CN103668958B - Impregnation-processantibacterial antibacterial polyester fabric and preparation method thereof - Google Patents

Impregnation-processantibacterial antibacterial polyester fabric and preparation method thereof Download PDF

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Publication number
CN103668958B
CN103668958B CN201210359270.2A CN201210359270A CN103668958B CN 103668958 B CN103668958 B CN 103668958B CN 201210359270 A CN201210359270 A CN 201210359270A CN 103668958 B CN103668958 B CN 103668958B
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Prior art keywords
impregnation
antibacterial
processantibacterial
polyester fabric
preparation
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Expired - Fee Related
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CN201210359270.2A
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Chinese (zh)
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CN103668958A (en
Inventor
宋国新
黄毅
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Guangdong Gaohang Intellectual Property Operation Co ltd
Guangdong Zhida Medical Equipment Science And Technology Co ltd
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Shanghai Taohong Chemical Technology Co Ltd
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Abstract

The invention discloses a kind of Impregnation-processantibacterial antibacterial polyester fabric and preparation method thereof, the preparation method of described Impregnation-processantibacterial antibacterial polyester fabric, comprise dipping, dehydration and baking step, described impregnation steps is: in antibiotic finishing solution, flood 15-20 minute by under dacron normal temperature, in described antibiotic finishing solution, antibacterial finishing agent consumption is 1.0-3.0%o.w.f, and bath raio is 1:15-1:30.Impregnation-processantibacterial antibacterial polyester fabric prepared by the present invention; there is the performance such as deodorization, anticorrosion, high to the bacteriostasis rate of Escherichia coli and staphylococcus aureus, still remain on higher level through 30 washing bacteriostasis rates; thus protection health, that improves clothing wears performance.

Description

Impregnation-processantibacterial antibacterial polyester fabric and preparation method thereof
Technical field
The present invention relates to a kind of dacron and preparation method thereof, particularly relate to a kind of Impregnation-processantibacterial antibacterial polyester fabric and preparation method thereof.
Background technology
As everyone knows, survive various microorganism in the environment of human lives, on the skin of only upper half of human body, every square metre just has 50-5000 microorganism, wherein some is useful to human body, or even it is indispensable, but also there are many microorganisms to impair health, they can survive in people's fabric used in everyday, as socks, underwear, underpants, cotton-wadded quilt, sheet, towel etc., at warm tide. in wet environment, these microorganisms are with the sweat of human secretory, grease, the decomposed substance of scurf or fabric itself is bred rapidly as nutriment, form a large amount of harmful bacterium, they can go out the volatile compounds frowzy such as various lower fatty acid and amine by catalyze metabolic decomposition product, add the smell that the secretion of bacterium itself rots with its dead bones of the body, discharge nauseating bad odor, more seriously they also can produce abnormal stimulation to human body skin, bring out various disease of skin, even can propagate various disease as venereal disease, skin disease etc., unhealthful.In addition, the existence of microorganism also can cause fabric fibre macromolecules degradation, the phenomenon such as make fabric occur tendering, variable color, to go mouldy, and affects the outward appearance of clothes and ornament, color and luster; For some militarias, as parachute, gun cover, tent etc., then entail dangers to safety, affects fighting capacity, and consequence is hardly imaginable, therefore people always by every means kill harmful microorganism.
Antibacterial fabric process refers to use to kill and processes fabric or fiber to the medicament of the microorganism that human body and clothing are harmful to.
But the antibacterial treatment of existing dacron, unsatisfactory.
Summary of the invention
For the deficiencies in the prior art, one of technical problem to be solved by this invention is to provide a kind of preparation method of Impregnation-processantibacterial antibacterial polyester fabric.
Two of technical problem to be solved by this invention is to provide a kind of Impregnation-processantibacterial antibacterial polyester fabric.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of preparation method of Impregnation-processantibacterial antibacterial polyester fabric, comprise dipping, dehydration and baking step, described impregnation steps is: in antibiotic finishing solution, flood 15-20 minute by under dacron normal temperature, in described antibiotic finishing solution, antibacterial finishing agent consumption is 1.0-3.0%o.w.f, and bath raio is 1:15-1:30.
Described baking step is: by fabric drying at 90-110 DEG C of temperature.
Described antibacterial finishing agent, be made up of the component of following weight parts: TCC 10-30 part, 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether 15-25 part, dodecyl carboxymethyl sodium form imidazoline acetate 30-50 part, ethylenediamine two salicyl large acetic acid ferrisodium 0.5-1.5 part, decamethylene biguanides dihydrochloride 4-6 part.
Above-mentioned each component is uniformly mixed, described antibacterial finishing agent can be obtained.
TCC, No. CAS: 101-20-2, molecular formula: C 13h 9cl 3n 2o, English name: Triclocarban, Chinese another name: trichlorine kappa, Trichlorocarbanilide.There is broad spectrum antibacterial, have suppression and killing effect to pathogen microorganisms such as Gram-negative and gram-positive bacteria, fungi and fractionated viral, to light, thermally-stabilised.
2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether, another name: the chloro-2-of triclosan, triclosan, 5-(2,4-dichlorophenoxy) phenol, English name: Phenol, 5-chloro-2-(2,4-dichlorophenoxy), be abbreviated as DP300, No. CAS: 3380-34-5, molecular formula: C 12h 7cl 3o 4.Nontoxic, there is broad-spectrum antimicrobial effect.
Dodecyl carboxymethyl sodium form imidazoline acetate, sodium laulyl carboxymethylimidazoline acetate, No. CAS: 64041-76-5.
The large acetic acid ferrisodium of ethylenediamine two salicyl, Sodium ferric EDDHA, No. CAS: 16455-61-1.
Decamethylene biguanides dihydrochloride, Decamethylenediguanidinedihydrochloride, No. CAS: 301-15-5.
A kind of Impregnation-processantibacterial antibacterial polyester fabric, adopts above-mentioned method for sorting to be prepared from.
The advantage major embodiment of technical solution of the present invention is: Impregnation-processantibacterial antibacterial polyester fabric prepared by the present invention; there is the performance such as deodorization, anticorrosion; high to the bacteriostasis rate of Escherichia coli and staphylococcus aureus; still higher level is remained on through 30 washing bacteriostasis rates; thus protection health, that improves clothing wears performance.
Detailed description of the invention
Embodiment 1
Each raw material is taken by embodiment corresponding to table 11 data.Be uniformly mixed, antibacterial finishing agent of the present invention can be obtained.
Embodiment 2
Each raw material is taken by embodiment corresponding to table 12 data.Be uniformly mixed, antibacterial finishing agent of the present invention can be obtained.
Embodiment 3
Each raw material is taken by embodiment corresponding to table 13 data.Be uniformly mixed, antibacterial finishing agent of the present invention can be obtained.
Table 1: antibacterial finishing agent formula table unit: kilogram
Embodiment 1 Embodiment 2 Embodiment 3
TCC 20 40 20
Irgacare MP 20 / 20
Dodecyl carboxymethyl sodium form imidazoline acetate 40 40 40
The large acetic acid ferrisodium of ethylenediamine two salicyl / 1 1
Decamethylene biguanides dihydrochloride / 5 5
Embodiment 4
The antibiotic finish of dacron:
Dipping: flood under dacron normal temperature 18 minutes in antibiotic finishing solution, in described antibiotic finishing solution, antibacterial finishing agent consumption described in embodiment 1 is 2.0%o.w.f, and bath raio is 1:20.
Dehydration, then by fabric drying at 100 DEG C of temperature, Impregnation-processantibacterial antibacterial polyester fabric of the present invention can be obtained.
Embodiment 5
The antibiotic finish of dacron:
Dipping: flood under dacron normal temperature 18 minutes in antibiotic finishing solution, in described antibiotic finishing solution, antibacterial finishing agent consumption described in embodiment 2 is 2.0%o.w.f, and bath raio is 1:20.
Dehydration, then by fabric drying at 100 DEG C of temperature, Impregnation-processantibacterial antibacterial polyester fabric of the present invention can be obtained.
Embodiment 6
The antibiotic finish of dacron:
Dipping: flood under dacron normal temperature 18 minutes in antibiotic finishing solution, in described antibiotic finishing solution, antibacterial finishing agent consumption described in embodiment 3 is 2.0%o.w.f, and bath raio is 1:20.
Dehydration, then by fabric drying at 100 DEG C of temperature, Impregnation-processantibacterial antibacterial polyester fabric of the present invention can be obtained.
Test case 1
Adopt evaluation the 3rd part of standard GB/T/T 20944.3-2008 antibacterial textile performance: succusion carries out antibiotic property quantitative test, and test result is in table 2.
Impregnation-processantibacterial antibacterial polyester fabric of the present invention, has the performance such as deodorization, anticorrosion, high to the bacteriostasis rate of Escherichia coli and staphylococcus aureus, still remains on higher level through 30 washing bacteriostasis rates, thus protection health, that improves clothing wears performance.

Claims (3)

1. the preparation method of an Impregnation-processantibacterial antibacterial polyester fabric, comprise dipping, dehydration and baking step, it is characterized in that, described impregnation steps is: in antibiotic finishing solution, flood 15-20 minute by under dacron normal temperature, in described antibiotic finishing solution, antibacterial finishing agent consumption is 1.0-3.0%o.w.f, and bath raio is 1:15-1:30;
Described antibacterial finishing agent, be made up of the component of following weight parts: TCC 10-30 part, 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether 15-25 part, dodecyl carboxymethyl sodium form imidazoline acetate 30-50 part, ethylenediamine two salicyl large acetic acid ferrisodium 0.5-1.5 part, decamethylene biguanides dihydrochloride 4-6 part.
2. the preparation method of Impregnation-processantibacterial antibacterial polyester fabric as claimed in claim 1, it is characterized in that, described baking step is: by fabric drying at 90-110 DEG C of temperature.
3. an antibacterial dacron fabric, is characterized in that: adopt the preparation method of the Impregnation-processantibacterial antibacterial polyester fabric described in claim 1 or 2 to be prepared from.
CN201210359270.2A 2012-09-24 2012-09-24 Impregnation-processantibacterial antibacterial polyester fabric and preparation method thereof Expired - Fee Related CN103668958B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104047091B (en) * 2014-06-27 2016-04-13 江苏金宏针纺织有限公司 Fire retardant, anticorrosive polyester knitted fabric
CN111569532A (en) * 2020-04-28 2020-08-25 天津城建大学 Preparation method of environment-friendly efficient antibacterial filter material
CN117488433A (en) * 2023-02-07 2024-02-02 上海康君丝新材料有限公司 Method for manufacturing antibacterial polyester fiber

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5135542A (en) * 1989-03-29 1992-08-04 Nitto Boseki Co., Ltd. Method for finishing a cellulosic fabric: treatment with phosporus amide compound
CN101538770A (en) * 2009-03-04 2009-09-23 常熟市欣鑫经纬编有限公司 Terylene coral fleece blanket fabrics and processing method thereof
CN101716359A (en) * 2009-12-08 2010-06-02 北京欧凯纳斯科技有限公司 Sterilization and pasteurization material and application thereof
CN102771922A (en) * 2012-07-09 2012-11-14 昆山市周市惠宏服装厂 Novel fabric cloth for working clothes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5135542A (en) * 1989-03-29 1992-08-04 Nitto Boseki Co., Ltd. Method for finishing a cellulosic fabric: treatment with phosporus amide compound
CN101538770A (en) * 2009-03-04 2009-09-23 常熟市欣鑫经纬编有限公司 Terylene coral fleece blanket fabrics and processing method thereof
CN101716359A (en) * 2009-12-08 2010-06-02 北京欧凯纳斯科技有限公司 Sterilization and pasteurization material and application thereof
CN102771922A (en) * 2012-07-09 2012-11-14 昆山市周市惠宏服装厂 Novel fabric cloth for working clothes

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Inventor after: Chen Manfu

Inventor after: Qin Hui

Inventor before: Song Guoxin

Inventor before: Huang Yi

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170519

Address after: 528000, No. 816, building 3, building 61, cultural and creative garden, Foshan street, Guicheng street, Nanhai District, Guangdong, China

Patentee after: Guangdong Zhida medical equipment science and Technology Co.,Ltd.

Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China

Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd.

Effective date of registration: 20170519

Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China

Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd.

Address before: 200137 room 1F79, building, No. 528, Yang Gao Bei Road, Shanghai, Pudong New Area

Patentee before: SHANGHAI TAOHONG CHEMICAL TECHNOLOGY Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150916

Termination date: 20210924