CN103643773A - Photoinduced optical storage ceramic tile and producing method thereof - Google Patents
Photoinduced optical storage ceramic tile and producing method thereof Download PDFInfo
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- CN103643773A CN103643773A CN201310672431.8A CN201310672431A CN103643773A CN 103643773 A CN103643773 A CN 103643773A CN 201310672431 A CN201310672431 A CN 201310672431A CN 103643773 A CN103643773 A CN 103643773A
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- photic
- light
- optical storage
- temperature frit
- photic light
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- 239000000919 ceramic Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000003860 storage Methods 0.000 title abstract description 7
- 230000003287 optical effect Effects 0.000 title abstract 6
- 235000015895 biscuits Nutrition 0.000 claims abstract description 16
- 238000007639 printing Methods 0.000 claims abstract description 12
- 239000011521 glass Substances 0.000 claims abstract description 10
- 239000004744 fabric Substances 0.000 claims abstract description 8
- 238000010304 firing Methods 0.000 claims abstract 2
- 239000000463 material Substances 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 19
- 239000011449 brick Substances 0.000 claims description 15
- 238000004020 luminiscence type Methods 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000012190 activator Substances 0.000 claims description 6
- 238000007688 edging Methods 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 6
- 150000002910 rare earth metals Chemical class 0.000 claims description 6
- 229910003668 SrAl Inorganic materials 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims 5
- 239000000126 substance Substances 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000005034 decoration Methods 0.000 abstract description 2
- 239000000049 pigment Substances 0.000 abstract description 2
- 239000011232 storage material Substances 0.000 abstract 2
- 238000007650 screen-printing Methods 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 description 6
- 230000002688 persistence Effects 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 238000004891 communication Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000002431 foraging effect Effects 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- -1 is prepared from Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
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- 239000004615 ingredient Substances 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- 230000000630 rising effect Effects 0.000 description 1
- 239000001060 yellow colorant Substances 0.000 description 1
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Abstract
The invention discloses a photoinduced optical storage ceramic tile and a producing method thereof. Photoinduced optical storage materials are made to be a photoinduced optical storage glass layer on a ceramic biscuit firing billet through a printing or cloth technology, various colors can be displayed in the dark, and the afterglow time is long. Silk-screen printing or cloth technology can be adopted, patterns and designs can be changed at any time, and female and male dies can have the various decoration artistic effects strong in stereoscopic impression and rich in pattern gradation in cooperation with pigment cooler modulation. The producing method of the photoinduced optical storage ceramic tile solves the problem that existing photoinduced optical storage materials are poor in wear resistance, weather resistance and chemical resistance.
Description
Technical field
The invention belongs to the preparation field of architectural pottery product, be specifically related to a kind of photic light ceramic brick and production method thereof held.
Background technology
Photic light-storing material is called again light storage type self luminous material, on-radiation light-storing material, non-transformer self-luminescent material etc.This material was initiatively inhaled visible rays such as holding sunshine, light, ultraviolet light, veiling glare after 5～10 minutes, just can continue in the dark luminous 6-8 hour, and can according to actual needs, make it send the multiple colouramas such as red, green, blue, Huang, purple.Due to its distinctive high brightness, fast extinction, the long good physicochemical properties such as light that hold, making it be widely used in the every field such as architectural decoration, communications and transportation, security against fire, electronic communication, electric apparatus, instrument and meter, petrochemical industry, subway tunnel, printing printing and dyeing, advertising board, bullion, is extremely rising decorative hair luminescent material of 21 century.
The sign made from photic light-storing material, can be widely used in road caution sign, prohibitory sign, Warning Mark, tourist district's sign, road construction safety sign and facility, changeable-message sign, people can clearly recognize in the weather of dark, foggy, bad weather, reduce the incidence of traffic accident, make the guiding of highway communication more convenient, thoughtful.Photic light-storing material is a kind of luminescent material of Intelligent energy-saving, its not electricity consumption, and equipment that need not be complicated, does not generate heat, can not cause fire, utilizes the sunlight on daytime and the light at night to hold light; Night automatic luminous, completely without manual operation.
The photic light-storing material great majority that use for safety sign on the market at present adopt the resin paste that contains transparent resinous principle and light-storage luminant pigment ingredient and form light-storage luminant layer, the transparent resinous principle that coordinates 95% weight of total amount in resin paste, above-mentioned material is as the uses such as mark of road, and abrasion performance, weatherability, chemical resistance are all poor.
Summary of the invention
In view of the deficiencies in the prior art, the object of the present invention is to provide a kind of photic light ceramic brick and production method thereof held, be intended to solve existing photic light-storing material abrasion performance, weatherability, the poor problem of chemical resistance.
For achieving the above object, the technical solution used in the present invention is as follows:
The photic light ceramic brick that holds is made photic luminescence glass layer by photic light-storing material through printing or distributing technique on ceramic biscuit, can present in the dark multiple color, and persistence is long.
Described photic luminescence glass layer, wherein, if by typography, formula by mass percentage, comprises 10 ~ 30% photic light-accumulating powder, 10 ~ 30% high temperature frit, 0 ~ 1% glaze stain and 40 ~ 60% stamp-pad ink; If press distributing technique, formula by mass percentage, comprises 10 ~ 50% photic light-accumulating powder, 60 ~ 80% low temperature frit and 0 ~ 1% glaze stain.
Wherein, described photic light-accumulating powder is rear-earth-doped high temperature long-afterglow material, by rare earth activators doping matrix material, is prepared from, and matrix material is specially Sr
4a1
4o
25, SrAl
2o
4, Sr
2mgSi
2o
7, CaA1
2o
4, CaTiO
3in one or more combination.
Wherein, rare earth activators comprises Eu
2+, Dy
3+, Nd
3+, Ce
3+, Pr
3+, Tb
3+, Yb
2+in one or more combination.
Wherein, the fineness of described high temperature frit is 100-200 order; The fineness of low temperature frit is 70-100 order.
The present invention discloses a kind of photic process of holding light ceramic brick product, this technique can adopt serigraphy or distributing technique, can change at any time floral designs, coordinate colorant toning, male and female mold more can present the multiple decorative artistic effect that third dimension is strong, pattern level is abundant.
Mainly comprise the steps:
(1) the photic light-accumulating powder taking by formula is crossed to 800 mesh sieves;
(2) if by typography, take high temperature frit and glaze stain by formula, after mixing with photic light-accumulating powder, cross 80 mesh sieves, add stamp-pad ink, stir; If press distributing technique, by formula, take low temperature frit and glaze stain, after mixing with photic light-accumulating powder, cross 80 mesh sieves;
(3), if by typography, the slip preparing is crossed to the logical reticulated printing of 80 orders on ceramic biscuit; If press distributing technique, mixed frit is crossed to the logical screen cloth material of 80 orders on ceramic biscuit;
(4) in adobe, execute again one deck low temperature frit;
(5) through 850-950 ℃ of kiln, burn till afterwards edging polishing.
beneficial effect
1, photic light-storing material is covered on ceramic body as glass composite bed, the product of making is compared to resinae product on the market, more wear-resisting, chemical resistance, longer service life.
2, adopt ceramic process to produce, technology controlling and process is easy, can be used for producing in enormous quantities.
3, adopt frit serigraphy or distributing technique, can change at any time floral designs, coordinate colorant toning, male and female mold more can present the multiple decorative artistic effect that third dimension is strong, pattern level is abundant.
Accompanying drawing explanation
Fig. 1 is the rear-earth-doped photic process chart prepared by light ceramic brick that holds.
The specific embodiment
The photic light ceramic brick that holds is made photic luminescence glass layer by photic light-storing material through printing or distributing technique on ceramic biscuit.
Described photic luminescence glass layer, wherein, if by typography, formula by mass percentage, comprises 10 ~ 30% photic light-accumulating powder, 10 ~ 30% high temperature frit, 0 ~ 1% glaze stain and 40 ~ 60% stamp-pad ink; If press distributing technique, formula by mass percentage, comprises 10 ~ 50% photic light-accumulating powder, 60 ~ 80% low temperature frit and 0 ~ 1% glaze stain.
Wherein, described photic light-accumulating powder is rear-earth-doped high temperature long-afterglow material, by rare earth activators doping matrix material, is prepared from, and matrix material is specially Sr
4a1
4o
25, SrAl
2o
4, Sr
2mgSi
2o
7, CaA1
2o
4, CaTiO
3in one or more combination.
Wherein, rare earth activators comprises Eu
2+, Dy
3+, Nd
3+, Ce
3+, Pr
3+, Tb
3+, Yb
2+in one or more combination.
Wherein, the fineness of described high temperature frit is 100-200 order; The fineness of low temperature frit is 70-100 order.
The present invention discloses a kind of photic process of holding light ceramic brick, comprise the steps:
(1) the photic light-accumulating powder taking by formula is crossed to 800 mesh sieves;
(2) if by typography, take high temperature frit and glaze stain by formula, after mixing with photic light-accumulating powder, cross 80 mesh sieves, add stamp-pad ink, stir; If press distributing technique, by formula, take low temperature frit and glaze stain, after mixing with photic light-accumulating powder, cross 80 mesh sieves;
(3), if by typography, the slip preparing is crossed to the logical reticulated printing of 80 orders on ceramic biscuit; If press distributing technique, mixed frit is crossed to the logical screen cloth material of 80 orders on ceramic biscuit;
(4) in adobe, execute again one deck low temperature frit;
(5) through 850-950 ℃ of kiln, burn till afterwards edging polishing.
Process of the present invention is made photic luminescence glass layer by photic light-storing material through printing or distributing technique on ceramic biscuit, can present in the dark multiple color, and persistence is long.This technique can adopt serigraphy or distributing technique, can change at any time floral designs, coordinates colorant toning, male and female mold more can present the multiple decorative artistic effect that third dimension is strong, pattern level is abundant.Method disclosed by the invention, has solved existing photic light-storing material abrasion performance, weatherability, the poor problem of chemical resistance.
Embodiment 1:
By mass percentage, by 15% Sr
4a1
4o
25doping Eu
2+, Dy
3+energy-saving luminous material and 15% CaA1
2o
4doping Eu
2+, Nd
3+energy-saving luminous material is crossed 800 mesh sieves together, mixes with 70% low temperature frit (fineness is 70-100 order), crosses afterwards 80 mesh sieves.Get ceramic biscuit, mixed frit is crossed to the logical screen cloth material of 80 orders on ceramic biscuit, then execute one deck low temperature frit.Through 850 ℃ of kilns, burn till afterwards, edging polishing, finished product holds light ceramic brick for what send out in the dark coloured light sky blue, reaches 6.5 hours persistence.This Ceramic Tiles has 4 grades of abrasion resistancies, good weatherability properties, is difficult for aging, strong resistance to chemical corrosion, 18%(V/V) hydrochloric acid---GHA level, 100g/L potassium hydroxide---GHA level.
Embodiment 2:
By mass percentage, by 25% Sr
2mgSi
2o
7energy-saving luminous material is crossed 800 mesh sieves, mixed afterwards 80 mesh sieves, then add 50% stamp-pad ink with 25% high temperature frit (fineness is 100-200 order), stirs.Mixed slip is crossed to the logical reticulated printing of 80 orders on ceramic biscuit, then execute one deck low temperature frit.Through 950 ℃ of kilns, burn till afterwards, edging polishing, finished product is the green light of turning blue in the dark holds light ceramic brick, reaches 8 hours persistence.This Ceramic Tiles has 4 grades of abrasion resistancies, good weatherability properties, is difficult for aging, strong resistance to chemical corrosion, 18%(V/V) hydrochloric acid---GHA level, 100g/L potassium hydroxide---GHA level.
Embodiment 3:
By mass percentage, by 30% SrAl
2o
4doping Eu
2+, Dy
3+energy-saving luminous material is crossed 800 mesh sieves, mixes with 70% low temperature frit (fineness is 70-100 order).Additional 0.3% golden yellow colorant, 0.3% Red pigment, mix respectively.Get ceramic biscuit, mixed frit crossed respectively to 80 orders flower nets, through secondary material distributing on ceramic biscuit.After cloth, then execute one deck low temperature frit, through 900 ℃ of kilns, burn till afterwards edging polishing.Finished product, for the colour with floral designs holds light ceramic brick, reaches 7 hours persistence.This Ceramic Tiles has 4 grades of abrasion resistancies, good weatherability properties, is difficult for aging, strong resistance to chemical corrosion, 18%(V/V) hydrochloric acid---GHA level, 100g/L potassium hydroxide---GHA level.
Finally it should be noted that: obviously, above-described embodiment is only for example of the present invention is clearly described, and the not restriction to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without also giving all embodiments.And the apparent variation of being amplified out thus or change are still among protection scope of the present invention.
Claims (8)
1. the photic light ceramic brick that holds, is characterized in that: on ceramic biscuit, photic light-storing material is made to photic luminescence glass layer by printing or distributing technique.
2. the photic light ceramic brick that holds according to claim 1, it is characterized in that: while adopting typography, the raw material mass mixture ratio of described photic luminescence glass layer, comprises 10 ~ 30% photic light-accumulating powder, 10 ~ 30% high temperature frit, 0 ~ 1% glaze stain and 40 ~ 60% stamp-pad ink; Adopt distributing technique, the raw material mass mixture ratio of described photic luminescence glass layer, comprises 10 ~ 50% photic light-accumulating powder, 60 ~ 80% low temperature frit and 0 ~ 1% glaze stain.
3. the photic light ceramic brick that holds according to claim 2, is characterized in that: described photic light-accumulating powder is rear-earth-doped high temperature long-afterglow material, by rare earth activators doping matrix material, be prepared from,
Wherein, described matrix material is specially Sr
4a1
4o
25, SrAl
2o
4, Sr
2mgSi
2o
7, CaA1
2o
4, CaTiO
3in one or more combination;
Described rare earth activators comprises Eu
2+, Dy
3+, Nd
3+, Ce
3+, Pr
3+, Tb
3+, Yb
2+in one or more combination.
4. a photic production method of holding light ceramic brick as described in claim 1-3 any one, is characterized in that: comprises the steps,
(1) the photic light-accumulating powder taking by raw material proportioning is sieved;
(2) if by typography, take high temperature frit and glaze stain by raw material proportioning, after mixing with photic light-accumulating powder, cross 80 mesh sieves, add stamp-pad ink, stir; If press distributing technique, by raw material proportioning, take low temperature frit and glaze stain, after mixing with photic light-accumulating powder, cross 80 mesh sieves;
(3), if by typography, the slip preparing is crossed to logical reticulated printing on ceramic biscuit; If press distributing technique, mixed frit is crossed to logical screen cloth material on ceramic biscuit;
(4) in adobe, execute again one deck low temperature frit;
(5) through kiln, burn till afterwards edging polishing.
5. production method according to claim 4, is characterized in that: the photic light-accumulating powder in described step (1) is crossed grit number and is: 800 orders.
6. production method according to claim 4, is characterized in that, in described step (2), the fineness of high temperature frit is 100-200 order; The fineness of low temperature frit is 70-100 order.
7. production method according to claim 4, is characterized in that, the order number of crossing logical reticulated printing or cloth in described step (3) is: 80 orders.
8. production method according to claim 4, is characterized in that, in described step (5), firing temperature is 850-950 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310672431.8A CN103643773B (en) | 2013-12-12 | 2013-12-12 | One is photic stores light ceramic brick and production method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310672431.8A CN103643773B (en) | 2013-12-12 | 2013-12-12 | One is photic stores light ceramic brick and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103643773A true CN103643773A (en) | 2014-03-19 |
| CN103643773B CN103643773B (en) | 2015-11-25 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310672431.8A Active CN103643773B (en) | 2013-12-12 | 2013-12-12 | One is photic stores light ceramic brick and production method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108484225A (en) * | 2015-12-30 | 2018-09-04 | 李乔利 | A kind of application of accumulating type luminous glaze glass ceramic material |
| CN112010673A (en) * | 2020-10-26 | 2020-12-01 | 佛山市东鹏陶瓷发展有限公司 | Luminous ceramic tile and preparation method thereof |
| CN113845306A (en) * | 2021-10-09 | 2021-12-28 | 广东松发陶瓷股份有限公司 | Ceramic color glaze material for underglaze transfer printing decoration, daily ceramic utensil and preparation method thereof |
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|---|---|---|---|---|
| CN1197043A (en) * | 1998-04-27 | 1998-10-28 | 况学成 | Luminous printing glaze and prodn. method of printed luminous glazed tile |
| CN1408679A (en) * | 2002-08-28 | 2003-04-09 | 佛山欧神诺陶瓷有限公司 | Method for producing pattern permeating ceramic tile |
| GB2404379A (en) * | 2003-07-12 | 2005-02-02 | Andrew David Curtis | Method of producing a photoluminescent mosaic glass tile |
| CN1609027A (en) * | 2003-10-20 | 2005-04-27 | 梁锋 | High temperature luminous glazing and its production process and application in luminous glazed tile |
| CN101215189A (en) * | 2008-01-21 | 2008-07-09 | 尤晴波 | Outdoor cold-light source (luminous brick, noctilucent brick, fluorescent brick) |
| KR20090007342U (en) * | 2008-01-16 | 2009-07-21 | 김진철 | A Photo Luminescence Tile For Safety Refuge Mark |
-
2013
- 2013-12-12 CN CN201310672431.8A patent/CN103643773B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1197043A (en) * | 1998-04-27 | 1998-10-28 | 况学成 | Luminous printing glaze and prodn. method of printed luminous glazed tile |
| CN1408679A (en) * | 2002-08-28 | 2003-04-09 | 佛山欧神诺陶瓷有限公司 | Method for producing pattern permeating ceramic tile |
| GB2404379A (en) * | 2003-07-12 | 2005-02-02 | Andrew David Curtis | Method of producing a photoluminescent mosaic glass tile |
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| CN101215189A (en) * | 2008-01-21 | 2008-07-09 | 尤晴波 | Outdoor cold-light source (luminous brick, noctilucent brick, fluorescent brick) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108484225A (en) * | 2015-12-30 | 2018-09-04 | 李乔利 | A kind of application of accumulating type luminous glaze glass ceramic material |
| CN112010673A (en) * | 2020-10-26 | 2020-12-01 | 佛山市东鹏陶瓷发展有限公司 | Luminous ceramic tile and preparation method thereof |
| CN113845306A (en) * | 2021-10-09 | 2021-12-28 | 广东松发陶瓷股份有限公司 | Ceramic color glaze material for underglaze transfer printing decoration, daily ceramic utensil and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103643773B (en) | 2015-11-25 |
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Address after: 528138 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan Patentee after: FOSHAN OCEANO CERAMICS Co.,Ltd. Address before: 528137 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan Patentee before: OCEANO CERAMICS Co.,Ltd. |
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Effective date of registration: 20231228 Address after: 333000 Jingdezhen Ceramic Industrial Park, Fuliang County, Jingdezhen City, Jiangxi Province Patentee after: JINGDEZHEN OUSHENNUO CERAMIC CO.,LTD. Address before: 528138 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan Patentee before: FOSHAN OCEANO CERAMICS Co.,Ltd. |