CN103626306A - Method for comprehensive application treatment of heavy metal ion wastewater - Google Patents
Method for comprehensive application treatment of heavy metal ion wastewater Download PDFInfo
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- CN103626306A CN103626306A CN201310706968.1A CN201310706968A CN103626306A CN 103626306 A CN103626306 A CN 103626306A CN 201310706968 A CN201310706968 A CN 201310706968A CN 103626306 A CN103626306 A CN 103626306A
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Abstract
The invention discloses a method for comprehensive application treatment of heavy metal ion wastewater. A first settling pond for microorganism treatment is arranged, and the first settling pond is communicated with a cooling tank of a plastic extruder. The method has the advantages as follows: 1, the specially-made microbial flora namely specially-made EM (effective microorganism) bacterial flora are adopted, chaff activated carbon and wood charcoal are adopted as bacteria beds, the contact area of the bacteria beds and a water body is large, and the heavy metal ions can be effectively adsorbed; 2, afterheat of cooling water of the plastic extruder is adopted, the microorganism treatment can be kept under the proper environment of 30-40 DEG C all the time when an energy source is saved, and the heavy metal ions in the water body can be adsorbed to the maximal extent; 3, a water pump continuously carries out cold and hot flow circulation on the cooling water of the plastic extruder and water inside the first settling pond, so that macromolecular organic matters in the water body can be evenly adsorbed by the wood charcoal and the chaff activated carbon in a floating wood fence to be supplied to the specially-made EM bacterial flora for growth and propagation.
Description
(1) technical field
The present invention relates to the method that a kind of method that water integrated application is processed, particularly effluent containing heavy metal ions integrated application are processed.
(2) background technology
Utilizing microbial treatment sewage is the main direction of environmental protection industry from now on, the mechanism of action is to take as the leading factor with photosynthetic bacteria group, yeast flora, actinomycete group, collaborative other beneficial microorganism acting in conjunction, produce antioxidant, by approach such as redox fermentations, harmful poisonous sewage is converted into harmless nontoxic cleaning water, becomes and be harmful to as useful.
In effluent containing heavy metal ions, contain a large amount of hexavalent chromiums, lead ion, mercury ion, ferric ion, cupric ion etc., but in existing biofermentation method, do not have a kind ofly for the specific microflora of heavy metal ion sewage, there is no the method for reasonably using this microflora to process effluent containing heavy metal ions yet.
We know that the water coolant of plastics extruder is very low to the requirement of water quality simultaneously.
(3) summary of the invention
In order to overcome existing effluent containing heavy metal ions, process difficult deficiency, the invention provides a kind of energy-conservation employing biological chemistry comprehensive regulation effluent containing heavy metal ions, in process, can also serve as the method that water coolant integrated application is processed.
The technical scheme that the present invention solves its technical problem is: a kind of method that effluent containing heavy metal ions integrated application is processed, comprise the steps,
A, water body is extracted in the first settling tank, in described the first settling tank, be provided with oxygen supply pump, in the first settling tank, in water body per ton, 2 grams of grease dispersion agents have been sowed, and water body per ton arranges 1 and above floating wooden fence, floating wooden fence lower end is provided with filtering net, in each floating wooden fence, on filtering net, lay charcoal and husk gac and add up to 1 kilogram, 3 grams of dried orange peels, water on described dried orange peel and have spilt 10 grams of microbiobacterial agents;
Described microbiobacterial agent preparation method is as follows, and 1 mass parts EM bacterial classification pulvis adds 9 mass parts water 1 mass parts sugar 1 mass parts dried orange peels, 30～40 degrees Celsius of ferment in the open one week, and liquid taking bacterium liquid is as microbiobacterial agent;
What this EM bacterial classification pulvis adopted is the EM probiotic bacterium dry powder bacterial classification that is produced from Shen Zhong bio tech ltd, Henan, and in this patent, grease dispersion agent adopts liquid detergent, can select white cat board liquid detergent.
B, in the first settling tank, 20 centimetres of the waters surface arrange water inlet pipe and rising pipe below, described rising pipe is communicated with the cooling tank cooling water inlet of plastics extruder, described water inlet pipe is communicated with the cooling tank cooling water outlet of plastics extruder, also being provided with water pump ceaselessly returns water body pump in the first settling tank in the first settling tank and circulates toward cooling tank, water body absorbs the used heat of plastics extruder extrusion plastic generation and remains between 30～40 degree, carries out about 1～3 day;
C, the water in the first settling tank is transferred in the second settling tank, water body per ton is put into 500～1500 grams of scavenging agents, and water body per ton arranges 1 and above floating wooden fence, floating wooden fence lower end is provided with filtering net, lays charcoal and husk gac and add up to 1 kg water in the second settling tank standing 24 hours in each floating wooden fence on filtering net;
The following component that described scavenging agent is calculated with mass ratio forms: 1000 parts, chlorinated lime, 40 parts of polymerize aluminum chlorides, 100 parts of clorox, 2 parts of grease dispersion agents;
Microorganism in water is cleaned agent and kills, and under flocculation precipitation, the heavy metal ion accumulating in microorganism has also been fallen to precipitation from water body under the effect of polymerize aluminum chloride, and scavenging agent also can precipitate with Heavy Metals in Waters ionic reaction simultaneously.
D, water body in the second settling tank is filtered and enters the 3rd and hold in pond through polypropylene filter, through ozonizer oxidation sterilizing.Described polypropylene filter plays to be given the not yet precipitated organism getting off in water to precipitate, and interception is combined in the heavy metal ion in organism.Ozonizer can reduce chlorine residue in water at water oxygen chlorion, and reduces the hardness of water body.
A design for floating wooden fence, described filtering net is nylon filtering net and is provided with 4 layers, and described floating wooden fence is China fir quality, is shaped as square and length is 30 centimetres, and floating wooden fence high is 10 centimetres.Described nylon filtering net is 4 layers, make EM bacterium colony can be seated in easily on nylon wire breeding and can active adsorption the first settling tank water body in heavy metal ion, China fir fence also can slowly be corroded as nutritional bed by EM bacterium colony in water, simultaneously also can Adsorption of Heavy Metal Ions.
Beneficial effect of the present invention is: 1, adopting special microbiobacterial agent is special EM bacterium colony, and adopt husk gac and charcoal as bacterium bed, bacterium bed and water body contact area are large, effectively the heavy metal ion such as Adsorption of Chromium ion, lead ion, mercury ion, iron ion, cupric ion.2, adopt the waste heat of plastics extruder water coolant, when having saved the energy, can keep microbiological treatment movable under 30～40 degrees Celsius of suitable environment all the time, maximum possible be drawn to the heavy metal ion in water body.3, water pump is ceaselessly carrying out cold and hot water circulation in the water coolant of plastics extruder and the first settling tank, larger molecular organics in water body can be adsorbed by the charcoal in floating wooden fence and husk gac uniformly, offer the breeding of special EM colony growth, avoid that water body is too muddy has influence on the cooling of plastics extruder.4,, in wastewater treatment, also completed cooling to plastics extruder extrusion plastic.
(4) accompanying drawing explanation
Fig. 1 is the schematic diagram of the floating wooden fence of the present invention.
Fig. 2 is the sectional view after dried orange peel, charcoal, husk gac of loading onto of the floating wooden fence of the present invention.
(5) embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
Embodiment mono-
The method that effluent containing heavy metal ions integrated application is processed, comprises the steps,
A, water body is extracted in the first settling tank, in described the first settling tank, be provided with oxygen supply pump, in the first settling tank, in water body per ton, 2 grams of grease dispersion agents have been sowed, and water body per ton arranges 1 floating wooden fence, floating wooden fence lower end is provided with filtering net, in each floating wooden fence, on filtering net, lay charcoal and husk gac and add up to 1 kilogram, 3 grams of dried orange peels, water on described dried orange peel and have spilt 10 grams of microbiobacterial agents;
Described microbiobacterial agent preparation method is as follows, and 1 mass parts EM bacterial classification pulvis adds 9 mass parts water 1 mass parts sugar 1 mass parts dried orange peels, 30-40 degree Celsius of ferment in the open one week, and liquid taking bacterium liquid is as microbiobacterial agent;
What this EM bacterial classification pulvis adopted is the EM probiotic bacterium dry powder bacterial classification that is produced from Shen Zhong bio tech ltd, Henan, and in this patent, grease dispersion agent adopts liquid detergent, can select white cat board liquid detergent.
B, in the first settling tank, 20 centimetres of the waters surface arrange water inlet pipe and rising pipe below, described rising pipe is communicated with the cooling tank cooling water inlet of plastics extruder, described water inlet pipe is communicated with the cooling tank cooling water outlet of plastics extruder, also being provided with water pump ceaselessly returns water body pump in the first settling tank in the first settling tank and circulates toward cooling tank, water body absorbs the used heat of plastics extruder extrusion plastic generation and remains between 30～40 degree, carries out about 2 days;
C, the water in the first settling tank is transferred in the second settling tank, water body per ton is put into 1000 grams of scavenging agents, and water body per ton arranges 1 floating wooden fence, floating wooden fence lower end is provided with filtering net, lays charcoal and husk gac and add up to 1 kg water in the second settling tank standing 24 hours in each floating wooden fence on filtering net;
The following component that described scavenging agent is calculated with mass ratio forms: 1000 parts, chlorinated lime, 40 parts of polymerize aluminum chlorides, 100 parts of clorox, 2 parts of grease dispersion agents;
Microorganism in water is cleaned agent and kills, and under flocculation precipitation, the heavy metal ion accumulating in microorganism has also been fallen to precipitation from water body under the effect of polymerize aluminum chloride, and scavenging agent also can precipitate with Heavy Metals in Waters ionic reaction simultaneously.
D, water body in the second settling tank is filtered and enters the 3rd and hold in pond through polypropylene filter, through ozonizer oxidation sterilizing.Described polypropylene filter plays to be given the not yet precipitated organism getting off in water to precipitate, and interception is combined in the heavy metal ion in organism.Ozonizer can reduce chlorine residue in water at water oxygen chlorion, and reduces the hardness of water body.
By reference to the accompanying drawings 1 and 2, the design of a kind of floating wooden fence (1), described filtering net is nylon filtering net (2) and is provided with 4 layers, described floating wooden fence is China fir quality, being shaped as square and length (A) is 30 centimetres, floating wooden fence high (B) is 10 centimetres, is placed with charcoal (3) and husk gac (4), dried orange peel (5) on described nylon filtering net.
Described nylon filtering net is 4 layers, make EM bacterium colony can be seated in easily on nylon wire breeding and can active adsorption the first settling tank water body in heavy metal ion, China fir fence also can slowly be corroded as nutritional bed by EM bacterium colony in water, simultaneously also can Adsorption of Heavy Metal Ions.
Heavy metal ion-containing waste water heavy mental treatment cross-reference list position mg/L
| Heavy metal kind | Ferric ion | Hexavalent chromium | Cupric ion | Lead ion | Mercury ion |
| Before processing | 117.17 | 4.09 | 2.28 | 3.84 | 1.14 |
| After step ab | 2.24 | 1.34 | 1.24 | 0.79 | 0.02 |
| After step abcd | 0.03 | 0.07 | 0.14 | 0.06 | N／A |
Benefit of the present invention: 1, adopting special microbiobacterial agent is special EM bacterium colony, and adopt husk gac and charcoal as bacterium bed, bacterium bed and water body contact area are large, effectively the heavy metal ion such as Adsorption of Chromium ion, lead ion, mercury ion, iron ion, cupric ion.2, adopt the waste heat of plastics extruder water coolant, when having saved the energy, can keep microbiological treatment movable under 30～40 degrees Celsius of suitable environment all the time, maximum possible be drawn to the heavy metal ion in water body.3, water pump is ceaselessly carrying out cold and hot water circulation in the water coolant of plastics extruder and the first settling tank, larger molecular organics in water body can be adsorbed by the charcoal in floating wooden fence and husk gac uniformly, offer the breeding of special EM colony growth, avoid that water body is too muddy has influence on the cooling of plastics extruder.4,, in wastewater treatment, also completed cooling to plastics extruder extrusion plastic.
Claims (4)
1. the method that effluent containing heavy metal ions integrated application is processed, is characterized in that: comprises the steps,
A, water body is extracted in the first settling tank, in described the first settling tank, be provided with oxygen supply pump, in the first settling tank, in water body per ton, 2 grams of grease dispersion agents have been sowed, and water body per ton arranges 1 and above floating wooden fence, floating wooden fence lower end is provided with filtering net, in each floating wooden fence, on filtering net, lay charcoal and husk gac and add up to 1 kilogram, 3 grams of dried orange peels, water on described dried orange peel and have spilt 10 grams of microbiobacterial agents;
Described microbiobacterial agent preparation method is as follows, and 1 mass parts EM bacterial classification pulvis adds 9 mass parts water 1 mass parts sugar 1 mass parts dried orange peels, 30～40 degrees Celsius of ferment in the open one week, and liquid taking bacterium liquid is as microbiobacterial agent;
B, in the first settling tank, 20 centimetres of the waters surface arrange water inlet pipe and rising pipe below, described rising pipe is communicated with the cooling tank cooling water inlet of plastics extruder, described water inlet pipe is communicated with the cooling tank cooling water outlet of plastics extruder, also being provided with water pump ceaselessly returns water body pump in the first settling tank in the first settling tank and circulates toward cooling tank, water body absorbs the used heat of plastics extruder extrusion plastic generation and remains between 30～40 degree, carries out about 1～3 day.
2. the method that a kind of effluent containing heavy metal ions integrated application according to claim 1 is processed, is characterized in that: after step b, also include step c,
C, the water in the first settling tank is transferred in the second settling tank, water body per ton is put into 1000 grams of scavenging agents, and water body per ton arranges 1 and above floating wooden fence, floating wooden fence lower end is provided with filtering net, lays charcoal and husk gac and add up to 1 kg water in the second settling tank standing 24 hours in each floating wooden fence on filtering net;
The following component that described scavenging agent is calculated with mass ratio forms: 1000 parts, chlorinated lime, 40 parts of polymerize aluminum chlorides, 100 parts of clorox, 2 parts of grease dispersion agents.
3. the method that a kind of effluent containing heavy metal ions integrated application according to claim 2 is processed, is characterized in that: after step c, also include steps d,
D, water body in the second settling tank is filtered and enters the 3rd and hold in pond through polypropylene filter, through ozonizer oxidation sterilizing.
4. the method for processing according to a kind of effluent containing heavy metal ions integrated application one of claims 1 to 3 Suo Shu, it is characterized in that: described filtering net is nylon filtering net and is provided with 4 layers, described floating wooden fence is China fir quality, be shaped as square and length is 30 centimetres, floating wooden fence high is 10 centimetres.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105036471A (en) * | 2015-07-26 | 2015-11-11 | 李娜 | Method for removing sewage pollutants containing lead |
| CN105601050A (en) * | 2016-03-17 | 2016-05-25 | 富阳鸿祥技术服务有限公司 | Biological fermentation-heavy metal sedimentation purifying method |
| CN105621632A (en) * | 2016-03-17 | 2016-06-01 | 富阳鸿祥技术服务有限公司 | Biological fermentation and heavy metal precipitation purification pool |
| CN105936564A (en) * | 2015-09-16 | 2016-09-14 | 深圳市中南环保科技控股有限公司 | Biochemical system for treatment of heavy metals wastewater and process thereof |
| CN106673298A (en) * | 2016-12-05 | 2017-05-17 | 蚌埠市国乐汽配有限公司 | Wastewater treatment system for automotive engine oil cooler producing workshop |
| CN108238677A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of water body cadmium ion enrichment treatment device |
| CN108238679A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of water body lead ion enrichment treatment device |
| CN108238678A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of water body copper ion enrichment treatment device |
| CN115353258A (en) * | 2022-08-29 | 2022-11-18 | 江苏利然环保科技有限公司 | Modular water purification device for improving water quality of water body |
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| CN105036471A (en) * | 2015-07-26 | 2015-11-11 | 李娜 | Method for removing sewage pollutants containing lead |
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| CN105621632A (en) * | 2016-03-17 | 2016-06-01 | 富阳鸿祥技术服务有限公司 | Biological fermentation and heavy metal precipitation purification pool |
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| CN108238677A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of water body cadmium ion enrichment treatment device |
| CN108238679A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of water body lead ion enrichment treatment device |
| CN108238678A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of water body copper ion enrichment treatment device |
| CN108238678B (en) * | 2016-12-27 | 2020-06-09 | 中国科学院宁波城市环境观测研究站 | Water copper ion enrichment processing apparatus |
| CN108238679B (en) * | 2016-12-27 | 2020-06-09 | 中国科学院宁波城市环境观测研究站 | Water lead ion enrichment treatment device |
| CN108238677B (en) * | 2016-12-27 | 2020-08-18 | 中国科学院宁波城市环境观测研究站 | Water cadmium ion enrichment treatment device |
| CN115353258A (en) * | 2022-08-29 | 2022-11-18 | 江苏利然环保科技有限公司 | Modular water purification device for improving water quality of water body |
| CN115353258B (en) * | 2022-08-29 | 2023-10-27 | 江苏利然环保科技有限公司 | Modularized water purifying device for improving water quality of water body |
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