CN103556269B - A kind of bamboo-carbon viscose fibre with metal-like and preparation method thereof - Google Patents
A kind of bamboo-carbon viscose fibre with metal-like and preparation method thereof Download PDFInfo
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Abstract
The present invention, in order to adapt to the demand of produce market client, solves the problem of bamboo-carbon viscose fibre spinnability difference, provides a kind of bamboo-carbon viscose fibre with metal-like and preparation method thereof.It is characterized in that: by spinning front injection, metal bamboo charcoal solution is mixed with viscose glue, finished product is obtained through wet spinning, post processing, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, zinc, aluminium content 0.01 ~ 3% in fiber, bamboo charcoal content 0.1 ~ 10%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 4 ~ 5 grades.Bamboo-carbon viscose fibre of the present invention not only has antibacterial, uvioresistant, deodorization functions, good gas permeability, absorbability, and has unique blue and white metallic luster, and the ultimate strength of fiber is high, and cost is low.
Description
Technical field
The present invention relates to textile industry viscose glue technical field, be specifically related to a kind of bamboo-carbon viscose fibre with metal-like.
Background technology
Bamboo charcoal is primarily of element compositions such as charcoal, hydrogen, oxygen, and quality is hard, fine and closely woven porous, high adsorption capacity, its adsorption capacity is more than 10 times of same volume charcoal, and contained mineral matter is more than 5 times of same volume charcoal, therefore has the function of good deodorizing, anticorrosion, adsorb peculiar smell.Nano bamboo micro mist also has effect of good antibacterial, sterilization, can adsorb and in and acidic materials contained by sweat, reach effect of skin whitening.Moreover, the emissive material of bamboo charcoal or good far infrared and anion.The blended health fiber of bamboo charcoal can transmitting anion and add and do not damage equipment again man-hour, the shortcoming that when overcoming negative-ion fiber processing fabric, card grinding is serious, the dark welcome by processing client and favor.Except above advantage, due to own characteristic, bamboo charcoal blended fiber also has antistatic behaviour and electromagnetic radiation resisting function, and succeeding in developing of it brings more benefit to human health.Can say that bamboo charcoal blended fiber meets the various selection of people to health product, also meet the requirement of fabric manufacturer, be have the various functions fiber type advantages such as magnetic health care fiber, far IR fibre, anti-bacterial fibre simultaneously
Upgrading new product, wide market.
Fiber has the metallic luster of glittering noble quality, unique style, and be smooth to the touch softness, can meet the demand of market user.As 200710027672.1, the patent of invention that name is called " Nano Silver bamboo charcoal dispersion liquid and prepare the method for nano-silver bamboo charcoal fiber ", disclose a kind of Nano Silver bamboo charcoal dispersion liquid and prepare the method for nano-silver bamboo charcoal fiber, cellulose viscose pulp is adopted jointly to be sent to Nano Silver bamboo charcoal dispersion liquid the method that spinning machine carries out spinning after maturation and two roads are filtered, particle diameter 20 ~ the 60nm of Nano Silver, the particle diameter of bamboo charcoal is not more than 0.5 μm.Nano-silver bamboo charcoal fiber has metallic luster, but Nano Silver is expensive, and production cost is too high.
Summary of the invention
The present invention is directed to above-mentioned technical problem, simultaneously in order to adapt to the demand of produce market client, solving the problem of bamboo-carbon viscose fibre spinnability difference, providing a kind of bamboo-carbon viscose fibre with metal-like and preparation method thereof.Bamboo-carbon viscose fibre of the present invention not only has antibacterial, uvioresistant, deodorization functions, good gas permeability, absorbability, and has unique blue and white metallic luster, can purely spin or with other fiber blend jeans, the ultimate strength of fiber is high, and cost is low.
For achieving the above object, the present invention adopts following technical scheme:
A kind of bamboo-carbon viscose fibre with metal-like, it is characterized in that: by spinning front injection, metal bamboo charcoal solution is mixed with viscose glue, finished product is obtained through wet spinning, post processing, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, and zinc, aluminium content 0.01 ~ 3% in fiber, bamboo charcoal content 0.1 ~ 10%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 4 ~ 5 grades.
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal long filament, dry strong 2.0 ~ 2.7cN/dtex, dryly stretches 16 ~ 22%, dryly stretches variation≤8%.
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, dry strong 2.8 ~ 3.5cN/dtex, dryly stretches 16 ~ 20%, dry strong variation≤18%, fault≤4mg/100g.
In bamboo charcoal, the carbon crystallite of similar graphite is by " the capable structure of gyration " arrangement, has strongly been cross-linked to form flourishing microcellular structure between its crystallite.The size of hole is not quite similar, and imperfect structures appears in pore surface, in addition ash content and other heteroatomic existence, and make it produce defect and unsaturated valency, thus its surface has suction-operated.The present invention utilizes the suction-operated of bamboo charcoal, metal can be adsorbed well.
By weight, zinc, aluminium account for 10 ~ 30% of agglomerate material to described metal master batch.The defencive function of carrier under this ratio to metallic is best, and metal ion can be adsorbed better by bamboo charcoal.
The particle diameter of described zinc, aluminium is 30 ~ 80nm, can fully by bamboo Charcoal Adsorption, and not easily wash-out, can be uniformly dispersed in after mixing in viscose glue, contributes to the spinnability improving strand.
The preparation method of the bamboo-carbon viscose fibre of metal-like of the present invention, be directly sent to the spinning of spinning board after fully being mixed by static mixer with viscose glue by metal bamboo charcoal solution, post processing obtains finished product; The flow velocity that described metal bamboo charcoal solution enters static mixer is greater than the flow velocity that viscose glue enters static mixer.
After viscose glue enters the pipeline of static mixer, can solidify and cause line clogging, the flow velocity of metal bamboo charcoal solution is greater than viscose glue, is introduced into pipeline, avoids entering of viscose glue, can not cause plugging.
The preparation method of described metal bamboo charcoal solution: first bamboo charcoal powder is added alkali, thickener, dispersant, be dispersed in water, through stirring, grinding evenly, obtains bamboo charcoal solution; Mix with metal master batch again, after stirring, leave standstill 30 ~ 120min, the absorption of bamboo charcoal to zinc, aluminium is reached capacity.
Described dispersant is still dispersant polyacrylic acid sodium salt, and by weight, addition is 1 ~ 2%.Contribute to bamboo charcoal powder to be uniformly dispersed in water, and not free settling; Meanwhile, solution liquid bubble-free, does not affect the spinnability of fiber.
Described thickener is cellulose thickener, and by weight, addition is 1 ~ 5%.Object is the viscosity increasing bamboo charcoal solution, consistent with the viscosity of viscose glue and alkalinity, makes it to have compatibility with viscose glue, does not destroy, affects the stability of viscose glue, ensure that the spinnability of bamboo-carbon fibre.
Metal bamboo charcoal solution of the present invention, Li Jing≤0.8 μm of bamboo charcoal is 4 ~ 6% containing alkali mass fraction, and viscosity is 30 ~ 70s(falling ball viscosity).
Viscosity 30 ~ 70s(falling ball viscosity of viscose glue of the present invention), degree of ripeness 7 ~ 12mL, containing alkali 4 ~ 6%, the fine content 8 ~ 10% of first.
The consisting of of coagulating bath in described spinning process: sulfuric acid 100 ~ 120g/L, sodium sulphate 240 ~ 320g/L, zinc sulfate 1 ~ 8g/L, aluminum sulfate 1 ~ 10g/L; The temperature of coagulating bath is 40 ~ 50 DEG C.
The object adding aluminum sulfate in coagulating bath is: improve fibre strength, degree of stretching, and reduce zinc sulfate consumption, zinc ion is heavy metal, to water body, soil pollution seriously, and wastewater treatment difficulty.Adding of aluminum sulfate, realize low zinc or without zinc environmental protection spining technology, adopt the acid bath technique of the high salt of low acid simultaneously, avoid the problem of viscose glue easy fracture of wire because of impure.
The spinning mixture temperature of described spinning process is 10 ~ 20 DEG C.Because the viscosity of bamboo charcoal is lower, cause the overall viscosity of spinning solution to decline, therefore the setting outline of spinning temperature is lower than common process temperature.Reducing temperature can prevent spinning solution surface viscosity from declining, and improves the rheological property of spinning solution, improves the uniformity of bamboo-carbon powder distribution.
Be added with bamboo charcoal in fiber of the present invention, therefore spinnability and product strength and elongation can reduce, and simultaneously due to the reduction of uniformity, must reduce spinning speed, prevent broken end, improve spinnability.Different according to viscose filament yarn and short fiber technique, take following spinning technique respectively, ensure spinning good spinning property, fiber strength and elongation is high simultaneously.
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal long filament, and technological process is: stoste preparation-spinning-washing-drying-one-tenth cylinder-finished product.
The speed of spinning of described spinning process is 70 ~ 90m/min, jet stretch 0 ~-8%, nervous drawing-off 6 ~ 8%; Bake out temperature 70 ~ 100 DEG C.
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, and technological process is: stoste preparation-spinning-plasticizing drawing-off-cut-out-washing-drying-finished product.
The speed of spinning of described spinning process is 40 ~ 55m/min, total draft 120 ~ 160%; Bake out temperature 100 ~ 140 DEG C.
Beneficial effect of the present invention is:
1, the bamboo-carbon viscose fibre with metal-like of the present invention, zinc, aluminium content 0.01 ~ 3% in fiber, bamboo charcoal content 0.1 ~ 10%, water-fastness COLOR FASTNESS 4 ~ 5 grades.Metal-like bamboo-carbon fibre bacteriostasis rate of the present invention can reach 96.4%, has significant antibiotic effect, far infrared transmissivity 88.9%, has significant far-infrared health care function; Rate of ultraviolet shield 99.0%, has significant rate of ultraviolet shield; Ammonia adsorption rate >=50%, has significant deodorization functions.And there is good gas permeability, absorbability, and there is unique blue and white metallic luster, can purely spin or with other fiber blend jeans, the intensity of fiber is higher, and cost is far below Nano Silver bamboo-carbon viscose fibre.
2, the present invention adopts metallic zinc, aluminium and bamboo charcoal solution mixing system for metal bamboo charcoal solution, and in master batch, zinc, aluminium account for 10 ~ 30% of agglomerate material.The defencive function of carrier under this ratio to zinc, aluminium is best, and zinc, aluminium can be adsorbed better by bamboo charcoal.Fully mix with viscose glue, and the loss of zinc, aluminium is little, cost-saving, is applicable to large-scale production.
3, the thickener and alkali that do not have in prior art is added in the preparation raw material of bamboo charcoal solution that the bamboo-carbon viscose fibre of metal-like of the present invention adopts, object is the viscosity and the alkalinity that increase bamboo charcoal solution, make it consistent with the viscosity of viscose glue and alkalinity, with viscose glue, there is compatibility, do not destroy, affect the stability of viscose glue, ensure that the spinnability of bamboo-carbon fibre.
4, the preparation raw material of bamboo charcoal solution of the present invention selects still dispersant polyacrylic acid sodium salt, contributes to bamboo charcoal powder and is uniformly dispersed in water, and not free settling; Meanwhile, solution liquid bubble-free, does not affect the spinnability of fiber, is the further guarantee of bamboo-carbon fibre spinnability.
5, Li Jing≤0.8 μm of the bamboo charcoal of metal bamboo charcoal solution of the present invention, is 4 ~ 6% containing alkali mass fraction, and viscosity is 30 ~ 70s.Such setting is in order to consistent with the viscosity and alkalinity of viscose glue, makes it to have compatibility with viscose glue, does not destroy, affects the stability of viscose glue; Li Jing≤0.8 μm of bamboo charcoal, the adsorption function of bamboo charcoal obviously strengthens.Bamboo charcoal pulp adopts above index effectively to ensure that the spinnability of spinning.
6, production technology of the present invention, the spinning of spinning board is directly sent to after metal bamboo charcoal solution is fully mixed by static mixer with viscose glue, without the need to increasing bamboo charcoal storage tank and filter plant again after mixing, reduce the intermediate hold time, mixed liquor is avoided to change, and greatly reduce in daily production process and tear filter open, the waste of viscose glue, bamboo charcoal solution when rushing jar and pipeline, reduce the pollution of expense that environmental wastewater administers and environment simultaneously.Meanwhile, after viscose glue enters the pipeline of static mixer, can solidify and cause line clogging, the flow velocity of metal bamboo charcoal solution is greater than viscose glue, is introduced into pipeline, avoids entering of viscose glue, can not cause plugging, guarantees that spinning process carries out smoothly.
7, in spinning process of the present invention coagulating bath consist of the high salt of low acid, temperature controls at 40 ~ 50 DEG C, and containing aluminum sulfate in the composition of coagulating bath, is to improve fibre strength, degree of stretching, and reduces zinc sulfate consumption, realizes low zinc or without zinc environmental protection spining technology; Adopt the acid bath technique of the high salt of low acid simultaneously, avoid the problem of viscose glue easy fracture of wire because of impure, further ensure the spinnability of strand.
8, the spinning mixture temperature of spinning process of the present invention controls at 10 ~ 20 DEG C, because the viscosity of bamboo charcoal is lower, cause the overall viscosity of spinning solution to decline, therefore the setting outline of spinning solution temperature is lower than common process temperature.Reducing temperature can prevent spinning solution surface viscosity from declining, and improves the rheological property of spinning solution, improves the uniformity of bamboo-carbon powder distribution.
9, different according to viscose filament yarn and short fiber technique of the present invention, strictly control the technological parameter of spinning respectively.Owing to being added with bamboo charcoal in fiber, therefore spinnability and product strength and elongation can reduce, and simultaneously due to the reduction of uniformity, must reduce spinning speed, prevent broken end, improve spinnability.
Detailed description of the invention
Below in conjunction with detailed description of the invention, essentiality content of the present invention is described in further detail.
Embodiment 1
A kind of bamboo-carbon viscose fibre with metal-like, by spinning front injection, metal bamboo charcoal solution is mixed with viscose glue, finished product is obtained through wet spinning, post processing, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, and zinc, aluminium content 0.01% in fiber, bamboo charcoal content 0.1%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 4 grades.
Embodiment 2
One has metal-like bamboo charcoal long filament, being mixed by metal bamboo charcoal solution, obtaining finished product through wet spinning, post processing by spinning front injection with viscose glue, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, zinc, aluminium content 3% in fiber, bamboo charcoal content 10%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 5 grades, dry strong 2.7cN/dtex, dryly stretch 22%, dryly stretch variation≤8%.
Embodiment 3
One has metal-like bamboo charcoal long filament, being mixed by metal bamboo charcoal solution, obtaining finished product through wet spinning, post processing by spinning front injection with viscose glue, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, zinc, aluminium content 0.08% in fiber, bamboo charcoal content 0.2%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 4 grades, dry strong 2.0cN/dtex, dryly stretch 16%, dryly stretch variation≤8%.
By weight, zinc, aluminium account for 10% of agglomerate material to described metal master batch.
Embodiment 4
One has metal-like bamboo charcoal long filament, being mixed by metal bamboo charcoal solution, obtaining finished product through wet spinning, post processing by spinning front injection with viscose glue, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, zinc, aluminium content 0.5% in fiber, bamboo charcoal content 1%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 4 grades, dry strong 2.2cN/dtex, dryly stretch 20%, dryly stretch variation≤8%.
Described metal master batch adopts polypropylene as base material.
By weight, zinc, aluminium account for 30% of agglomerate material to described metal master batch.
The particle diameter of described metallic zinc, aluminium is 30nm.
Embodiment 5
One has metal-like bamboo charcoal short fiber, being mixed by metal bamboo charcoal solution, obtaining finished product through wet spinning, post processing by spinning front injection with viscose glue, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, and zinc, aluminium content 2% in fiber, bamboo charcoal content 5%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 4 grades, dry strong 2.8cN/dtex, dryly stretch 16%, dry strong variation≤18%, fault≤4mg/100g.
Described metal master batch adopts polypropylene as base material.
By weight, zinc, aluminium account for 15% of agglomerate material to described metal master batch.
The particle diameter of described metallic zinc, aluminium is 80nm.
Embodiment 6
One has metal-like bamboo charcoal short fiber, being mixed by metal bamboo charcoal solution, obtaining finished product through wet spinning, post processing by spinning front injection with viscose glue, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, and zinc, aluminium content 2.5% in fiber, bamboo charcoal content 6%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 5 grades, dry strong 3.5cN/dtex, dryly stretch 20%, dry strong variation≤18%, fault≤4mg/100g.
By weight, zinc, aluminium account for 20% of agglomerate material to described metal master batch.
The particle diameter of described metallic zinc, aluminium is 50nm.
Embodiment 7
One has metal-like bamboo charcoal short fiber, being mixed by metal bamboo charcoal solution, obtaining finished product through wet spinning, post processing by spinning front injection with viscose glue, described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, and zinc, aluminium content 0.6% in fiber, bamboo charcoal content 3.6%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 5 grades, dry strong 3.2cN/dtex, dryly stretch 17%, dry strong variation≤18%, fault≤4mg/100g.
By weight, zinc, aluminium account for 25% of agglomerate material to described metal master batch.
The particle diameter of described metallic zinc, aluminium is 65nm.
Embodiment 8
The preparation method of the bamboo-carbon viscose fibre of metal-like of the present invention, be directly sent to the spinning of spinning board after fully being mixed by static mixer with viscose glue by metal bamboo charcoal solution, post processing obtains finished product; The flow velocity that described metal bamboo charcoal solution enters static mixer is greater than the flow velocity that viscose glue enters static mixer.
Embodiment 9
The embodiment of the present embodiment is substantially the same manner as Example 8, on this basis:
The preparation method of described metal bamboo charcoal solution: first bamboo charcoal powder is added alkali, thickener, dispersant, be dispersed in water, through stirring, grinding evenly, obtains bamboo charcoal solution; Mix with metal master batch again, after stirring, leave standstill 30min, the absorption of bamboo charcoal to metallic is reached capacity.
Embodiment 10
The embodiment of the present embodiment is substantially the same manner as Example 8, on this basis:
The preparation method of described metal bamboo charcoal solution: first bamboo charcoal powder is added alkali, thickener, dispersant, be dispersed in water, through stirring, grinding evenly, obtains bamboo charcoal solution; Mix with metal master batch again, after stirring, leave standstill 120min, the absorption of bamboo charcoal to metallic is reached capacity.
Described dispersant is still dispersant polyacrylic acid sodium salt, by weight, addition be 1.2%.
Embodiment 11
The embodiment of the present embodiment is substantially the same manner as Example 8, on this basis:
The preparation method of described metal bamboo charcoal solution: first bamboo charcoal powder is added alkali, thickener, dispersant, be dispersed in water, through stirring, grinding evenly, obtains bamboo charcoal solution; Mix with metal master batch again, after stirring, leave standstill 50min, the absorption of bamboo charcoal to metallic is reached capacity.
Described dispersant is still dispersant polyacrylic acid sodium salt, by weight, addition be 1%.
Described thickener is cellulose thickener, and by weight, addition is 1%.
In described bamboo charcoal pulp, the amount of bamboo charcoal powder is 50%.
Embodiment 12
The embodiment of the present embodiment is substantially the same manner as Example 8, on this basis:
The preparation method of described metal bamboo charcoal solution: first bamboo charcoal powder is added alkali, thickener, dispersant, be dispersed in water, through stirring, grinding evenly, obtains bamboo charcoal solution; Mix with metal master batch again, after stirring, leave standstill 60min, the absorption of bamboo charcoal to metallic is reached capacity.
Described dispersant is still dispersant polyacrylic acid sodium salt, by weight, addition be 2%.
Described thickener is cellulose thickener, and by weight, addition is 5%.
In described bamboo charcoal pulp, the amount of bamboo charcoal powder is 10%.
Embodiment 13
The embodiment of the present embodiment is substantially the same manner as Example 8, on this basis:
The preparation method of described metal bamboo charcoal solution: first bamboo charcoal powder is added alkali, thickener, dispersant, be dispersed in water, through stirring, grinding evenly, obtains bamboo charcoal solution; Mix with metal master batch again, after stirring, leave standstill 90min, the absorption of bamboo charcoal to metallic is reached capacity.
Described dispersant is still dispersant polyacrylic acid sodium salt, by weight, addition be 1.6%.
Described thickener is cellulose thickener, and by weight, addition is 1.5%.
In described bamboo charcoal pulp, the amount of bamboo charcoal powder is 30%.
Embodiment 14
The present embodiment is substantially identical with the embodiment of embodiment 8, on this basis:
Described metal bamboo charcoal solution, the particle diameter of bamboo charcoal is 0.8 μm, is 5% containing alkali mass fraction, and viscosity is 35s.
Embodiment 15
The present embodiment is substantially identical with the embodiment of embodiment 8, on this basis:
Described metal bamboo charcoal solution, the particle diameter of bamboo charcoal is 0.2 μm, is 4% containing alkali mass fraction, and viscosity is 30s.
Viscosity 30s, the degree of ripeness 7mL of described viscose glue, containing alkali 4%, the fine content 8% of first.
Embodiment 16
The present embodiment is substantially identical with the embodiment of embodiment 13, on this basis:
Described metal bamboo charcoal solution, the particle diameter of bamboo charcoal is 0.3 μm, is 6% containing alkali mass fraction, and viscosity is 70s.
Viscosity 70s, the degree of ripeness 12mL of described viscose glue, containing alkali 6%, the fine content 10% of first.
Embodiment 17
The present embodiment is substantially identical with the embodiment of embodiment 13, on this basis:
Described metal bamboo charcoal solution, the particle diameter of bamboo charcoal is 0.5 μm, is 5.5% containing alkali mass fraction, and viscosity is 55s.
Viscosity 55s, the degree of ripeness 8mL of described viscose glue, containing alkali 5.5%, the fine content 9% of first.
Embodiment 18
The present embodiment is substantially identical with the embodiment of embodiment 8, on this basis:
The consisting of of coagulating bath in described spinning process: sulfuric acid 100g/L, sodium sulphate 240g/L, zinc sulfate 1g/L, aluminum sulfate 1g/L; The temperature of coagulating bath is 40 DEG C.
Embodiment 19
The present embodiment is substantially identical with the embodiment of embodiment 13, on this basis:
The consisting of of coagulating bath in described spinning process: sulfuric acid 120g/L, sodium sulphate 320g/L, zinc sulfate 8g/L, aluminum sulfate 10g/L; The temperature of coagulating bath is 50 DEG C.
The spinning mixture temperature of described spinning process is 10 DEG C.
Embodiment 20
The present embodiment is substantially identical with the embodiment of embodiment 17, on this basis:
The consisting of of coagulating bath in described spinning process: sulfuric acid 110g/L, sodium sulphate 260g/L, zinc sulfate 2g/L, aluminum sulfate 5g/L; The temperature of coagulating bath is 45 DEG C.
The spinning mixture temperature of described spinning process is 15 DEG C.
Embodiment 21
The present embodiment is substantially identical with the embodiment of embodiment 17, on this basis:
The consisting of of coagulating bath in described spinning process: sulfuric acid 105g/L, sodium sulphate 300g/L, zinc sulfate 3g/L, aluminum sulfate 6g/L; The temperature of coagulating bath is 46 DEG C.
The spinning mixture temperature of described spinning process is 20 DEG C.
Embodiment 22
The present embodiment is substantially identical with the embodiment of embodiment 8, on this basis:
Described metal-like bamboo charcoal solution viscose is metal-like bamboo charcoal long filament, and technological process is: stoste preparation-spinning-washing-drying-one-tenth cylinder-finished product.
Embodiment 23
The present embodiment is substantially identical with the embodiment of embodiment 8, on this basis:
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal long filament, and technological process is: stoste preparation-spinning-washing-drying-one-tenth cylinder-finished product.
The speed of spinning of described spinning process is 70m/min, jet stretch 0%, nervous drawing-off 8%; Bake out temperature 80 DEG C.
Embodiment 24
The present embodiment is substantially identical with the embodiment of embodiment 13, on this basis:
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal long filament, and technological process is: stoste preparation-spinning-washing-drying-one-tenth cylinder-finished product.
The speed of spinning of described spinning process is 90m/min, jet stretch-8%, nervous drawing-off 6%; Bake out temperature 70 DEG C.
Embodiment 25
The present embodiment is substantially identical with the embodiment of embodiment 21, on this basis:
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal long filament, and technological process is: stoste preparation-spinning-washing-drying-one-tenth cylinder-finished product.
The speed of spinning of described spinning process is 80m/min, jet stretch-5%, nervous drawing-off 7%; Bake out temperature 100 DEG C.
Embodiment 26
The present embodiment is substantially identical with the embodiment of embodiment 8, on this basis:
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, and technological process is: stoste preparation-spinning-plasticizing drawing-off-cut-out-washing-drying-finished product.
Embodiment 27
The present embodiment is substantially identical with the embodiment of embodiment 8, on this basis:
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, and technological process is: stoste preparation-spinning-plasticizing drawing-off-cut-out-washing-drying-finished product.
The speed of spinning of described spinning process is 55m/min, total draft 150%; Bake out temperature 120 DEG C.
Embodiment 28
The present embodiment is substantially identical with the embodiment of embodiment 17, on this basis:
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, and technological process is: stoste preparation-spinning-plasticizing drawing-off-cut-out-washing-drying-finished product.
The speed of spinning of described spinning process is 40m/min, total draft 120%; Bake out temperature 100 DEG C.
Embodiment 29
The present embodiment is substantially identical with the embodiment of embodiment 21, on this basis:
Described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, and technological process is: stoste preparation-spinning-plasticizing drawing-off-cut-out-washing-drying-finished product.
The speed of spinning of described spinning process is 48m/min, total draft 160%; Bake out temperature 140 DEG C.
Claims (11)
1. there is a preparation method for the bamboo-carbon viscose fibre of metal-like, it is characterized in that: be directly sent to the spinning of spinning board after fully being mixed by static mixer with viscose glue by metal bamboo charcoal solution, post processing obtains finished product; The flow velocity that described metal bamboo charcoal solution enters static mixer is greater than the flow velocity that viscose glue enters static mixer; Described metal bamboo charcoal solution mixes by containing zinc, the metal master batch of aluminium and bamboo charcoal solution, by weight, and zinc, aluminium content 0.01 ~ 3% in fiber, bamboo charcoal content 0.1 ~ 10%, ammonia absorptivity >=50%, gas permeability >=500mm/s, water-fastness COLOR FASTNESS 4 ~ 5 grades;
The preparation method of described metal bamboo charcoal solution: first bamboo charcoal powder is added alkali, thickener, dispersant, be dispersed in water, through stirring, grinding evenly, obtains bamboo charcoal solution; Mix with metal master batch again, after stirring, leave standstill 30 ~ 120min, the absorption of bamboo charcoal to metallic is reached capacity;
Described dispersant is still dispersant polyacrylic acid sodium salt, by weight, addition be 1 ~ 2%;
Described thickener is cellulose thickener, and by weight, addition is 1 ~ 5%;
Described metal bamboo charcoal solution, Li Jing≤0.8 μm of bamboo charcoal is 4 ~ 6% containing alkali mass fraction, and viscosity is 30 ~ 70s;
Viscosity 30 ~ 70s, the degree of ripeness 7 ~ 12mL of described viscose glue, be 4 ~ 6% containing alkali mass fraction, the fine content 8 ~ 10% of first.
2. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 1, it is characterized in that: described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal long filament, dry strong 2.0 ~ 2.7cN/dtex, dryly stretches 16 ~ 22%, dryly stretches variation≤8%.
3. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 1, it is characterized in that: described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, dry strong 2.8 ~ 3.5cN/dtex, dryly stretch 16 ~ 20%, dry strong variation≤18%, fault≤4mg/100g.
4. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 1, is characterized in that: by weight, zinc, aluminium account for 10 ~ 30% of agglomerate material to described metal master batch.
5. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 4, is characterized in that: the particle diameter of described metallic zinc, aluminium is 30 ~ 80nm.
6. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 1, is characterized in that: consisting of of coagulating bath: sulfuric acid 100 ~ 120g/L, sodium sulphate 240 ~ 320g/L, zinc sulfate 1 ~ 8g/L, aluminum sulfate 1 ~ 10g/L; The temperature of coagulating bath is 40 ~ 50 DEG C.
7. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 1, is characterized in that: spinning mixture temperature is 10 ~ 20 DEG C.
8. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 1, it is characterized in that: described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal long filament, and technological process is: stoste preparation-spinning-washing-drying-one-tenth cylinder-finished product.
9. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 8, is characterized in that: spinning speed is 70 ~ 90m/min, jet stretch 0 ~-8%, nervous drawing-off 6 ~ 8%; Bake out temperature 70 ~ 100 DEG C.
10. a kind of preparation method with the bamboo-carbon viscose fibre of metal-like according to claim 1, it is characterized in that: described metal-like bamboo-carbon viscose fibre is metal-like bamboo charcoal short fiber, and technological process is: stoste preparation-spinning-plasticizing drawing-off-cut-out-washing-drying-finished product.
11. a kind of preparation methods with the bamboo-carbon viscose fibre of metal-like according to claim 10, is characterized in that: spinning speed is 40 ~ 55m/min, total draft 120 ~ 160%; Bake out temperature 100 ~ 140 DEG C.
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