CN103613793A - Preparation method of puncture-resistant sole material - Google Patents
Preparation method of puncture-resistant sole material Download PDFInfo
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- CN103613793A CN103613793A CN201310586907.6A CN201310586907A CN103613793A CN 103613793 A CN103613793 A CN 103613793A CN 201310586907 A CN201310586907 A CN 201310586907A CN 103613793 A CN103613793 A CN 103613793A
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Abstract
The invention relates to a material for making a sole, and particularly relates to a preparation method of a puncture-resistant sole material. The method comprises the following steps: (1) weighing the dosages of various rubbers and ingredients according to the formula ratio; (2) mixing by using an open mill; (3) vulcanizing by using a press vulcanizer or a rubber injection machine. The preparation method is reasonable in design; the sole material does not easily generate slippage and fracture phenomena of a molecular chain when encountering sharp objects by a ternary combined design method of chloroprene rubber, natural rubber and butadiene styrene rubber, and simultaneously has the characteristics of light weight and slow heat transfer, and the puncture resistance of the sole is greatly improved.
Description
Technical field
The present invention relates to manufacture the material at the bottom of boots, be specially a kind of preparation method of anti-puncture boots bottom material.
Background technology
Development along with guard technology; all kinds of footwears (boots) are of a great variety; various functions are also day by day perfect; some special occasions particularly; as fire protection sector need to have the functions such as fire-retardant, corrosion-resistant, anti-skidding, anti-puncture, for military Protective Boots (footwear), to possess to the protection of military toxic agent, high-risk chemical, have simultaneously fire-retardant, anti-puncture ability.No matter for military or civilian, at the bottom of boots, anti-puncture performance is one of important use properties of boots (footwear).If be not highly resistant to the piercing through of sharp object, bursting, poisonous, hazardous and noxious substances can be infiltrated in boots (footwear), and human body is produced to harm.
When contact sharp object, very easily there is slippage, the fracture of molecular chain in boots bottom material, boots (footwear) end is pierced.In order to strengthen the anti-puncture performance at the bottom of boots, general by increasing the anti-puncture layer of metal, ensure the puncture resistance at the bottom of boots.Adopt which when effectively improving anti-puncture performance, also bring the problem of three aspects:: the one, weight metal is large, increases the physiological stress of human body; The 2nd, the flexibility at boots (footwear) end is poor; The 3rd, metal level easily transmits surface temperature, in high temperature or microthermal climate, easily worsens the interior temperature and humidity of boots (footwear), and comfortableness is poor.
Summary of the invention
The present invention adds metal to put puncture layer and the problems referred to above of existence in order to solve in boots bottom material, and a kind of preparation method of anti-puncture boots bottom material is provided.
The present invention adopts following technical scheme to realize:
A preparation method for anti-puncture boots bottom material, comprises the steps:
(1), by formula rate, weigh the consumption of various rubber and Synergist S-421 95;
Described formula is comprised of the raw material of following parts by weight:
Natural rubber: 20～60; Chloroprene rubber: 40～20; Styrene-butadiene rubber(SBR): 40～20; Sulfur: 1.2～2.0; Altax: 0.3～0.8; Captax: 0.3～1.0; Zinc oxide: 5.0～7.0; Stearic acid: 1.0～2.5; High abrasion carbon black: 25～35; Antioxidant D: 0.8～1.5; Antioxidant 4010: 1.0～2.0; Magnesium oxide: 1.5～2.5.
(2), use mill to carry out mixing: natural rubber, chloroprene rubber, styrene-butadiene rubber(SBR) to be put into mill and fully plasticated, front roll temperature≤40 ℃, rear roll temperature≤55 ℃, roll spacing 0.1～0.5mm, time 10～15min;
Add antioxidant D (N-phenyl-2-naphthylamine), antioxidant 4010 (N cyclohexyl N' phenyl P phenylene diamine), stearic acid, magnesium oxide, roller temperature is constant, roll spacing 0.5～1.0mm, time 2～3min;
Add zinc oxide, high abrasion carbon black, roller temperature is constant, roll spacing 0.5～1.0mm, time 5～6min;
Add altax (2,2'-dithio-bis-benzothiazole), captax (2-thiol group phenylpropyl alcohol thiazole), roller temperature is constant, roll spacing 0.5～1.0mm, time 2～3min;
Add Sulfur, roller temperature is constant, roll spacing 0.5～0.1mm, time 2～3min;
(eight is a kind of working method adopting in rubber compounding process cutter to eight cuttves, its objective is and promotes that rubber fully mixes with various Synergist S-421 95s, forms uniform mixed phase.Detailed process be with tapping knife along the direction of roller axially parallel with 45 ° of rubber tapping, the glue of piling up on roller is broken into volume, each is once a cutter for left and right, eight times altogether), roller temperature is constant, roll spacing 0.1～0.5mm, time 6～8min;
Play triangle bag, roller temperature is constant, roll spacing 0.1～0.3mm, time 6～8min;
Slice, the film that roller temperature is constant, thickness is 1.0～1.5mm, time 1～2min;
(3), use vulcanizing press or rubber injection machine to vulcanize: cure conditions: 150 ℃ of temperature, time 10min, pressure 10MPa.
The present invention one selects the rubber having from reinforcing property (crystallization), and such material, when running into External Force Acting, can produce stretch crystallization, and Intermolecular Forces increases, and is intermolecularly difficult for slippage, fracture; The 2nd, select the material that volume effect is large, the damping action of increase and sharp object, to complete the impedance of extraneous sharp object.
According to above-mentioned principle, the present invention has adopted chloroprene rubber glue, natural rubber, styrene-butadiene rubber(SBR) co-mixing system.Chloroprene rubber molecular structure is regular, contains chlorine atomic polarity group in molecular chain, has increased intermolecular reactive force, under external force, easily produces stretch crystallization, is intermolecularly difficult for slippage, while running into sharp object, is difficult for being pierced, bursting.But chloroprene rubber is at low temperatures, after produce stretching, be difficult to restore to the original state, flexible resistance, winter hardiness are poor.Natural rubber, except having strain crystallization performance, has excellent cold tolerance, flexible resistance simultaneously, can make up the poor problem of chloroprene rubber winter hardiness.On styrene-butadiene rubber(SBR), contain a large amount of phenyl ring, by the volume effect the forming sharp object that can contact with it to external world with viscous effect form effective retardation.
The present invention is reasonable in design, by chloroprene rubber+natural rubber+styrene-butadiene rubber(SBR) ternary, also use method of design, when running into sharp object, material for sole of shoe is difficult for occurring the phenomenon of molecular chain slippage, fracture, greatly improve the anti-puncture performance at the bottom of boots, there is lightweight, the slow feature of conducting heat simultaneously, by professional institution, evaluate, the material of same thickness, its anti-puncture performance reaches advanced international level.Material thickness is that 2mm can reach 760N, has solved that metal anti-puncture layer weight loading is large, flexible resistance is poor, the fast problem of conducting heat.
Embodiment
Below specific embodiments of the invention are elaborated.
embodiment 1
An anti-puncture boots bottom material, is comprised of the proportioning of following parts by weight:
Natural rubber: 40; Chloroprene rubber: 20; Styrene-butadiene rubber(SBR): 35; Sulfur: 1.5; Altax: 0.3; Captax: 1; Zinc oxide: 5.5; Stearic acid: 2; High abrasion carbon black: 30; Antioxidant D: 1.2; Antioxidant 4010: 1.5; Magnesium oxide: 1.5.
Preparation method is as follows:
(1), by formula rate, weigh the consumption of various rubber and Synergist S-421 95;
(2), use mill to carry out mixing: natural rubber, chloroprene rubber, styrene-butadiene rubber(SBR) to be put into mill and fully plasticated, front roll temperature≤40 ℃, rear roll temperature≤55 ℃, roll spacing 0.5mm, time 10min;
Add antioxidant D, antioxidant 4010, stearic acid, magnesium oxide, roller temperature is constant, roll spacing 0.7mm, time 2min;
Add zinc oxide, high abrasion carbon black, roller temperature is constant, roll spacing 1.0mm, time 5min;
Add altax, captax, roller temperature is constant, roll spacing 0.9mm, time 3min;
Add Sulfur, roller temperature is constant, roll spacing 0.5mm, time 2min;
Eight cuttves, roller temperature is constant, roll spacing 0.2mm, time 6min;
Play triangle bag, roller temperature is constant, roll spacing 0.3mm, time 6min;
Slice, the film that roller temperature is constant, thickness is 1.0mm, time 1min;
(3), use vulcanizing press or rubber injection machine to vulcanize: cure conditions: 150 ℃ of temperature, time 10min, pressure 10MPa.
embodiment 2
An anti-puncture boots bottom material, is comprised of the proportioning of following parts by weight:
Natural rubber: 30; Chloroprene rubber: 35; Styrene-butadiene rubber(SBR): 20; Sulfur: 2; Altax: 0.5; Captax: 0.7; Zinc oxide: 6; Stearic acid: 1; High abrasion carbon black: 25; Antioxidant D: 1; Antioxidant 4010: 1; Magnesium oxide: 2.
Preparation method is as follows:
(1), by formula rate, weigh the consumption of various rubber and Synergist S-421 95;
(2), use mill to carry out mixing: natural rubber, chloroprene rubber, styrene-butadiene rubber(SBR) to be put into mill and fully plasticated, front roll temperature≤40 ℃, rear roll temperature≤55 ℃, roll spacing 0.1mm, time 12min;
Add antioxidant D, antioxidant 4010, stearic acid, magnesium oxide, roller temperature is constant, roll spacing 0.5mm, time 3min;
Add zinc oxide, high abrasion carbon black, roller temperature is constant, roll spacing 0.6mm, time 5min;
Add altax, captax, roller temperature is constant, roll spacing 0.5mm, time 2min;
Add Sulfur, roller temperature is constant, roll spacing 0.1mm, time 3min;
Eight cuttves, roller temperature is constant, roll spacing 0.3mm, time 7min;
Play triangle bag, roller temperature is constant, roll spacing 0.2mm, time 8min;
Slice, the film that roller temperature is constant, thickness is 1.3mm, time 1min;
(3), use vulcanizing press or rubber injection machine to vulcanize: cure conditions: 150 ℃ of temperature, time 10min, pressure 10MPa.
embodiment 3
An anti-puncture boots bottom material, is comprised of the proportioning of following parts by weight:
Natural rubber: 60; Chloroprene rubber: 40; Styrene-butadiene rubber(SBR): 40; Sulfur: 1.2; Altax: 0.8; Captax: 0.5; Zinc oxide: 5.0; Stearic acid: 2.5; High abrasion carbon black: 28; Antioxidant D: 1.5; Antioxidant 4010: 2.0; Magnesium oxide: 2.5.
Preparation method is as follows:
(1), by formula rate, weigh the consumption of various rubber and Synergist S-421 95;
(2), use mill to carry out mixing: natural rubber, chloroprene rubber, styrene-butadiene rubber(SBR) to be put into mill and fully plasticated, front roll temperature≤40 ℃, rear roll temperature≤55 ℃, roll spacing 0.2mm, time 10min;
Add antioxidant D, antioxidant 4010, stearic acid, magnesium oxide, roller temperature is constant, roll spacing 1.0mm, time 2.5min;
Add zinc oxide, high abrasion carbon black, roller temperature is constant, roll spacing 0.5mm, time 6min;
Add altax, captax, roller temperature is constant, roll spacing 0.7mm, time 2min;
Add Sulfur, roller temperature is constant, roll spacing 0.8mm, time 3min;
Eight cuttves, roller temperature is constant, roll spacing 0.5mm, time 8min;
Play triangle bag, roller temperature is constant, roll spacing 0.3mm, time 6min;
Slice, the film that roller temperature is constant, thickness is 1.5mm, time 1min;
(3), use vulcanizing press or rubber injection machine to vulcanize: cure conditions: 150 ℃ of temperature, time 10min, pressure 10MPa.
embodiment 4
An anti-puncture boots bottom material, is comprised of the proportioning of following parts by weight:
Natural rubber: 20; Chloroprene rubber: 30; Styrene-butadiene rubber(SBR): 25; Sulfur: 1.7; Altax: 0.4; Captax: 0.3; Zinc oxide: 7.0; Stearic acid: 1.5; High abrasion carbon black: 35; Antioxidant D: 0.8; Antioxidant 4010: 1.3; Magnesium oxide: 2.2.
Preparation method is as follows:
(1), by formula rate, weigh the consumption of various rubber and Synergist S-421 95;
(2), use mill to carry out mixing: natural rubber, chloroprene rubber, styrene-butadiene rubber(SBR) to be put into mill and fully plasticated, front roll temperature≤40 ℃, rear roll temperature≤55 ℃, roll spacing 0.4mm, time 13min;
Add antioxidant D, antioxidant 4010, stearic acid, magnesium oxide, roller temperature is constant, roll spacing 0.8mm, time 3min;
Add zinc oxide, high abrasion carbon black, roller temperature is constant, roll spacing 0.8mm, time 5min;
Add altax, captax, roller temperature is constant, roll spacing 1.0mm, time 3min;
Add Sulfur, roller temperature is constant, roll spacing 0.6mm, time 2min;
Eight cuttves, roller temperature is constant, roll spacing 0.1mm, time 6min;
Play triangle bag, roller temperature is constant, roll spacing 0.1mm, time 7min;
Slice, the film that roller temperature is constant, thickness is 1.2mm, time 1min;
(3), use vulcanizing press or rubber injection machine to vulcanize: cure conditions: 150 ℃ of temperature, time 10min, pressure 10MPa.
Claims (1)
1. a preparation method for anti-puncture boots bottom material, is characterized in that: comprise the steps:
(1), by formula rate, weigh the consumption of various rubber and Synergist S-421 95;
Formula is comprised of the raw material of following parts by weight: natural rubber: 20～60; Chloroprene rubber: 40～20; Styrene-butadiene rubber(SBR): 40～20; Sulfur: 1.2～2.0; Altax: 0.3～0.8; Captax: 0.3～1.0; Zinc oxide: 5.0～7.0; Stearic acid: 1.0～2.5; High abrasion carbon black: 25～35; Antioxidant D: 0.8～1.5; Antioxidant 4010: 1.0～2.0; Magnesium oxide: 1.5～2.5;
(2), use mill to carry out mixing: natural rubber, chloroprene rubber, styrene-butadiene rubber(SBR) to be put into mill and fully plasticated, front roll temperature≤40 ℃, rear roll temperature≤55 ℃, roll spacing 0.1～0.5mm, time 10～15min;
Add antioxidant D, antioxidant 4010, stearic acid, magnesium oxide, roller temperature is constant, roll spacing 0.5～1.0mm, time 2～3min;
Add zinc oxide, high abrasion carbon black, roller temperature is constant, roll spacing 0.5～1.0mm, time 5～6min;
Add altax, captax, roller temperature is constant, roll spacing 0.5～1.0mm, time 2～3min;
Add Sulfur, roller temperature is constant, roll spacing 0.5～0.1mm, time 2～3min;
Eight cuttves, roller temperature is constant, roll spacing 0.1～0.5mm, time 6～8min;
Play triangle bag, roller temperature is constant, roll spacing 0.1～0.3mm, time 6～8min;
Slice, the film that roller temperature is constant, thickness is 1.0～1.5mm, time 1～2min;
(3), use vulcanizing press or rubber injection machine to vulcanize: cure conditions: 150 ℃ of temperature, time 10min, pressure 10MPa.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310586907.6A CN103613793B (en) | 2013-11-21 | 2013-11-21 | The preparation method of Puncture resistant boot sole material |
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| CN201310586907.6A CN103613793B (en) | 2013-11-21 | 2013-11-21 | The preparation method of Puncture resistant boot sole material |
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| CN103613793A true CN103613793A (en) | 2014-03-05 |
| CN103613793B CN103613793B (en) | 2016-03-02 |
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| CN201310586907.6A Expired - Fee Related CN103613793B (en) | 2013-11-21 | 2013-11-21 | The preparation method of Puncture resistant boot sole material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104311931A (en) * | 2014-11-04 | 2015-01-28 | 天长市高新技术创业服务中心 | High-strength ageing-resistant wear-resisting anti-flaming modified styrene butadiene rubber |
| CN105949549A (en) * | 2016-05-06 | 2016-09-21 | 际华三五三九制鞋有限公司 | Multifunctional protective shoe |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619146A (en) * | 2009-08-07 | 2010-01-06 | 中国化工橡胶桂林有限公司 | Rubber composition for tire side of all-steel giant project tire and all-steel giant project tire |
| US20110258886A1 (en) * | 2010-04-26 | 2011-10-27 | Ku Do Moon | Slip-Resistant Rubber Composition, Outsole Using the Rubber Composition and Method of Manufacturing the Outsole |
| CN102977478A (en) * | 2012-11-26 | 2013-03-20 | 山西新华化工有限责任公司 | Flame-retardant rubber material capable of protecting high-risk chemicals and method for preparing same |
-
2013
- 2013-11-21 CN CN201310586907.6A patent/CN103613793B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619146A (en) * | 2009-08-07 | 2010-01-06 | 中国化工橡胶桂林有限公司 | Rubber composition for tire side of all-steel giant project tire and all-steel giant project tire |
| US20110258886A1 (en) * | 2010-04-26 | 2011-10-27 | Ku Do Moon | Slip-Resistant Rubber Composition, Outsole Using the Rubber Composition and Method of Manufacturing the Outsole |
| CN102977478A (en) * | 2012-11-26 | 2013-03-20 | 山西新华化工有限责任公司 | Flame-retardant rubber material capable of protecting high-risk chemicals and method for preparing same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104311931A (en) * | 2014-11-04 | 2015-01-28 | 天长市高新技术创业服务中心 | High-strength ageing-resistant wear-resisting anti-flaming modified styrene butadiene rubber |
| CN105949549A (en) * | 2016-05-06 | 2016-09-21 | 际华三五三九制鞋有限公司 | Multifunctional protective shoe |
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| CN103613793B (en) | 2016-03-02 |
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| CB03 | Change of inventor or designer information |
Inventor after: Yang Jiangong Inventor after: Chang Huifang Inventor after: Zhang Zhongjie Inventor after: Qi Jiahao Inventor after: Huang Ying Inventor before: Yang Jiangong Inventor before: Chang Huifang Inventor before: Zhang Zhongjie Inventor before: Qi Jiahao Inventor before: Huang Ying |
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Granted publication date: 20160302 Termination date: 20211121 |