CN1036599C - permeable jacket oil - Google Patents
permeable jacket oil Download PDFInfo
- Publication number
- CN1036599C CN1036599C CN94108734A CN94108734A CN1036599C CN 1036599 C CN1036599 C CN 1036599C CN 94108734 A CN94108734 A CN 94108734A CN 94108734 A CN94108734 A CN 94108734A CN 1036599 C CN1036599 C CN 1036599C
- Authority
- CN
- China
- Prior art keywords
- oil
- kilograms
- jacket
- leather
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000005498 polishing Methods 0.000 claims abstract description 13
- 239000005018 casein Substances 0.000 claims abstract description 10
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000021240 caseins Nutrition 0.000 claims abstract description 10
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 8
- 235000011187 glycerol Nutrition 0.000 claims abstract description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 229920002545 silicone oil Polymers 0.000 claims abstract description 8
- 239000008117 stearic acid Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 239000012174 chinese wax Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 235000013305 food Nutrition 0.000 claims description 7
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 6
- 238000004945 emulsification Methods 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 235000010241 potassium sorbate Nutrition 0.000 claims description 5
- -1 Amber acid ester Chemical class 0.000 claims description 4
- 235000013599 spices Nutrition 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 239000012466 permeate Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- CHHHXKFHOYLYRE-STWYSWDKSA-M potassium sorbate Chemical class [K+].C\C=C\C=C\C([O-])=O CHHHXKFHOYLYRE-STWYSWDKSA-M 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 238000002203 pretreatment Methods 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- 239000010985 leather Substances 0.000 abstract description 25
- 230000015572 biosynthetic process Effects 0.000 abstract description 17
- 239000003921 oil Substances 0.000 abstract description 17
- 230000035699 permeability Effects 0.000 abstract description 6
- 239000004359 castor oil Substances 0.000 abstract description 2
- 235000019438 castor oil Nutrition 0.000 abstract description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract description 2
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 229940045860 white wax Drugs 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 16
- 238000003786 synthesis reaction Methods 0.000 description 16
- 239000000463 material Substances 0.000 description 9
- 239000003643 water by type Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 5
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000004302 potassium sorbate Substances 0.000 description 3
- 229940069338 potassium sorbate Drugs 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 210000000795 conjunctiva Anatomy 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 150000003890 succinate salts Chemical class 0.000 description 2
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention belongs to the field of polishing compositions, is used for polishing the surface of leather, and is permeable jacket oil which mainly comprises casein, resin, pigment, preservative, penetrant, white wax, glycerin, castor oil, silicone oil, turpentine, stearic acid and the like. The permeable jacket oil has strong permeability, solves the defects of film formation and poor permeability on the surface of leather, has natural luster, and can be widely applied to leather products.
Description
The present invention relates to a kind of polishing oil for jacket, is a kind of polishing composition, is particularly useful for the polishing oil for jacket of leather surface polishing.
At present, the domestic jacket oil of selling on the market all is filming type, fragrant or medicine type jacket oil.The common feature of this three classes jacket oil is to be coated in leather surface to form one deck protective film, and leather is played protection, soft and moist and effect such as prevent to fade.But facts have proved that above-mentioned jacket oil is short, not durable action time, can not be penetrated into leather organization internal, protection leather natural grain, cause the ventilation property of leather bad, stored for a long time easily mouldy.Chinese patent 90107800 discloses a kind of drug fragrant type jacket oil, and its main purpose is in order to make leather mildew-resistant, mothproof, to increase gloss and protection leather.For this reason, it has increased herbal mediciment, fatting agent etc. in prescription.But this jacket oil through be coated with wipe away after, form conjunctiva at leather surface, poor permeability, action time corresponding weak point, luminance brightness is strong simultaneously, gloss is nature.
The objective of the invention is in order to solve the above-mentioned shortcoming, particularly conjunctiva problem that present jacket oil exists.The polishing oil for jacket that the present invention proposes is wiped away leather surface through being coated with, and is permeable in the middle of the leather fiber, keeps the leather natural grain, strong sense of reality, and good air permeability, toughness is strong.
The objective of the invention is to realize by following prescription (by weight percentage):
Acid casein food grade: the 0.4-3.8% of Chinese wax: 0.5-5%
Peregal: 1-4% silicone oil: 0.3-3.0%
Turps: 0.2-1.0% Viscotrol C: 0.5-8.0%
Amber acid ester: 0.5-8.0% glycerine: 1-5%
Stearic acid: 0.5-2.0% is acrylic resin modified: 5-25%
Pigment, three plough sour potassium, mould inhibitors, spices are an amount of; Surplus is a water.
Accompanying drawing 1 is the technological process of production figure of polishing oil for jacket of the present invention.
In order to obtain polishing oil for jacket of the present invention, according to above-mentioned prescription and 1 its technological process of production is further elaborated by reference to the accompanying drawings:
1, gets Chinese wax and emulsifying agent average adding and put into reactor, heat up (being not less than 90 ℃) , under stirring state, add the softening water of stearic acid, silicone oil and 80 ℃~100 ℃, at the uniform velocity stir After mixing 20 minutes, material is put into emulsifier carry out emulsification through leaving standstill. Material is cooled to after the emulsification Room temperature is put into synthesis tank.
2, (be junket dragon adhesive, its molecular weight is between the 25000-35000, and molecular formula is C in casein with acidity in blender170H
268N
42SPO
51, produced by Inner Mongol Hailar City dairy products factory) and soft Change water and mix thoroughly, under stirring state, add respectively turpentine oil, leather pigment and castor oil, to be mixed equal Put into synthesis tank after even.
3, get bleeding agent amber acid esters, glycerine and put into blender and stir, put into after adding softening water In the synthesis tank.
4, with various material stirrings in the synthesis tank evenly after, under stirring state, add the softening water of surplus Dilution adds respectively acrylic resin modified (being the KS-2 resin), essence, anticorrisive agent then Three potassium sorbates and mould inhibitor are mixed thoroughly and are namely put into the bottle placer tinning after 5 minutes and make finished product.
The KS-2 resin can be buied by market, and its molecular weight is 2000-30000, and this product structure formula is:R, R " be the different carbon chain hydrocarbon-based; X is-COOH ,-CONH2、
The functions such as-CN Group, n=20-30.
Advantage of the present invention is that permeability is strong, and is not residual at leather surface, and chemical reaction does not take place, can Prevent that the leather surface oil layer is dry and cracked. Because the effect of bleeding agent and the collaborative effect between each additive, Make the leather softness and high resilience, good hand feeling, smooth, gloss nature keep the natural grain of leather, Good air permeability can prolong service life of leather. Jacket oil of the present invention is particularly useful for medium and high classes The leather goods.
Below in conjunction with embodiment prescription and production method are described further:
Example 1, get 1 kilogram of Chinese wax, 0.5 kilogram of stearic acid, 1 kilogram of emulsifying agent peregal, 0.3 kilogram of silicone oil, add in the reactor, heat up and be not less than 90 ℃, add 80 ℃~100 ℃ 10 kilograms of softening waters, after mixing 15 minutes thoroughly, continue to add 20 kilograms of softening waters (80 ℃~100 ℃) and stirred 5 minutes, after leaving standstill, material is put into emulsor, the emulsification postcooling is put into synthesis tank to room temperature; Get 1 kilogram of acid casein food grade and softening water and in mixing tank, mix thoroughly for 10 kilograms, add respectively under stirring state then that 0.4 kilogram in turps, leather pigment are an amount of, 2 kilograms of Viscotrol C, put into synthesis tank after mixing; Get 1 kilogram of 1 kilogram of permeate agent succinate and glycerine, put into mixing tank, put into synthesis tank after adding 10 kilograms of softening waters through stirring.Then various materials in the above-mentioned synthesis tank are stirred, and adding surplus softening water dilution under stirring state, add acrylic resin modified 20 kilograms, 0.05 kilogram in essence, 0.05 kilogram of sanitas three potassium sorbate, 0.1 kilogram of mould inhibitor at last respectively, after mixing 5 minutes thoroughly, promptly put into filling machine and carry out tinning, make finished product.
Example 2, get 3 kilograms of Chinese wax, 1.6 kilograms of stearic acid, 2 kilograms of peregals, 0.5 kilogram of silicone oil, add in the reactor, heating up is not less than 90 ℃, adds 80 ℃~100 ℃ 10 kilograms of softening waters, after mixing 15 minutes thoroughly, continue to add 20 kilograms of softening waters (80 ℃~100 ℃) and stirred 5 minutes, after leaving standstill, material is put into emulsor, the emulsification postcooling is put into synthesis tank to room temperature; Getting 3 kilograms of acid casein food grade and softening water mixes thoroughly in mixing tank for 10 kilograms.It is an amount of to add 1.0 kilograms in turps, 4 kilograms of Viscotrol C and leather pigment then under stirring state respectively, puts into synthesis tank after mixing; Get 2 kilograms of 3 kilograms of succinates and glycerine, put into mixing tank, put into synthesis tank after adding 10 kilograms of softening waters through stirring.Then various materials in the above-mentioned synthesis tank are stirred, and adding surplus softening water dilution under stirring state, add acrylic resin modified 15 kilograms, 0.05 kilogram in essence, 0.1 kilogram of mould inhibitor, 0.05 kilogram of three potassium sorbate at last respectively, after mixing 5 minutes thoroughly, promptly put into filling machine and carry out tinning, make finished product.
Example 3, get 5 kilograms of Chinese wax, 2 kilograms of stearic acid, 4 kilograms of peregals, 0.6 kilogram of silicone oil adds in the reactor heat up (being not less than 90 ℃), 10 kilograms of softening waters that add 80 ℃~100 ℃, after mixing 15 minutes thoroughly, continue to add 20 kilograms of softening waters (80 ℃~100 ℃), restir 5 minutes, after leaving standstill, material is put into emulsor, and the emulsification postcooling is put into synthesis tank to room temperature; Get 3 kilograms of acid casein food grade and softening water and mix thoroughly in mixing tank for 10 kilograms, it is an amount of to add 1 kilogram in turps, 5 kilograms of Viscotrol C and leather pigment then under stirring state respectively, puts into synthesis tank after mixing; Get 5 kilograms of succinates, glycerine is put into mixing tank for 2 kilograms, after stir adding 10 kilograms of softening waters, puts into synthesis tank; After various materials stir in the above-mentioned synthesis tank, under stirring state, add the dilution of surplus softening water, add 0.05 kilogram of acrylic resin modified 13 kilograms, 0.05 kilogram in essence, 0.1 kilogram of mould inhibitor and three potassium sorbate at last respectively, after mixing 5 minutes thoroughly, promptly put into filling machine and carry out tinning, make finished product.
Claims (2)
1, a kind of polishing oil for jacket, contain acid casein food grade, acrylic resin modified, fatting agent, pigment, sanitas three potassium sorbates, spices, it is characterized in that also containing permeate agent succinate, Chinese wax, emulsifying agent peregal, glycerine, Viscotrol C, silicone oil, turps and stearic acid in this polishing oil for jacket, its composition is by weight percentage:
Acid casein food grade: the 0.4-3.8% of Chinese wax: 0.5-5%
Peregal: 1-4 % silicone oil: 0.3-3.0%
Turps: 0.2-1.0% Viscotrol C: 0.5-8.0%
Amber acid ester: 0.5-8.0% glycerine: 1-5%
Stearic acid: 0.5-2.0% is acrylic resin modified: 5-25%
Pigment, three plough sour potassium, mould inhibitors, spices are an amount of; Surplus is a water; Acid casein food grade is a casein cement adhesive, and its molecular weight is between the 25000-350000, and molecular formula is C
170H
208N
42SPO
51, acrylic resin modified its molecular weight of the KS-2 of being resin is 2000-30000, structural formula is:
N=20-30, R, R " be the different carbon chain hydrocarbon-based; X is-COOH ,-CONH:,
Functional groups such as-CN.
2, polishing oil for jacket according to claim 1 is characterized in that Chinese wax and emulsifying agent are through heating, after the stirring, emulsification pre-treatment, further handling through emulsor and make wax liquid uniform particles, stable.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN94108734A CN1036599C (en) | 1994-07-25 | 1994-07-25 | permeable jacket oil |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN94108734A CN1036599C (en) | 1994-07-25 | 1994-07-25 | permeable jacket oil |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1100742A CN1100742A (en) | 1995-03-29 |
CN1036599C true CN1036599C (en) | 1997-12-03 |
Family
ID=5033609
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94108734A Expired - Fee Related CN1036599C (en) | 1994-07-25 | 1994-07-25 | permeable jacket oil |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1036599C (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102115639B (en) * | 2011-04-07 | 2013-06-05 | 燕山大学 | Quick polishing shoe cream |
CN103666285A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Caring and polishing oil for leather jacket |
CN103666284A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Waterproof wear-resisting leather clothing brightener |
CN104358148A (en) * | 2014-10-25 | 2015-02-18 | 合肥市安山涂层织物有限公司 | Cold-resistant flame-retardant leather penetrant and preparation method thereof |
CN104358150A (en) * | 2014-10-29 | 2015-02-18 | 合肥市安山涂层织物有限公司 | Strong-alkali-resistant high-permeability penetrant for leather |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3785860A (en) * | 1967-05-24 | 1974-01-15 | Rohm & Haas | Floor polishing method and article |
US4200561A (en) * | 1978-07-17 | 1980-04-29 | Allied Chemical Corporation | Stable, compatible thixotropic gel with copolymer gelling agent |
CN1059923A (en) * | 1990-09-14 | 1992-04-01 | 周志平 | Drug fragrant type jacket oil |
-
1994
- 1994-07-25 CN CN94108734A patent/CN1036599C/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3785860A (en) * | 1967-05-24 | 1974-01-15 | Rohm & Haas | Floor polishing method and article |
US4200561A (en) * | 1978-07-17 | 1980-04-29 | Allied Chemical Corporation | Stable, compatible thixotropic gel with copolymer gelling agent |
CN1059923A (en) * | 1990-09-14 | 1992-04-01 | 周志平 | Drug fragrant type jacket oil |
Also Published As
Publication number | Publication date |
---|---|
CN1100742A (en) | 1995-03-29 |
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