CN103657251A - High silica glass fiber composite high-temperature-resistant filter felt and preparation method thereof - Google Patents

High silica glass fiber composite high-temperature-resistant filter felt and preparation method thereof Download PDF

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CN103657251A
CN103657251A CN201310703066.2A CN201310703066A CN103657251A CN 103657251 A CN103657251 A CN 103657251A CN 201310703066 A CN201310703066 A CN 201310703066A CN 103657251 A CN103657251 A CN 103657251A
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glass fibre
temperature
resistant filter
filter felt
resurrection glass
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CN103657251B (en
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黄美蓉
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Boao Zongheng Network Technology Co ltd
Nantong Jinpeng Glass Fiber Products Co ltd
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Shanghai Qiucheng New Material Technology Co Ltd
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Abstract

The invention discloses a high silica glass fiber composite high-temperature-resistant filter felt and a preparation method thereof. The preparation method of the high silica glass fiber composite high-temperature-resistant filter felt comprises the following steps: (1) vertically interweaving warp basalt yarns and weft polysulfonamide yarns to form base cloth; (2) manufacturing high silica glass fiber into high silica glass fiber layers through an air-laid process or a mechanical-laid process; (3) overlapping the high silica glass fiber layers on the upper surface and the lower surface of the base cloth, and preliminarily pre-punching; (4) main-punching. The prepared high silica glass fiber composite high-temperature-resistant filter felt has the advantages of high-temperature resisting, chemical resisting and inflaming retarding characteristics, high dust removing rate and high strength retention rate after heating for 100 hours, and is applicable to filtering for dust removing in the high-temperature working environment of 300-400 DEG C.

Description

Resurrection glass fibre complex fire resistant filter felt and preparation method thereof
Technical field
The present invention relates to a kind of high temperature filtration felt and preparation method thereof, relate in particular to a kind of resurrection glass fibre complex fire resistant filter felt and preparation method thereof.
Background technology
In China, the develop rapidly of electric power, iron and steel, chemistry, cement, waste incineration etc. " high flow rate, maximum discharge, high pollution " industry, to people, created more rich, easily and efficiently life in, the sustainable development of the natural resources of Ye Dui China, the energy, environment has caused serious threat.In the atmosphere pollution of these social industrial discharges, mainly comprise high-temperature flue gas, dust, SOX, NOX etc.If directly entered in atmosphere without improvement, can directly or indirectly have influence on respiratory system, cardiovascular system, central nervous system, immune system of people etc., and and then threaten the life security of human body.
The main target of industrial dedusting technology is to control the discharge of pollution sources flue gas particles, minimizing atmosphere pollution.The current processing for industrial high temperature flue gas, that mainly takes has wet dedusting, electric precipitation, three kinds of methods of bag-type dusting, wherein sack cleaner is all better than wet dedusting and electric precipitation at aspects such as efficiency of dust collection, disposable and long-term investment expense, equipment requirement and performances, after replacing gradually both and occupy main flow industrial dust collector market.The core of sack cleaner is high temperature resistance filtration material, and the performance quality of high temperature resistance filtration material will be directly connected to efficient, reliable and stable, the long-play of deduster.
Increasingly strict along with domestic and international environmental regulation, countries in the world are more and more paid attention to the exploitation of Filters and application.Home and abroad dust arrester installation has inertial dust separator, cyclone dust collectors, wet scrubber, bag filter, electrostatic precipitator etc. multiple, except specific use, bag filter (hereinafter to be referred as bag hose) and the electrostatic filters of adopting, wherein bag hose accounts for 80% left and right more.The critical component of bag hose is filtering material.Filtering material has cotton, hair, synthetic fibers, glass fibre, ceramic fibre, metallic fiber etc. multiple, and most widely used is glass fibre and synthetic fibers.Glass fibre because temperature tolerance is high, corrosion-resistant, smooth surface, dust peeling property and good stability of the dimension, as filtering material, use existing half a century.
At present, high-temperature filter material industry has to accept challenges, and notice is transferred to " upgrading " from " increment " and come up, specifically comprise promote filtrate strainability, reduce filtration resistance, improve corrosion-and high-temp-resistant performance, increase service life.
Summary of the invention
For above shortcomings in prior art, one of technical problem to be solved by this invention is to provide a kind of preparation method of resurrection glass fibre complex fire resistant filter felt.Two of technical problem to be solved by this invention is to provide a kind of resurrection glass fibre complex fire resistant filter felt.
Technical problem to be solved by this invention is achieved by the following technical solution:
A preparation method for resurrection glass fibre complex fire resistant filter felt, comprises the steps:
(1) by warp thread basalt yarn and weft yarn polysulfonamide yarns vertical interweaving mutually, make base cloth;
(2) resurrection glass fibre is made to resurrection glass fibre layer through air-laid process or mechanical net-forming process;
(3) lapping of base cloth above and below stacks above-mentioned resurrection glass fibre layer, preliminary pre-needling;
(4) main acupuncture, makes described resurrection glass fibre complex fire resistant filter felt.
Further, can also comprise:
(5) impregnation process:
(6) preliminary drying, oven dry and high-temperature shaping.
The impregnation process of step (5) is specially:
The described resurrection glass fibre complex fire resistant filter felt that step (4) is made floods in dipping emulsion;
Technological parameter: dipping temperature 70-90 ℃, dip time 5-20 minute, controls liquid carrying rate (being pick-up) 50-150%;
Described dipping emulsion, is comprised of following materials by weight percentage: 10-14% ptfe emulsion, 1-3% silicone oil, 0.2-0.6% coupling agent, surplus are water.Under normal temperature and pressure, each raw material is uniformly mixed, can makes described dipping emulsion.
In described ptfe emulsion, polytetrafluoroethylene content is 55-65wt%.Ptfe emulsion, can select the ptfe emulsion of the trade mark TE3859 of du pont company.TE3859 ptfe emulsion is milky white liquid, is the dispersion concentrate under nonionic surface active agent exists after tetrafluoroethylene polymerization, polytetrafluoroethylene (PTFE) solids content 60wt%.Through disperseing the goods after concentrate is processed, there is remarkable chemical stability and remarkable resistance to chemical attack ability, as resistance to strong acid, highly basic, strong oxidizer etc., there is outstanding heat-resisting, cold-resistant and wear resistance, long-term serviceability temperature scope is-200~250 ℃.Also have excellent electrical insulating property, and be not subject to the impact of temperature and frequency.
Described silicone oil can be: chain alkyl end-blocking silicone oil DK-285, long-chain alkyl benzene SE2203 silicone oil or Dow Corning Corporation
Figure BDA0000440989720000031
pMX-200 silicone oil.
Described coupling agent is silane coupler.Preferably, described coupling agent is N-β-(aminoethyl)-γ aminopropyl trimethoxysilane and/or 3-mercaptopropyltriethoxysilane.Optimally, described coupling agent is comprised of 10-30 weight portion N-β-(aminoethyl)-γ aminopropyl trimethoxysilane and 10-30 weight portion 3-mercaptopropyltriethoxysilane.
N-β-(aminoethyl)-γ aminopropyl trimethoxysilane, CAS:1760-24-3.Another name: silane coupler KH-900, the external corresponding trade mark: A-1122 (GE); Z-6020 (DOW CORNING); KBM-603 (Japanese SHIN-ETSU HANTOTAI).
3-mercaptopropyltriethoxysilane, CAS:14814-09-6.Another name: silane coupler 580, the external corresponding trade mark: A-1891 (U.S. GE/OSi company) and KBM-803 (Japanese Shin-Etsu Chemial Co., Ltd).
In step (6), described preliminary drying temperature is 100-120 ℃; Bake out temperature is 130-150 ℃; High-temperature shaping temperature is 210-250 ℃.
In step (6), described preliminary drying, oven dry and high-temperature shaping complete by framing shaping machine.
Air-laid process described in step (2), is state of the art, is specifically as follows:
1. fiber is opened bag; 2. fiber opening-employing air flow delivery fiber, to form the mixed and disorderly even fibre web of arranging of fiber; 3. fiber mixes; 4. fibre impurity-removing; 5. fiber feeds the cylinder of high speed rotary after mixing; 6. fibre shedding; 7. air-flow conveying fiber is condensed into fleece; 8. output fiber net-evenly carried and condense upon on lace curtaining by air-flow, forms distributed in three dimensions, in length and breadth to the little fleece of powerful difference.
Mechanical net-forming process described in step (2), is state of the art, is specifically as follows:
1. shredding: by opener, resurrection glass fibre is carried out to shredding, make it reach fluffy state;
2. combing: send into carding machine and be carded to fibre web;
3. lapping: use lapping machine to carry out lapping.
In the present invention, described resurrection glass fibre Shi You U.S. H.I.Thompson company, on the Research foundation of OWENS CORNING glass fibre company, takes the lead in carrying out suitability for industrialized production.Its manufacture method is to select suitable pristine glass composition, makes the various goods such as yarn, cloth according to simple glass fibre manufacturing technique, through acid leach, by being dissolved in sour component in glass, sweetens off, and makes SiO 2enriching quantity reaches more than 96%, then through thermal sintering sizing, obtains the high silica fiber goods of heatproof.
Resurrection glass fibre is a kind of high-temperature-resistant inorganic fibre, softening point approaches 1700 ℃, can under 900 ℃ of environment, use for a long time, moment can resistance to thousands of degree airflow scourings, thereby, can be used for the purposes such as spacecraft solar heat protection ablator, high temperature resistant thermal insulation fire-proof material, high-temperature insulation material, high-temperature gas gather dust, liquid filtering, metal molten filtration, purification.
The present invention also provides a kind of resurrection glass fibre complex fire resistant filter felt, adopts said method to be prepared from.
The resurrection glass fibre complex fire resistant filter felt that adopts the present invention to prepare, there is high temperature resistant, chemical resistance and fire-retardant characteristic, and after dust is peeled off rate and heating in 100 hours, strength retention is higher, is applicable to dust removal by filtration in 300-400 ℃ of high-temperature work environment.
The specific embodiment
Embodiment 1
The preparation method of resurrection glass fibre complex fire resistant filter felt, comprises the steps:
(1) by warp thread basalt yarn and weft yarn polysulfonamide yarns in air-jet loom vertical interweaving mutually, make base cloth; Control warp count: weft count=1:1, base cloth grammes per square metre 400g/m 2.
(2) by resurrection glass fibre through mechanical net-forming process, make resurrection glass fibre layer;
1. shredding: by opener, resurrection glass fibre is carried out to shredding, make it reach fluffy state; 2. combing: send into carding machine and be carded to fibre web; 3. lapping: use lapping machine to carry out lapping.
(3) lapping of base cloth above and below stacks above-mentioned resurrection glass fibre layer, preliminary pre-needling;
(4) main acupuncture, makes described resurrection glass fibre complex fire resistant filter felt.
The resurrection glass fibre complex fire resistant filter felt finally making, is three layers of layer structure, and ground floor is resurrection glass fibre layer; The second layer is base cloth, and described base cloth is interwoven by warp thread basalt yarn and weft yarn polysulfonamide yarns; The 3rd layer is resurrection glass fibre layer.
Table 1: resurrection glass fibre complex fire resistant filter felt material grammes per square metre table
? Grammes per square metre
Resurrection glass fibre layer (ground floor) 200g/m 2
Base cloth (second layer) 400g/m 2
Resurrection glass fibre layer (the 3rd layer) 200g/m 2
Embodiment 2
On the resurrection glass fibre complex fire resistant filter felt basis of embodiment 1 preparation, further, increase following step:
(5) impregnation process:
By table 2, corresponding embodiment 2 takes each raw material, under normal temperature and pressure, each raw material is uniformly mixed, and can make described dipping emulsion.
The described resurrection glass fibre complex fire resistant filter felt that step (4) is made carries out impregnation process, technological parameter: 80 ℃ of dipping temperatures, dip time 10 minutes, controls liquid carrying rate (being pick-up) 100% in above-mentioned dipping emulsion.
(6) preliminary drying, oven dry and high-temperature shaping in framing shaping machine, controlling preliminary drying temperature is 110 ℃; Bake out temperature is 140 ℃; High-temperature shaping temperature is 230 ℃.
Table 2 dipping emulsion formula table unit: kilogram
Figure BDA0000440989720000051
Embodiment 3
Embodiment 3 is substantially the same manner as Example 2, and unique difference is: dipping emulsion formula is different.
By table 2, corresponding embodiment 3 takes each raw material, under normal temperature and pressure, each raw material is uniformly mixed, and can make dipping emulsion.
Embodiment 4
Embodiment 4 is substantially the same manner as Example 2, and unique difference is: dipping emulsion formula is different.
By table 2, corresponding embodiment 4 takes each raw material, under normal temperature and pressure, each raw material is uniformly mixed, and can make dipping emulsion.
Embodiment 5
Embodiment 5 is substantially the same manner as Example 2, and unique difference is: dipping emulsion formula is different.
By table 2, corresponding embodiment 5 takes each raw material, under normal temperature and pressure, each raw material is uniformly mixed, and can make dipping emulsion.
Test case
According to HJ/T324-2006 environmental protection product specification requirement sack cleaner filtrate, to carry out dust and peel off rate and the rear strength retention test of heating in 100 hours, concrete data see the following form.
Table 3: test data table
? Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Dust is peeled off rate, % 85 83 82 69
Strength retention after heating in 100 hours, % 94 92 91 88
Embodiment 2-4 compares with embodiment 5, increases impregnation process, and after dust is peeled off rate and heating in 100 hours, strength retention is all greatly improved.
Especially, embodiment 2 compares with embodiment 3-4, coupling agent N-β-(aminoethyl)-γ aminopropyl trimethoxysilane and the composite use of 3-mercaptopropyltriethoxysilane in the dipping emulsion of impregnation process, Synergistic, after dust is peeled off rate and heating in 100 hours, strength retention is all greatly improved.

Claims (5)

1. a preparation method for resurrection glass fibre complex fire resistant filter felt, comprises the steps:
(1) by warp thread basalt yarn and weft yarn polysulfonamide yarns vertical interweaving mutually, make base cloth;
(2) resurrection glass fibre is made to resurrection glass fibre layer through air-laid process or mechanical net-forming process;
(3) lapping of base cloth above and below stacks above-mentioned resurrection glass fibre layer, preliminary pre-needling;
(4) main acupuncture, makes described resurrection glass fibre complex fire resistant filter felt.
2. the preparation method of resurrection glass fibre complex fire resistant filter felt as claimed in claim 1, is characterized in that, also comprises the steps:
(5) impregnation process;
(6) preliminary drying, oven dry and high-temperature shaping.
3. the preparation method of resurrection glass fibre complex fire resistant filter felt as claimed in claim 2, is characterized in that, the impregnation process of described step (5) is:
The described resurrection glass fibre complex fire resistant filter felt that step (4) is made floods in dipping emulsion;
Described dipping emulsion, is comprised of following materials by weight percentage: 10-14% ptfe emulsion, 1-3% silicone oil, 0.2-0.6% coupling agent, surplus are water;
Described coupling agent is N-β-(aminoethyl)-γ aminopropyl trimethoxysilane and/or 3-mercaptopropyltriethoxysilane, preferably, described coupling agent is comprised of 10-30 weight portion N-β-(aminoethyl)-γ aminopropyl trimethoxysilane and 10-30 weight portion 3-mercaptopropyltriethoxysilane.
4. the preparation method of resurrection glass fibre complex fire resistant filter felt as claimed in claim 2 or claim 3, is characterized in that:
In step (6), described preliminary drying temperature is 100-120 ℃, and bake out temperature is 130-150 ℃, and high-temperature shaping temperature is 210-250 ℃.
5. a resurrection glass fibre complex fire resistant filter felt, adopts in claim 1-4 method described in any one to be prepared from.
CN201310703066.2A 2013-12-18 2013-12-18 Resurrection glass fibre complex fire resistant filter felt and preparation method thereof Expired - Fee Related CN103657251B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104786616A (en) * 2015-04-23 2015-07-22 陕西华特新材料股份有限公司 Preparation method of high-silicon-oxygen composite felt
CN106039845A (en) * 2016-06-30 2016-10-26 安徽省德邦瓷业有限公司 Ceramic filter material and preparation method thereof
CN107227611A (en) * 2017-07-06 2017-10-03 清远凯荣德玻璃纤维有限公司 Surface conditioning agent and preparation method thereof
CN107604669A (en) * 2017-10-23 2018-01-19 安徽屹翔滤材有限公司 A kind of preparation method of glass fiber filter felt
CN111188195A (en) * 2020-01-14 2020-05-22 广东东方一哥新材料股份有限公司 Silicon nitride fiber surface treating agent and preparation method thereof
CN111389095A (en) * 2020-04-06 2020-07-10 台州市皓天产业用布股份有限公司 High silica polytetrafluoroethylene tectorial membrane filter cloth

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CN101032674A (en) * 2006-03-08 2007-09-12 东丽纤维研究所(中国)有限公司 Filtering material of thermal stability and the purpose thereof
CN101406780A (en) * 2007-10-08 2009-04-15 东丽纤维研究所(中国)有限公司 Filter material and use
CN101564619A (en) * 2008-04-22 2009-10-28 东丽纤维研究所(中国)有限公司 Reinforcing fabric for non-woven fabric heat-resisting filter material and application thereof
CN101612496A (en) * 2009-07-29 2009-12-30 东华大学 High temperature resistance basalt fiber composite filter material and preparation method
CN202136879U (en) * 2011-06-22 2012-02-08 中材科技股份有限公司 Filter material coated with basalt fiber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101032674A (en) * 2006-03-08 2007-09-12 东丽纤维研究所(中国)有限公司 Filtering material of thermal stability and the purpose thereof
CN101406780A (en) * 2007-10-08 2009-04-15 东丽纤维研究所(中国)有限公司 Filter material and use
CN101564619A (en) * 2008-04-22 2009-10-28 东丽纤维研究所(中国)有限公司 Reinforcing fabric for non-woven fabric heat-resisting filter material and application thereof
CN101612496A (en) * 2009-07-29 2009-12-30 东华大学 High temperature resistance basalt fiber composite filter material and preparation method
CN202136879U (en) * 2011-06-22 2012-02-08 中材科技股份有限公司 Filter material coated with basalt fiber

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104786616A (en) * 2015-04-23 2015-07-22 陕西华特新材料股份有限公司 Preparation method of high-silicon-oxygen composite felt
CN106039845A (en) * 2016-06-30 2016-10-26 安徽省德邦瓷业有限公司 Ceramic filter material and preparation method thereof
CN107227611A (en) * 2017-07-06 2017-10-03 清远凯荣德玻璃纤维有限公司 Surface conditioning agent and preparation method thereof
CN107604669A (en) * 2017-10-23 2018-01-19 安徽屹翔滤材有限公司 A kind of preparation method of glass fiber filter felt
CN111188195A (en) * 2020-01-14 2020-05-22 广东东方一哥新材料股份有限公司 Silicon nitride fiber surface treating agent and preparation method thereof
CN111389095A (en) * 2020-04-06 2020-07-10 台州市皓天产业用布股份有限公司 High silica polytetrafluoroethylene tectorial membrane filter cloth

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