CN103526423B - Anti-mite modal fiber fabric - Google Patents
Anti-mite modal fiber fabric Download PDFInfo
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- CN103526423B CN103526423B CN201310530101.5A CN201310530101A CN103526423B CN 103526423 B CN103526423 B CN 103526423B CN 201310530101 A CN201310530101 A CN 201310530101A CN 103526423 B CN103526423 B CN 103526423B
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Abstract
The invention discloses a kind of anti-mite modal fiber fabric, the raw material hybrid woven adopting following weight portion to form forms: 50-70 part Modal fibre, 30-50 part mite-assistant fiber.Anti-mite modal fiber fabric of the present invention, comfortable and easy to wear, and there is good anti-mite drive mite effect.
Description
Technical field
The present invention relates to a kind of fabric, particularly relate to a kind of anti-mite modal fiber fabric.
Background technology
Mite class is the monoid of most species in Arthropoda arachnid, and mite class existing on the earth can have 500,000 kinds more than, and their form, habit and habitat are varied, can find the trace of mite class on earth Anywhere.Medical domain is studied the disease that the dirt mite be distributed in people's living environment causes, research shows that it is a kind of strong sensibiligen, the people in the whole world nearly 1/10 suffers from anaphylactia, and wherein the morbidity of asthma, allergic rhinitis and atopical dermatitis etc. is all closely bound up with existing of house dust mite.
Along with the development of world architecture technology and the abundant of people's material life, indoor living environment has a very large change, the improvement of house airtight performance, indoor pollution is assembled, improper ventilation adds the growth that indoor humidity is also conducive to mould and house dust mite simultaneously, thus making dirt mite become allergen the most general in living environment, the change of life style and working method then makes the time of people 80% spend in indoor.The change of environment facilitates dirt mite and grows, and people too increase the contact with dust mite allergen in the prolongation of indoor residence time, and the incidence of disease of the diseases such as dust mite allergy asthma increases thereupon.Therefore, the control of dirt mite receives the extensive concern of countries in the world researcher.
Because the textiles in room is the main place of dirt mite evil life, there is the chemical reagent that kills mite or drive mite effect give the anti-mite of textiles by adding in textiles and drive mite function, in the process using textiles, realize anti-mite drive mite, become a kind of new trend.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is to provide a kind of anti-mite modal fiber fabric.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of anti-mite modal fiber fabric, the raw material hybrid woven adopting following weight portion to form forms: 50-70 part Modal fibre, 30-50 part mite-assistant fiber.
Anti-mite modal fiber fabric of the present invention can adopt industry universal method first Modal fibre and mite-assistant fiber to be carried out blending, obtained blended yarn, then adopts industry universal method to be woven into anti-mite modal fiber fabric this blended yarn.The preparation method of obvious described blended yarn woven fabric itself does not have originality, is only to adopt prior art, and innovation of the present invention is the difference of fabric blend fibre raw material and proportioning.
Described mite-assistant fiber, material is terylene, also drives mite agent containing 0.05-0.15wt%.Describedly drive mite agent and be made up of 30-50 weight portion Fenamidone, 30-50 weight portion decis and 10-30 weight portion lauryl carboxymethyl sodium form imidazoline acetate.
Fenamidone, CAS:161326-34-7.Decis, CAS:52918-63-5.Lauryl carboxymethyl sodium form imidazoline acetate, CAS:64041-76-5.
Described mite-assistant fiber, is prepared from by following step:
(1) by terylene with drive mite agent and mix, extrude, cut into slices, obtainedly drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio driving mite agent;
(2) drive mite terylene chips heating and melting by described, extruding, spray silk is shaping.
Further, the coupling agent of described mite-assistant fiber also containing 0.02-0.10wt%.
Described coupling agent is titanate coupling agent.
Described coupling agent is made up of 60-80wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 20-40wt% bis-(triethanolamine) metatitanic acid diisopropyl ester.
Isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, CAS:67691-13-8.Two (triethanolamine) metatitanic acid diisopropyl ester, CAS:36673-16-2.
Described mite-assistant fiber, is prepared from by following step:
(1) mixed with terylene by coupling agent, obtain modified dacron, wherein the mass ratio of terylene and coupling agent is 100:0.02-100:0.10;
(2) by modified dacron with drive mite agent and mix, extrude, cut into slices, obtainedly drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio driving mite agent;
(3) drive mite terylene chips heating and melting by described, extruding, spray silk is shaping.
Below main raw material fiber of the present invention is introduced:
Modal fibre, be called for short Modal fiber, be the tModified Cellulose Fibers of the koplon of Austrian Lenzin (Lenzing) company exploitation, the raw material of this fiber adopts the beech in Europe, first be made into wood pulp, then be processed into fiber by special spinning technique.This products material is all natural material, harmless, and can natural decomposition, environmental sound.The raw material of Modal fibre is the spinney originating from Europe, and being made through special spinning technique after making wooden slurries, is a kind of cellulose fibre, belongs to cellulose fibre together so the same with cotton, is pure natural fabric.
Terylene is an important kind in synthetic fiber, is the trade name of China's polyester fiber.It is with p-phthalic acid (PTA) or dimethyl terephthalate (DMT) (DMT) and ethylene glycol (EG) for raw material is through esterification or ester exchange and polycondensation reaction and obtained fiber-forming polymer---polyethylene terephthalate (PET), through the fiber that spinning and post processing are made.
Anti-mite modal fiber fabric of the present invention, mite-proof agent is embedded in fibrous inside, wearing and washing the process of textiles, surface one deck mite-proof agent is washed off, new mite-proof agent is had again to supplement from interior stripping, form again the new anti-mite layer of one deck at fabric face, play anti-mite effect, thus embody excellent washability.
Anti-mite modal fiber fabric of the present invention, comfortable and easy to wear, and there is good anti-mite drive mite effect.
Detailed description of the invention
Embodiment 1:
(1) 0.06 weight portion coupling agent is mixed with 100 weight portion terylene, obtain modified dacron;
Described coupling agent is made up of 70wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 30wt% bis-(triethanolamine) metatitanic acid diisopropyl ester;
(2) above-mentioned modified dacron and 0.1 weight portion are driven mite agent to mix, extrude, cut into slices, obtain and drive mite terylene chips;
Describedly drive mite agent and be made up of 40wt% Fenamidone, 40wt% decis and 20wt% lauryl carboxymethyl sodium form imidazoline acetate;
(3) drive mite terylene chips heating and melting by above-mentioned, extruding, spray silk is shaping, obtained mite-assistant fiber.
Embodiment 2:
Adopt the substantially identical method of embodiment 1 to prepare mite-assistant fiber, unique difference is: described coupling agent is two (triethanolamine) metatitanic acid diisopropyl ester, and addition is also 0.06 weight portion.
Embodiment 3:
Adopt the substantially identical method of embodiment 1 to prepare mite-assistant fiber, unique difference is: described coupling agent is isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, and addition is also 0.06 weight portion.
Embodiment 4:
Adopt the substantially identical method of embodiment 1 to prepare mite-assistant fiber, unique difference is: do not add any coupling agent.
Embodiment 5
The blending mass ratio of the mite-assistant fiber of Modal fibre, embodiment 1 is 60:40.
By the mite-assistant fiber of Modal fibre and embodiment 1, adopt artificial mixed in a small amount, volume made by opening picking machinery, and blended sliver made by carding machine;
By above-mentioned blended sliver, obtain described anti-mite modal fiber fabric by pre-drawing machine, drawing frame, Speed frames, fine spining machine and bobbin winder successively.Obtained blended yarn, number is 21
s, the twist is 330.
Again by above-mentioned obtained anti-mite modal fiber fabric, adopt conventional weaving process can obtain described anti-mite modal fiber fabric, plain cloth, fabric grammes per square metre is 180 grams/m.
Embodiment 6
The blending mass ratio of the mite-assistant fiber of Modal fibre, embodiment 2 is 60:40.The method of embodiment 5 is adopted to prepare anti-mite modal fiber fabric.
Embodiment 7
The blending mass ratio of the mite-assistant fiber of Modal fibre, embodiment 3 is 60:40.The method of embodiment 5 is adopted to prepare anti-mite modal fiber fabric.
Embodiment 8
The blending mass ratio of the mite-assistant fiber of Modal fibre, embodiment 4 is 60:40.The method of embodiment 5 is adopted to prepare anti-mite modal fiber fabric.
Test case 1:
" the anti-mite bedding of the FZ/T62012-2009 " standard of employing, to the anti-mite modal fiber fabric of above-mentioned employing embodiment 5-8, carry out anti-mite performance test:
Table 1: anti-mite performance test table
Test case 2:
Embodiment 1 drives mite agent (40wt% Fenamidone, 40wt% decis and 20wt% lauryl carboxymethyl sodium form imidazoline acetate) toxicity test:
(1) mite agent aqueous solution per os acute toxicity is driven; Get 1wt% and drive the Kunming kind standard small white mouse disposable per os gavage of the mite agent aqueous solution to 40 empty stomach 16h, drive mite agent aqueous solution dosage up to 20000mg/kg.Observe animal and poisoning manifestations every day, seven days terminate experiment, and each group animal used as test is in whole experimentation, and without any poisoning manifestations, diet and motion are all normal, none animal dead.
(2) to skin irritation: cut respectively by 10 Japan's large ear tag quasi-experiment backbone diamond wools of rabbit, 1wt% will be flooded drive the gauze of the mite agent aqueous solution, on the skin that exposes on right side of applying ointment or plaster.Observe application site skin after 24 hours, all do not occur the irritation such as erythema and oedema, according to skin irritatin strength grading standard, this drives mite agent and belongs to non-stimulated material to skin.
(3) to eye irritation: 1wt% to be driven the mite agent aqueous solution, the directly instillation Japan large ear tag quasi-experiment right eye of rabbit, left eye compares, passive closed 5 seconds, then clean with normal saline flushing, observe after 24 hours, eyes are all without exception, according to eye irritation strength grading standard, this drives mite agent and belongs to non-stimulated material to eyes.
Anti-mite modal fiber fabric of the present invention, mite-proof agent is embedded in fibrous inside, wearing and washing the process of textiles, surface one deck mite-proof agent is washed off, new mite-proof agent is had again to supplement from interior stripping, form again the new anti-mite layer of one deck at fabric face, play anti-mite effect, thus embody excellent washability.
Claims (1)
1. an anti-mite modal fiber fabric, is characterized in that, the raw material hybrid woven adopting following weight portion to form forms: 50-70 part Modal fibre, 30-50 part mite-assistant fiber;
Described mite-assistant fiber, material is terylene, also drives mite agent containing 0.05-0.15wt%;
The coupling agent of described mite-assistant fiber also containing 0.02-0.10wt%;
Describedly drive mite agent and be made up of 30-50 weight portion Fenamidone, 30-50 weight portion decis and 10-30 weight portion lauryl carboxymethyl sodium form imidazoline acetate;
Described coupling agent is made up of 60-80wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 20-40wt% bis-(triethanolamine) metatitanic acid diisopropyl ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310530101.5A CN103526423B (en) | 2013-10-31 | 2013-10-31 | Anti-mite modal fiber fabric |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310530101.5A CN103526423B (en) | 2013-10-31 | 2013-10-31 | Anti-mite modal fiber fabric |
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| CN103526423A CN103526423A (en) | 2014-01-22 |
| CN103526423B true CN103526423B (en) | 2015-08-05 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112609294B (en) * | 2020-12-10 | 2022-05-27 | 安徽三宝棉纺针织投资有限公司 | Environment-friendly antibacterial anti-mite fiber fabric for home textiles |
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| CN1060855A (en) * | 1991-03-05 | 1992-05-06 | 宁波市化工研究设计院 | Multifuncitonal organosilicon emulsion, coupling agent and preparation method thereof |
| CN101168863A (en) * | 2007-11-28 | 2008-04-30 | 盛虹集团有限公司 | Highly effective acarid-proof terylene fibre |
| CN102505232A (en) * | 2011-10-31 | 2012-06-20 | 上海飞龙纺织有限公司 | Flax fiber and modal fiber blended yarn and production method thereof |
| CN102793298A (en) * | 2012-08-13 | 2012-11-28 | 广东宏杰内衣实业有限公司 | Process for producing far Infrared anti-bacteria and mite-proof functional brassiere |
| CN103361805A (en) * | 2013-08-06 | 2013-10-23 | 上海婉静纺织科技有限公司 | China-hemp, modal and Dacron blended fabric |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CL2007003743A1 (en) * | 2006-12-22 | 2008-07-11 | Bayer Cropscience Ag | COMPOSITION THAT INCLUDES FENAMIDONA AND AN INSECTICIDE COMPOUND; AND METHOD TO CONTROL FITOPATOGENOS CULTURES AND INSECTS FACING OR PREVENTIVELY. |
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2013
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Patent Citations (5)
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| CN1060855A (en) * | 1991-03-05 | 1992-05-06 | 宁波市化工研究设计院 | Multifuncitonal organosilicon emulsion, coupling agent and preparation method thereof |
| CN101168863A (en) * | 2007-11-28 | 2008-04-30 | 盛虹集团有限公司 | Highly effective acarid-proof terylene fibre |
| CN102505232A (en) * | 2011-10-31 | 2012-06-20 | 上海飞龙纺织有限公司 | Flax fiber and modal fiber blended yarn and production method thereof |
| CN102793298A (en) * | 2012-08-13 | 2012-11-28 | 广东宏杰内衣实业有限公司 | Process for producing far Infrared anti-bacteria and mite-proof functional brassiere |
| CN103361805A (en) * | 2013-08-06 | 2013-10-23 | 上海婉静纺织科技有限公司 | China-hemp, modal and Dacron blended fabric |
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| 纯棉织物耐久防螨抗菌整理的研究;邹承淑等;《纺织科学研究》;20010925(第03期);全文 * |
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Inventor after: Zhang Mingsheng Inventor before: Yuan Juan |
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Effective date of registration: 20160603 Address after: 515357 relaxation Industrial Zone, processing zone, quicksand East Po, Puning, Guangdong, Jieyang Patentee after: Guangdong relaxation Clothing Industry Co., Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T158 Patentee before: Shanghai Wanjing Textile Technology Co., Ltd. |
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Address after: 515357 Zhang Yue Industrial Zone, quicksand East clothing processing zone, Puning, Guangdong, Jieyang Patentee after: Guangdong Zhang Chi Dress Industry Co., Ltd. Address before: 515357 relaxation Industrial Zone, processing zone, quicksand East Po, Puning, Guangdong, Jieyang Patentee before: Guangdong relaxation Clothing Industry Co., Ltd. |