CN103636610A - Methoxyfenozide-cyantraniliprole-containing insecticidal composition - Google Patents
Methoxyfenozide-cyantraniliprole-containing insecticidal composition Download PDFInfo
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- CN103636610A CN103636610A CN201310530844.2A CN201310530844A CN103636610A CN 103636610 A CN103636610 A CN 103636610A CN 201310530844 A CN201310530844 A CN 201310530844A CN 103636610 A CN103636610 A CN 103636610A
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- China
- Prior art keywords
- methoxyfenozide
- cyantraniliprole
- bromine cyanogen
- insect amide
- cyanogen insect
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Abstract
The invention discloses a methoxyfenozide-cyantraniliprole-containing insecticidal composition. The methoxyfenozide-cyantraniliprole-containing insecticidal composition comprises methoxyfenozide as a first active ingredient, cyantraniliprole as a second active ingredient and a common auxiliary component; and a weight ratio of methoxyfenozide to cyantraniliprole in the methoxyfenozide-cyantraniliprole-containing insecticidal composition is in a range of 20: 1 to 1: 30. A lot of indoor and outdoor experiments prove that the methoxyfenozide-cyantraniliprole-containing insecticidal composition has obvious synergism, has good prevention and control effects on injurious insects such as chilo suppressalis walker, tryproyza incertulas, rice leaf roller and plant hopper on paddy rice, and prodenia litura, beet armyworm, diamondback moth, cabbage caterpillar, aphid, whitefly, thrips and flea beetle on vegetables, reduces an insecticide use amount in practical application, reduces insecticide residues on crops, reduces environmental pollution, and delays production of insecticide resistance of injurious insects.
Description
Technical field
The present invention relates to agricultural insecticide composition and application thereof, specifically a kind of to take methoxyfenozide and bromine cyanogen insect amide be the composite Pesticidal combination of active ingredient, is applied to the control of the upper insect of agricultural.
Background technology
Methoxyfenozide (methoxyfenozide): belonging to bishydrazide insecticide, is a kind of insect growth regulator, IGR.Insect takes food after medicament, produces the reaction of casting off a skin and starts to cast off a skin, and causes larva dehydration, hungry and dead owing to not casting off a skin completely.Be mainly used in preventing and treating the larva of lepidoptera pest, as beet armyworm, prodenia litura, cabbage caterpillar, cotton bollworm, apple leaf miner, fall webworm, pine caterpillars, looper and the snout moth's larva of rice etc.
Bromine cyanogen insect amide (cyantraniliprole): be second generation ryanodine receptor inhibitor insecticides, can efficiently activate insect ryanodine receptor, excessively the calcium ion in calcium storehouse in release cells, causes insect paralysis dead.The insects such as Lepidoptera, Semiptera and coleoptera are had to higher activity.This medicine shows mammal and the extremely significant selective difference of insect ryanodine receptor simultaneously, and this has improved the safety to mammal, other vertebrates and other natural enemies greatly.
The pesticide resistance problem of pest is a global problem, is the emphasis problem that agricultural science and technology worker pays close attention to always.Along with the continuity year in year out of Chemical Control of Harmful Insects,, the increase of agricultural chemicals usage amount and non-science are used the factors such as agricultural chemicals, cause pest resistance day by day serious, the pest species that produces resistance is on the increase.Meanwhile, high-intensity use agricultural chemicals, has caused that Practice for Pesticide Residue in Agricultural Products exceeds standard, the series of problems such as contaminated environment and the increase of peasant's drug cost, is unfavorable for agriculture sustainable development.
Therefore, development is efficient, low toxicity, the different mechanism of action, have again the composite product of synergistic function simultaneously, not only contributes to delay the generation of pest resistance to insecticide, but also can extend service life of pesticide species, reduce using dosage, cost-saving, reduce the pollution to environment.
The inventor conducts in-depth research the compounded formula screening of methoxyfenozide and bromine cyanogen insect amide, find that methoxyfenozide and bromine cyanogen insect amide carry out composite, within the scope of certain compound proportion, there is obvious synergistic function, in actual use, insect on crops is had to good control efficiency, after further study, completed the present invention.
Through retrieval, have not yet to see the composite pertinent literature report of methoxyfenozide and bromine cyanogen insect amide.
Summary of the invention
The object of the present invention is to provide the Pesticidal combination of a kind of methoxyfenozide and bromine cyanogen insect amide, this complex composition has obvious synergistic function, is applied to prevent and treat rice-stem borer, paddy stem borer, rice leaf roller, plant hopper and vegetables prodenia litura, beet armyworm, diamond-back moth, cabbage caterpillar, aphid, aleyrodid, thrips, flea beetle.
Another object of the present invention is to the Pesticidal combination containing methoxyfenozide and bromine cyanogen insect amide, in use can reduce dosage, reduce the residual quantity of agricultural chemicals on crops, delay the generation of pest resistance to insecticide; Can also make it to the control efficiency of insect, than single dose, use and compare obvious raising separately, laborsaving, economical, reduce farmer's burdens.
Technical scheme of the present invention: a kind of methoxyfenozide and bromine cyanogen insect amide Pesticidal combination, take methoxyfenozide and bromine cyanogen insect amide is active ingredient, all the other are in agricultural chemicals, to allow to use and acceptable auxiliary element, and methoxyfenozide and the weight ratio of bromine cyanogen insect amide in composition are 20:1～1:30.
Pesticidal combination of the present invention can be prepared into by known method any one formulation of using in applicable agricultural production, and reasonable formulation has suspending agent, aqueous emulsion, microemulsion, granule, water dispersible granules and wetting powder.
Pesticidal combination of the present invention is applicable to prevent and treat changes snout moth's larva, paddy stem borer, rice leaf roller, plant hopper and vegetables prodenia litura, beet armyworm, diamond-back moth, cabbage caterpillar, aphid, aleyrodid, thrips, flea beetle on paddy rice.
The frequency of administration of Pesticidal combination of the present invention and amount of application have small variations with crops, insect, weather condition variation, can be by using suitable dosage to reach the object of effective control.
Compared with prior art, the invention has the advantages that:
1, methoxyfenozide and bromine cyanogen insect amide are composite has a synergistic function, has expanded insecticidal spectrum, than the independent use of single dose, has obviously improved the control efficiency to insect;
2, methoxyfenozide and bromine cyanogen insect amide have respectively the different mechanism of action, can delay the generation of pest resistance to insecticide;
3, two kinds of active ingredients of methoxyfenozide and bromine cyanogen insect amide are composite, reduced agricultural chemicals usage amount, reduced use cost and the pollution to environment.
Embodiment
In order to understand better essence of the present invention, below in conjunction with Toxicity Determination and field control effectiveness test embodiment, content of the present invention is described further, but can not be considered as limitation of the present invention.
1, methoxyfenozide and the bromine cyanogen insect amide indoor joint toxicity measuring to diamond-back moth.
For trying worm: the indoor Individual Size diamond-back moth third-instar larvae consistent with physiological status of for many generations raising.
Reagent agent: the former medicine of 98.5% methoxyfenozide and the former medicine of 94% bromine cyanogen insect amide.
Test method: adopt the malicious blade method of folder, with reference to the agricultural industry criteria NY/T1154.2-2006 > > of the < < People's Republic of China (PRC), concrete grammar is as follows.
First with the card punch of diameter 1cm, beat and get leaf butterfly, put into culture dish, moisturizing.Then with capillary dropper by each treatment agent from low concentration, every leaf butterfly drop 1 μ L liquid, after solvent evaporates and another sheet involutory making of leaf butterfly of scribbling gelatinized corn starch press from both sides malicious leaf butterfly, make in the hole of the complete 12Kong of being put in tissue culturing plate.In each hole of last tissue culturing plate, connect 1 examination worm, in the intelligent insectary that to be placed in 26 ± 1 ℃ of temperature, relative moisture be 70%.Connect worm after 2～4 hours, wait trying worm, taken food after pastille leaf butterfly, in cultivating plate hole, add clean feed to continue to raise to investigation, eliminate the examination worm that has not eaten a complete leaf butterfly.4 repetitions are established in every processing, often repeat to be no less than 12 malicious leaf butterflies of folder, and establish not containing the processing of the corresponding organic solvent of medicament in contrast.After processing, 24h investigation examination worm death condition, records total borer population and dead borer population.
With DPS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, and according to the co-toxicity coefficient (CTC value) of the abundant method calculating of Sun Yun mixture.
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) * 100.
The percentage composition of B in percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] * 100.
According to the NY/T11547.7-2006 insecticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Table 1, methoxyfenozide and the bromine cyanogen insect amide indoor joint toxicity measuring result to diamond-back moth.
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Methoxyfenozide | 5.69 | 100.00 | -- | -- |
| Bromine cyanogen insect amide | 1.48 | 384.46 | -- | -- |
| Methoxyfenozide: bromine cyanogen insect amide (20:1) | 3.75 | 151.73 | 113.55 | 133.63 |
| Methoxyfenozide: bromine cyanogen insect amide (10:1) | 3.17 | 179.50 | 125.86 | 142.62 |
| Methoxyfenozide: bromine cyanogen insect amide (1:1) | 1.58 | 360.13 | 242.23 | 148.67 |
| Methoxyfenozide: bromine cyanogen insect amide (1:10) | 1.01 | 563.37 | 358.60 | 157.10 |
| Methoxyfenozide: bromine cyanogen insect amide (1:20) | 1.12 | 508.04 | 370.91 | 136.97 |
| Methoxyfenozide: bromine cyanogen insect amide (1:30) | 1.23 | 462.60 | 375.28 | 123.27 |
As can be seen from Table 1, methoxyfenozide and bromine cyanogen insect amide mixed ratio be 20:1～1:30(by weight) scope in when composite, co-toxicity coefficient (CTC) is all greater than 120, explanation shows synergistic function to diamond-back moth, and visible methoxyfenozide and bromine cyanogen insect amide be composite has reasonability and feasibility.
2, methoxyfenozide and the bromine cyanogen insect amide indoor joint toxicity measuring to rice fulgorid.
For trying worm: the indoor Individual Size rice fulgorid tritonymph consistent with physiological status of for many generations raising.
Reagent agent: the former medicine of 98.5% methoxyfenozide and the former medicine of 94% bromine cyanogen insect amide.
Test method: adopt rice stem infusion process to measure, with reference to the agricultural industry criteria NY/T1154.11-2008 > > of the < < People's Republic of China (PRC), concrete grammar is as follows.
First choose the healthy and strong consistent rice seedlings in tillering stage of laboratory cultures, grubbed out, clean, be cut into the long band root rice stem of about 10cm, In Shade drying.Then ready rice stem is flooded to 30s in the liquid preparing, taking-up is dried, and with wet absorbent cotton, encases root moisturizing, and outsourcing preservative film, is placed in test tube, every test tube 3 strains.Then with pest sucking device, will try worm and move in test tube, 15 of every pipes, the mouth of pipe encases with gauze.Finally the examination worm after processing being placed in to condition of culture is temperature (26 ± 1) ℃, and relative moisture 60%-80%, periodicity of illumination is L:D=(16:8) raise under the condition of h.4 repetitions are established in every processing, and establish not containing the processing of the corresponding organic solvent of medicament in contrast.After processing, 48h investigation examination worm death condition, records total borer population and dead borer population.
With DPS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, and according to the co-toxicity coefficient (CTC value) of the abundant method calculating of Sun Yun mixture.
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) * 100.
The percentage composition of B in percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] * 100.
According to the NY/T11547.7-2006 insecticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Table 2, methoxyfenozide and the bromine cyanogen insect amide indoor joint toxicity measuring result to rice fulgorid.
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Methoxyfenozide | 55.16 | 100.00 | ---- | ---- |
| Bromine cyanogen insect amide | 23.87 | 231.09 | ---- | ---- |
| Methoxyfenozide: bromine cyanogen insect amide (20:1) | 41.26 | 133.69 | 106.24 | 125.83 |
| Methoxyfenozide: bromine cyanogen insect amide (10:1) | 35.74 | 154.34 | 111.92 | 137.90 |
| Methoxyfenozide: bromine cyanogen insect amide (1:1) | 23.61 | 233.63 | 165.54 | 141.13 |
| Methoxyfenozide: bromine cyanogen insect amide (1:10) | 16.29 | 338.61 | 219.17 | 154.50 |
| Methoxyfenozide: bromine cyanogen insect amide (1:20) | 17.16 | 321.45 | 224.84 | 142.96 |
| Methoxyfenozide: bromine cyanogen insect amide (1:30) | 18.22 | 302.74 | 226.86 | 133.45 |
As can be seen from Table 2, methoxyfenozide and bromine cyanogen insect amide mixed ratio be 20:1～1:30(by weight) scope in when composite, co-toxicity coefficient (CTC) is all greater than 120, illustrates rice fulgorid is shown to synergistic function.Visible methoxyfenozide and bromine cyanogen insect amide be composite has reasonability and feasibility.
3, the composite field control effectiveness test to wild cabbage diamond-back moth of methoxyfenozide and bromine cyanogen insect amide.
Adopt 10% bromine cyanogen insect amide methoxyfenozide suspending agent (6% bromine cyanogen insect amide: 4% methoxyfenozide) control wild cabbage diamond-back moth, investigation insect population radix before dispenser, after medicine, 3d, 7d, 10d investigate respectively residual borer population alive, investigation Shi Mei community is undertaken by diagonal 5 point samplings, look into residual diamondback moth larvae on 2 strain wild cabbages at every, record the borer population of living, calculate control efficiency.Control efficiency computational methods are as follows:
Control efficiency (%)=(1-CK
1* Pt
1/ CK
2* Pt
2) * 100.
Wherein: CK
1represent the front insect population number of check plot medicine; Pt
1represent insect population number after treatment region medicine;
CK
2represent insect population number after the medicine of check plot; Pt
2represent the front insect population number for the treatment of region medicine.
Table 3, respectively process the result of the test of chemical control wild cabbage diamond-back moth.
As can be seen from Table 3,10% bromine cyanogen insect amide methoxyfenozide suspending agent is along with the increase of using dosage obviously promotes the control efficiency of wild cabbage diamond-back moth; When preparation mu consumption is 8-10 gram, after medicine, 3d, 7d, 10d are all obviously better than each single dose to the preventive effect of wild cabbage diamond-back moth and use separately, after medicine, 10d preventive effect all still reaches more than 85% simultaneously, illustrate that this compound drug has good lasting effect, in pilot survey process, do not find that this compound drug produces poisoning to wild cabbage.
4, the composite field control effectiveness test to rice hoppers of methoxyfenozide and bromine cyanogen insect amide.
Adopt 10% bromine cyanogen insect amide methoxyfenozide water dispersible granules (8% bromine cyanogen insect amide: 2% methoxyfenozide) for preventing and treating rice hoppers, investigation insect population radix before dispenser, after medicine, 3d, 7d, 10d investigate respectively residual borer population alive, investigation Shi Mei community is undertaken by parallel jump method, investigate 20 points, 2 clumps every, shake or pat rice clump, between statistics rice clump, the plant hopper quantity of floating on water, calculates control efficiency.Control efficiency computational methods are as follows:
Control efficiency (%)=(1-CK
1* Pt
1/ CK
2* Pt
2) * 100.
Wherein: CK
1represent the front insect population number of check plot medicine; Pt
1represent insect population number after treatment region medicine;
CK
2represent insect population number after the medicine of check plot; Pt
2represent the front insect population number for the treatment of region medicine.
Table 4, respectively process the result of the test of chemical control rice hoppers.
As can be seen from Table 4,10% bromine cyanogen insect amide methoxyfenozide water dispersible granules is along with the increase of using dosage obviously promotes the control efficiency of rice hoppers; When preparation mu consumption is 18-20 gram, after medicine, 3d, 7d, 10d are all obviously better than each single dose to the preventive effect of rice hoppers and use separately, after medicine, 10d preventive effect all still reaches more than 80% simultaneously, illustrate that this compound drug has good lasting effect, in pilot survey process, do not find that this compound drug produces poisoning to paddy rice.
In sum, the present invention adopts the complex composition of methoxyfenozide and bromine cyanogen insect amide, has synergistic function.Compare with existing unitary agent, insecticidal effect obviously improves, and the lasting period is long, to crop safety, is worth applying in agricultural production.
Claims (3)
1. methoxyfenozide and a bromine cyanogen insect amide Pesticidal combination, is characterized in that: active ingredient is methoxyfenozide and bromine cyanogen insect amide, and methoxyfenozide and the weight ratio of bromine cyanogen insect amide in composition are 20:1～1:30.
2. methoxyfenozide according to claim 1 and bromine cyanogen insect amide Pesticidal combination, is characterized in that: the formulation of described Pesticidal combination is a kind of in suspending agent, aqueous emulsion, microemulsion, granule, water dispersible granules and wetting powder.
3. methoxyfenozide according to claim 1 and bromine cyanogen insect amide Pesticidal combination, is characterized in that: be applicable to prevent and treat and on paddy rice, change snout moth's larva, paddy stem borer, rice leaf roller, plant hopper and vegetables prodenia litura, beet armyworm, diamond-back moth, cabbage caterpillar, aphid, aleyrodid, thrips, flea beetle.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105519537A (en) * | 2014-10-25 | 2016-04-27 | 陕西美邦农药有限公司 | Pesticide insecticidal composition containing N-(2-(tert-butylaminoformyl)-4-chloro-6-methylphenyl)-1-(3-chloropyridin-2-yl)-3-fluoromethoxy-1H-pyrazolyl-5-formamide (ZJ3757) |
| CN105994287A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and methoxyfenozide and application thereof |
| WO2022009224A1 (en) * | 2020-07-10 | 2022-01-13 | Rajdhani Petrochemicals Private Limited | An insecticidal composition for pest control comprising of diacylhydrazines |
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|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| WO2009018185A2 (en) * | 2007-07-30 | 2009-02-05 | E. I. Du Pont De Nemours And Company | Ectoparasite control method |
| CN102595901A (en) * | 2009-09-04 | 2012-07-18 | 杜邦公司 | N-(cyanophenyl)pyrazolecarboxamide aqueous formulation |
-
2013
- 2013-10-30 CN CN201310530844.2A patent/CN103636610A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| WO2009018185A2 (en) * | 2007-07-30 | 2009-02-05 | E. I. Du Pont De Nemours And Company | Ectoparasite control method |
| CN102595901A (en) * | 2009-09-04 | 2012-07-18 | 杜邦公司 | N-(cyanophenyl)pyrazolecarboxamide aqueous formulation |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105519537A (en) * | 2014-10-25 | 2016-04-27 | 陕西美邦农药有限公司 | Pesticide insecticidal composition containing N-(2-(tert-butylaminoformyl)-4-chloro-6-methylphenyl)-1-(3-chloropyridin-2-yl)-3-fluoromethoxy-1H-pyrazolyl-5-formamide (ZJ3757) |
| CN105994287A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and methoxyfenozide and application thereof |
| WO2022009224A1 (en) * | 2020-07-10 | 2022-01-13 | Rajdhani Petrochemicals Private Limited | An insecticidal composition for pest control comprising of diacylhydrazines |
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Application publication date: 20140319 |