CN103569952B - The preparation method of one-dimensional Polymers periodic micro structure - Google Patents
The preparation method of one-dimensional Polymers periodic micro structure Download PDFInfo
- Publication number
- CN103569952B CN103569952B CN201310560890.7A CN201310560890A CN103569952B CN 103569952 B CN103569952 B CN 103569952B CN 201310560890 A CN201310560890 A CN 201310560890A CN 103569952 B CN103569952 B CN 103569952B
- Authority
- CN
- China
- Prior art keywords
- quartz fibre
- preparation
- micro structure
- structural
- micro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a kind of preparation method of one-dimensional Polymers periodic micro structure, the method comprises the following steps: dimethyl silicone polymer is filled the composite construction of quartzy fiber gap along quartz fibre axial split, be placed in the quartz fibre of HF acid solution erosion removal splitting section, form the micro-structural of periodically semicolumn depression; Utilize above-mentioned micro-structural for template, impress the high molecular polymers such as polystyrene, polymethyl methacrylate, dimethyl silicone polymer, photoresist at substrate surface by modes such as hot pressing, photo-crosslinking, heat cross-linkings, form one-dimensional Polymers periodic micro structure.The inventive method is novel, and the micro-structural of acquisition can obtain application in fields such as photoelectricity, the energy, biologies.
Description
Technical field
The present invention relates to the preparation method of a kind of sub-micron and micron fine structure material, particularly a kind of technology of preparing of one-dimensional Polymers periodic micro structure.
Background technology
One-dimensional Polymers periodic micro structure has important application background.Template prepared by the passage that they can be used as the waveguide of optical transport, the anti-reflecting layer of solar cell, microfluid are advanced, other fine structure material etc.The method mainly photoetching of current preparation, its preparation flow is complicated, and cost is high.
Summary of the invention
The object of this invention is to provide the preparation method of the low one-dimensional Polymers periodic micro structure of a kind of preparation cost.
In order to realize foregoing invention object, the technical solution used in the present invention is as follows:
The preparation method of one-dimensional Polymers periodic micro structure, comprises the following steps:
(1) micron, sub-micron quartz fibre is assembled by self-assembling technique, obtain the quartz fibre bundle that arrangement is regular, by the dimethyl silicone polymer that described quartz fibre bundle is 0.1-0.6 by physics or chemical method packing volume ratio, obtain the composite construction that dimethyl silicone polymer fills quartzy fiber gap;
(2) by above-mentioned composite construction along quartz fibre axial split, be placed in the quartz fibre of HF acid solution erosion removal splitting section, form the micro-structural of periodically semicolumn depression;
(3) utilize above-mentioned micro-structural for template, prepare the high molecular polymers such as polystyrene, polymethyl methacrylate, dimethyl silicone polymer, photoresist at substrate surface by modes such as hot pressing, photo-crosslinking, heat cross-linkings, form one-dimensional Polymers periodic micro structure.
Compared with prior art, its remarkable advantage is with low cost in the present invention, without the need to large-scale instrument, and simple and reliable process.The inventive method is novel, and the micro-structural of acquisition can obtain application in fields such as photoelectricity, the energy, biologies.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the preparation method of one-dimensional Polymers periodic micro structure.Step (A) is for fill dimethyl silicone polymer with the composite construction of quartzy fiber gap along quartz fibre axial split; Step (B), for being placed on the quartz fibre of erosion removal splitting section in HF acid solution, forms the micro-structural of periodically semicolumn depression; Step (C), for utilizing above-mentioned micro-structural for template, at substrate surface impression polymer, forms one-dimensional Polymers periodic micro structure.
Detailed description of the invention
The present invention is described in further detail below.
The composite construction that in embodiment, dimethyl silicone polymer fills quartzy fiber gap obtains according to the method for patent ZL200710134575.2, be specially: assemble micron, sub-micron quartz fibre by self-assembling technique, obtain the quartz fibre bundle that arrangement is regular, by the dimethyl silicone polymer that described quartz fibre bundle is 0.1-0.6 by physics or chemical method packing volume ratio.
Embodiment 1: the composite construction of dimethyl silicone polymer being filled quartzy fiber gap, along quartz fibre axial split, is placed in the quartz fibre of HF acid solution erosion removal splitting section, forms the micro-structural of periodically semicolumn depression; Utilize above-mentioned micro-structural for template, impress polystyrene at substrate surface by hot pressing, form polystyrene one-dimensional Polymers periodic micro structure.
Embodiment 2: the composite construction of dimethyl silicone polymer being filled quartzy fiber gap, along quartz fibre axial split, is placed in the quartz fibre of HF acid solution erosion removal splitting section, forms the micro-structural of periodically semicolumn depression; Utilize above-mentioned micro-structural for template, at substrate surface by photo-crosslinking photoresist, form photoresist one-dimensional Polymers periodic micro structure.
Embodiment 3: the composite construction of dimethyl silicone polymer being filled quartzy fiber gap, along quartz fibre axial split, is placed in the quartz fibre of HF acid solution erosion removal splitting section, forms the micro-structural of periodically semicolumn depression; Utilize above-mentioned micro-structural for template, at substrate surface by heat cross-linking dimethyl silicone polymer, form dimethyl silicone polymer one-dimensional Polymers periodic micro structure.
Embodiment 4: the composite construction of dimethyl silicone polymer being filled quartzy fiber gap, along quartz fibre axial split, is placed in the quartz fibre of HF acid solution erosion removal splitting section, forms the micro-structural of periodically semicolumn depression; Utilize above-mentioned micro-structural for template, at substrate surface by hot pressing polymethyl methacrylate, form polymethyl methacrylate one-dimensional Polymers periodic micro structure.
Claims (3)
1. the preparation method of one-dimensional Polymers periodic micro structure, is characterized in that, said method comprising the steps of:
(1) micron, sub-micron quartz fibre is assembled by self-assembling technique, obtain the quartz fibre bundle that arrangement is regular, by the dimethyl silicone polymer that described quartz fibre bundle is 0.1-0.6 by physics or chemical method packing volume ratio, obtain the composite construction that dimethyl silicone polymer fills quartzy fiber gap;
(2) by above-mentioned composite construction along quartz fibre axial split, be placed in the quartz fibre of HF acid solution erosion removal splitting section, form the micro-structural of periodically semicolumn depression;
(3) utilize above-mentioned micro-structural for template, prepare one-dimensional Polymers periodic micro structure at substrate surface.
2. the preparation method of one-dimensional Polymers periodic micro structure according to claim 1, is characterized in that, in step (3), described preparation method is hot pressing, photo-crosslinking or heat cross-linking.
3. the preparation method of one-dimensional Polymers periodic micro structure according to claim 1 and 2, is characterized in that, in step (3), described polymer is polystyrene, polymethyl methacrylate, dimethyl silicone polymer or photoresist.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310560890.7A CN103569952B (en) | 2013-11-12 | 2013-11-12 | The preparation method of one-dimensional Polymers periodic micro structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310560890.7A CN103569952B (en) | 2013-11-12 | 2013-11-12 | The preparation method of one-dimensional Polymers periodic micro structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103569952A CN103569952A (en) | 2014-02-12 |
| CN103569952B true CN103569952B (en) | 2016-01-20 |
Family
ID=50042767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310560890.7A Active CN103569952B (en) | 2013-11-12 | 2013-11-12 | The preparation method of one-dimensional Polymers periodic micro structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103569952B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1769034A (en) * | 2005-10-20 | 2006-05-10 | 南京大学 | Method for preparing micron planar bravais lattice or chain lattice on polymer surface |
| CN1772463A (en) * | 2005-10-20 | 2006-05-17 | 南京大学 | Prepn of submicron/micron micro lens array on polymer surface |
| CN101070139A (en) * | 2007-03-19 | 2007-11-14 | 南京大学 | Method for preparing micron/submicron metal ring and open-mouth metal ring |
| CN101143705A (en) * | 2007-11-01 | 2008-03-19 | 南京大学 | Method for preparing micrometer and submicron probe arrays |
| CN101234221A (en) * | 2008-01-04 | 2008-08-06 | 南京大学 | Method of preparing micro needle array syringe |
-
2013
- 2013-11-12 CN CN201310560890.7A patent/CN103569952B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1769034A (en) * | 2005-10-20 | 2006-05-10 | 南京大学 | Method for preparing micron planar bravais lattice or chain lattice on polymer surface |
| CN1772463A (en) * | 2005-10-20 | 2006-05-17 | 南京大学 | Prepn of submicron/micron micro lens array on polymer surface |
| CN101070139A (en) * | 2007-03-19 | 2007-11-14 | 南京大学 | Method for preparing micron/submicron metal ring and open-mouth metal ring |
| CN101143705A (en) * | 2007-11-01 | 2008-03-19 | 南京大学 | Method for preparing micrometer and submicron probe arrays |
| CN101234221A (en) * | 2008-01-04 | 2008-08-06 | 南京大学 | Method of preparing micro needle array syringe |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103569952A (en) | 2014-02-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Jia et al. | Scalable, anisotropic transparent paper directly from wood for light management in solar cells | |
| Huang et al. | Ultrafast digital printing toward 4D shape changing materials. | |
| Li et al. | Uniform vertical trench etching on silicon with high aspect ratio by metal-assisted chemical etching using nanoporous catalysts | |
| Camargo et al. | Localised actuation in composites containing carbon nanotubes and liquid crystalline elastomers | |
| Albero et al. | Fabrication of spherical microlenses by a combination of isotropic wet etching of silicon and molding techniques | |
| Li et al. | Facile method for modulating the profiles and periods of self-ordered three-dimensional alumina taper-nanopores | |
| WO2011039068A3 (en) | Thermo-electric energy converter having a three-dimensional micro-structure, method for producing the energy converter and use of the energy converter | |
| Sukhdeo et al. | Bandgap-customizable germanium using lithographically determined biaxial tensile strain for silicon-compatible optoelectronics | |
| BR112016003919A2 (en) | MANUFACTURE OF HIERARCHICAL SILICA NANOMEMBRANES AND USES OF THE SAME FOR SOLID PHASE EXTRACTION OF NUCLEIC ACIDS | |
| Rajan et al. | Polymer micro-fiber Bragg grating | |
| CN103569952B (en) | The preparation method of one-dimensional Polymers periodic micro structure | |
| Kim et al. | Milliwatt-level fiber-coupled laser power from photonic crystal band-edge laser | |
| CN102134066B (en) | Carbon nano tube device and manufacturing method thereof | |
| CN101825744B (en) | High-nonlinearity composite-structure micro-nano optical wave conducting wire and preparation method thereof | |
| CN103018819B (en) | Method for preparing high polymer micro-nano fiber bragg grating based on nanoimprint lithography | |
| CN103569955B (en) | The preparation method of colloid micro ball post array | |
| CN103569959B (en) | The preparation method of quartz wedge-polymer composite fibrous array | |
| Liu et al. | From nanocone to nanodisc: Structural transformation of gold nanoarrays via simple mechanical stresses | |
| Liang et al. | Design and fabrication of polymer-based multimode interference optical splitters | |
| Burgoyne et al. | Screening conditions for rationally engineered electrodeposition of nanostructures (SCREEN): Electrodeposition and applications of polypyrrole nanofibers using microfluidic gradients | |
| CN103569954A (en) | Method for preparing micron submicron reaction vessel array | |
| CN103569957A (en) | Method for preparing polymer micron/submicron line array structure | |
| CN116540491B (en) | Transparent wood surface imprinting optical device and application thereof | |
| CN103138840A (en) | Multiple soliton achieving method based on Weierstrass function | |
| Sun et al. | Multiple Bound State Soliton Pulses in the All Polarization Maintaining Fiber Laser |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhou Yineng Inventor before: Lu Minghui |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170616 Address after: 510000, Guangdong Province, Zengcheng District, Xintang Town, Yao Tian Village, Guangzhou Wai Economic Cooperation, new Wai Industrial Zone, three row, four behind the building Patentee after: GUANGZHOU HONGWEI NEW MATERIALS TECHNOLOGY Co.,Ltd. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170616 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 214192 No. three, No. 99, Furong Road, Wuxi, Jiangsu Patentee before: WUXI IMPRINT NANO TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180330 Address after: 226100 Jiangsu city of Nantong Province Haimen Haimen Textile Industrial Park Avenue South are Dieshiqiao electric mall 3 floor Patentee after: Haimen Huaxia Li Li Network Technology Service Co.,Ltd. Address before: 510000, Guangdong Province, Zengcheng District, Xintang Town, Yao Tian Village, Guangzhou Wai Economic Cooperation, new Wai Industrial Zone, three row, four behind the building Patentee before: GUANGZHOU HONGWEI NEW MATERIALS TECHNOLOGY Co.,Ltd. |