CN103651473A - Insecticidal combination containing metaflumizone and cyantraniliprole - Google Patents
Insecticidal combination containing metaflumizone and cyantraniliprole Download PDFInfo
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- CN103651473A CN103651473A CN201210412012.6A CN201210412012A CN103651473A CN 103651473 A CN103651473 A CN 103651473A CN 201210412012 A CN201210412012 A CN 201210412012A CN 103651473 A CN103651473 A CN 103651473A
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- metaflumizone
- insect amide
- cyanogen insect
- cyantraniliprole
- pesticidal combination
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Abstract
The invention relates to an insecticidal combination containing metaflumizone and cyantraniliprole. The insecticidal combination comprises effective components obtained by mixing the metaflumizone and the cyantraniliprole, and also comprises auxiliary components; the mass ratio of the metaflumizone to the cyantraniliprole of the effective components is (1-80):(80-1); the total mass of the metaflumizone and the cyantraniliprole which serve as the effective components accounts for 1-80 percent of the total mass of the whole combination. The mixed pesticide combination disclosed by the invention can be prepared into pesticide formulations such as missible oil, a suspending agent, wettable powder, water dispersible granules, emulsion in water and microemulsion. The insecticidal combination is mainly used for preventing and treating larvas and adults of lepidoptera, insect pests of hemiptera and certain coleopteras.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, particularly relate to a kind of Pesticidal combination that contains metaflumizone and cyanogen insect amide.
Background technology
Metaflumizone is a kind of brand-new compound that BASF Aktiengesellschaft and Japanese agricultural chemicals company develop jointly, and belongs to semicarbazones insecticides.The mechanism of action of metaflumizone is unique, and itself has insecticidal activity, does not need bioactivation, with existing each insecticides without cross resistance.Metaflumizone can be prevented and treated larva, the adult of lepidoptera pest and some coleoptera effectively, can also be for preventing and treating the insects such as ant, termite, fly class, cicada dung beetle.Metaflumizone chemical name is (E+Z)-2-[2-(4-cyano group benzene)-1-(3-trifluoromethylbenzene) ethylidene]-N-(4-trifluomethoxybenzene) hydrazine carbonyl oxamides, its structural chemical formula is
Cyanogen insect amide is also bromine cyanogen insect amide (cyantraniliprole, it is E.I.Du Pont Company's second generation ryanodine receptor inhibitor insecticides that success is developed after chlorantraniliprole, cyanogen insect amide is that the various polar groups by changing on phenyl ring form, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.Residual effect is short, and insecticidal action is fast, the cyanogen insect amide chemistry bromo-1-of 3-(3-chloro-2-pyridyl)-4 by name, and 5-dihydro-1 h-pyrazole-5-formamide, its chemical structural formula is
In the real process of agricultural production, using chemical agent is the most effectively means of control plant pest, but the problem the most easily producing by chemical control insect is the generation of pest resistance to insecticide.And long-term use single chemical insecticide continuously high dose, easily cause the series of problems such as residual, environmental pollution of medicament.Reasonably chemical insecticide is composite or be mixed and have expansion insecticidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay pest resistance and the positive feature such as drug-fast generation and development, pesticide compositional or to be mixed be one of the effective method the most addressing the above problem.We filter out metaflumizone and cyanogen insect amide is composite on the basis of lab screening and field trial, have obvious synergistic effect.And about metaflumizone and the composite Pesticidal combination of cyanogen insect amide and application, there is no at present people reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective agricultural insecticide composition.Be mainly used in preventing and treating larva, the adult of Lepidoptera, Semiptera insect and some coleoptera.
Technical scheme of the present invention realizes by following measures:
A kind of Pesticidal combination that contains metaflumizone and cyanogen insect amide, in this Pesticidal combination, the mass ratio of active ingredient metaflumizone and cyanogen insect amide is 1～80: 80～1, described Pesticidal combination of the present invention is through toxicity test experimental verification, the mass ratio of metaflumizone and cyanogen insect amide is 1～40: 40～1 o'clock, and synergistic effect is better.
The formulations of pesticide that compound pesticide composition of the present invention can be mixed with are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.Metaflumizone and the cyanogen insect amide gross mass in preparation accounts for the 1%-80% of the whole quality of the pharmaceutical preparations, while wherein accounting for 5%-50%, and toxicity and residually reach good balance, cost is also lower.
The specific embodiments of the formulations of pesticide that Pesticidal combination of the present invention is mixed with is as follows:
Described Pesticidal combination is cream preparation, and the mass fraction of component is:
1～80 part of metaflumizone
1～80 part of cyanogen insect amide
10～30 parts of conventional emulsifiers
20～50 parts of conventional solvents
1～5 part of conventional synergist.
The concrete production stage of this cream preparation is for first adding active ingredient metaflumizone and cyanogen insect amide in solvent the oily liquids that becomes transparent and homogeneous after adding again emulsifier, synergist to stir after dissolving completely, filling, can be made into the cream preparation of the present composition.
Described Pesticidal combination is suspending agent, and the mass fraction of component is:
1～80 part of metaflumizone
1～80 part of cyanogen insect amide
5～20 parts of dispersants
1～5 part of antifreezing agent
0.1～2 part of thickener
0.1～0.8 part of defoamer
0～10 part of penetrating agent
0.1～5 part of pH value conditioning agent
Water surplus.
The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active ingredient metaflumizone and cyanogen insect amide, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, can be made into the suspending agent preparation of the present composition.
Described Pesticidal combination is wetting powder, and the mass fraction of component is:
1～80 part of metaflumizone
1～50 part of cyanogen insect amide
3～10 parts of dispersants
1～5 part of wetting agent
Filler surplus.
The concrete production stage of this wetting powder is: by above-mentioned formula, active ingredient metaflumizone is mixed with cyanogen insect amide and dispersant, wetting agent and filler, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
Described Pesticidal combination is water dispersible granules, and the mass fraction of component is:
1～80 part of metaflumizone
1～50 part of cyanogen insect amide
3～10 parts of dispersants
1～10 part of wetting agent
1～5 part of disintegrant
Filler surplus.
The concrete production stage of this water dispersible granules is: by above-mentioned formula, active ingredient metaflumizone is mixed with cyanogen insect amide and dispersant, wetting agent, disintegrant and filler, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, can be made into the water dispersible granules of the present composition.
Described Pesticidal combination is aqueous emulsion, and the mass fraction of component is:
1 ~ 50 part of metaflumizone
1 ~ 50 part of cyanogen insect amide
3～30 parts of emulsifier
5～15 parts of solvents
2～15 parts of stabilizing agents
1～5 part of antifreezing agent
0.1～8 part of defoamer
0.2～2 part of thickener
Water surplus
The concrete production stage of this aqueous emulsion is: first metaflumizone and cyanogen insect amide, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, can be made into the aqueous emulsion of the present composition.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, and diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in water equal solvent are arbitrarily than the mixture forming.
Described dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene methyl ether condensate sulfate, alkylsulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, and Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen is phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, a kind of in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
In Pesticidal combination of the present invention, active ingredient metaflumizone and cyanogen insect amide are composite has a notable synergistic effect, can reduce effective ingredient consumption, delay the generation of pest resistance to insecticide, and reduced to become to produce cost and use cost, be mainly used in preventing and treating larva, the adult of Lepidoptera, Semiptera insect and some coleoptera.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio of below mentioning (comprising percentage) is all ratio of quality and the number of copies.
Embodiment: metaflumizone proportioning co-toxicity experiments different from cyanogen insect amide.
1.1 reagent agent
96% the former medicine of Buprofezin, 95% the former medicine of cyanogen insect amide, above-mentioned former medicine provides by research and development department of Qingdao Hailir Pesticides and Chemical Co., Ltd..
1.2 test targets
The third-instar larvae of the responsive type beet armyworm that 5 generations of indoor continuous raising and its Individual Size are consistent with physiological status.Temperature (25 ± 2) ℃.Relative moisture 65% ± 5%, periodicity of illumination 12/12h (L/D).
1.3 experimental procedure
1.3.1 medicament preparation
First use the former medicine of acetone solution, according to the result of preliminary experiment, two appropriate former medicines are made into 5 different proportionings, with acetone, each processing is diluted to respectively to 5 concentration gradients more stand-by, the ratio of 5 metaflumizone proportioning active ingredients different from cyanogen insect amide is respectively 20:22; 24:18; 28:14; 32:10; 36:6.
1.3.2 chemicals treatment
The drop method that adopts NY/T1 154.1-2006 to recommend is measured.By micro intravenous drip device solvent clean, regulate dropper to stand-by state.With writing brush, choose the examination worm CO of neat and consistent
2slight paralysis is placed in 9cm culture dish, then with micro intravenous drip device, medicament is dripped to the belly of polypide by head, every some drops physic liquor 0.1L, the corresponding acetone containing with drop 0.1L be treated to contrast, the examination worm after drop is moved to (28
2) ℃, in the culture dish of relative moisture 75%, normally cultivate.Every processing repeats for 4 times, 20 examination worms of every repetition.
1.4 control time
After processing, 24h investigation examination worm death condition (judgement examination worm death standard is gently to sting without autonomic response with pin), records total borer population and dead borer population.
1.5 data statistics and analysis
According to investigation statistics, calculate the corrected mortality that each is processed.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1 154.7-2006.If contrast lethality <5%, does not proofread and correct, contrast lethality, between 5%-20%, is proofreaied and correct by formula 2, contrast lethality >20%, and test need be reformed.
The logarithm value of drug concentration (mg/L) of take is independent variable x, and the probability value of corrected mortality of take is dependent variable y, sets up respectively virulence regression equation formula, adopts DPS software to calculate the LC of single dose and each proportioning mixture
50according to the abundant method of Sun Yun, calculate co-toxicity coefficient (CTC).Co-toxicity coefficient CTC, computing formula is as follows: (take metaflumizone as standard medicament, its toxicity index is 100):
The LC of the toxicity index of cyanogen insect amide (TI)=metaflumizone
50the LC of/cyanogen insect amide
50* 100
The LC of true toxicity index (ATI)=metaflumizone of M
50the LC of/M
50* 100
TI * P cyanogen insect amide of TI * P metaflumizone+cyanogen insect amide of theoretical toxicity index (TTI)=metaflumizone of M
TTI * 100 of the ATI/M of the co-toxicity coefficient of M (CTC)=M
In formula:
M is the mixture of metaflumizone and the different proportionings of cyanogen insect amide
P metaflumizone is metaflumizone shared ratio in mixture
P cyanogen insect amide is cyanogen insect amide shared ratio in mixture
2.1 toxicity test results
Table 1 metaflumizone and the cyanogen insect amide indoor measurement result to beet pretty young woman at night
As can be seen from the table, in active ingredient first dimension salt: triflumuron ratio is 20:22; 24:18; 28:14; 32:10; When 36:6 dilutes respectively, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein metaflumizone: the synergistic effect that cyanogen insect amide is 28::14 is the most obvious, and co-toxicity coefficient is 174.39.Result of the test shows, under indoor conditions, metaflumizone and cyanogen insect amide all have higher activity to beet armyworm, and suggestion is carried out further field control effectiveness test to suitable proportion 28::14 left and right mixture preparation, to evaluate its field practical application effect.
The experimental result of 3 field trial control beet armyworms, paddy rice rice leaf roller
3.1 field trial control beet armyworms
3.1.1 test method
Test is carried out at Kaiping City, Guangdong Province suburb truck garden.By each, process design concentration and carry out routine to water spray.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.During dispenser, field beet armyworm is 1～2 instar larvae peak period.
Duration of test weather is good, and daily mean temperature is 17.8～26.4 ℃.Dispenser same day is without rain.
3.1.2 investigation method
In dispenser Qian Mei community by 5 samplings of diagonal. every wild cabbage 2～3 strains (depending on insect density) of choosing Beet Armyworm Eggs and larva.Statistics is demarcated beet exigua larvae head number in strain. using this as dispenser before insect population radix.After dispenser the 3rd, 7,10d investigates respectively the beet exigua larvae number of determining residual survival in strain. using and proofread and correct insect population decline rate as control efficiency
3.1.3 drug effect computational methods
Insect population decline rate (%)=(larva number after medicine prelarva number-medicine)/medicine prelarva number * 100
Preventive effect (%)=(treatment region insect population decline rate-contrast insect population decline rate)/(100-check plot insect population decline rate) * 100
3.1.4 poisoning investigation method
Within 1,3,7,14 days after medicine, observe wild cabbage growing state, range estimation medicament to wild cabbage without poisoning.
3.1.5 field control effectiveness test result
The experimental result of table 2 treatment agent control beet armyworm
The Mixed Pharmacy of different proportion, tests by different consumptions as can be seen from Table 2, and after medicine, it is all better than contrasting medicament to the control of beet armyworm.42% metaflumizone cyanogen insect amide (28:14) SC insecticidal effect of 14 days after medicine is respectively 90.24,91.64,92.61..Insecticidal effect increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to wild cabbage does not all appear in each treatment agent, illustrates that it is safe to wild cabbage.Advise that the insecticide different from the mechanism of action mixes use to delay the generation of pest resistance to insecticide.
4.1 field experiment control paddy rice rice leaf roller
4.1.1 test method
Test in Xiangyin, Hunan institute of agricultural sciences experimental field.By each, process design concentration and carry out routine to water spray.Spraying equipment is WF-16 type knapsack hand sprayer, and shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.During dispenser, field rice leaf roller is 1～2 instar larvae peak period.Every 667 m
2to the water yield, be 50kg.
Duration of test weather is good, and daily mean temperature is 19.0～28.2 ℃.Dispenser same day is without rain.
4.1.2 investigation method
Adopt 5 point samplings, 5 points are selected in every community, every community 20m
2, 5 clumps every, investigate altogether 25 clumps of paddy rice.Before dispenser and after dispenser the 3rd, 7d investigates respectively whole blades of 25 clumps, wins all the old and new worm bags, then stripping bag records residual borer population alive, calculates insect population decline rate and proofreaies and correct preventive effect; After medicine, 20d investigates leaf roll number the present age when harm is shaped, and calculates leaf roll rate and preventive effect.Notice that viewing test chemicals treatment has or not poisoning to paddy rice.
4.1.3 drug effect computational methods.
Insect population decline rate (%)=
* 100
Correction preventive effect (%)=
* 100;
Leaf roll preventive effect (%)=
* 100.
4.1.4 poisoning investigation method
It is good that community paddy growth is respectively processed in duration of test observation, all finds no poisoning phenomenon and occur.
4.2 field control effectiveness test result of the tests
Table 3 treatment agent control paddy rice rice leaf roller field control effectiveness test result
As can be seen from Table 3, the Mixed Pharmacy of different proportion, by different consumptions, carry out field trial, after medicine, it is all better than contrasting medicament to the control efficiency of paddy rice rice leaf roller, 42% metaflumizone cyanogen insect amide (28:14) control paddy rice rice leaf roller is effective, insecticidal effect increases progressively along with the increase of consumption, more than the lasting period reaches 20d.20d after medicine, this processing leaf roll preventive effect reaches more than 85%, shows that this patent has very strong desinsection and protecting effect of leaves.According to experimental observation, each medication processing all without poisoning, finds that this composite product also has good preventive effect to rice fulgorid to paddy rice simultaneously.Suggestion in the insect ovum hatching peak phase to the phase dispenser of 1--2 instar larvae.It is to crop and Environmental security, and use is worth promoting.
By above raw survey and field experiment; we can know that the compounded pesticides that the present invention contains metaflumizone and cyanogen insect amide has good control efficiency to insects such as beet armyworm, paddy rice rice leaf roller; to target crop safety; compare with single dose; Pesticidal combination of the present invention has mechanism of action uniqueness; consumption is few; instant effect; the advantage that lasting period is long; so; in research and development of the present invention and popularization, have very large economic benefit, to the volume increase of peasant household crop with increase income and the protection tool of local environment is of great significance.
Claims (5)
1. a Pesticidal combination that contains metaflumizone and cyanogen insect amide, it is characterized in that: the active ingredient of this Pesticidal combination is metaflumizone and cyanogen insect amide binary built, all the other are auxiliary element, and wherein the mass ratio of active ingredient metaflumizone and cyanogen insect amide is 1～80: 80～1.
2. Pesticidal combination according to claim 1, is characterized in that: the mass ratio of metaflumizone and cyanogen insect amide is preferably 1～40: 40～1.
3. Pesticidal combination according to claim 1, is characterized in that: metaflumizone and the cyanogen insect amide gross weight in preparation accounts for 1%～80% of whole preparation gross mass.
4. Pesticidal combination according to claim 3, is characterized in that: metaflumizone and the cyanogen insect amide gross weight in preparation accounts for 5%～50% of whole preparation gross mass.
5. according to the Pesticidal combination described in claim 1 or 2 or 3 or 4, it is characterized in that: the formulations of pesticide that compound pesticide composition of the present invention can be made are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104012558A (en) * | 2014-05-14 | 2014-09-03 | 青岛瀚生生物科技股份有限公司 | Compound insecticide containing metaflumizone and tetrchlorantraniliprole |
| CN105994328A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| CN103238614A (en) * | 2012-02-10 | 2013-08-14 | 陕西美邦农药有限公司 | Insecticidal composition containing metaflumizone and cyantraniliprole |
-
2012
- 2012-10-25 CN CN201210412012.6A patent/CN103651473A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| CN103238614A (en) * | 2012-02-10 | 2013-08-14 | 陕西美邦农药有限公司 | Insecticidal composition containing metaflumizone and cyantraniliprole |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104012558A (en) * | 2014-05-14 | 2014-09-03 | 青岛瀚生生物科技股份有限公司 | Compound insecticide containing metaflumizone and tetrchlorantraniliprole |
| CN105994328A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof |
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Application publication date: 20140326 |