CN103568385A - Heat-preservation hard composite carbon fiber felt and preparation method thereof - Google Patents
Heat-preservation hard composite carbon fiber felt and preparation method thereof Download PDFInfo
- Publication number
- CN103568385A CN103568385A CN201310489217.9A CN201310489217A CN103568385A CN 103568385 A CN103568385 A CN 103568385A CN 201310489217 A CN201310489217 A CN 201310489217A CN 103568385 A CN103568385 A CN 103568385A
- Authority
- CN
- China
- Prior art keywords
- carbon fiber
- felt
- preparation
- carbon fibre
- hard heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Nonwoven Fabrics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Ceramic Products (AREA)
Abstract
The invention discloses a heat-preservation hard composite carbon fiber felt and a preparation method thereof. The preparation method comprises the following steps: forming a carbon fiber vacuum filtration layer, compositing a viscose-based carbon fiber felt or polyacrylonitrile-based carbon fiber felt, soaking a binding agent, needling, coating an upper surface processing layer, forming and postprocessing. The heat-preservation hard composite carbon fiber felt and the preparation method thereof provided by the invention have the advantages that the cost performance optimization design is carried out on a product according to a specific operating environment, the designability of the density of the whole felt is high, the density of an organic padding is relatively low, a high density fiber stacking structure which is corresponding to a high temperature surface is effectively formed, a heat insulation effect is excellent, a low density fiber stacking structure which is corresponding to a low temperature surface is effectively formed, and the cost is economic.
Description
Technical field
The present invention relates to hard heat-insulated felt of a kind of carbon fiber reinforce plastic and preparation method thereof.
Background technology
Carbon fiber hard insulation quilt is a kind of high-end insulation material being applied in the stoves such as sintering cemented carbide stove, monocrystaline silicon stove, vacuum smelting furnace, vacuum heat treatment furnace, gaseous phase deposition stove, and energy-saving and emission-reduction, improving product grade etc. are had to vital effect.
Carbon fiber hard insulation quilt in the market be take polyacrylonitrile-radical needled carbon fiber and viscose base carbon fibre insulation quilt as main, separately has a small amount of asphalt base carbon fiber insulation quilt and phenolic aldehyde base carbon fibre insulation material.Polyacrylonitrile carbon fiber felt low price, but easily fall slag, viscose base insulation quilt low temperature high insulating effect, but the resistance to ablation ability of high temperature and soak effect are not ideal, asphalt-based carbon fiber and phenolic aldehyde carbon-fiber high-temperature heat-insulating property and resistance to ablation ability are best, but expensive, and become felt effect poor.Thereby the general acupuncture carbon felt that the hard heat-insulated felt of polyacrylonitrile-radical mainly adopts forms with binding agent layering bonding, heat treatment, as patent CN102408254A, CN201010254699; The hard heat-insulated felt of asphaltic base has and adopts two kinds of Nomex laminate adhesive goods and the vacuum formings of chopped strand wet method, wherein wet method vacuum forming felt has the features such as density and structure designability are strong, easily process on surface, ash content is low, enjoy user to favor, but too high cost has limited its application space greatly.
Patent CN200810011610.6 discloses a kind of method of preparing hard carbon fibrous carbon felt, and ground carbon fiber fully mixes with binding agent and dispersant solution, through vacuum filtration or compression molding, then through not melting and carbonization treatment.The hard carbon fiber thermal insulation felt technique making is like this simple, but density adjustable range is little, especially can not prepare low density rigid insulation quilt.And due to dispersion complicated components, be difficult to realize the dispersion of the carbon fiber that draw ratio is larger, the actual following short fiber of 1mm of can only realizing disperses, easily carbon felt internal fiber Density Distribution is inhomogeneous, thereby the carbon skewness of insulation quilt inside after carbonization, makes product heat-proof quality and intensity limited.Asphalt-based carbon fiber acupuncture moulding is comparatively complicated and higher to raw material intensity and toughness reguirements, is unfavorable for cost optimization.
Summary of the invention
The object of the present invention is to provide a kind of reasonable in design, hard heat-insulated felt of carbon fiber reinforce plastic of the performance advantage of Cost optimization, outstanding variety classes carbon fiber and preparation method thereof.
The present invention makes full use of the high temperature resistant and anti-ablation advantage of asphalt base carbon fiber or phenolic aldehyde base carbon fibre, make full use of low temperature heat-insulating property advantage and the low-cost advantage of viscose carbon fiber, and Polyacrylonitrile carbon fiber felt low-cost advantage, the another surface erosion-resistant processing layer that increases, adopt whole three-decker, improve the quality of products and reduce material cost.
The present invention adopts the moulding of asphalt-based carbon fiber wet method vacuum filtration, can reduce costs, and can be adjusted fibre density and be realized graded by the mode of wet moulding.
A preparation method for the hard heat-insulated felt of carbon fiber reinforce plastic, comprises the following steps:
(1) carbon fiber vacuum filtration formable layer:
A. disperse: by 100 parts, the carbon fiber of isotropism length 2-30mm, dispersant 0.1-2 part, organic filler 0-40 part, anti-ablation filler 0-5 part, water 3000-5000 part stir, and form finely dispersed compound;
B. injection molding vacuum filtration: by finely dispersed compound, be cast in vacuum filtration mould, it is 10-50mm that suction filtration obtains thickness, density 0.06-0.30g/cm
3carbon fiber vacuum filtration layer;
(2) compound viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre acupuncture carpet veneer:
A. according to required area, cutting density is 0.08-0.15g/cm
3, the viscose base carbon fibre felt of thickness 5-15mm or polyacrylonitrile-based carbon fibre Nomex;
B. on viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre Nomex, brush phenolic resins or the furfural resin of solid content 25%-60%;
C. viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre Nomex are coated with and are brushed with one of binding agent and face down and pack in vacuum filtration mould, itself and carbon fiber vacuum filtration layer are closely attached;
(3) soak binding agent, acupuncture and apply upper surface processing layer:
A. prepare phenolic resins or furfural resin 500-1000 part of solid content 1%-25%, carbon black 0.01-5 part, the following coke powder 0.01-5 of 200 order part, the following anti-ablation filler 0.1-5 part of 200 orders, 0.1mm-10mm chopped carbon fiber 0.1-5 part, mixes;
B. above-mentioned preparation is pressed to 20kg/m
2-80kg/m
2add in vacuum filtration mould, material 1-30 minute in dipping vacuum filtration mould, adopt with effective length and be greater than 30mm simultaneously, the longitudinal acupuncture of needle plate of planting that diameter is greater than 2.67mm pricker penetrates each layer of felt, needling density 5000-25000 pin/square meter, makes the chopped carbon fiber adding run through as much as possible whole three-decker, and the longitudinal arrangement that increases each fiber of interlayer is with interspersed, and then carry out secondary suction filtration, on the surface of material, form the upper surface processing layer of the thick densification of 0.1-1mm;
(4) moulding: after the demoulding, pressurization 0.001-0.2MPa is also heated to 100-300 ℃ of curing molding, makes curing molding felt;
(5) post processing: under vacuum or inert gas environment, curing molding felt is heated to 600-1500 ℃ of charing, is heated to 1800-3000 ℃ of graphitization, make the hard heat-insulated felt of carbon fiber reinforce plastic.
In step (1), described carbon fiber is asphalt base carbon fiber, polyacrylonitrile-based carbon fibre, one or more mixing compositions of phenolic aldehyde base carbon fibre.
In step (1), described carbon fiber also asphaltic base fusion-free fibre and asphalt base carbon fiber in the mixture of the ratio of 1:1-100.
In step (1), described dispersant is that one or more mixing wherein of methylcellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethylcellulose, polyacrylamide or polyvinyl alcohol form.
In step (1), described organic filler is organic fiber, organic granular, one or more of polyvinyl alcohol, pitch, polyethylene, PP GRANULES or fiber, consists of.
In step (1), described anti-ablation filler is one or more compositions in coke powder, carborundum, boron nitride, silicon nitride, boron carbide.
In step (2), the sandwich construction that described viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre Nomex can also be bonded together by one or both some layers that form of viscose base carbon fibre felt, polyacrylonitrile-based carbon fibre Nomex is replaced.
After step (5), can also, on the surface of the hard heat-insulated felt of carbon fiber reinforce plastic, with phenolic resins, paste charcoal cloth, carbon paper or flexible graphite paper paste layer.
A hard heat-insulated felt, is prepared by the preparation method of the hard heat-insulated felt of above-mentioned a kind of carbon fiber reinforce plastic.
The present invention has following beneficial effect:
Structure after optimization and design of material make carbon fiber hard insulation quilt in serviceability, designability is greatly improved in price, can carry out cost performance optimal design according to concrete environment for use completely.
General patent and technology adopt 2mm(with the following optimum of 1mm) following milled fiber, the technique that this patent adopts wet moulding and again adds binding agent and chopped carbon fiber acupuncture and secondary suction filtration, guarantee fiber dispersion and effectively avoided solvent type resin and the interference of emulsifying resin to dispersion, and can effectively longitudinally strengthen, improved greatly the intensity of product.
Wet moulding layer adopts organic filler, makes the minimum 0.06g/cm of reaching of wet moulding layer density in the situation that not destroying asphalt-based carbon fiber or the dispersion of phenolic aldehyde base carbon fibre
3,, make the density designability of whole felt high.And, organic filler density is lower, effectively formed the graded of wet moulding layer internal fiber stacked structure density, it is the corresponding high-density fiber stacked structure of high temperature face, insulation effect is more excellent, the corresponding low-density fibre stacked structure of low temperature face, cost is more economical, the actual user demand of more fitting.
The specific embodiment
Example 1:
(1) carbon fiber vacuum filtration formable layer: adopting isotropism length is that 100 parts of the chopped asphalt base carbon fibers of 5mm, 0.1 part of methylcellulose, 0.5 part of polyacrylamide, length are 25 parts of 5mm vinals, 1 part of 200 order boron nitride, 5000 parts, water, stir, be cast in particular manufacturing craft, suction filtration moulding makes the pre-felt of asphalt-based carbon fiber that thickness is 38mm.
(2) compound viscose base carbon fibre carpet veneer: cutting mould is equal to the thick density 0.12g/cm of big or small 5mm
3viscose base carbon fibre felt, brushes 50% phenolic resins, packs mould into and is fitted in preformed asphalt base carbon fiber felt surface.
(3) soak binding agent, acupuncture and apply upper surface processing layer: 500 parts, the phenolic resins of preparation solid content 5%, 1 part of carbon black, 200 1 part of order coke powder, 200 5 parts of order boron nitride, length is the uniform dispersion of 2 parts of 0.1mm-6mm chopped carbon fibers, by 20kg/m
2add in mould, and adopt with effective length 33mm, the longitudinal acupuncture of needle plate of planting of diameter 2.67mm pricker penetrates each layer of felt, needling density 10000 pins/square meter, then secondary suction filtration.
(4) moulding: the demoulding, pressurization 0.01MPa is also heated to 150 ℃ of curing moldings.
(5) post processing: in inert nitrogen gas, curing molding felt is in 1000 ℃ of charings, 1800 ℃ of graphitizations in inert gas argon gas, and by rubbed finish, to obtain thickness be the hard heat-insulated felt of 40mm carbon fiber reinforce plastic, global density 0.15g/cm
3.
Example 2
(1) carbon fiber vacuum filtration formable layer: adopting isotropism length is that 20 parts of the chopped asphaltic base fusion-free fibres of 20mm, length are that 80 parts of the chopped asphalt base carbon fibers of 5mm, 0.1 part of hydroxyethylcellulose, 0.5 part of polyacrylamide, length are 20 parts of 5mm polypropylene fibres, 1 part of 200 order boron carbide, 4000 parts, water, stir, be cast in particular manufacturing craft, suction filtration moulding makes the pre-felt of the thick asphalt-based carbon fiber of 42mm, fiber accumulations density 0.08g/cm
3.
(2) compound viscose base carbon fibre felt and polyacrylonitrile-based carbon fibre acupuncture carpet veneer: cutting mould is equal to big or small thickness 10mm density 0.14g/cm
3polyacrylonitrile-based carbon fibre Nomex, brushes 60% phenolic resins, packs mould into and is fitted in preformed asphalt base carbon fiber felt surface.Cutting mould is equal to big or small thickness 5mm density 0.12g/cm again
3viscose base carbon fibre felt, brushes 60% phenolic resins, packs mould into and is fitted in polyacrylonitrile-based carbon fibre Nomex surface.
(3) soak binding agent, acupuncture and apply upper surface processing layer: 500 parts, the phenolic resins of preparation solid content 7%, 1 part of carbon black, 200 1 part of order coke powder, 200 3 parts of order boron carbides, length is the uniform dispersion of 2 parts of 0.1mm-6mm chopped carbon fibers, by 20kg/m
2add in mould, and adopt with effective length 40mm, the longitudinal acupuncture of needle plate of planting of diameter 3mm pricker penetrates each layer of felt, needling density 5000 pins/square meter, then secondary suction filtration.
(4) moulding: the demoulding, pressurization 0.01MPa is also heated to 200 ℃ of curing moldings.
(5) post processing: in inert nitrogen gas, curing molding felt is in 1000 ℃ of charings, 1800 ℃ of graphitizations in inert gas argon gas, and by rubbed finish, to obtain thickness be the hard heat-insulated felt of 52mm carbon fiber reinforce plastic, global density 0.155g/cm
3.
Example 3
(1) carbon fiber vacuum filtration formable layer: adopting isotropism length is that 10 parts of the chopped asphaltic base fusion-free fibres of 10mm, length are 90 parts of the chopped asphalt base carbon fibers of 3mm, 0.2 part of carboxymethyl cellulose, 0.5 part of polyacrylamide, 10 parts of 80 order polyethylene particles, 1 part of 200 order boron carbide, 4000 parts, water, stir, be cast in particular manufacturing craft, suction filtration moulding makes the pre-felt of thickness 40mm asphalt base carbon fiber, fiber accumulations density 0.09g/cm
3.
(2) compound viscose base carbon fibre felt and polyacrylonitrile-based carbon fibre acupuncture carpet veneer: cutting mould is equal to big or small thickness 5mm density 0.14g/cm
3polyacrylonitrile-based carbon fibre fibrofelt, brushes 45% phenolic resins, packs mould into and is fitted in preformed asphalt base carbon fiber felt surface.Cutting mould is equal to big or small thickness 10mm density 0.12g/cm again
3viscose base carbon fibre felt, brushes 60% phenolic resins, packs mould into and is fitted in polyacrylonitrile-based carbon fibre Nomex surface.
(3) soak binding agent, acupuncture and apply upper surface processing layer: 500 parts, the phenolic resins of preparation solid content 10%, 0.5 part of carbon black, 200 0.5 part of order coke powder, 200 2 parts of order boron carbides, length is the uniform dispersion of 1 part of 0.1mm-6mm chopped carbon fiber, by 30kg/m
2add in mould, and adopt with effective length 40mm, the longitudinal acupuncture of needle plate of planting of diameter 3mm pricker penetrates each layer of felt, needling density 5000 pins/square meter, then secondary suction filtration.
(4) moulding: the demoulding, pressurization 0.005MPa is also heated to 150 ℃ of curing moldings.
(5) post processing: in the nitrogen of inert gas, curing molding felt is in 1000 ℃ of charings, 1800 ℃ of graphitizations in the argon gas of inert gas, and obtain the hard heat-insulated felt of thickness 50mm carbon fiber reinforce plastic, global density 0.145g/cm by rubbed finish
3.
Example 4
(1) carbon fiber vacuum filtration formable layer: adopt 100 parts of the chopped asphalt base carbon fibers of the long isotropism of 3mm, 0.1 part of carboxymethyl cellulose, 0.5 part of polyacrylamide, 5 parts of the long vinals of 5mm, 4000 parts, water, stir, be cast in particular manufacturing craft, suction filtration moulding makes the pre-felt of the thick asphalt-based carbon fiber of 35mm, fiber accumulations density 0.11g/cm
3.
(2) compound viscose base carbon fibre carpet veneer: cutting mould is equal to big or small thickness 10mm density 0.12g/cm
3viscose base carbon fibre felt, brushes 40% phenolic resins, packs mould into and is fitted in preformed asphalt base carbon fiber felt surface.
(3) soak binding agent, acupuncture and apply upper surface processing layer: 500 parts, the phenolic resins of preparation solid content 15%, 0.5 part of carbon black, 200 0.5 part of order coke powder, 200 2 parts of order boron carbides, length is the uniform dispersion of 3 parts of 3mm-6mm chopped carbon fibers, by 80kg/m
2add in mould, and adopt with effective length 33mm, the longitudinal acupuncture of needle plate of planting of diameter 2.67mm pricker penetrates each layer of felt, needling density 15000 pins/square meter, then secondary suction filtration.
(4) moulding: the demoulding, pressurization 0.1MPa is also heated to 150 ℃ of curing moldings.
(5) post processing: in the nitrogen of inert gas, curing molding felt is in 1000 ℃ of charings, 1800 ℃ of graphitizations in the argon gas of inert gas, and by rubbed finish, to obtain thickness be the hard heat-insulated felt of 42mm carbon fiber reinforce plastic, global density 0.18g/cm
3.
Example 5
(1) carbon fiber vacuum filtration formable layer: adopt 100 parts of the chopped asphalt base carbon fibers of the long isotropism of 3mm, 0.1 part of carboxymethyl cellulose, 0.5 part of polyacrylamide, length 0.1mm to grind 5 parts of pitch fibers (waste silk), 1 part of 200 order boron carbide, 4000 parts, water, stir, be cast in particular manufacturing craft, suction filtration moulding makes the pre-felt of the thick asphalt-based carbon fiber of 35mm, fiber accumulations density 0.12g/cm
3.
(2) compound viscose base carbon fibre carpet veneer: cutting mould is equal to big or small thickness 10mm density 0.12g/cm
3two, viscose base carbon fibre felt, brushes 40% phenolic resins, packs successively mould into.
(3) soak binding agent, acupuncture and apply upper surface processing layer: 500 parts, the phenolic resins of preparation solid content 15%, 0.5 part of carbon black, 200 0.5 part of order coke powder, 200 2 parts of order boron carbides, length is the uniform dispersion of 3 parts of 3mm-6mm chopped carbon fibers, by 60kg/m
2add in mould, and adopt with effective length 40mm, the longitudinal acupuncture of needle plate of planting of diameter 3mm pricker penetrates each layer of felt, needling density 15000 pins/square meter, then secondary suction filtration.
(4) moulding: the demoulding, pressurization 0.1MPa is also heated to 150 ℃ of curing moldings.
(5) post processing: in the nitrogen of inert gas, curing molding felt is in 1000 ℃ of charings, 1800 ℃ of graphitizations in the argon gas of inert gas, and obtain the hard heat-insulated felt of the thick carbon fiber reinforce plastic of 50mm, global density 0.175g/cm by rubbed finish
3.
Example 6
(1) carbon fiber vacuum filtration formable layer: adopt 100 parts of the long phenolic aldehyde base carbon fibres of 5mm, 0.1 part of carboxymethyl cellulose, 0.5 part of polyacrylamide, 4000 parts, water, stir, be cast in particular manufacturing craft, suction filtration moulding makes the pre-felt of the thick phenolic aldehyde base carbon fibre of 35mm, fiber accumulations density 0.11g/cm
3.
(2) composite polypropylene itrile group carbon fiber Nomex and viscose base carbon fibre carpet veneer: cutting mould is equal to big or small thickness 10mm density 0.14g/cm
3polyacrylonitrile-based carbon fibre Nomex, brushes 40% phenolic resins, packs mould into and is fitted in preformed phenolic aldehyde base carbon fibre felt surface.Cutting mould is equal to big or small thickness 5mm density 0.12g/cm again
3viscose base carbon fibre felt, brushes 40% phenolic resins, packs mould into and is fitted in polyacrylonitrile-based carbon fibre Nomex surface.
(3) soak binding agent, acupuncture and apply upper surface processing layer: 500 parts, the phenolic resins of preparation solid content 15%, 0.5 part of carbon black, 200 0.5 part of order coke powder, 200 2 parts of order boron carbides, length is the uniform dispersion of 3 parts of 6mm-10mm chopped carbon fibers, by 50kg/m
2add in mould, and adopt with effective length 33mm, the longitudinal acupuncture of needle plate of planting of diameter 2.67mm pricker penetrates each layer of felt, needling density 25000 pins/square meter, then secondary suction filtration.
(4) moulding: the demoulding, pressurization 0.1MPa is also heated to 150 ℃ of curing moldings.
(5) post processing: in the nitrogen of inert gas, curing molding felt is in 1000 ℃ of charings, 1800 ℃ of graphitizations in the argon gas of inert gas, and obtain the hard heat-insulated felt of the thick carbon fiber reinforce plastic of 47mm, global density 0.18g/cm by rubbed finish
3.
Claims (9)
1. a preparation method for the hard heat-insulated felt of carbon fiber reinforce plastic, is characterized in that comprising the following steps:
(1) carbon fiber vacuum filtration formable layer:
A. disperse: by 100 parts, the carbon fiber of length 2-30mm, dispersant 0.1-2 part, organic filler 0-40 part, anti-ablation filler 0-5 part, water 3000-5000 part stir, and form finely dispersed compound;
B. injection molding vacuum filtration: by finely dispersed compound, be cast in vacuum filtration mould, it is 10-50mm that suction filtration obtains thickness, density 0.06-0.30g/cm
3carbon fiber vacuum filtration layer;
(2) compound viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre acupuncture carpet veneer:
A. cutting density is 0.08-0.15g/cm
3, the viscose base carbon fibre felt of thickness 5-15mm or polyacrylonitrile-based carbon fibre Nomex;
B. on viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre Nomex, brush phenolic resins or the furfural resin of solid content 25%-60%;
C. viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre Nomex are coated with and are brushed with one of binding agent and face down and pack in vacuum filtration mould, itself and carbon fiber vacuum filtration layer are closely attached;
(3) soak binding agent, acupuncture and apply upper surface processing layer:
A. prepare phenolic resins or furfural resin 500-1000 part of solid content 1%-25%, carbon black 0.01-5 part, the following coke powder 0.01-5 of 200 order part, the following anti-ablation filler 0.1-5 part of 200 orders, length is 0.1mm-10mm chopped carbon fiber 0.1-5 part, mixes;
B. above-mentioned preparation is pressed to 20kg/m
2-80kg/m
2add in vacuum filtration mould, material 1-30 minute in dipping vacuum filtration mould, and employing is greater than 30mm with effective length, the longitudinal acupuncture of needle plate of planting that diameter is greater than 2.67mm pricker penetrates each layer of felt, needling density 5000-25000 pin/square meter, then secondary suction filtration, forms the upper surface processing layer of the thick densification of 0.1-1mm on the surface of material;
(4) moulding: after the demoulding, pressurization 0.001-0.2MPa is also heated to 100-300 ℃ of curing molding, makes curing molding felt;
(5) post processing: under vacuum or inert gas environment, curing molding felt is heated to 600-1500 ℃ of charing, is heated to 1800-3000 ℃ of graphitization, make the hard heat-insulated felt of carbon fiber reinforce plastic.
2. the preparation method of the hard heat-insulated felt of a kind of carbon fiber reinforce plastic according to claim 1, is characterized in that: in step (1), described carbon fiber is asphalt base carbon fiber, polyacrylonitrile-based carbon fibre, one or more mixing compositions of phenolic aldehyde base carbon fibre.
3. the preparation method of the hard heat-insulated felt of a kind of carbon fiber reinforce plastic according to claim 1, is characterized in that: in step (1), described carbon fiber is that asphaltic base fusion-free fibre and asphalt base carbon fiber are in the mixture of the ratio of 1:1-100.
4. the preparation method of the hard heat-insulated felt of a kind of carbon fiber reinforce plastic according to claim 1, it is characterized in that: in step (1), described dispersant is that one or more mixing wherein of methylcellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethylcellulose, polyacrylamide or polyvinyl alcohol form.
5. the preparation method of the hard heat-insulated felt of a kind of carbon fiber reinforce plastic according to claim 1; it is characterized in that: in step (1); described organic filler is organic fiber, organic granular, one or more of polyvinyl alcohol, pitch, polyethylene, PP GRANULES or fiber, consists of.
6. the preparation method of the hard heat-insulated felt of a kind of carbon fiber reinforce plastic according to claim 1, is characterized in that: in step (1), described anti-ablation filler is one or more compositions in coke powder, carborundum, boron nitride, silicon nitride, boron carbide.
7. the preparation method of the hard heat-insulated felt of a kind of carbon fiber reinforce plastic according to claim 1, it is characterized in that: in step (2), described viscose base carbon fibre felt or polyacrylonitrile-based carbon fibre Nomex are replaced by one or both some layers of sandwich constructions being bonded together that form of viscose base carbon fibre felt, polyacrylonitrile-based carbon fibre Nomex.
8. the preparation method of the hard heat-insulated felt of a kind of carbon fiber reinforce plastic according to claim 1, is characterized in that: after step (5), on the surface of the hard heat-insulated felt of carbon fiber reinforce plastic, with phenolic resins, paste charcoal cloth, carbon paper or flexible graphite paper paste layer.
9. the hard heat-insulated felt of carbon fiber reinforce plastic, is characterized in that: prepared by the preparation method by the hard heat-insulated felt of a kind of carbon fiber reinforce plastic claimed in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310489217.9A CN103568385B (en) | 2013-10-18 | 2013-10-18 | Heat-preservation hard composite carbon fiber felt and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310489217.9A CN103568385B (en) | 2013-10-18 | 2013-10-18 | Heat-preservation hard composite carbon fiber felt and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103568385A true CN103568385A (en) | 2014-02-12 |
| CN103568385B CN103568385B (en) | 2015-04-22 |
Family
ID=50041490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310489217.9A Expired - Fee Related CN103568385B (en) | 2013-10-18 | 2013-10-18 | Heat-preservation hard composite carbon fiber felt and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103568385B (en) |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058777A (en) * | 2014-07-09 | 2014-09-24 | 四川创越炭材料有限公司 | Semi-continuous production method for carbon fiber hard insulation quilt |
| CN104167235A (en) * | 2014-07-25 | 2014-11-26 | 江苏通光光缆有限公司 | Conductive fiber cable |
| CN104383751A (en) * | 2014-11-04 | 2015-03-04 | 厦门三维丝环保股份有限公司 | Stiffening filter material structure for high-temperature-resistant filter drum |
| CN104633395A (en) * | 2014-12-24 | 2015-05-20 | 中国建筑材料科学研究总院 | Hard thermal insulation felt and manufacturing method thereof |
| CN104891950A (en) * | 2015-05-12 | 2015-09-09 | 湖南搏盛天弘新材料技术有限公司 | Hard carbon fiber heat insulation board and preparation method thereof |
| CN105178090A (en) * | 2015-09-13 | 2015-12-23 | 北京化工大学 | Preparation method of chopped-fiber oriented felt |
| CN105801146A (en) * | 2016-04-15 | 2016-07-27 | 航天材料及工艺研究所 | Continuous density gradient low-density porous carbon bonding composite material and preparing method thereof |
| CN105967714A (en) * | 2016-05-23 | 2016-09-28 | 苏州思创源博电子科技有限公司 | Preparation method of composite carbon pottery material |
| CN105967717A (en) * | 2016-05-23 | 2016-09-28 | 苏州思创源博电子科技有限公司 | Preparation method of carbon fiber thermal-insulation board |
| CN106007519A (en) * | 2016-05-23 | 2016-10-12 | 苏州思创源博电子科技有限公司 | Preparation method of compound carbon fiber heat-insulation material |
| CN106626710A (en) * | 2016-12-30 | 2017-05-10 | 嘉兴启晟碳材料有限公司 | Carbon fiber insulation hard felt and preparation method thereof |
| CN106757764A (en) * | 2016-12-28 | 2017-05-31 | 上海交通大学 | A kind of New Regenerated carbon fiber felt reinforcement and preparation method thereof |
| CN106904986A (en) * | 2017-02-23 | 2017-06-30 | 辽宁奥亿达新材料有限公司 | A kind of manufacture method of high-performance composite carbon fiber insulation board |
| CN106319979B (en) * | 2016-08-22 | 2018-06-29 | 广东亚太新材料科技有限公司 | A kind of method for improving composite material delamination resistance energy |
| CN108248135A (en) * | 2016-12-28 | 2018-07-06 | 唯多维科技（天津）有限公司 | The composite material and preparation method of a kind of activated carbon fiber containing polyacrylonitrile-radical |
| CN109456063A (en) * | 2018-12-07 | 2019-03-12 | 烟台凯泊复合材料科技有限公司 | A kind of CF/Si of monocrystalline silicon draw machines3N4Composite material crucible side and preparation method thereof |
| CN109763209A (en) * | 2019-01-31 | 2019-05-17 | 山东瑞城宇航碳材料有限公司 | A method of manufacture high thermal conductivity asphalt base carbon fiber |
| CN109916953A (en) * | 2019-05-06 | 2019-06-21 | 山东众途复合材料有限公司 | The measuring method of the thermal coefficient of gap shape heat-barrier material under superhigh temperature vacuum or inert atmosphere |
| CN109944082A (en) * | 2019-04-04 | 2019-06-28 | 北京卫星制造厂有限公司 | For large-sized low-density long fibre needling structure dimension control method |
| CN110002888A (en) * | 2019-05-16 | 2019-07-12 | 江苏米格新材料有限公司 | A kind of method of staple fiber preparation Carbon fiber thermal insulation felt |
| CN113235307A (en) * | 2021-04-26 | 2021-08-10 | 因达孚先进材料(苏州)有限公司 | Hard heat-preservation viscose-based graphite felt and preparation method thereof |
| CN114164557A (en) * | 2021-12-30 | 2022-03-11 | 湖南东映特碳沥青材料有限公司 | Carbon fiber hard felt and preparation method thereof |
| CN115387131A (en) * | 2022-07-20 | 2022-11-25 | 江苏米格新材料有限公司 | Hard carbon fiber felt composite coating and preparation method thereof |
| CN115418197A (en) * | 2022-08-31 | 2022-12-02 | 湖南大学 | Preparation method of phase-change energy storage material |
| CN116655397A (en) * | 2023-07-28 | 2023-08-29 | 浙江德鸿碳纤维复合材料有限公司 | Carbon/carbon composite material based on short carbon fibers and preparation method thereof |
| CN117046027A (en) * | 2023-06-27 | 2023-11-14 | 湖北及安盾消防科技有限公司 | High-insulation low-corrosion pulse type aerosol fire extinguishing agent and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006114896A1 (en) * | 2005-04-22 | 2006-11-02 | Kureha Corporation | Adhesive agent for thermally insulating material and carbonized laminate for thermally insulating material using the same |
| CN101550017A (en) * | 2009-05-12 | 2009-10-07 | 湖南金博复合材料科技有限公司 | High temperature furnace-grade curing carbon fiber thermal insulating material and production technology thereof |
| CN101591178A (en) * | 2008-05-30 | 2009-12-02 | 鞍山塞诺达碳纤维有限公司 | The manufacturing of rigid carbon-fiber heat-insulation material and surface treatment method |
| JP2011201750A (en) * | 2010-03-26 | 2011-10-13 | Toyo Tanso Kk | Carbon/carbon composite material and method for producing the same |
| CN202293474U (en) * | 2011-11-02 | 2012-07-04 | 上海摩根特种材料有限公司 | Novel carbon fiber insulation material and polycrystal ingot furnace |
| US20120219778A1 (en) * | 2009-10-06 | 2012-08-30 | Sgl Carbon Se | Composite material containing soft carbon fiber felt and hard carbon fiber felt |
-
2013
- 2013-10-18 CN CN201310489217.9A patent/CN103568385B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006114896A1 (en) * | 2005-04-22 | 2006-11-02 | Kureha Corporation | Adhesive agent for thermally insulating material and carbonized laminate for thermally insulating material using the same |
| CN101591178A (en) * | 2008-05-30 | 2009-12-02 | 鞍山塞诺达碳纤维有限公司 | The manufacturing of rigid carbon-fiber heat-insulation material and surface treatment method |
| CN101550017A (en) * | 2009-05-12 | 2009-10-07 | 湖南金博复合材料科技有限公司 | High temperature furnace-grade curing carbon fiber thermal insulating material and production technology thereof |
| US20120219778A1 (en) * | 2009-10-06 | 2012-08-30 | Sgl Carbon Se | Composite material containing soft carbon fiber felt and hard carbon fiber felt |
| JP2011201750A (en) * | 2010-03-26 | 2011-10-13 | Toyo Tanso Kk | Carbon/carbon composite material and method for producing the same |
| CN202293474U (en) * | 2011-11-02 | 2012-07-04 | 上海摩根特种材料有限公司 | Novel carbon fiber insulation material and polycrystal ingot furnace |
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058777B (en) * | 2014-07-09 | 2015-09-09 | 四川创越炭材料有限公司 | The semi-continuous production method of the hard heat-insulated felt of a kind of Carbon fibe |
| CN104058777A (en) * | 2014-07-09 | 2014-09-24 | 四川创越炭材料有限公司 | Semi-continuous production method for carbon fiber hard insulation quilt |
| CN104167235A (en) * | 2014-07-25 | 2014-11-26 | 江苏通光光缆有限公司 | Conductive fiber cable |
| CN104383751A (en) * | 2014-11-04 | 2015-03-04 | 厦门三维丝环保股份有限公司 | Stiffening filter material structure for high-temperature-resistant filter drum |
| CN104633395A (en) * | 2014-12-24 | 2015-05-20 | 中国建筑材料科学研究总院 | Hard thermal insulation felt and manufacturing method thereof |
| CN104891950A (en) * | 2015-05-12 | 2015-09-09 | 湖南搏盛天弘新材料技术有限公司 | Hard carbon fiber heat insulation board and preparation method thereof |
| CN105178090A (en) * | 2015-09-13 | 2015-12-23 | 北京化工大学 | Preparation method of chopped-fiber oriented felt |
| CN105801146B (en) * | 2016-04-15 | 2018-12-21 | 航天材料及工艺研究所 | Low density porous carbon bonding composites of gradient of continuous densityization and preparation method thereof |
| CN105801146A (en) * | 2016-04-15 | 2016-07-27 | 航天材料及工艺研究所 | Continuous density gradient low-density porous carbon bonding composite material and preparing method thereof |
| CN105967714A (en) * | 2016-05-23 | 2016-09-28 | 苏州思创源博电子科技有限公司 | Preparation method of composite carbon pottery material |
| CN105967717A (en) * | 2016-05-23 | 2016-09-28 | 苏州思创源博电子科技有限公司 | Preparation method of carbon fiber thermal-insulation board |
| CN106007519A (en) * | 2016-05-23 | 2016-10-12 | 苏州思创源博电子科技有限公司 | Preparation method of compound carbon fiber heat-insulation material |
| CN106319979B (en) * | 2016-08-22 | 2018-06-29 | 广东亚太新材料科技有限公司 | A kind of method for improving composite material delamination resistance energy |
| CN106757764A (en) * | 2016-12-28 | 2017-05-31 | 上海交通大学 | A kind of New Regenerated carbon fiber felt reinforcement and preparation method thereof |
| CN108248135A (en) * | 2016-12-28 | 2018-07-06 | 唯多维科技（天津）有限公司 | The composite material and preparation method of a kind of activated carbon fiber containing polyacrylonitrile-radical |
| CN106757764B (en) * | 2016-12-28 | 2019-04-02 | 上海交通大学 | A kind of New Regenerated carbon fiber felt reinforcement and preparation method thereof |
| CN106626710A (en) * | 2016-12-30 | 2017-05-10 | 嘉兴启晟碳材料有限公司 | Carbon fiber insulation hard felt and preparation method thereof |
| CN106904986A (en) * | 2017-02-23 | 2017-06-30 | 辽宁奥亿达新材料有限公司 | A kind of manufacture method of high-performance composite carbon fiber insulation board |
| CN109456063A (en) * | 2018-12-07 | 2019-03-12 | 烟台凯泊复合材料科技有限公司 | A kind of CF/Si of monocrystalline silicon draw machines3N4Composite material crucible side and preparation method thereof |
| CN109763209A (en) * | 2019-01-31 | 2019-05-17 | 山东瑞城宇航碳材料有限公司 | A method of manufacture high thermal conductivity asphalt base carbon fiber |
| CN109944082B (en) * | 2019-04-04 | 2021-07-09 | 北京卫星制造厂有限公司 | Dimensional precision control method for large-size low-density long fiber needling structure |
| CN109944082A (en) * | 2019-04-04 | 2019-06-28 | 北京卫星制造厂有限公司 | For large-sized low-density long fibre needling structure dimension control method |
| CN109916953A (en) * | 2019-05-06 | 2019-06-21 | 山东众途复合材料有限公司 | The measuring method of the thermal coefficient of gap shape heat-barrier material under superhigh temperature vacuum or inert atmosphere |
| CN110002888A (en) * | 2019-05-16 | 2019-07-12 | 江苏米格新材料有限公司 | A kind of method of staple fiber preparation Carbon fiber thermal insulation felt |
| CN113235307A (en) * | 2021-04-26 | 2021-08-10 | 因达孚先进材料(苏州)有限公司 | Hard heat-preservation viscose-based graphite felt and preparation method thereof |
| CN114164557A (en) * | 2021-12-30 | 2022-03-11 | 湖南东映特碳沥青材料有限公司 | Carbon fiber hard felt and preparation method thereof |
| CN114164557B (en) * | 2021-12-30 | 2023-07-25 | 湖南东映特碳沥青材料有限公司 | Carbon fiber hard felt and preparation method thereof |
| CN115387131A (en) * | 2022-07-20 | 2022-11-25 | 江苏米格新材料有限公司 | Hard carbon fiber felt composite coating and preparation method thereof |
| CN115418197A (en) * | 2022-08-31 | 2022-12-02 | 湖南大学 | Preparation method of phase-change energy storage material |
| CN117046027A (en) * | 2023-06-27 | 2023-11-14 | 湖北及安盾消防科技有限公司 | High-insulation low-corrosion pulse type aerosol fire extinguishing agent and preparation method thereof |
| CN116655397A (en) * | 2023-07-28 | 2023-08-29 | 浙江德鸿碳纤维复合材料有限公司 | Carbon/carbon composite material based on short carbon fibers and preparation method thereof |
| CN116655397B (en) * | 2023-07-28 | 2023-10-27 | 浙江德鸿碳纤维复合材料有限公司 | Carbon/carbon composite material based on short carbon fibers and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103568385B (en) | 2015-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103568385B (en) | Heat-preservation hard composite carbon fiber felt and preparation method thereof | |
| CN104230368B (en) | Asphalt base carbon fiber non-woven mat warming plate and manufacture method thereof | |
| CN101628816B (en) | Method for manufacturing high-density rigid carbon-fiber heat-insulation material | |
| CN101134678B (en) | High-temperature resistant composite material | |
| CN104261853B (en) | Asphalt base carbon fiber non-woven mat heat-preservation cylinder and manufacture method thereof | |
| CN101591178B (en) | Method for manufacturing rigid carbon fiber heat insulating material and surface treatment method | |
| US20060177663A1 (en) | Carbon-carbon composite article manufactured with needled fibers | |
| CN101798774B (en) | Carbon fiber paper and preparation method thereof | |
| CN109704800A (en) | One kind being based on the molding short carbon fiber toughened ceramic composite forming method of direct write | |
| CN102575400A (en) | Composite material comprising soft carbon fiber felt and hard carbon fiber felt | |
| CN105439607B (en) | A kind of hard Carbon fiber thermal insulation felt and preparation method thereof | |
| CN104058776B (en) | A kind of preparation method of the hard carbon fiber heat preservation material be made up of Carbon fibe ball | |
| CN107323025A (en) | Vertical orientated composite of a kind of interlayer high heat conduction fine hair and preparation method thereof | |
| CN104891950B (en) | A kind of hard carbon fibre thermal-insulation plate and preparation method thereof | |
| CN103073318A (en) | Boron carbide/carbon fiber composite ceramic and preparation method thereof | |
| CN103482980A (en) | C/SiC composite material and preparation method of same | |
| CN101671192A (en) | Preparation method of reinforced carbon-based composite material of carbon foam preform | |
| CN204224476U (en) | Asphalt base carbon fiber non-woven mat heat-preservation cylinder | |
| JP2018024174A (en) | Molding heat insulator and manufacturing method therefor | |
| CN103626472B (en) | A kind of ultrahigh-temperature lagging material and preparation method thereof | |
| CN102211765A (en) | Method for preparing carbon material with high heat conductivity by densifying gaps of graphite paper | |
| CN103193495A (en) | Production method of insulation materials used for crystal pulling furnace | |
| CN102211766A (en) | Rapid low-cost preparation method of high heat conduction carbon material | |
| CN110028329A (en) | A kind of high heat-conducting ceramic based composites and preparation method thereof | |
| CN106631059B (en) | ZrC modified pitch base C/C composite material and preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Heat-preservation hard composite carbon fiber felt and preparation method thereof Effective date of registration: 20161104 Granted publication date: 20150422 Pledgee: Ma Jiaolu Pledgor: Sichuan Chuangyue Carbon Material Co., Ltd. Registration number: 2016510000060 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150422 Termination date: 20191018 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |