layer silicon oxide one layer thin, it deposits one layer of silicon nitride again;
(3) forming multiple block optical cement region by photoetching process on silicon nitride layer surface, these block optical cement regions are each independently distributed and cover silicon nitride layer surface;
(4) with dry ecthing method, the silicon nitride etch under the region not having optical cement to cover is fallen, then optical cement is removed clean;
(5) using the silicon oxide that boiler tube sintering process is the two-way growth thick layer of upper and lower surface of silicon oxide in the region not having silicon nitride, now due to the growth that silicon oxide is downward, silicon face becomes the lower prominent curved surface that some are separate;
(6) use phosphoric acid that remaining silicon nitride is removed;
(7) in step (6) gained plane of crystal ion implantation implanting impurity ion, the now region of the surface of the wafer silicon oxide of (5) described thickness in steps, foreign ion is blocked from entering to silicon face;
(8) by boiler tube sintering process, foreign ion being diffused to silicon chip surface P region formed below, its silicon epitaxy layer with lower floor's N-type constitutes PN junction;
(9) forming a ring-type optical cement region by photoetching process in the surface of step (8) gained crystal, this ring-type optical cement region is positioned at the edge of plane of crystal and covers plane of crystal;
(10) with dry or wet etch method, the silicon oxide under the region not having optical cement to cover is etched away, then optical cement is removed clean;
(11) in the surface Schottky metal of step (10) gained wafer, and the schottky interface of metallic silicon is formed with boiler tube or quick heat treatment method;
(12) in the surface metal-layer of the surface of step (11) gained wafer evaporation or sputter thick layer, then with photoetching and engraving method, surface metal-layer is carried out separating or independent;
(13) silicon chip substrate is thinned to suitable thickness, and at the bottom surface of wafer evaporation or sputter metal layer on back.
2. use the method that the selective oxidation technology of silicon manufactures junction barrier schottky diode according to claim 1, it is characterised in that: in step (2), described silicon oxide is SiO2, described silicon nitride is Si3N4
3. the method that the selective oxidation technology of use silicon according to claim 1 or claim 2 manufactures junction barrier schottky diode, it is characterised in that: in step (2), the thickness of silicon oxide is less than the thickness of silicon nitride.
4. use the method that the selective oxidation technology of silicon manufactures junction barrier schottky diode according to claim 1, it is characterised in that: in step (8), foreign ion diffusion depth in vertical direction is the degree of depth of prominent curved surface less than or equal under epitaxial layer.
5. use the method that the selective oxidation technology of silicon manufactures junction barrier schottky diode according to claim 1, it is characterised in that:
When using N+ type silicon chip substrate, then the epitaxial layer covered is N-type epitaxial layer, and the foreign ion injected is the compound ions of the boron ion of P type or boron;
When using P+ type silicon chip substrate, then the epitaxial layer covered is P-type epitaxial layer, and the foreign ion injected is phosphonium ion or the arsenic ion of N-type.
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CN105590850A (en) * 2014-10-23 2016-05-18 无锡华润华晶微电子有限公司 Schottky diode manufacturing method
CN106298775B (en) * 2015-05-20 2019-12-24 北大方正集团有限公司 Hybrid rectifier diode and manufacturing method thereof
CN105226103A (en) * 2015-10-14 2016-01-06 上海芯石微电子有限公司 Containing schottky device and the manufacture method of directed diffusion junctions
CN105762076B (en) * 2016-02-29 2019-01-18 重庆平伟实业股份有限公司 A kind of production technology of diffused high-voltage great-current Schottky chip
CN106298977B (en) * 2016-10-26 2019-11-15 苏州捷芯威半导体有限公司 Diode anode structure, longitudinal diode and transverse diode
CN107221604A (en) * 2017-06-01 2017-09-29 深圳市华星光电技术有限公司 Organic Light Emitting Diode and manufacture method
CN113130624A (en) * 2021-03-26 2021-07-16 先之科半导体科技(东莞)有限公司 Low-loss Schottky rectifier tube and forming process thereof
CN113314618A (en) * 2021-06-04 2021-08-27 厦门吉顺芯微电子有限公司 Planar Schottky rectifier device with increased contact area and manufacturing method thereof

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DE19853743C2 (en) * 1998-11-21 2000-10-12 Micronas Intermetall Gmbh Semiconductor component with at least one Zener diode and at least one Schottky diode connected in parallel thereto, and method for producing the semiconductor components
CN1591908A (en) * 2003-08-18 2005-03-09 谢福淵 Junction barrier schottky device of low forward flow voltage drop and high reverse blocking voltage
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CN101452967B (en) * 2007-11-30 2010-11-03 上海华虹Nec电子有限公司 Schottky barrier diode device and manufacturing method thereof
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