CN103540283A - Urea-formaldehyde glue adhesive and preparation method thereof - Google Patents
Urea-formaldehyde glue adhesive and preparation method thereof Download PDFInfo
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- CN103540283A CN103540283A CN201310491519.XA CN201310491519A CN103540283A CN 103540283 A CN103540283 A CN 103540283A CN 201310491519 A CN201310491519 A CN 201310491519A CN 103540283 A CN103540283 A CN 103540283A
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Abstract
The invention relates to a urea-formaldehyde glue adhesive and a preparation method thereof. Compared with the existing the urea-formaldehyde glue adhesive, the urea-formaldehyde glue adhesive disclosed by the invention contains a modifier, a formaldehyde deodorant, an iron oxide and a thickening agent, wherein addition of appropriate parts by weight of modifier is capable of reducing water carried into a base material during gluing and lowering the permeation of the glue adhesive; addition of appropriate parts by weight of formaldehyde deodorant is capable of effectively reducing formaldehyde volatilization during the preparation process and avoiding environment pollution; appropriate parts by weight of iron oxide serves as a pigment and is capable of visually displaying the glue application volume during glue application; and addition of appropriate parts by weight of added thickening agent is capable of enhancing the initial adhesion of the glue adhesive on the premise of ensuring the gluing strength.
Description
Technical field
The present invention relates to a kind of tackiness agent and preparation method thereof, particularly a kind of urea-formaldehyde glue tackiness agent and preparation method thereof, belongs to glued board adhesive field.
Background technology
Timber possesses and has special advantage in current four large materials, and wet effect and heat-insulating sound-insulating effect are conciliate in the native texture of timber, color, moisture absorption, can bring many-sided comforts such as vision, the sense of hearing and sensation to people.In recent years, along with people are to the naturally requirement of " green " living environment, timber is more and more subject to liking of people.Yet, once the over-exploitation of natural resource and unreasonable consumption had been made to timber resource shortage, supply falls short of demand becomes worldwide problem.The saving and substitution timber that emerges as of the wood processing industry that fast growing wood, inferior material be raw material of take has been opened up wide prospect, for relaxing timber imbalance between supply and demand, has made outstanding contribution.
Glued board belongs to a kind of common sheet material in wood processing industry, it is formed by tackiness agent is bonding by multilayer single plate, conventional tackiness agent has urea-formaldehyde glue, melamino-formaldehyde glue and polyvinyl acetate latex at present, most widely used is urea-formaldehyde glue, it can adapt to plywood hot-pressing moulding, water-tolerant, low price.But urea-formaldehyde glue easily infiltration causes seep through, and tack is poor, and owing to having used formaldehyde harmful, not environmental protection.
Summary of the invention
In view of this, the object of this invention is to provide a kind of urea-formaldehyde glue tackiness agent and preparation method thereof, this urea formaldehyde glue dissolubility reduces, and osmosis reduction and waving of making processes formaldehyde are few, do not pollute the environment.
For achieving the above object, urea-formaldehyde glue tackiness agent of the present invention, comprises following component by weight: 300～400 parts, formaldehyde, 160～220 parts, urea, 30～60 parts of properties-correcting agent, 3～12 parts of tackifier, 10～20 parts of trimeric cyanamides, 8～15 parts of sodium cellulosates, 8～15 parts of formaldehyde deodovization agents, 8～15 parts of ferric oxide, 20～30 parts, solidifying agent, wherein said formaldehyde is that quality percentage composition is 37% industrial formol.
Urea-formaldehyde glue glue paste of the present invention, wherein preferred solidifying agent is hydrogen peroxide.
Urea-formaldehyde glue glue paste of the present invention, wherein preferred properties-correcting agent is one or more of paraformaldehyde, acetaldehyde, propionic aldehyde and butyraldehyde.
Urea-formaldehyde glue glue paste of the present invention, wherein preferred tackifier are one or more in polyvinyl alcohol, modified corn starch and Vinyl Acetate Copolymer fat liquor.
In addition, the invention still further relates to the method for the above-mentioned urea-formaldehyde glue tackiness agent of preparation, comprise the following steps:
(1) weigh by weight the formaldehyde that the quality percentage composition of 300～400 parts is 37%, the urea of 160～220 parts, the properties-correcting agent of 30～60 parts, the tackifier of 3～12 parts, the trimeric cyanamide of 10～20 parts, the sodium cellulosate of 8～15 parts, the formaldehyde deodovization agent of 8～15 parts, the ferric oxide of 8～15 parts, the solidifying agent of 20～30 parts;
(2) formaldehyde that formaldehyde deodovization agent step 1 being weighed and quality percentage composition are 37% adds in reactor, heating formaldehyde temperature to 35 ℃～40 ℃, with sodium hydroxide solution, regulate pH=7.5～9.0, then the sodium cellulosate that adds first urea and step 1 to weigh;
(3) while continuing to be heated to formaldehyde temperature in reactor and reach 75 ℃～80 ℃, stop heating, by the remaining temperature of reactor self, be warming up to 90 ℃～92 ℃, with sodium hydroxide solution, regulate pH=9.5～11, then add second batch urea; Be incubated 90～120 minutes;
(4) adjust pH to 4.5～5.0, react to viscosity 60～80cp;
(5) adjust pH to 6.5～7.0, add the 3rd batch of urea, temperature is controlled at 80 ℃～90 ℃, reacts to viscosity 140～160cp;
(6) adjust pH to 7.0～7.5, the properties-correcting agent, trimeric cyanamide and the tackifier that add the 4th batch of urea, step 1 to take, temperature maintains 75 ℃, is incubated 20～40 minutes, cooling;
(7) temperature is down to below 40 ℃, and the ferric oxide and the solidifying agent that then add step 1 to weigh, after stirring, regulate pH=7.5～8.0, put glue, obtain urea-formaldehyde glue;
Wherein, first to fourth batch of urea amount adding is respectively 50%～60%, and 5%～10%, 30%～40%, 1%～15%.
Method of the present invention, wherein preferably adjusting the selected acid of pH is one or more in sulfuric acid, hydrochloric acid and phosphoric acid.
Method of the present invention, wherein preferably adjusting the selected alkali of pH is sodium hydroxide.
Useful technique effect of the present invention is:
1. due to the present invention, add the properties-correcting agent of approrpiate wts part, while having reduced gluing, be brought into the moisture in base material, reduced the osmosis of tackiness agent.
2. add the formaldehyde deodovization agent of approrpiate wts part, in making processes, can effectively reduce the volatilization of formaldehyde, avoided contaminate environment.
3. add the ferric oxide of approrpiate wts part, as pigment, in Process of Applying Glue, can intuitively show resin added.
4. added the tackifier of approrpiate wts part, guaranteed, under the prerequisite of bonding strength, can to improve the tack of tackiness agent.
Embodiment
Below in conjunction with embodiment and experimental data, to the present invention is above-mentioned, be described in more detail with other technical characterictic and advantage.
Embodiment 1: the preparation of urea-formaldehyde glue glue paste 1
Composition of raw materials:
Concrete preparation process is as follows:
(1) weigh the formaldehyde that the quality percentage composition of 300g is 37%, the urea of 160g, the paraformaldehyde of 30g, the polyvinyl alcohol of 3g, the trimeric cyanamide of 10g, the sodium cellulosate of 8g, the formaldehyde deodovization agent of 8g, the ferric oxide of 8g, hydrogen peroxide 20g;
(2) formaldehyde that formaldehyde deodovization agent step 1 being weighed and quality percentage composition are 37% adds in reactor, and heating formaldehyde temperature to 35 ℃～40 ℃, regulates pH=7.5 with sodium hydroxide solution, then the sodium cellulosate that adds 80g urea and step 1 to weigh;
(3) while continuing to be heated to formaldehyde temperature in reactor and reach 75 ℃～80 ℃, stop heating, by the remaining temperature of reactor self, be warming up to 90 ℃～92 ℃, with sodium hydroxide solution, regulate pH=9.5, then add 10g urea; Be incubated 90～120 minutes;
(4) adjust pH to 4.5～5.0, react to viscosity 60cp;
(5) adjust pH to 6.5～7.0, add 52g urea, temperature is controlled at 80 ℃～90 ℃, reacts to viscosity 140cp;
(6) adjust pH to 7.0～7.5, the paraformaldehyde, trimeric cyanamide and the polyvinyl alcohol that add 18g urea, step 1 to take, temperature maintains 75 ℃, is incubated 20～40 minutes, cooling;
(7) temperature is down to below 40 ℃, and the ferric oxide and the hydrogen peroxide that then add step 1 to weigh, after stirring, regulate pH=7.5, put glue, obtain urea-formaldehyde glue.
Embodiment 2: the preparation of urea-formaldehyde glue glue paste 2
Composition of raw materials:
Concrete preparation process is as follows:
(1) weigh the formaldehyde that the quality percentage composition of 330g is 37%, the urea of 170g, the acetaldehyde of 40g, the modified corn starch of 6g, the trimeric cyanamide of 13g, the sodium cellulosate of 10g, the formaldehyde deodovization agent of 10g, the ferric oxide of 10g, hydrogen peroxide 23g;
(2) formaldehyde that formaldehyde deodovization agent step 1 being weighed and quality percentage composition are 37% adds in reactor, and heating formaldehyde temperature to 35 ℃～40 ℃, regulates pH=8.0 with sodium hydroxide solution, then the sodium cellulosate that adds 85g urea and step 1 to weigh;
(3) while continuing to be heated to formaldehyde temperature in reactor and reach 75 ℃～80 ℃, stop heating, by the remaining temperature of reactor self, be warming up to 90 ℃～92 ℃, with sodium hydroxide solution, regulate pH=9.5～11, then add 15g urea; Be incubated 90～120 minutes;
(4) adjust pH to 4.5～5.0, react to viscosity 70cp;
(5) adjust pH to 6.5～7.0, add 55g urea, temperature is controlled at 80 ℃～90 ℃, reacts to viscosity 145cp;
(6) adjust pH to 7.0～7.5, the acetaldehyde, trimeric cyanamide and the modified corn starch that add 15g urea, step 1 to take, temperature maintains 75 ℃, is incubated 20～40 minutes, cooling;
(7) temperature is down to below 40 ℃, and the ferric oxide and the hydrogen peroxide that then add step 1 to weigh, after stirring, regulate pH=7.5, put glue, obtain urea-formaldehyde glue.
Embodiment 3: the preparation of urea-formaldehyde glue glue paste 3
Composition of raw materials:
Concrete preparation process is as follows:
(1) weigh the formaldehyde that the quality percentage composition of 360g is 37%, the urea of 180g, the propionic aldehyde of 50g, the modified corn starch of 9g, the trimeric cyanamide of 16g, the sodium cellulosate of 13g, the formaldehyde deodovization agent of 13g, the ferric oxide of 13g, hydrogen peroxide 26g;
(2) formaldehyde that formaldehyde deodovization agent step 1 being weighed and quality percentage composition are 37% adds in reactor, and heating formaldehyde temperature to 35 ℃～40 ℃, regulates pH=9.0 with sodium hydroxide solution, then the sodium cellulosate that adds 100g urea and step 1 to weigh;
(3) while continuing to be heated to formaldehyde temperature in reactor and reach 75 ℃～80 ℃, stop heating, by the remaining temperature of reactor self, be warming up to 90 ℃～92 ℃, with sodium hydroxide solution, regulate pH=10, then add 10g urea; Be incubated 90～120 minutes;
(4) adjust pH to 4.5～5.0, react to viscosity 70cp;
(5) adjust pH to 6.5～7.0, add 60g urea, temperature is controlled at 80 ℃～90 ℃, reacts to viscosity 150cp;
(6) adjust pH to 7.0～7.5, the propionic aldehyde, trimeric cyanamide and the modified corn starch that add 10g urea, step 1 to take, temperature maintains 75 ℃, is incubated 20～40 minutes, cooling;
(7) temperature is down to below 40 ℃, and the ferric oxide and the hydrogen peroxide that then add step 1 to weigh, after stirring, regulate pH=7.8, put glue, obtain urea-formaldehyde glue.
Embodiment 4: the preparation of urea-formaldehyde glue glue paste 4
Composition of raw materials:
Concrete preparation process is as follows:
(1) weigh the formaldehyde that the quality percentage composition of 400g is 37%, the urea of 200g, the propionic aldehyde of 60g, the Vinyl Acetate Copolymer fat liquor of 12g, the trimeric cyanamide of 20g, the sodium cellulosate of 15g, the formaldehyde deodovization agent of 15g, the ferric oxide of 15g, hydrogen peroxide 30g;
(2) formaldehyde that formaldehyde deodovization agent step 1 being weighed and quality percentage composition are 37% adds in reactor, and heating formaldehyde temperature to 35 ℃～40 ℃, regulates pH=8.5 with sodium hydroxide solution, then the sodium cellulosate that adds 100g urea and step 1 to weigh;
(3) while continuing to be heated to formaldehyde temperature in reactor and reach 75 ℃～80 ℃, stop heating, by the remaining temperature of reactor self, be warming up to 90 ℃～92 ℃, with sodium hydroxide solution, regulate pH=11, then add 10g urea; Be incubated 90～120 minutes;
(4) adjust pH to 4.5～5.0, react to viscosity: 80cp;
(5) adjust pH to 6.5～7.0, add 60g urea, temperature is controlled at 80 ℃～90 ℃, reacts to viscosity 160cp;
(6) adjust pH to 7.0～7.5, the propionic aldehyde, trimeric cyanamide and the Vinyl Acetate Copolymer fat liquor that add 10g urea, step 1 to take, temperature maintains 75 ℃, is incubated 20～40 minutes, cooling;
(7) temperature is down to below 40 ℃, and the ferric oxide and the hydrogen peroxide that then add step 1 to weigh, after stirring, regulate pH=7.6, put glue, obtain urea-formaldehyde glue.
Reference examples
Composition of raw materials:
Concrete preparation process is as follows:
(1) weigh the formaldehyde that the quality percentage composition of 360g is 37%, the urea of 180g, the trimeric cyanamide of 16g, the sodium cellulosate of 13g, hydrogen peroxide 26g;
(2) formaldehyde that formaldehyde deodovization agent step 1 being weighed and quality percentage composition are 37% adds in reactor, heating formaldehyde temperature to 35 ℃～40 ℃, with sodium hydroxide solution, regulate pH=7.5～9.0, then the sodium cellulosate that adds 100g urea and step 1 to weigh;
(3) while continuing to be heated to formaldehyde temperature in reactor and reach 75 ℃～80 ℃, stop heating, by the remaining temperature of reactor self, be warming up to 90 ℃～92 ℃, with sodium hydroxide solution, regulate pH=9.5, then add 10g urea; Be incubated 90～120 minutes;
(4) adjust pH to 4.5～5.0, react to viscosity 60cp;
(5) adjust pH to 6.5～7.0, add 60g urea, temperature is controlled at 80 ℃～90 ℃, reacts to viscosity 145cp;
(6) adjust pH to 7.0～7.5, add 10g urea, temperature maintains 75 ℃, is incubated 20～40 minutes, cooling;
(7) temperature is down to below 40 ℃, regulates pH=7.8, puts glue, obtains urea-formaldehyde glue.
Test result
Utilize the urea-formaldehyde glue tackiness agent of the embodiment of the present invention 1 to embodiment 4 method acquisition and the urea-formaldehyde glue tackiness agent that reference examples method obtains, that according to method in GB/T14074-2006, measures tackiness agent is solid containing indexs such as, pH, viscosity, set time, water-soluble, shelf liveves, according to the method in GB/T18883-2002, measure airborne formaldehyde content in urea-formaldehyde glue tackiness agent making processes, result is as shown in the table:
Table 1
As shown in Table 1, the solid content of embodiment 1 to 4 will be apparently higher than reference examples, simultaneously water-solublely will be worse than reference examples, and suitable with reference examples aspect set time and storage stability.Therefore, meeting under the prerequisite of glue performance and product stability, the present invention can obviously improve the perviousness of urea-formaldehyde glue tackiness agent, meanwhile, in embodiment 1 to 4 urea-formaldehyde glue making processes, formaldehyde content is all lower than 0.1mg/m3, lower than GB/T18883-2002 specified standards value, and in the glue process of reference examples, the formaldehyde volatilizing can stimulate eyes, cause and shed tears.
Test example
Utilize the urea-formaldehyde glue tackiness agent of the embodiment of the present invention 1 to 4 method acquisition and the urea-formaldehyde glue tackiness agent of reference examples acquisition to produce respectively 3 layers of glued board test specimen 1,2,3,4,5; Veneer is the veneer of grey olive processing, and water ratio is 6-12%;
The preparation of pre-pressing process condition and test specimen: Amount of spread 400g/ ㎡ (two-sided), preload pressure is 20-25MPa, the time is 60 minutes.
Heat pressing process is, pressure is 140-150MPa, temperature 120-140 ℃, and the time is 30-50s/mm.
According to GB9846-2004, the slab saw solution suppressing is become to standard specimen, with omnipotent mechanical test machine, measure the bonding strength of slab, test result is as shown in the table:
Table 2
| Numbering | The bonding strength of slab after precompressed | The bonding strength of slab after hot pressing |
| Embodiment 1 | 0.62 | 2.08 |
| Embodiment 2 | 0.58 | 1.95 |
| Embodiment 3 | 0.64 | 2.12 |
| Embodiment 4 | 0.56 | 1.96 |
| Reference examples | 0.26 | 0.93 |
As shown in Table 2, compare with reference examples, under the same conditions, bonding strength after embodiment 1 to 4 precompressed will be significantly better than reference examples, so the tack of embodiment 1 to 4 is better than reference examples, in addition, bonding strength from hot pressing, the bonding strength of embodiment 1 to 4 also will be significantly better than contrast, and hence one can see that, and that urea-formaldehyde glue tackiness agent of the present invention overcome existing tackiness agent tack is poor, the shortcoming such as gluing effect is bad.
Finally explanation is, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can modify or be equal to replacement technical scheme of the present invention, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of claim scope of the present invention.
Claims (7)
1. a urea-formaldehyde glue tackiness agent, it is characterized in that, comprise by weight following component: 300～400 parts, formaldehyde, 160～220 parts, urea, 30～60 parts of properties-correcting agent, 3～12 parts of tackifier, 10～20 parts of trimeric cyanamides, 8～15 parts of sodium cellulosates, 8～15 parts of formaldehyde deodovization agents, 8～15 parts of ferric oxide, 20～30 parts, solidifying agent, wherein said formaldehyde is that quality percentage composition is 37% industrial formol.
2. tackiness agent according to claim 1, is characterized in that: described solidifying agent is hydrogen peroxide.
3. tackiness agent according to claim 1, is characterized in that: described properties-correcting agent is one or more of paraformaldehyde, acetaldehyde, propionic aldehyde and butyraldehyde.
4. tackiness agent according to claim 1, is characterized in that: described tackifier are one or more in polyvinyl alcohol, modified corn starch and vinyl acetate between to for plastic fat liquor.
5. the method for the urea-formaldehyde glue tackiness agent described in preparation claim 1-4 any one, is characterized in that, comprises the following steps:
(1) weigh by weight the formaldehyde that the quality percentage composition of 300～400 parts is 37%, the urea of 160～220 parts, the properties-correcting agent of 30～60 parts, the tackifier of 3～12 parts, the trimeric cyanamide of 10～20 parts, the sodium cellulosate of 8～15 parts, the formaldehyde deodovization agent of 8～15 parts, the ferric oxide of 8～15 parts, the solidifying agent of 20～30 parts;
(2) formaldehyde that formaldehyde deodovization agent step 1 being weighed and quality percentage composition are 37% adds reactor, heating formaldehyde temperature to 35 ℃～40 ℃, with sodium hydroxide solution, regulate pH=7.5～9.0, then the sodium cellulosate that adds first urea and step 1 to weigh;
(3) while continuing to be heated to formaldehyde temperature in reactor and reach 75 ℃～80 ℃, stop heating, by the remaining temperature of reactor self, be warming up to 90 ℃～92 ℃, with sodium hydroxide solution, regulate pH=9.5～11, then add second batch urea; Be incubated 90～120 minutes;
(4) adjust pH to 4.5～5.0, react to viscosity 60～80cp;
(5) adjust pH to 6.5～7.0, add the 3rd batch of urea, temperature is controlled at 80 ℃～90 ℃, reacts to viscosity 140～160cp;
(6) adjust pH to 7.0～7.5, the properties-correcting agent, trimeric cyanamide and the tackifier that add the 4th batch of urea, step 1 to take, temperature maintains 75 ℃, is incubated 20～40 minutes, cooling;
(7) temperature is down to below 40 ℃, and the ferric oxide and the solidifying agent that then add step 1 to weigh, after stirring, regulate pH=7.5～8.0, put glue, obtain urea-formaldehyde glue;
Wherein, first to fourth batch of urea amount adding is respectively 50%～60%, and 5%～10%, 30%～40%, 1%～15%.
6. method according to claim 5, is characterized in that: the selected acid of described tune pH is one or more in sulfuric acid, hydrochloric acid and phosphoric acid.
7. method according to claim 5, is characterized in that: the selected alkali of described adjusting pH is sodium hydroxide.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497471A (en) * | 2016-10-28 | 2017-03-15 | 浙江欧仁新材料有限公司 | A kind of fire-retardant ultrasound fusion glue and preparation method thereof |
| CN107118723A (en) * | 2017-05-27 | 2017-09-01 | 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 | A kind of emery cloth urea-formaldehyde adhesive and preparation method |
| CN107177326A (en) * | 2017-05-08 | 2017-09-19 | 贵港市鑫宏木业有限公司 | The special viscose glue mixture of bamboo plywood |
| CN107298957A (en) * | 2017-07-31 | 2017-10-27 | 安徽佳诺威木业有限公司 | A kind of preparation method of high-strength water-resistance urea-formaldehyde resin adhesive |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101244571A (en) * | 2008-03-21 | 2008-08-20 | 中国林业科学研究院林产化学工业研究所 | Method for manufacturing E0 level wood veneer |
| CN102352200A (en) * | 2011-09-13 | 2012-02-15 | 大连鹏鸿木业有限公司 | Novel adhesive and preparation method thereof |
| CN102604575A (en) * | 2012-03-31 | 2012-07-25 | 黑龙江大学 | Modified urea formaldehyde adhesive and preparation method thereof |
| CN103031095A (en) * | 2012-12-12 | 2013-04-10 | 永港伟方（北京）科技股份有限公司 | Adhesive for veneering of artificial board and preparation method of adhesive |
-
2013
- 2013-10-18 CN CN201310491519.XA patent/CN103540283A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101244571A (en) * | 2008-03-21 | 2008-08-20 | 中国林业科学研究院林产化学工业研究所 | Method for manufacturing E0 level wood veneer |
| CN102352200A (en) * | 2011-09-13 | 2012-02-15 | 大连鹏鸿木业有限公司 | Novel adhesive and preparation method thereof |
| CN102604575A (en) * | 2012-03-31 | 2012-07-25 | 黑龙江大学 | Modified urea formaldehyde adhesive and preparation method thereof |
| CN103031095A (en) * | 2012-12-12 | 2013-04-10 | 永港伟方（北京）科技股份有限公司 | Adhesive for veneering of artificial board and preparation method of adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 孙丰文等: ""双氧水用作脲醛树脂胶黏剂固化剂的研究"", 《中国人造板》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497471A (en) * | 2016-10-28 | 2017-03-15 | 浙江欧仁新材料有限公司 | A kind of fire-retardant ultrasound fusion glue and preparation method thereof |
| CN107177326A (en) * | 2017-05-08 | 2017-09-19 | 贵港市鑫宏木业有限公司 | The special viscose glue mixture of bamboo plywood |
| CN107118723A (en) * | 2017-05-27 | 2017-09-01 | 江苏省江南新型复合研磨材料及制品工程技术研究中心有限公司 | A kind of emery cloth urea-formaldehyde adhesive and preparation method |
| CN107298957A (en) * | 2017-07-31 | 2017-10-27 | 安徽佳诺威木业有限公司 | A kind of preparation method of high-strength water-resistance urea-formaldehyde resin adhesive |
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Application publication date: 20140129 |