Summary of the invention
In order to overcome fire resistance and the defect such as heat-insulating property is poor, rupture strength, impact strength is low and easily make moist of the wall thermal insulating Flameproof composite material of prior art, the invention provides preferably wall thermal insulating fire-resistant composite panel of a kind of fire resistance and heat-insulating property and other performance parameter parameters, it is much better than market common product.
The object of the invention is to be achieved through the following technical solutions:
The gypsum plank of a kind of wall thermal insulating fire-resistant composite panel ,Qi You lower floor and the mask paper on upper strata form; Between described gypsum plank and described mask paper, by binding material, be bonded;
Described gypsum plank is prepared as follows and forms:
According to weight portion, take following raw material: 1 part of line borate, 1 part of sodium succinate, 2 parts, phenolic resins, 6 parts of hydroxyethylcelluloses, 6 parts of starch ethers, 8 parts of glass fiber, 8 parts of polyvinyl alcohol, borax 8-10 part, quartz sand 10-12 part, chitin 10-12 part, dolomite dust 15-20 part, pyrite dust 20-30 part, kieselguhr 30-40 part, water 50-60 part and land plaster 100-120 part;
Above-mentioned each raw material is mixed, then put in mortar mixer, stir and obtain mixed slurry, then mixed slurry is injected to die casting and become sheet material, the demoulding after sheet material solidifies, finally sheet material being placed in to temperature is 60 ℃, in the hygrothermal environment that humidity is 60% 12 hours, obtains gypsum plank;
Described mask paper is prepared as follows and forms:
In pond with slurry, according to weight portion, prepare burden: 300 parts of 5 parts of cornstarch, 5 parts of sodium phosphate trimers, 20 parts of starch ethers, 30 parts, calcium sulfate, 70 parts of PLAs, 80 parts of glass fiber, 100 parts, water, charcoal powder 150 and precipitated calcium carbonates;
First each batching in pond with slurry is stirred and obtains slurry, then enter head box, slurry is evenly distributed in fourdrinier part, enter subsequently vacuum system and carry out first step dehydration, take off more than 50% moisture, form half wet page; Half wet page enters squeezer and carries out second step dehydration, and controlled pressure 30MPa dewaters 30 minutes; Finally, enter dryer and carry out the 3rd step dehydration, controlling temperature is 120 ℃, and the time is 15 minutes, obtains mask paper;
Described binding material is prepared as follows and forms:
According to weight portion, get 1 part of 5 parts of ethylene-vinyl acetate resins (EVA), 3 parts of white glue with vinyl, 2 parts of French chalk, 1 part, agar and casein; Be uniformly mixed and get final product;
The consumption of binding material is that every square metre of bond area is used 100g.
The beneficial effect that the present invention obtains:
1. the wall thermal insulating fire-resistant composite panel fire resistance that prepared by the present invention and heat-insulating property be strong, it is long, environment friendly and pollution-free to meet fiery stability time, can effectively remove pernicious gas;
2. the composite plate that prepared by the present invention all improves greatly in performance parameters such as compressive strength and anti-folding modulus of elasticity, is better than market like product completely, possesses good market prospects;
3. raw material sources of the present invention are extensive, and preparation technology's simple possible, can large-scale industrialization promotion.
The specific embodiment
Below employing specific embodiment is further explained the present invention, but should regard the restriction to initiative spirit of the present invention as.
Embodiment 1
The gypsum plank of a kind of wall thermal insulating fire-resistant composite panel ,Qi You lower floor and the mask paper on upper strata form; Between described gypsum plank and described mask paper, by binding material, be bonded;
Described gypsum plank is prepared as follows and forms:
According to weight portion, take following raw material: 100 parts of 1 part of line borate, 1 part of sodium succinate, 2 parts, phenolic resins, 6 parts of hydroxyethylcelluloses, 6 parts of starch ethers, 8 parts of glass fiber, 8 parts of polyvinyl alcohol, 8 parts of boraxs, 10 parts of quartz sands, 10 parts of chitins, 15 parts of dolomite dusts, 20 parts of pyrite dusts, kieselguhr 30-part, 50 parts, water and land plasters;
Above-mentioned each raw material is mixed, then put in mortar mixer, stir and obtain mixed slurry, then mixed slurry is injected to die casting and become sheet material, the demoulding after sheet material solidifies, finally sheet material being placed in to temperature is 60 ℃, in the hygrothermal environment that humidity is 60% 12 hours, obtains the gypsum plank that thickness is 10mm;
Described mask paper is prepared as follows and forms:
In pond with slurry, according to weight portion, prepare burden: 300 parts of 5 parts of cornstarch, 5 parts of sodium phosphate trimers, 20 parts of starch ethers, 30 parts, calcium sulfate, 70 parts of PLAs, 80 parts of glass fiber, 100 parts, water, charcoal powder 150 and precipitated calcium carbonates;
First each batching in pond with slurry is stirred and obtains slurry, then enter head box, slurry is evenly distributed in fourdrinier part, enter subsequently vacuum system and carry out first step dehydration, take off more than 50% moisture, form half wet page; Half wet page enters squeezer and carries out second step dehydration, and controlled pressure 30MPa dewaters 30 minutes; Finally, enter dryer and carry out the 3rd step dehydration, controlling temperature is 120 ℃, and the time is 15 minutes, and obtaining thickness is the mask paper of 2mm;
Described binding material is prepared as follows and forms:
According to weight portion, get 1 part of 5 parts of ethylene-vinyl acetate resins (EVA), 3 parts of white glue with vinyl, 2 parts of French chalk, 1 part, agar and casein; Be uniformly mixed and get final product;
The consumption of binding material is that every square metre of bond area is used 100g.
Embodiment 2
The gypsum plank of a kind of wall thermal insulating fire-resistant composite panel ,Qi You lower floor and the mask paper on upper strata form; Between described gypsum plank and described mask paper, by binding material, be bonded;
Described gypsum plank is prepared as follows and forms:
According to weight portion, take following raw material: 120 parts of 1 part of line borate, 1 part of sodium succinate, 2 parts, phenolic resins, 6 parts of hydroxyethylcelluloses, 6 parts of starch ethers, 8 parts of glass fiber, 8 parts of polyvinyl alcohol, 10 parts of boraxs, 12 parts of quartz sands, 12 parts of chitins, 20 parts of dolomite dusts, 30 parts of pyrite dusts, 40 parts, kieselguhr, 60 parts, water and land plasters;
Above-mentioned each raw material is mixed, then put in mortar mixer, stir and obtain mixed slurry, then mixed slurry is injected to die casting and become sheet material, the demoulding after sheet material solidifies, finally sheet material being placed in to temperature is 60 ℃, in the hygrothermal environment that humidity is 60% 12 hours, obtains the gypsum plank that thickness is 10mm;
Described mask paper is prepared as follows and forms:
In pond with slurry, according to weight portion, prepare burden: 300 parts of 5 parts of sodium phosphate trimers, 20 parts of starch ethers, 30 parts, calcium sulfate, 70 parts of PLAs, 80 parts of glass fiber, 100 parts, water, charcoal powder 150 and precipitated calcium carbonates;
First each batching in pond with slurry is stirred and obtains slurry, then enter head box, slurry is evenly distributed in fourdrinier part, enter subsequently vacuum system and carry out first step dehydration, take off more than 50% moisture, form half wet page; Half wet page enters squeezer and carries out second step dehydration, and controlled pressure 30MPa dewaters 30 minutes; Finally, enter dryer and carry out the 3rd step dehydration, controlling temperature is 120 ℃, and the time is 15 minutes, and obtaining thickness is the mask paper of 2mm;
Described binding material is prepared as follows and forms:
According to weight portion, get 1 part of 5 parts of ethylene-vinyl acetate resins (EVA), 3 parts of white glue with vinyl, 2 parts of French chalk, 1 part, agar and casein; Be uniformly mixed and get final product;
The consumption of binding material is that every square metre of bond area is used 100g.
Embodiment 3
Wall thermal insulating fire-resistant composite panel various aspects of performance parameter experiment prepared by the present invention detects:
Contrast test 1: the composite plate of preparing according to patented method (CN200710139236); The composite plate of embodiment 1 preparation, the composite plate (comparing without cornstarch with embodiment 1) of embodiment 2 preparations, the results are shown in Table 1.
Table 1
Group |
Maximum operation (service) temperature ℃ |
Compressive strength kpa |
Coefficient of thermal conductivity W/ (m.K) |
Anti-folding modulus of elasticity mpa |
Contrast test 1 |
600 |
178 |
0.068 |
3547 |
The embodiment of the present invention 1 |
980 |
323 |
0.016 |
7219 |
The embodiment of the present invention 2 |
990 |
315 |
0.023 |
7135 |
The composite plate fire resistance of the embodiment of the present invention 1 preparation is A1 level after tested, and meeting fiery stability time is 80 minutes above (with reference to GB/T9775-2008 standard).The composite plate of the embodiment of the present invention 1 preparation possesses good fire resistance and lower coefficient of thermal conductivity, and its heat-insulating property is better, and possesses preferably compressive strength and anti-folding modulus of elasticity, is better than market like product completely, possesses good market prospects.
Finally, it is also to be noted that, what more than enumerate is only several specific embodiments of the present invention.Obviously, the invention is not restricted to above embodiment, can also have many distortion.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention, all should think protection scope of the present invention.