CN103524845B - 一种无卤阻燃热塑性聚烯烃电缆料 - Google Patents
一种无卤阻燃热塑性聚烯烃电缆料 Download PDFInfo
- Publication number
- CN103524845B CN103524845B CN201310461375.3A CN201310461375A CN103524845B CN 103524845 B CN103524845 B CN 103524845B CN 201310461375 A CN201310461375 A CN 201310461375A CN 103524845 B CN103524845 B CN 103524845B
- Authority
- CN
- China
- Prior art keywords
- retardant
- fire retardant
- powder
- cable
- hour
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 23
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 12
- 229920002397 thermoplastic olefin Polymers 0.000 title abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims abstract description 6
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims abstract description 6
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 6
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 6
- 239000003822 epoxy resin Substances 0.000 claims abstract description 6
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 6
- 235000011187 glycerol Nutrition 0.000 claims abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 6
- 150000003014 phosphoric acid esters Chemical class 0.000 claims abstract description 6
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 6
- 229920003987 resole Polymers 0.000 claims abstract description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 β-chloropropyl Chemical group 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 241000221035 Santalaceae Species 0.000 claims description 3
- 235000008632 Santalum album Nutrition 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 239000010977 jade Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229940093429 polyethylene glycol 6000 Drugs 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- 239000000341 volatile oil Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 229940012185 zinc palmitate Drugs 0.000 claims description 3
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- 239000000779 smoke Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 abstract description 2
- 238000002485 combustion reaction Methods 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract description 2
- 239000003112 inhibitor Substances 0.000 abstract description 2
- 239000002574 poison Substances 0.000 abstract description 2
- 231100000614 poison Toxicity 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
Abstract
本发明提供了一种无卤阻燃热塑性聚烯烃电缆料，由下列重量份的原料制成：聚乙烯树脂20-30、酚醛树脂10-15、E-12环氧树脂10-20、乙烯共聚物20-30、聚磷酸铵10-15、硼酸锌5-10、三TCPP阻燃剂三(β-氯丙基)磷酸酯5-10、柠檬酸三丁酯10-14、煅烧陶土4-5、棕榈油10-15、甘油5-7、3-氨丙基三甲氧基硅烷5-8、双酚A？2-3、次磷酸铝12-15、聚四氟乙烯1-2、改性填料7-9。本发明的电缆料配方中的阻燃剂由硼酸盐类阻燃剂和磷氮阻燃剂复配而成，添加少量的阻燃增效剂就使电缆料具有良好的阻燃效果和优良的抑烟效果，该电缆料的烟密度低、毒性指数低。
Description
技术领域
本发明涉及电缆料领域，具体涉及一种无卤阻燃热塑性聚烯烃电缆料。
背景技术
随着全球经济的迅猛发展，及人类环保意识的增强，各领域对电线电缆的质量和性能的要求越来越高，因电线、电缆的老化而引发的火灾也越来越多，如何降低火灾的发生率及发生火灾的时的死亡率，低烟、无卤、阻燃、环保也成为电线电缆行业的发展方向。其中无卤低烟阻燃电缆料的需求量越来越大，目前无卤低烟阻燃电缆料的生产大多是在聚烯烃基材中加入大量的氢氧化镁或氢氧化镁来达到阻燃效果，然而，大量无机材料的加入，影响了电缆料的物理机械性能和加工工艺性能，其在常温下柔软性能、耐气候性差、耐油性、耐低温性能都不是很好。
发明内容
本发明提供了一种无卤阻燃热塑性聚烯烃电缆料。
本发明采用的技术方案为：
一种无卤阻燃热塑性聚烯烃电缆料，其特征在于：由下列重量份的原料制成：聚乙烯树脂20-30、酚醛树脂10-15、E-12环氧树脂10-20、乙烯共聚物20-30、聚磷酸铵10-15、硼酸锌5-10、三TCPP阻燃剂三(β-氯丙基)磷酸酯5-10、柠檬酸三丁酯10-14、煅烧陶土4-5、棕榈油10-15、甘油5-7、3-氨丙基三甲氧基硅烷5-8、双酚A2-3、次磷酸铝12-15、聚四氟乙烯1-2、改性填料7-9。
所述的无卤阻燃热塑性聚烯烃电缆料，其特征在于，由下列重量份的组分原料制备而得：聚乙烯树脂28、酚醛树脂14、E-12环氧树脂16、乙烯共聚物25、聚磷酸铵14、硼酸锌8、三TCPP阻燃剂三(β-氯丙基)磷酸酯6、柠檬酸三丁酯13、煅烧陶土5、棕榈油12、甘油6、3-氨丙基三甲氧基硅烷6、双酚A3、次磷酸铝14、聚四氟乙烯1、改性填料8。
所述的无卤阻燃热塑性聚烯烃电缆料，其特征在于，所述的改性填料是通过下列方法制备而得：
将沸石在500-550℃下煅烧3-4小时，取出后，加入3-4%的氢氧化钠溶液中研磨1-2小时，然后，加入12-15%的盐酸溶液，调节PH值为4-5，陈化10-15小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末，然后，向所得粉末中加入相当于粉末重量1-2%的檀香精油、4-5%纳米玉石粉、1-2%的棕榈酸锌、1-2%的硬脂酸钙、共同研磨1-2小时后，再加入相当于粉末重量2-3%的甲基三乙氧基硅烷、2-3%聚乙二醇6000、2-3%的吗啉，10000-13000转/分的高速分散均匀，即得。
按配方比例称取各组分原料，将称取的组分原料，在高速混合机中搅拌均匀，再在145-175℃的温度区间下经密炼机密炼，双螺杆挤出，磨面热切造粒，旋风分离机送料，振动筛筛分然后包装，即得到电缆料成品。
有益效果
本发明的电缆料配方中的阻燃剂由硼酸盐类阻燃剂和磷氮阻燃剂复配而成，添加少量的阻燃增效剂就使电缆料具有良好的阻燃效果和优良的抑烟效果，该电缆料的烟密度低、毒性指数低。
具体实施方式
无卤阻燃热塑性聚烯烃电缆料，由下列重量（kg）的原料制成：
聚乙烯树脂28、酚醛树脂14、E-12环氧树脂16、乙烯共聚物25、聚磷酸铵14、硼酸锌8、三TCPP阻燃剂三(β-氯丙基)磷酸酯6、柠檬酸三丁酯13、煅烧陶土5、棕榈油12、甘油6、3-氨丙基三甲氧基硅烷6、双酚A3、次磷酸铝14、聚四氟乙烯1、改性填料8。
本发明的电缆料的制备方法：
按配方比例称取各组分原料，将称取的组分原料，在高速混合机中搅拌均匀，再在145-175℃的温度区间下经密炼机密炼，双螺杆挤出，磨面热切造粒，旋风分离机送料，振动筛筛分然后包装，即得到电缆料成品。
其中，改性填料是通过下列方法制备而得：
将沸石在520℃下煅烧4小时，取出后，加入4%的氢氧化钠溶液中研磨1.5小时，然后，加入15%的盐酸溶液，调节PH值为4，陈化12小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末，然后，向所得粉末中加入相当于粉末重量1%的檀香精油、4.5%纳米玉石粉、2%的棕榈酸锌、1%的硬脂酸钙、共同研磨2小时后，再加入相当于粉末重量3%的甲基三乙氧基硅烷、2%聚乙二醇6000、2%的吗啉，10000-13000转/分的高速分散均匀，即得。
本实施例制得的电缆料的性能测试结果如下表：
Claims (2)
1.一种阻燃热塑性聚烯烃电缆料，其特征在于：由下列重量份的原料制成：聚乙烯树脂20-30、酚醛树脂10-15、E-12环氧树脂10-20、乙烯共聚物20-30、聚磷酸铵10-15、硼酸锌5-10、TCPP阻燃剂三(β-氯丙基)磷酸酯5-10、柠檬酸三丁酯10-14、煅烧陶土4-5、棕榈油10-15、甘油5-7、3-氨丙基三甲氧基硅烷5-8、双酚A2-3、次磷酸铝12-15、聚四氟乙烯1-2、改性填料7-9；
所述的改性填料是通过下列方法制备而得：将沸石在500-550℃下煅烧3-4小时，取出后，加入3-4%的氢氧化钠溶液中研磨1-2小时，然后，加入12-15%的盐酸溶液，调节pH值为4-5，陈化10-15小时，再加氢氧化钠溶液调节研磨液pH为中性，过滤，烘干得到填料粉末，然后，向所得粉末中加入相当于粉末重量1-2%的檀香精油、4-5%纳米玉石粉、1-2%的棕榈酸锌、1-2%的硬脂酸钙、共同研磨1-2小时后，再加入相当于粉末重量2-3%的甲基三乙氧基硅烷、2-3%聚乙二醇6000、2-3%的吗啉，10000-13000转/分的高速分散均匀，即得。
2.根据权利要求1所述的阻燃热塑性聚烯烃电缆料，其特征在于，由下列重量份的组分原料制备而得：聚乙烯树脂28、酚醛树脂14、E-12环氧树脂16、乙烯共聚物25、聚磷酸铵14、硼酸锌8、TCPP阻燃剂三(β-氯丙基)磷酸酯6、柠檬酸三丁酯13、煅烧陶土5、棕榈油12、甘油6、3-氨丙基三甲氧基硅烷6、双酚A3、次磷酸铝14、聚四氟乙烯1、改性填料8。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310461375.3A CN103524845B (zh) | 2013-09-30 | 2013-09-30 | 一种无卤阻燃热塑性聚烯烃电缆料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310461375.3A CN103524845B (zh) | 2013-09-30 | 2013-09-30 | 一种无卤阻燃热塑性聚烯烃电缆料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103524845A CN103524845A (zh) | 2014-01-22 |
| CN103524845B true CN103524845B (zh) | 2016-04-13 |
Family
ID=49927219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310461375.3A Expired - Fee Related CN103524845B (zh) | 2013-09-30 | 2013-09-30 | 一种无卤阻燃热塑性聚烯烃电缆料 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103524845B (zh) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881291A (zh) * | 2014-02-26 | 2014-06-25 | 黄忠娟 | 一种增强型阻燃塑料 |
| CN103992541A (zh) * | 2014-04-25 | 2014-08-20 | 安徽华鸿电气股份有限公司 | 一种耐磨电缆料 |
| CN104072848A (zh) * | 2014-06-23 | 2014-10-01 | 李雪红 | 一种聚乙烯耐磨塑料 |
| CN105482203A (zh) * | 2015-12-15 | 2016-04-13 | 中冠电缆有限公司 | 一种掺杂改性硅树脂的氯丁橡胶基电缆料及其制备方法 |
| CN105542390A (zh) * | 2016-01-27 | 2016-05-04 | 安徽卓越电缆有限公司 | 一种耐热阻燃电缆绝缘材料制备方法 |
| CN106905663A (zh) * | 2017-03-24 | 2017-06-30 | 合肥羿振电力设备有限公司 | 一种电缆材料及其制备方法 |
| CN107492410A (zh) * | 2017-07-04 | 2017-12-19 | 昆明三川电线电缆有限公司 | 一种低卤耐高温电缆 |
| CN110335717B (zh) * | 2019-08-05 | 2021-04-09 | 江苏耘和线缆有限公司 | 一种阻燃线缆及加工方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0212575A2 (en) * | 1985-08-16 | 1987-03-04 | E.I. Du Pont De Nemours And Company | Halogen-free flame resistant thermoplastic compostion |
| CN101143944A (zh) * | 2006-09-13 | 2008-03-19 | 中国石油天然气股份有限公司 | 一种聚乙烯用无卤膨胀型阻燃剂 |
| CN101817952A (zh) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | 柔软型低烟无卤阻燃聚烯烃电缆料及其制备方法 |
| CN101831100A (zh) * | 2010-04-26 | 2010-09-15 | 大连圣迈新材料有限公司 | 一种低烟无卤阻燃电子线料 |
| CN102367306A (zh) * | 2011-05-17 | 2012-03-07 | 顺德职业技术学院 | 高效无卤阻燃聚丙烯复合材料及其制备方法 |
| CN102746612A (zh) * | 2012-07-05 | 2012-10-24 | 同济大学 | 一种无卤阻燃、增韧酚醛泡沫塑料的制备方法 |
| CN103172918A (zh) * | 2011-12-22 | 2013-06-26 | 上海杰事杰新材料(集团)股份有限公司 | 一种低烟无卤阻燃电缆料及其制备方法 |
-
2013
- 2013-09-30 CN CN201310461375.3A patent/CN103524845B/zh not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0212575A2 (en) * | 1985-08-16 | 1987-03-04 | E.I. Du Pont De Nemours And Company | Halogen-free flame resistant thermoplastic compostion |
| CN101143944A (zh) * | 2006-09-13 | 2008-03-19 | 中国石油天然气股份有限公司 | 一种聚乙烯用无卤膨胀型阻燃剂 |
| CN101831100A (zh) * | 2010-04-26 | 2010-09-15 | 大连圣迈新材料有限公司 | 一种低烟无卤阻燃电子线料 |
| CN101817952A (zh) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | 柔软型低烟无卤阻燃聚烯烃电缆料及其制备方法 |
| CN102367306A (zh) * | 2011-05-17 | 2012-03-07 | 顺德职业技术学院 | 高效无卤阻燃聚丙烯复合材料及其制备方法 |
| CN103172918A (zh) * | 2011-12-22 | 2013-06-26 | 上海杰事杰新材料(集团)股份有限公司 | 一种低烟无卤阻燃电缆料及其制备方法 |
| CN102746612A (zh) * | 2012-07-05 | 2012-10-24 | 同济大学 | 一种无卤阻燃、增韧酚醛泡沫塑料的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103524845A (zh) | 2014-01-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103524845B (zh) | 一种无卤阻燃热塑性聚烯烃电缆料 | |
| CN103524913B (zh) | 一种阻燃耐油耐老化热塑性弹性体电缆料 | |
| CN103571009B (zh) | 低烟无卤阻燃电缆料 | |
| CN103571008B (zh) | 一种低烟无卤阻燃聚烯烃电缆料 | |
| CN103571010B (zh) | 一种低烟无卤阻燃电缆料 | |
| CN103524938B (zh) | 一种耐磨型无卤阻燃电缆料 | |
| CN103524904B (zh) | 一种特种电缆料及其制备方法 | |
| CN103524937B (zh) | 一种高阻燃聚氯乙烯电缆料 | |
| CN103524933B (zh) | 一种阻燃电缆料及其制备方法 | |
| CN103525075B (zh) | 一种高阻燃高耐热无卤阻燃热塑性电缆料 | |
| CN103571031B (zh) | 一种低烟环保电缆料 | |
| CN103524865B (zh) | 一种纳米改性低收缩低烟无卤阻燃聚烯烃电缆料 | |
| CN103524895B (zh) | 一种耐高温无卤阻燃聚丙烯电缆料及其制备方法 | |
| CN103525072B (zh) | 一种无卤阻燃聚苯醚电缆料 | |
| CN103540061A (zh) | 一种环保聚氯乙烯电缆料 | |
| CN103571030A (zh) | 一种低烟无卤硅烷自然交联聚烯烃电缆料及其制备方法 | |
| CN103571087B (zh) | 一种环保填充电缆料 | |
| CN103571088B (zh) | 一种环保耐寒耐腐蚀硅烷交联软聚氯乙烯电缆料 | |
| CN103524847B (zh) | 一种硅烷交联聚乙烯电缆料及其制备方法 | |
| CN103524842B (zh) | 一种柔软环保聚烯烃电缆料 | |
| CN103524939B (zh) | 一种耐寒耐油阻燃聚氯乙烯电缆料 | |
| CN103524867B (zh) | 一种光伏电缆用辐照交联型低烟无卤阻燃聚烯烃电缆料 | |
| CN103524846B (zh) | 一种耐温125℃无卤阻燃聚烯烃电缆料 | |
| CN103524820B (zh) | 一种柔软型无卤阻燃电缆料及其制备方法 | |
| CN103524932B (zh) | 一种雾面阻燃聚氯乙烯电线电缆料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Fu Yonghai Inventor before: He Chenglong Inventor before: He Yuan |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20171225 Address after: 236800 Anhui Bozhou City Qiaocheng Xintiandi WAL-MART International Shopping Plaza, Bozhou Qiaocheng District, Guangming Road, Anhui Patentee after: Bozhou Jingxing Network Technology Co. Ltd. Address before: 241002 Zhanghe Road, Yijiang District, Wuhu City, Anhui Province, hi tech Industrial Development Zone, No. 15 Patentee before: Wuhu Aerospace Special Cable Factory |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180117 Address after: Jiang Yi Cun Jiang Yi Da Dao Dong Si Road No. 8, one of the 528000 in Guangdong province Foshan city Shunde District Leliu Patentee after: Foshan Shunde District Jie Xin Tong Plastics Technology Co., Ltd. Address before: 236800 Anhui Bozhou City Qiaocheng Xintiandi WAL-MART International Shopping Plaza, Bozhou Qiaocheng District, Guangming Road, Anhui Patentee before: Bozhou Jingxing Network Technology Co. Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160413 Termination date: 20180930 |