CN103639403A - Special cobalt-based alloy powder for continuous wave fiber laser cladding - Google Patents
Special cobalt-based alloy powder for continuous wave fiber laser cladding Download PDFInfo
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- CN103639403A CN103639403A CN201310589796.4A CN201310589796A CN103639403A CN 103639403 A CN103639403 A CN 103639403A CN 201310589796 A CN201310589796 A CN 201310589796A CN 103639403 A CN103639403 A CN 103639403A
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- alloy powder
- continuous wave
- cobalt
- fiber laser
- based alloy
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- 239000000843 powder Substances 0.000 title claims abstract description 30
- 238000004372 laser cladding Methods 0.000 title claims abstract description 13
- 229910000531 Co alloy Inorganic materials 0.000 title abstract 4
- 239000000835 fiber Substances 0.000 title abstract 4
- 238000005253 cladding Methods 0.000 claims abstract description 14
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 14
- 239000010941 cobalt Substances 0.000 claims abstract description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 12
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052796 boron Inorganic materials 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 9
- 239000010703 silicon Substances 0.000 claims abstract description 9
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 21
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 239000000956 alloy Substances 0.000 claims description 16
- 239000013307 optical fiber Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 230000007547 defect Effects 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000012535 impurity Substances 0.000 abstract 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000005336 cracking Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005088 metallography Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Abstract
The invention discloses a special cobalt-based alloy powder for continuous wave fiber laser cladding. The special cobalt-based alloy powder for continuous wave fiber laser cladding contains, by weight, 8-12% of silicon nitride, 2-5% of antimony, 4-5% of boron, 3-5% of silicon, 5-8% of aluminum oxide, 1-2% of carbon and the balance of cobalt and inevitable impurities. The cobalt-based alloy powder is specially used for the cladding process of a continuous wave fiber laser, and a metal cladding layer which is compact in texture and high in hardness, toughness and corrosion resistance and does not have the defects of air holes, cracks, hole shrinking and the like can be formed on the surface of a tool and mold of base materials. Moreover, the technology is simple and environmentally friendly, and pre-heat treatment and post-heat treatment are not needed.
Description
Technical field
The present invention relates to a kind of alloy powder, be especially exclusively used in the Co-based alloy powder of continuous wave optical-fiber laser cladding.
Background technology
The principle of laser melting coating utilizes high energy laser beam to irradiate metal material exactly, makes its surface form laser molten pool, fills in new interpolation material simultaneously, treats that laser is cooling in the lump after inswept, forms thus the new cladding layer of one deck in metal surface.
Yet, on domestic market, almost there is no the metal dust of continuous wave optical-fiber laser cladding special use, common used alloy powder is mostly the metal alloy powders that is exclusively used in carbon dioxide laser.Because two kinds of sharp light wavelengths are different, carbon dioxide laser alloy powder used is directly used in after the cladding of continuous wave optical-fiber laser, laser absorption rate is lower, and easily there is the defects such as crackle, shrinkage porosite, shrinkage cavity, pore in cladding layer, for example in most self-fluxing alloy powders, the content of boron and silicon is higher, make some in laser cladding process be mingled with as borosilicate cannot be smoothly from emersion in the molten bath of rapid solidification, cause laser cladding layer cracking sensitivity large, when laser cladding layer hardness is high, cracking phenomena is particularly evident.Therefore, be necessary to develop a kind of metal alloy powders that is specifically designed to the cladding of continuous wave optical-fiber laser.
Summary of the invention
Technical problem to be solved by this invention is: the Co-based alloy powder that is exclusively used in the cladding of continuous wave optical-fiber laser is provided, this Co-based alloy powder is exclusively used in the cladding process of continuous wave optical fiber laser, can form one deck dense structure on the tool and mould surface of base material, the defects such as pore-free, crackle, shrinkage cavity, have the Metal Melting coating of high rigidity, high tenacity, highly corrosion resistant.And technique is simple, environmental protection, without heat treatment in advance and heat treatment afterwards.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is: be exclusively used in the Co-based alloy powder of continuous wave optical-fiber laser cladding, by its weight percent meter, contain 8-12% silicon nitride, 2-5% antimony, 4-5% boron, 3-5% silicon, 5-8% aluminium oxide, 1-2% carbon, surplus is cobalt.
The optimum ratio that is exclusively used in the Co-based alloy powder of continuous wave optical-fiber laser cladding is, comprises 9% silicon nitride, 4% antimony, and 5% boron, 3% silicon, 5% aluminium oxide, 1% carbon, surplus is cobalt.
The effect of the various compositions in metal alloy powders of the present invention:
Cobalt (Co) element: as the aggregate of alloy powder, thorough melting when cladding, together forms laser molten pool with the metal base of molten condition is uniformly distributed after coagulation for other elements or compound and becomes cladding layer in molten bath.
Silicon nitride (SiN
4): as adding material, silicon nitride has higher hardness and wearability, can improve hardness and the wearability of cladding layer metal; In addition, silicon nitride also plays deoxidation voluntarily and slag making, and silicon nitride can also be controlled dilution factor, improves the utilization rate of powder.
Antimony (Sb): fusing point is low, can be used for reducing the fusing point of alloy powder, thereby can reduce energy output.
Boron (B): play deoxidation voluntarily and slag making in alloy powder, can preferentially form borate with the oxygen element that enters molten bath, be covered in weld pool surface, prevent liquid metal over oxidation, low-alloyed fusing point can also fall, improve the wettability of melt to parent metal, the mobility of alloy and surface tension produce favorable influence.
Aluminium oxide (Al
2o
3): linear expansion coefficient is lower, can reduce the coefficient of thermal expansion of powder, reduces cracking sensitivity, improves the absorptivity of laser.
Carbon (C): for improving hardness and the wearability of material.
Beneficial effect of the present invention is: cobalt-based metal alloy powder of the present invention, in the cladding of continuous wave optical-fiber laser, has good thermal absorptivity to wavelength (960 nanometer～1.06 micron) for laser; In laser molten pool, although middle body temperature is higher, thermal conductivity is good, can be rapidly to molten bath four limits conduct heat; Liquid metal is stronger to the wettability of base material, the cladding layer compact structure finally forming, and the defects such as flawless, shrinkage cavity and porosity, pore, have the excellent metallography performance such as high rigidity, high-plasticity, highly corrosion resistant; Technique is simple, without heat treatment in advance and heat treatment afterwards.
Specific embodiment is described specific embodiments of the present invention in detail below by embodiment.
Embodiment mono-:
To be 8% silicon nitride by weight percentage, 2% antimony, 4% boron, 3% silicon, 5% aluminium oxide, 1% carbon, surplus is cobalt, nominal is got 500g sample, obtains 200-300 object cobalt-based metal alloy powder after sample preparation.
Embodiment 2
To be 12% silicon nitride by weight percentage, 5% antimony, 5% boron, 5% silicon, 8% aluminium oxide, 2% carbon, the ratio that surplus is cobalt takes 500g sample, obtains 200-300 object cobalt-based metal alloy powder after sample preparation.
Embodiment 3
To be 9% silicon nitride by weight percentage, 4% antimony, 5% boron, 3% silicon, 5% aluminium oxide, 1% carbon, surplus is cobalt, nominal is got 500g sample, obtains 200-300 object cobalt-based metal alloy powder after sample preparation.
The cobalt-based metal alloy powder being obtained by embodiment 3 preparations, at 2000W continuous wave optical-fiber laser power, spot size 10mm
2, sweep speed 15mm/s, under the process conditions such as powder feeding rate 20g/min, the surface of the work that is No. 45 steel to base material carries out Laser Cladding Treatment, and under room temperature, testing result is as shown in the table:
Claims (2)
1. be exclusively used in the Co-based alloy powder of continuous wave optical-fiber laser cladding, by its weight percent meter, contain 8-12% silicon nitride, 2-5% antimony, 4-5% boron, 3-5% silicon, 5-8% aluminium oxide, 1-2% carbon, surplus is cobalt.
2. the Co-based alloy powder that is exclusively used in the cladding of continuous wave optical-fiber laser as described in claim 1, is characterized in that: comprise 9% silicon nitride, and 4% antimony, 5% boron, 3% silicon, 5% aluminium oxide, 1% carbon, surplus is cobalt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310589796.4A CN103639403B (en) | 2013-11-20 | 2013-11-20 | Be exclusively used in the Co-based alloy powder of continuous wave optical-fiber laser cladding |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310589796.4A CN103639403B (en) | 2013-11-20 | 2013-11-20 | Be exclusively used in the Co-based alloy powder of continuous wave optical-fiber laser cladding |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103639403A true CN103639403A (en) | 2014-03-19 |
| CN103639403B CN103639403B (en) | 2015-09-30 |
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|---|---|---|---|
| CN201310589796.4A Active CN103639403B (en) | 2013-11-20 | 2013-11-20 | Be exclusively used in the Co-based alloy powder of continuous wave optical-fiber laser cladding |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5902498A (en) * | 1994-08-25 | 1999-05-11 | Qqc, Inc. | Methods of joining metal components and resulting articles particularly automotive torque converter assemblies |
| JP2008141011A (en) * | 2006-12-01 | 2008-06-19 | Hitachi Powdered Metals Co Ltd | Amorphous dust core |
| CN101486136A (en) * | 2009-02-27 | 2009-07-22 | 浙江省钎焊材料与技术重点实验室 | Cu-Sn-Sb silver-free middle-temperature solder and preparation method thereof |
| CN102650012A (en) * | 2012-05-05 | 2012-08-29 | 张家港市和昊激光科技有限公司 | Special cobalt-based metal ceramic alloy powder for optical fiber laser cladding |
| CN102990059A (en) * | 2012-12-19 | 2013-03-27 | 江苏新亚特钢锻造有限公司 | Silicide particle reinforced laser-clad high abrasion resistance cobalt-base alloy powder and preparation method thereof |
| CN102990058A (en) * | 2012-12-18 | 2013-03-27 | 江苏新亚特钢锻造有限公司 | Oxide particle reinforced laser-clad high abrasion resistance cobalt-base alloy powder and preparation method thereof |
| CN103305833A (en) * | 2013-06-18 | 2013-09-18 | 江苏和昊激光科技有限公司 | Special cobalt-based cermet alloy powder for laser cladding of surface of reamer |
| CN103302286A (en) * | 2013-06-18 | 2013-09-18 | 江苏和昊激光科技有限公司 | Cobalt-based metal ceramic alloy powder exclusively used in laser cladding of turning tool |
-
2013
- 2013-11-20 CN CN201310589796.4A patent/CN103639403B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5902498A (en) * | 1994-08-25 | 1999-05-11 | Qqc, Inc. | Methods of joining metal components and resulting articles particularly automotive torque converter assemblies |
| JP2008141011A (en) * | 2006-12-01 | 2008-06-19 | Hitachi Powdered Metals Co Ltd | Amorphous dust core |
| CN101486136A (en) * | 2009-02-27 | 2009-07-22 | 浙江省钎焊材料与技术重点实验室 | Cu-Sn-Sb silver-free middle-temperature solder and preparation method thereof |
| CN102650012A (en) * | 2012-05-05 | 2012-08-29 | 张家港市和昊激光科技有限公司 | Special cobalt-based metal ceramic alloy powder for optical fiber laser cladding |
| CN102990058A (en) * | 2012-12-18 | 2013-03-27 | 江苏新亚特钢锻造有限公司 | Oxide particle reinforced laser-clad high abrasion resistance cobalt-base alloy powder and preparation method thereof |
| CN102990059A (en) * | 2012-12-19 | 2013-03-27 | 江苏新亚特钢锻造有限公司 | Silicide particle reinforced laser-clad high abrasion resistance cobalt-base alloy powder and preparation method thereof |
| CN103305833A (en) * | 2013-06-18 | 2013-09-18 | 江苏和昊激光科技有限公司 | Special cobalt-based cermet alloy powder for laser cladding of surface of reamer |
| CN103302286A (en) * | 2013-06-18 | 2013-09-18 | 江苏和昊激光科技有限公司 | Cobalt-based metal ceramic alloy powder exclusively used in laser cladding of turning tool |
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| CN103639403B (en) | 2015-09-30 |
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Effective date of registration: 20160603 Address after: Wujin District of Jiangsu city in Changzhou province 213161 Chang Wu Road No. 801, Changzhou science and Technology City Tianhong building A block 8 Building Patentee after: Changzhou Tengen Industry Development Co.,Ltd. Address before: 215336, Jiangsu, Zhangjiagang province Daxin Town, Daxin village, Zhangjiagang city and Suzhou Hao Laser Technology Co., Ltd. Patentee before: Xu Liyun |
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Address after: Wujin District of Jiangsu city in Changzhou province 213161 Chang Wu Road No. 801, Changzhou science and Technology City Tianhong building A block 8 Building Patentee after: CHANGZHOU TIANZHENG INDUSTRIAL DEVELOPMENT CO.,LTD. Address before: Wujin District of Jiangsu city in Changzhou province 213161 Chang Wu Road No. 801, Changzhou science and Technology City Tianhong building A block 8 Building Patentee before: Changzhou Tengen Industry Development Co.,Ltd. |
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Denomination of invention: Cobalt-Based Alloy Powders for Continuous Wave Fiber Laser Cladding Effective date of registration: 20220811 Granted publication date: 20150930 Pledgee: China Zheshang Bank Co., Ltd. Changzhou Branch Pledgor: CHANGZHOU TIANZHENG INDUSTRIAL DEVELOPMENT CO.,LTD. Registration number: Y2022980012395 |
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Date of cancellation: 20231205 Granted publication date: 20150930 Pledgee: China Zheshang Bank Co.,Ltd. Changzhou Branch Pledgor: CHANGZHOU TIANZHENG INDUSTRIAL DEVELOPMENT CO.,LTD. Registration number: Y2022980012395 |
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Denomination of invention: Cobalt based alloy powder specifically designed for continuous wave fiber laser cladding Effective date of registration: 20231207 Granted publication date: 20150930 Pledgee: China Zheshang Bank Co.,Ltd. Changzhou Branch Pledgor: CHANGZHOU TIANZHENG INDUSTRIAL DEVELOPMENT CO.,LTD. Registration number: Y2023980069985 |
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