CN103524836A - Antimicrobial heat-conducting plastic - Google Patents

Antimicrobial heat-conducting plastic Download PDF

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Publication number
CN103524836A
CN103524836A CN201310440919.8A CN201310440919A CN103524836A CN 103524836 A CN103524836 A CN 103524836A CN 201310440919 A CN201310440919 A CN 201310440919A CN 103524836 A CN103524836 A CN 103524836A
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CN
China
Prior art keywords
mass parts
parts
plastic
heat
conducting plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201310440919.8A
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Chinese (zh)
Inventor
肖伟荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wujiang Tianyuan Plastic Co Ltd
Original Assignee
Wujiang Tianyuan Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wujiang Tianyuan Plastic Co Ltd filed Critical Wujiang Tianyuan Plastic Co Ltd
Priority to CN201310440919.8A priority Critical patent/CN103524836A/en
Publication of CN103524836A publication Critical patent/CN103524836A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an antimicrobial heat-conducting plastic which is prepared from the following components in parts by weight: 160-165 parts of HDPE (high-density polyethylene), 20-25 parts of formaldehyde, 10 parts of aluminum hydroxide, 10-15 parts of chlorinated paraffin wax, 10-15 parts of triethylenetetramine, 10-13 parts of zirconia, 10 parts of methanol and 10 parts of industrial grade dicumyl peroxide. The HDPE antimicrobial plastic has favorable antimicrobial function, and can obviously have an antibacterial action with lower consumption; the mechanical strength of the plastic is not influenced, and especially the heat-deformation temperature, mechanical temperature and electrical insulation properties of the plastic product are not lowered; and meanwhile, the antimicrobial heat-conducting plastic has favorable compatibility with resins, and does not migrate, precipitate or be extracted in the plastic product.

Description

A kind of antibiotic heat-conducting plastic
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of antibiotic heat-conducting plastic.
Technical background
Along with the raising day by day of social development and progress and living standard, people are more and more higher to the requirement of life, Working environment, especially hygienic condition.Because plastics have the advantages such as light weight, not corrosion, good insulating, so a lot of links of producing at household electrical appliances will be used plastics.But in daily life, quite a few unwanted bacteria is exist and breed on the surface of plastics, such as: phone, washing machine, computer, refrigerator, electric switch etc., and cause various diseases by contacting; Therefore in life, people inevitably will touch the microorganisms such as each bacterioid, mould, all can become bacterial contamination source and pathophoresis source.But along with the continuous enhancing of people to healthy and environmental consciousness, the demand of " antibacterial, sterilization " has been proposed to contacting plastic components frequently in daily life, this just require we live in the various plastic prods of use there is the effect of antibacterial and mouldproof.Household electrical appliances have a good application prospect with antibiotic plastic, along with the formal appearance of relative national standards GB21551.2-2010 " antibiotic, the degerming of family expenses and similar applications electrical equipment, the particular requirement of purification function anti-biotic material ", antibiotic plastic also will be more wide in the prospect of household electrical appliances market.
Simultaneously in order to adapt to different Working environments and user demand, thus can be to the plastics property improved performance, and and the plastics only with single function are in the more and more fierce market of competition now, more and more out inferior position.So need to carry out modification to plastics, make it there is a more than specific character, thereby strengthen the competitive power in market.
The integrated level of electronic circuit is more and more higher, and the gathering of heat is also more and more.Gathering of heat causes device temperature to raise, and job stability reduces.Therefore, its material requirements is had to high thermal conductivity, so that heat conducts rapidly.Yet, yet the heat-conducting plastic using in electronic product is on the market because the base material adopting mostly is non-high-temperature resistant material, causes the thermal conductivity of its worth product not high.
Summary of the invention
For above shortcomings in prior art, the object of the invention is to provide a kind of antibiotic heat-conducting plastic.
The object of the invention is to be achieved through the following technical solutions: a kind of antibiotic heat-conducting plastic, is comprised of following weight parts component: the dicumyl peroxide of 160-165 mass parts HDPE, 20-25 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 10-15 mass parts clorafin, 10-15 mass parts triethylene tetramine, 10-13 mass parts zirconium white, 10 mass parts methyl alcohol and 10 mass parts technical grades.
A heat-conducting plastic, is comprised of following weight parts component: the dicumyl peroxide of 160 mass parts HDPE, 21 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 12 mass parts clorafins, 14 mass parts triethylene tetramines, 11 mass parts zirconium whites, 10 mass parts methyl alcohol and 10 mass parts technical grades.
A heat-conducting plastic, is comprised of following weight parts component: the dicumyl peroxide of 165 mass parts HDPE, 21 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 15 mass parts clorafins, 11 mass parts triethylene tetramines, 13 mass parts zirconium whites, 10 mass parts methyl alcohol and 10 mass parts technical grades.
The beneficial effect that the present invention has: the plastics that the present invention makes have good heat conduction and antibacterial; And do not affect the physical strength of plastics; With the consistency of resin, to get well, in plastics, do not move, do not separate out, be not extracted simultaneously.
Embodiment
embodiment 1
The preparation of antibiotic heat-conducting plastic: the dicumyl peroxide of 160-165 mass parts HDPE, 20-25 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 10-15 mass parts clorafin, 10-15 mass parts triethylene tetramine, 10-13 mass parts zirconium white, 10 mass parts methyl alcohol and 10 mass parts technical grades is mixed and puts into stirrer, after stirring, through conventional banburying, open refining; Then by opening mixture after refining through granulator granulation, obtain particle, particle is put into tank cooling, then dry at normal temperatures; The salient features of the material that the present embodiment is prepared is as follows: tensile strength MPa(GB/T1040-2006): 35-37, elongation at break %(GB/T 1040-2006): 15-16; Shock strength kJ/m 2(GB/T1043-2008): 3-4; Flexural strength MPa(GB/T9341-2000): 45-46; Oxygen index % (GB/T2406-1993): 39-41; Vertical combustion rank UL-94: V0.The germ resistance of antibiotic plastic of the present invention is more excellent, and preparation technology is simple, and product cost is low, and the over-all properties of product is more excellent.
embodiment 2
The preparation of antibiotic heat-conducting plastic: the dicumyl peroxide of 160 mass parts HDPE, 21 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 12 mass parts clorafins, 14 mass parts triethylene tetramines, 11 mass parts zirconium whites, 10 mass parts methyl alcohol and 10 mass parts technical grades is mixed and puts into stirrer, after stirring, through conventional banburying, open refining; Then by opening mixture after refining through granulator granulation, obtain particle, particle is put into tank cooling, then dry at normal temperatures.
embodiment 3
The preparation of antibiotic heat-conducting plastic: the dicumyl peroxide of 165 mass parts HDPE, 21 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 15 mass parts clorafins, 11 mass parts triethylene tetramines, 13 mass parts zirconium whites, 10 mass parts methyl alcohol and 10 mass parts technical grades is mixed and puts into stirrer, after stirring, through conventional banburying, open refining; Then by opening mixture after refining through granulator granulation, obtain particle, particle is put into tank cooling, then dry at normal temperatures.

Claims (3)

1. an antibiotic heat-conducting plastic, is characterized in that being comprised of following weight parts component: the dicumyl peroxide of 160-165 mass parts HDPE, 20-25 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 10-15 mass parts clorafin, 10-15 mass parts triethylene tetramine, 10-13 mass parts zirconium white, 10 mass parts methyl alcohol and 10 mass parts technical grades.
2. a kind of antibiotic heat-conducting plastic according to claim 1, is characterized in that being comprised of following weight parts component: the dicumyl peroxide of 160 mass parts HDPE, 21 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 12 mass parts clorafins, 14 mass parts triethylene tetramines, 11 mass parts zirconium whites, 10 mass parts methyl alcohol and 10 mass parts technical grades.
3. a kind of antibiotic heat-conducting plastic according to claim 1, is characterized in that being comprised of following weight parts component: the dicumyl peroxide of 165 mass parts HDPE, 21 mass parts formaldehyde, 10 mass parts aluminium hydroxides, 15 mass parts clorafins, 11 mass parts triethylene tetramines, 13 mass parts zirconium whites, 10 mass parts methyl alcohol and 10 mass parts technical grades.
CN201310440919.8A 2013-09-25 2013-09-25 Antimicrobial heat-conducting plastic Withdrawn CN103524836A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310440919.8A CN103524836A (en) 2013-09-25 2013-09-25 Antimicrobial heat-conducting plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310440919.8A CN103524836A (en) 2013-09-25 2013-09-25 Antimicrobial heat-conducting plastic

Publications (1)

Publication Number Publication Date
CN103524836A true CN103524836A (en) 2014-01-22

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Family Applications (1)

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CN201310440919.8A Withdrawn CN103524836A (en) 2013-09-25 2013-09-25 Antimicrobial heat-conducting plastic

Country Status (1)

Country Link
CN (1) CN103524836A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1246495A (en) * 1998-09-01 2000-03-08 四川联合大学 High-density polyethylene based composition with high thermal conductivity
WO2006008240A1 (en) * 2004-07-16 2006-01-26 Ciba Specialty Chemicals Holding Inc. Porous inorganic materials containing polymer additives
CN102174229A (en) * 2011-03-28 2011-09-07 上海大学 Method for preparing antibacterial plastic product from nano-antibacterial powder taking talcum powder as carrier
CN102311568A (en) * 2011-04-27 2012-01-11 深圳市科聚新材料有限公司 Heat-conducting high density polyethylene composite material and preparation method as well as application thereof
CN103059380A (en) * 2013-01-06 2013-04-24 上海秋橙新材料科技有限公司 Antibacterial hdpe plastic

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1246495A (en) * 1998-09-01 2000-03-08 四川联合大学 High-density polyethylene based composition with high thermal conductivity
WO2006008240A1 (en) * 2004-07-16 2006-01-26 Ciba Specialty Chemicals Holding Inc. Porous inorganic materials containing polymer additives
CN102174229A (en) * 2011-03-28 2011-09-07 上海大学 Method for preparing antibacterial plastic product from nano-antibacterial powder taking talcum powder as carrier
CN102311568A (en) * 2011-04-27 2012-01-11 深圳市科聚新材料有限公司 Heat-conducting high density polyethylene composite material and preparation method as well as application thereof
CN103059380A (en) * 2013-01-06 2013-04-24 上海秋橙新材料科技有限公司 Antibacterial hdpe plastic

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Application publication date: 20140122