CN103535344A - Sulfosulfuron suspension for weed control - Google Patents

Sulfosulfuron suspension for weed control Download PDF

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Publication number
CN103535344A
CN103535344A CN201310431728.5A CN201310431728A CN103535344A CN 103535344 A CN103535344 A CN 103535344A CN 201310431728 A CN201310431728 A CN 201310431728A CN 103535344 A CN103535344 A CN 103535344A
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China
Prior art keywords
sulfosulfuron
preservative
agent
suspension
water
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CN201310431728.5A
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CN103535344B (en
Inventor
朱贲孝
周耀明
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WEIFANG ZHONGNONG UNITED CHEMICAL CO Ltd
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NANTONG JIAHE CHEMICAL CO Ltd
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Abstract

The invention discloses a sulfosulfuron suspension for weed control. The sulfosulfuron suspension for weed control comprises sulfosulfuron used as an active ingredient, a co-solvent, a wetting agent, a thickening agent, a preservative, a de-foaming agent and water with the volume ratios as follows: sulfosulfuron is 25-45%, the de-foaming agent is 0.5-1%, the co-solvent is 1-2.5%, the thickening agent is 1-2%, the wetting agent is 1-3%, the preservative is 0.5-1%, a dispersing agent is 1.5-3.5%, and the total volume is supplemented to be 100% by water. The sulfosulfuron suspension has the advantages that, through using water as the solvent, the danger to the environment caused by using a large amount of organic solvents in an emulsifiable concentrate is avoided, dust drift is avoided, the ground particles are small, the stability is good, the product is anti-corrosion and anti-freezing, and therefore the safety in transportation and storage is improved; the suspension is applied to a wheat field for weed control after a budding period of the wheat, then most broad-leaf weeds and grassy weeds can be prevented and controlled effectively, and the shift and retention of sulfosulfuron residue are avoided, and consequently, the safety of agricultural products is improved.

Description

The Sulfosulfuron suspending agent of weeding
Technical field
The present invention relates to pesticide production technology field, particularly a kind of Sulfosulfuron suspending agent of weeding.
Background technology
Sulfosulfuron is systemic herbicide, mainly by root system and the Foliage Absorption of plant.This product is branched-chain amino acid synthetic inhibitor, by hindering the biosynthesis of plant essential amino acid and isoleucine, makes cell stop division, plant stops growing then withered dead.Though existing, for preventing and kill off wheat paddock weed killer herbicide annual and perennial grass family and part broad leaved weed, can reach certain herbicidal effect, to the safety of wheat, can not guarantee.
In addition, the missible oil formulation weed killer herbicide of current domestic use need to be used a large amount of organic solvents, large to environmental hazard; Wetting powder is dust drift in producing and using, and causes the harm to environment and human body or even crops itself, does not also reach desirable herbicidal effect.
Summary of the invention
The object of the present invention is to provide a kind of Sulfosulfuron suspending agent that can replace the weeding of the emulsifiable concentrate of current use and the novel environment friendly of wetting powder and good impurity removing effect.
In order to realize object of the present invention, the invention discloses a kind of Sulfosulfuron suspending agent, its each volume of material ratio is:
Sulfosulfuron: 25%~45%; Defoamer: 0.5%~1%;
Cosolvent: 1%~2.5%; Thickener: 1%~2%;
Wetting agent: 1%~3%; Preservative: 0.5%~1%;
Dispersant: 1.5%~3.5%; Water complements to 100%.
Preferably, each volume of material ratio of weeding suspending agent used is:
Sulfosulfuron: 30%~40%; Defoamer: 0.5%~1%;
Cosolvent: 1%~1.5%; Thickener: 1%~2%;
Wetting agent: 1%~1.5%; Preservative: 0.5%~1%;
Dispersant: 1.5%~2.5%; Water complements to 100%.
Wherein, selected weeding suspending agent active component is Sulfosulfuron, and its chemical name is 1-(4,6-SDM-2-yl)-3-(2-ethylsulfonyl imidazoles [1,2-a] pyrimidin-3-yl) sulfonylureas.
Except active component, defoamer is one or more in organosilicon, dimethyl silicone polymer; Cosolvent is one or more in propane diols, glycerine; Thickener is one or more in urea, xanthans, sodium alginate; Wetting agent is one or more in alkylphenol formaldehyde APEO, fatty alcohol-polyoxyethylene ether, organic silicon modified by polyether oxygen alkane; Preservative is one or more in Sodium Benzoate, Kathon CG; Dispersant is one or more in calcium lignosulfonate, sodium methylene bis-naphthalene sulfonate.
Suspending agent of the present invention is made solvent with water, avoided a large amount of harm with an organic solvent environment being produced of emulsifiable concentrate, and without dust drift, abrasive grains is little, good stability, Anti-freeze fluid, the safety that has improved transportation and stored; After bud, be applied to wheat paddock weeding, can effectively prevent and kill off most of broad leaved weeds and grassy weed, and without transfer and the delay of Sulfosulfuron residue, the safety that has improved agricultural product, also can be used for uncultivated area weeding.
Embodiment:
Several embodiments of the present invention are described below, but content of the present invention is not limited to this completely.
Embodiment 1
The Sulfosulfuron suspending agent of weeding, wherein each volume of material ratio is: Sulfosulfuron: 25%; Organosilicon: 0.5%; Propane diols: 1%; Urea: 1%; Alkylphenol formaldehyde APEO: 3%; Sodium Benzoate: 1%; Calcium lignosulfonate: 1.5%; Water complements to 100%.
Embodiment 2
The Sulfosulfuron suspending agent of weeding, wherein each volume of material ratio is: Sulfosulfuron: 33%; Dimethyl silicone polymer: 1%; Glycerine: 2.5%; Xanthans: 2%; Organic silicon modified by polyether oxygen alkane: 1%; Kathon CG: 0.5%; Sodium methylene bis-naphthalene sulfonate: 3.5%; Water complements to 100%.
Embodiment 3
The Sulfosulfuron suspending agent of weeding, wherein each volume of material ratio is: Sulfosulfuron: 45%; Organosilicon and dimethyl silicone polymer: 0.5%; Propane diols and glycerine: 1.5%; Urea, sodium alginate and xanthans: 1.5%; Alkylphenol formaldehyde APEO and organic silicon modified by polyether oxygen alkane: 2%; Sodium Benzoate and Kathon CG: 0.5%; Calcium lignosulfonate and sodium methylene bis-naphthalene sulfonate: 2.5%; Water complements to 100%.
Embodiment 4
The Sulfosulfuron suspending agent of weeding, wherein each volume of material ratio is: Sulfosulfuron: 30%; Organosilicon: 0.5%; Propane diols: 1%; Urea: 1%; Alkylphenol formaldehyde APEO: 1%; Sodium Benzoate: 0.5%; Calcium lignosulfonate: 1.5%; Water complements to 100%.
Embodiment 5
The Sulfosulfuron suspending agent of weeding, wherein each volume of material ratio is: Sulfosulfuron: 35%; Dimethyl silicone polymer: 0.5%; Glycerine: 1%; Xanthans: 1%; Organic silicon modified by polyether oxygen alkane: 1.5%; Kathon CG: 1%; Sodium methylene bis-naphthalene sulfonate: 2%; Water complements to 100%.
Embodiment 6
The Sulfosulfuron suspending agent of weeding, wherein each volume of material ratio is: Sulfosulfuron: 40%; Organosilicon and dimethyl silicone polymer: 1%; Propane diols and glycerine: 1.5%; Urea, sodium alginate and xanthans: 2%; Alkylphenol formaldehyde APEO and organic silicon modified by polyether oxygen alkane: 1%; Sodium Benzoate and Kathon CG: 0.5%; Calcium lignosulfonate and sodium methylene bis-naphthalene sulfonate: 2.5%; Water complements to 100%.
The preparation method of the suspending agent of weeding, comprise the following steps: the former medicine of above-mentioned fluorine pyrrole acyl grass amine, cosolvent and water are added to respectively in batching kettle in proportion, stir 1~1.5 hour, pulping, the slurry of gained is delivered in colloid mill and is roughly ground 2~2.5 hours, then coarse grained abrasive is delivered in sand mill to sand milling 2.5~3 hours, sample analysis, average grain diameter is less than 3 microns; The feed liquid after sand milling is transported in compounding kettle again, adds the auxiliary agents such as dispersant, defoamer, thickener, wetting agent and preservative, fully stir 1 hour, sampling detects, and after test passes, feed liquid is delivered in finished product store groove to packing warehouse-in.
Batching kettle involved in the present invention, compounding kettle are enamel or stainless steel still, and colloid mill and sand mill are conventional industrial grinder.
The Sulfosulfuron suspending agent of prepare 6 groups of weedings that obtain is got respectively to same amount to be sprayed on the identical wheat sample field of containing volume grass family and broad leaved weed, after observing a period of time, find, grass family and broad leaved weed stop growing then withered dead, and the efficient of weeding is respectively 93.9%, 95.0%, 95.3%, 94.1%, 95.7% and 96.8%; Meanwhile, the growth situation of wheat is good.
After six groups of wheat sample field results, in grain and stalk, almost can't detect the residual of Sulfosulfuron; Be made into after goat and food stuff for chicken laying, in the milk of goat and hen, egg, Organ and tissue, also almost can't detect transfer and the delay of Sulfosulfuron residue.

Claims (3)

1. the Sulfosulfuron suspending agent of weeding, comprises active component, cosolvent, wetting agent, thickener, preservative, defoamer and water, it is characterized in that: the active component of described effective dose is Sulfosulfuron, and each volume of material ratio is:
Sulfosulfuron: 25%~45%; Defoamer: 0.5%~1%;
Cosolvent: 1 %~2.5%; Thickener: 1%~2%;
Wetting agent: 1%~3%; Preservative: 0.5%~1%;
Dispersant: 1.5%~3.5%; Water complements to 100%.
2. the Sulfosulfuron suspending agent of weeding according to claim 1, is characterized in that each volume of material ratio is:
Sulfosulfuron: 30%~40%; Defoamer: 0.5%~1%;
Cosolvent: 1%~1.5%; Thickener: 1%~2%;
Wetting agent: 1%~1.5%; Preservative: 0.5%~1%;
Dispersant: 1.5%~2.5%; Water complements to 100%.
3. the Sulfosulfuron suspending agent of weeding according to claim 1 and 2, is characterized in that described defoamer is selected from one or more of organosilicon, dimethyl silicone polymer; Described cosolvent is one or more that are selected from propane diols, glycerine; Described thickener is selected from one or more in urea, xanthans, sodium alginate; Described wetting agent is one or more in alkylphenol formaldehyde APEO, fatty alcohol-polyoxyethylene ether or organic silicon modified by polyether oxygen alkane; Described preservative is selected from one or more in Sodium Benzoate, Kathon CG; Described dispersant is one or more in calcium lignosulfonate, sodium methylene bis-naphthalene sulfonate.
CN201310431728.5A 2013-09-22 2013-09-22 The Sulfosulfuron suspending agent of weeding Active CN103535344B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112772669A (en) * 2020-12-31 2021-05-11 山东东合生物科技有限公司 Iprodione and procymidone suspending agent and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006098156A2 (en) * 2005-03-14 2006-09-21 Ishihara Sangyo Kaisha, Ltd. Herbicidal suspension
CN101827524A (en) * 2007-10-23 2010-09-08 杜邦公司 Herbicide mixture, method for controlling undesirable vegetation and use of herbicides
CN102771492A (en) * 2012-09-02 2012-11-14 陕西上格之路生物科学有限公司 Herbicide composition containing sulfosulfuron and clodinafop-propargyl
CN102835410A (en) * 2012-09-21 2012-12-26 徐弋舒 Method for compound use of rice herbicide
CN102893992A (en) * 2012-10-29 2013-01-30 南通嘉禾化工有限公司 Weeding suspending agent and preparation process thereof
CN103125514A (en) * 2013-03-17 2013-06-05 陕西农心作物科技有限公司 Wheat paddock weeding composition containing sulfosulfuron and flucarbazone

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006098156A2 (en) * 2005-03-14 2006-09-21 Ishihara Sangyo Kaisha, Ltd. Herbicidal suspension
CN101827524A (en) * 2007-10-23 2010-09-08 杜邦公司 Herbicide mixture, method for controlling undesirable vegetation and use of herbicides
CN102771492A (en) * 2012-09-02 2012-11-14 陕西上格之路生物科学有限公司 Herbicide composition containing sulfosulfuron and clodinafop-propargyl
CN102835410A (en) * 2012-09-21 2012-12-26 徐弋舒 Method for compound use of rice herbicide
CN102893992A (en) * 2012-10-29 2013-01-30 南通嘉禾化工有限公司 Weeding suspending agent and preparation process thereof
CN103125514A (en) * 2013-03-17 2013-06-05 陕西农心作物科技有限公司 Wheat paddock weeding composition containing sulfosulfuron and flucarbazone

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112772669A (en) * 2020-12-31 2021-05-11 山东东合生物科技有限公司 Iprodione and procymidone suspending agent and preparation method thereof

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Address after: 262737 Lingang Chemical Industry Park, Binhai Economic Development Zone, Weifang, Shandong

Patentee after: WEIFANG ZHONGNONG UNITED CHEMICAL Co.,Ltd.

Address before: 226100 Linjiang New District, Haimen City, Nantong City, Jiangsu Province

Patentee before: NANTONG JIAHE CHEMICALS CO.,LTD.