CN103554824B - Environment friendly flame-proof ABS material for electric energy meter of electric power system housing - Google Patents
Environment friendly flame-proof ABS material for electric energy meter of electric power system housing Download PDFInfo
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- CN103554824B CN103554824B CN201310527441.2A CN201310527441A CN103554824B CN 103554824 B CN103554824 B CN 103554824B CN 201310527441 A CN201310527441 A CN 201310527441A CN 103554824 B CN103554824 B CN 103554824B
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- abs
- power system
- energy meter
- environment friendly
- system housing
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- 239000000463 material Substances 0.000 title claims abstract description 29
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 12
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 12
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims abstract description 11
- 241000722946 Acanthocybium solandri Species 0.000 claims abstract description 11
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 11
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 11
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims abstract description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 13
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 238000004078 waterproofing Methods 0.000 abstract description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract description 2
- 230000002596 correlated effect Effects 0.000 abstract description 2
- 239000002932 luster Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 6
- 239000013064 chemical raw material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- -1 but in prior art Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of environment friendly flame-proof ABS material for electric energy meter of electric power system housing, formulated by ratio of weight and the number of copies by ABS, magnesium hydroxide, barium sulfate, nano titanium oxide, neopentyl glycol, PETO, trioctyl phosphate and potassium permanganate, each component is transferred under most scientific, the most rational state by the present invention, add a small amount of nanometer materials, improve correlated performance and the portion of techniques indexs such as the anti-flammability of material, water proofing property, thermostability, the feature of environmental protection and intensity, and cost is low, toughness is strong, improves mechanical property and luster performance；The nanotechnology formula with material and technique are effectively combined, improve product quality.
Description
Technical field
The present invention relates to a kind of environment-friendlyflame-retardant flame-retardant material, particularly relate to a kind of environment friendly flame-proof ABS material for electric energy meter of electric power system housing.
Background technology
It nanometer it is the least unit of length metering, the length of 1 nanometer is 1/1000000th of 1 millimeter, nanotechnology is in the length range of 1nm-100nm, direct composition various elements and the atom of material, atomic group, molecule, micel assemble there is the material of specific function or there is the high-quality precision and sophisticated technology of special performance products.Successful nanotechnology can be applicable to the every field such as electronics, chemical industry, military affairs, and countries in the world are all in research and development.Nanotechnology (nano raw material) is applied in ABS material, mainly by the double; two thin mechanism of Folium Nelumbinis, improves the resistance to water of ABS material.As ABS material, it is made up of multiple chemical raw material, prepares through science, unique physical and chemical reaction, if formula and technique are unreasonable, even if adding some nanoscale raw materials, there will not be too big raising in quality.
ABS material is shell mainly for the manufacture of instrument and meter, household electrical appliance, telephone set, television set etc. in China.Electric energy meter shell body commonly used in power system is also adopted by ABS material, but in prior art, ABS material is in order to have fire-retardant multi-effect of Denging, need to add multiple chemical raw material, and human body and environment are caused pollution.Namely, in prior art, ABS material anti-flammability, water proofing property and the key property such as environmental protection, intensity are difficult to take into account.
Summary of the invention
The present invention is directed to above-mentioned problems of the prior art, it is provided that a kind of environment friendly flame-proof ABS material for electric energy meter of electric power system housing, solve the problem that ABS material anti-flammability in prior art, water proofing property and the key property such as environmental protection, intensity are difficult to take into account.
Technical scheme is as follows:
It is formulated by following raw materials in parts by weight number ratio, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=100-180:40-80:40-80:10-26:10-25:10-20:10-20:10-20.
The preferred weight ratio of raw material of the present invention is, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=135:52:47:16:13:13:12:15.
Described ABS is acrylonitrile, butadiene and styrene copolymer, and the ratio of weight and number of three kinds of monomers is, acrylonitrile: butadiene: styrene=25-35:25-30:40-50.
Advantages of the present invention and having the beneficial effect that:
Each component is transferred under most scientific, the most rational state by the present invention, add a small amount of nanometer materials, improve correlated performance and the portion of techniques indexs such as the anti-flammability of material, water proofing property, thermostability, the feature of environmental protection and intensity, and cost is low, toughness is strong, improves mechanical property and luster performance；The nanotechnology formula with material and technique are effectively combined, improve product quality.
The advantage of material of the present invention is also embodied in, fabulous resistance to water；Excellent weatherability；Excellent tenacity；Excellent wearability；High-low temperature resistant.Due to ABS and other preparation of raw material above-mentioned, the subparticle of material is made to penetrate in basic unit so as to define an entirety, thus greatly improving anti-flammability and the feature of environmental protection.Especially the use of nano titanium oxide and potassium permanganate, makes to serve between each raw material the effect of Synergistic, the pollutant being possible not only in adsorption production process to produce, free from environmental pollution and health；And clearly enhance the performance of each material, achieve unexpected technique effect.
Detailed description of the invention
Embodiment 1
The weight ratio of raw material of the present invention is, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=135:52:47:16:13:13:12:15.
Described ABS is acrylonitrile, butadiene and styrene copolymer, and the ratio of weight and number of three kinds of monomers is, acrylonitrile: butadiene: styrene=30:28:45.
The preparation method of the present invention is, by above-mentioned ABS ratio of weight and number, prepares ABS material by this area conventional method；ABS, magnesium hydroxide, barium sulfate, nano titanium oxide, neopentyl glycol, PETO, trioctyl phosphate and potassium permanganate is taken again by above-mentioned ratio of weight and number, put into high-speed mixer and mixing 30min, put into screw extruder pelletize again, obtain, the rotating speed of screw extruder is 300 turns/min, and temperature is 200oC。
Embodiment 2
It is formulated by following raw materials in parts by weight number ratio, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=100:40:40:10:10:10:10:10.
Described ABS is acrylonitrile, butadiene and styrene copolymer, and the ratio of weight and number of three kinds of monomers is, acrylonitrile: butadiene: styrene=25:25:40.
Preparation method is with embodiment 1.
Embodiment 3
It is formulated by following raw materials in parts by weight number ratio, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=180:80:80:26:25:20:20:20.
Described ABS is acrylonitrile, butadiene and styrene copolymer, and the ratio of weight and number of three kinds of monomers is, acrylonitrile: butadiene: styrene=35:30:50.
Preparation method is with embodiment 1.
Embodiment 4
It is formulated by following raw materials in parts by weight number ratio, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=100:80:80:10:10:20:16:13.
Preparation method is with embodiment 1.
Embodiment 5
It is formulated by following raw materials in parts by weight number ratio, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=180:40:80:26:25:10:20:10.
Preparation method is with embodiment 1.
The present invention presses all technical of V0 level fire proofing detection, for the ease of reference, is listed in the table below:
From above-mentioned testing result, indices of the present invention all meets national standard, is suitable to industrial mass popularization and application.
Claims (3)
1. for the environment friendly flame-proof ABS material of electric energy meter of electric power system housing, it is characterized in that by following raw materials in parts by weight number ratio formulated, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=100-180:40-80:40-80:10-26:10-25:10-20:10-20:10-20；Described ABS is acrylonitrile, butadiene and styrene copolymer, and the ratio of weight and number of three kinds of monomers is, acrylonitrile: butadiene: styrene=25-35:25-30:40-50.
2. the environment friendly flame-proof ABS material for electric energy meter of electric power system housing according to claim 1, it is characterized in that by following raw materials in parts by weight number ratio formulated, ABS: magnesium hydroxide: barium sulfate: nano titanium oxide: neopentyl glycol: PETO: trioctyl phosphate: potassium permanganate=135:52:47:16:13:13:12:15.
3. the environment friendly flame-proof ABS material for electric energy meter of electric power system housing according to claim 1, it is characterized in that described ABS is acrylonitrile, butadiene and styrene copolymer, the ratio of weight and number of three kinds of monomers is, acrylonitrile: butadiene: styrene=30:28:45.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310527441.2A CN103554824B (en) | 2013-10-31 | 2013-10-31 | Environment friendly flame-proof ABS material for electric energy meter of electric power system housing |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310527441.2A CN103554824B (en) | 2013-10-31 | 2013-10-31 | Environment friendly flame-proof ABS material for electric energy meter of electric power system housing |
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| Publication Number | Publication Date |
|---|---|
| CN103554824A CN103554824A (en) | 2014-02-05 |
| CN103554824B true CN103554824B (en) | 2016-07-27 |
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| CN201310527441.2A Active CN103554824B (en) | 2013-10-31 | 2013-10-31 | Environment friendly flame-proof ABS material for electric energy meter of electric power system housing |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104031351B (en) * | 2014-06-27 | 2016-05-25 | 无锡市崇安区科技创业服务中心 | A kind of high-toughness halogen-free flame material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168613A (en) * | 2006-10-25 | 2008-04-30 | 比亚迪股份有限公司 | Method for modifying ABS plastic |
| CN102516701A (en) * | 2011-12-12 | 2012-06-27 | 吴江明峰聚氨酯制品有限公司 | Nano TiO2 reinforced ABS material |
| EP2505607A1 (en) * | 2011-04-01 | 2012-10-03 | Lg Chem, Ltd. | Thermoplastic ABS resin compositions having excellent resistance to flame retardancy |
| CN103146133A (en) * | 2013-04-10 | 2013-06-12 | 苏州旭光聚合物有限公司 | Anti-photoaging nano TiO2/ABS (acrylonitrile-butadiene-styrene) composite material and preparation method thereof |
-
2013
- 2013-10-31 CN CN201310527441.2A patent/CN103554824B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168613A (en) * | 2006-10-25 | 2008-04-30 | 比亚迪股份有限公司 | Method for modifying ABS plastic |
| EP2505607A1 (en) * | 2011-04-01 | 2012-10-03 | Lg Chem, Ltd. | Thermoplastic ABS resin compositions having excellent resistance to flame retardancy |
| CN102516701A (en) * | 2011-12-12 | 2012-06-27 | 吴江明峰聚氨酯制品有限公司 | Nano TiO2 reinforced ABS material |
| CN103146133A (en) * | 2013-04-10 | 2013-06-12 | 苏州旭光聚合物有限公司 | Anti-photoaging nano TiO2/ABS (acrylonitrile-butadiene-styrene) composite material and preparation method thereof |
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| CN103554824A (en) | 2014-02-05 |
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Effective date of registration: 20220616 Address after: 138001 No. 2277, chagannaoer street, Ningjiang district, Songyuan City, Jilin Province Patentee after: SONGYUAN POWER SUPPLY COMPANY OF STATE GRID JILINSHENG ELECTRIC POWER SUPPLY Co. Patentee after: State Grid Co., Ltd. Address before: No. 214, Zhongshan Road, Shenhe District, Shenyang, Liaoning 110013 Patentee before: Zhu Yong |