CN103666710A - Environmental-friendly hard water resistant cutting fluid and preparation method thereof - Google Patents

Environmental-friendly hard water resistant cutting fluid and preparation method thereof Download PDF

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Publication number
CN103666710A
CN103666710A CN201310653417.3A CN201310653417A CN103666710A CN 103666710 A CN103666710 A CN 103666710A CN 201310653417 A CN201310653417 A CN 201310653417A CN 103666710 A CN103666710 A CN 103666710A
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China
Prior art keywords
parts
cutting fluid
hard water
water
environmental
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Pending
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CN201310653417.3A
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Chinese (zh)
Inventor
章功国
王泾文
段宗银
李纯金
陈超
王淑妍
张少伍
王晓芬
谢勇
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Maanshan Hengyi Machinery Manufacturing Co Ltd
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Maanshan Hengyi Machinery Manufacturing Co Ltd
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Priority to CN201310653417.3A priority Critical patent/CN103666710A/en
Publication of CN103666710A publication Critical patent/CN103666710A/en
Pending legal-status Critical Current

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Abstract

An environmental-friendly hard water resistant cutting fluid is prepared from the following raw material: by weight, 3-4 parts of hydroxyethylidene-1,1-diphosphonic acid, 1-2 parts of morpholine, 1-2 parts of triethanolamine, 3-4 parts of polyethylene glycol, 3-4 parts of polyvinyl butyral, 1-2 parts of capric acid, 14-17 parts of kerosene, 2-3 parts of octyl phenol polyoxyethylene ether, 6-8 parts of an additive and 200parts of water; the environmental-friendly hard water resistant cutting fluid, by using the hydroxyethylidene-1,1-diphosphonic acid, has good calcium carbonate scale and iron scale prevention property, hard water resistant property, rust resistant property, good lubricity, wear resistance, antistatic property, and excellent antibacterial mouldproof performances, is applicable to a variety of cutting modes and workpiece materials, and is environmental-friendly and less harmful to human body.

Description

Anti-hard water cutting fluid of a kind of environmental protection and preparation method thereof
Technical field
The present invention relates to cutting fluid technical field, relate in particular to anti-hard water cutting fluid of a kind of environmental protection and preparation method thereof.
Background technology
Cutting fluid should possess good cooling performance, lubricity, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature.Cutting fluid can be divided into two classes, oil soluble cutting fluid and water-soluble metalworking liquid at present.General oil soluble cutting fluid lubrication performance is good, but poor cooling performance, and contain large amount of organic, contaminate environment.Although some water-soluble metalworking liquid cooling performances are good, there is again the poor problem of oilness and rust-proof effect, therefore research and development have concurrently oilness, cooling, rust-preventing characteristic, easy cleaning, nontoxic, tasteless, non-corrosive to human body, to equipment not burn into the non-staining cutting fluid of environment is just seemed to very important.
Summary of the invention
The object of the present invention is to provide anti-hard water cutting fluid of a kind of environmental protection and preparation method thereof, this cutting fluid has that rust-preventing characteristic is good, the feature of anti-hard water.
Technical scheme of the present invention is as follows:
The anti-hard water cutting fluid of environmental protection, is characterized in that being made by the raw material of following weight part: hydroxy ethylene diphosphonic acid 3-4, morpholine 1-2, trolamine 1-2, polyoxyethylene glycol 3-4, polyvinyl butyral acetal 3-4, capric acid 1-2, kerosene 14-17, polyoxyethylene octylphenol ether 2-3, auxiliary agent 6-8, water 200; Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, aluminum nitride powder 0.1-0.2, alcohol ester 12 1-2, tea-polyphenol 1-2, Kathon 1-2, Sodium orthomolybdate 2-3, Natvosol 5-8, peach gum 2-3, neopentyl glycol 3-4, ammonium persulphate 1-2, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of the anti-hard water cutting fluid of described environmental protection, is characterized in that comprising the following steps: water, polyoxyethylene octylphenol ether are mixed, be heated to 40-50 ℃; Under 3000-4000 rev/min of stirring, add polyoxyethylene glycol, polyvinyl butyral acetal, capric acid, kerosene, auxiliary agent, continue to be heated to 70-80 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-25 minute, obtain.
Beneficial effect of the present invention
Cutting fluid of the present invention is by being used hydroxy ethylene diphosphonic acid, there is good prevention calcium carbonate scale, iron dirt, anti-hard water, rust-preventing characteristic, this cutting fluid also has good oilness, resistance to abrasion, static resistance simultaneously, good antibacterial and mouldproof performance, is applicable to multiple cutting way and workpiece material; And environmentally friendly, little to harm.
Embodiment
The anti-hard water cutting fluid of environmental protection, by following weight part (kilogram) raw material make: hydroxy ethylene diphosphonic acid 3.5, morpholine 1.5, trolamine 1.5, polyoxyethylene glycol 3.5, polyvinyl butyral acetal 3.5, capric acid 1.5, kerosene 16, polyoxyethylene octylphenol ether 2.5, auxiliary agent 7, water 200; Described auxiliary agent by following weight part (kilogram) raw material make: polyoxyethylene sorbitan monooleate 2, aluminum nitride powder 0.1, alcohol ester 12, tea-polyphenol 1, Kathon 1, Sodium orthomolybdate 2, Natvosol 5, peach gum 3, neopentyl glycol 3, ammonium persulphate 1, water 20; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of the anti-hard water cutting fluid of described environmental protection, is characterized in that comprising the following steps: water, polyoxyethylene octylphenol ether are mixed, be heated to 45 ℃; Under 3500 revs/min of stirrings, add polyoxyethylene glycol, polyvinyl butyral acetal, capric acid, kerosene, auxiliary agent, continue to be heated to 75 ℃, stir 13 minutes; Add other remaining components, continue to stir 20 minutes, obtain.
The anti-hard water cutting fluid of the environmental protection testing data that this embodiment obtains is as follows:
Figure BDA0000430874510000021

Claims (2)

1. the anti-hard water cutting fluid of environmental protection, is characterized in that being made by the raw material of following weight part: hydroxy ethylene diphosphonic acid 3-4, morpholine 1-2, trolamine 1-2, polyoxyethylene glycol 3-4, polyvinyl butyral acetal 3-4, capric acid 1-2, kerosene 14-17, polyoxyethylene octylphenol ether 2-3, auxiliary agent 6-8, water 200; Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, aluminum nitride powder 0.1-0.2, alcohol ester 12 1-2, tea-polyphenol 1-2,2-n-octyl-4-isothiazoline-3-ketone 1-2, Sodium orthomolybdate 2-3, Natvosol 5-8, peach gum 2-3, neopentyl glycol 3-4, ammonium persulphate 1-2, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method of the anti-hard water cutting fluid of environmental protection according to claim 1, is characterized in that comprising the following steps: water, polyoxyethylene octylphenol ether are mixed, be heated to 40-50 ℃; Under 3000-4000 rev/min of stirring, add polyoxyethylene glycol, polyvinyl butyral acetal, capric acid, kerosene, auxiliary agent, continue to be heated to 70-80 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-25 minute, obtain.
CN201310653417.3A 2013-12-05 2013-12-05 Environmental-friendly hard water resistant cutting fluid and preparation method thereof Pending CN103666710A (en)

Priority Applications (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104342256A (en) * 2014-09-25 2015-02-11 无锡康柏斯机械科技有限公司 Oil-proof metal cutting liquid and preparation method thereof
CN104560326A (en) * 2014-12-30 2015-04-29 芜湖市润雨精密机械有限公司 Anti-hard-water and anti-fouling water-based cutting fluid and preparation method thereof
CN115786028A (en) * 2017-10-06 2023-03-14 卡斯特罗尔有限公司 Additive composition for metalworking fluids

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240217A (en) * 2008-02-29 2008-08-13 益田润石(北京)化工有限公司 Micro-emulsion type metal cutting liquor composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240217A (en) * 2008-02-29 2008-08-13 益田润石(北京)化工有限公司 Micro-emulsion type metal cutting liquor composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周雍鑫,周俊: "《金属加工液使用指南》", 31 May 2000, 中国石化出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104342256A (en) * 2014-09-25 2015-02-11 无锡康柏斯机械科技有限公司 Oil-proof metal cutting liquid and preparation method thereof
CN104560326A (en) * 2014-12-30 2015-04-29 芜湖市润雨精密机械有限公司 Anti-hard-water and anti-fouling water-based cutting fluid and preparation method thereof
CN115786028A (en) * 2017-10-06 2023-03-14 卡斯特罗尔有限公司 Additive composition for metalworking fluids
CN115786028B (en) * 2017-10-06 2024-04-02 卡斯特罗尔有限公司 Metal working fluid additive composition

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Application publication date: 20140326