CN103499889A - Auto-dimming spectacles and manufacturing method thereof - Google Patents
Auto-dimming spectacles and manufacturing method thereof Download PDFInfo
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Abstract
The invention discloses an auto-dimming spectacles and a manufacturing method thereof. The auto-dimming spectacles are characterized by being formed by stacking a photochromic layer, an anti-ultraviolet layer I, a substrate I, a transparent electrode layer I, a vertical alignment layer I, a dye liquid crystal layer, a vertical alignment layer II, a transparent electrode layer II, a substrate II and an anti-ultraviolet layer II sequentially from the front surface to a spectacles body, two or more spacing materials are arranged in the dye liquid crystal layer, planes of the substrate I and the substrate II are in matched fit with patterns on the transparent electrode layer I and the transparent electrode layer II, the substrate I, the substrate II, sealing mouths and sealing rings form a liquid crystal box, and the sealing mouths and the sealing rings are arranged around the dye liquid crystal layer. By optimized combination of photochromism and dye liquid crystals, dimming range of the auto-dimming spectacles is expanded; by processing of the liquid crystal layer different in thickness, continuous contract and brightness change under single voltage are realized; when the auto-dimming spectacles are worn in various environments with high light in daytime and with dark light in nighttime, visual experience is improved substantially.
Description
Technical field
The present invention relates to automatic anti-glare glasses and manufacture method thereof.
Background technology
Along with scientific and technological progress, various photochromic and electrochromic glasses are articles for use indispensable in daily life, the experience that the live and work that various safety goggles are people brings safety and comfort.Particularly the automatic anti-glare glasses have than common sunglasses and have more excellent performance.The principle of car steering safety goggles, welding glasses or automobile sunshading board with an automatic light meter is all that electricity causes light modulation the acute variation of environment light intensity or spectrum is modulated to the scope that human eye is comfortable.
It is long-standing that electricity causes automatic anti-glare glasses developing history, since the seventies in last century, shows the industry starting, and the automatic anti-glare glasses scheme that just has many utilizations to be similar to the display light modulation proposes.Due to the restriction of device optical modulation performance, the application of automatic anti-glare glasses is not smooth.Through the development of nearly about 30 years, the automatic anti-glare glasses just really welcome practical commodity.Practical application the earliest is welding glasses or the face shield of the anti-arc light of electric welding industry, is then the 3D glasses of stereo display, then is the automatic anti-glare glasses afterwards.From the maturation analysis of these projects, its technology overall background is the raising of the maturation of liquid crystal display device, particularly response speed.
Along with large-scale 3D glasses suitability for industrialized production, make liquid crystal glasses all slowly be accepted by people from outward appearance, weight and comfortable wearing degree aspect.Very natural abblendbar liquid crystal glasses enters the people visual field again.For improving the photic blind problem of aviation safety, wearing the automatic anti-glare glasses is one of solutions.The pilot is the meeting temporary blindness after strong illumination, photic blind effect that Here it is.Main technical requirements to the automatic anti-glare glasses is that (1) guarantees flight safety, and state when material does not power up is bright state; (2) bright state will reach 55% transmitance; (3) more than contrast requires 3:1; (4) imaging clearly, aberration is little; (5) use plastic base, also have many other requirements not enumerate at this.Finally the result of demonstration is exactly to use vertical orientated dye liquid crystal, has negated electrochromism, with the liquid crystal display mode of polaroid.Here it is our vertical orientated dye liquid crystal of anti-glare vehicle rearview mirror of knowing.The automatic anti-glare glasses, also have very important application prospect at military aspect simultaneously, be also to solve photic blind problem, and as laser weapon, or the high brightness high light of blast etc.
Desirable automatic anti-glare glasses are that pellucidity approaches 100%, and closed condition is light tight approaches 0, and response speed is along with the variation of surround lighting approaches Millisecond, but current technology is difficult to realize.The technical merit that existing invention reaches, because eyeglass can't turn-off or transparent along with environmental change reach desirable the transmitance of light, under bright state environment, as sunburst, when the automatic anti-glare glasses have good anti-dazzle effect, under the dim light such as the street lamp at night, because the transparency deficiency can't provide enough transmitances on the contrary, easily for action or driving, cause danger, or wear and experience bad; Otherwise under dark state environment, when the automatic anti-glare glasses have good transparency, owing to turn-offing, effect is bad can't provide enough anti-dazzle effects on the contrary, easily for eyes, damages, or wears and experience bad.Therefore, how to provide a kind of eyeglass that automatically changes transmitance along with strong and weak variation of ambient light that has, the intensity that can hang down light in high light decline, to maintain euphorosia, more can provide high permeability under dim light, has become one of important topic.CN101419301A, realize the change of above-mentioned characteristic by changing photochromic material.The invention of CN1641457A and CN101334566A provides a kind of electrochromism to solve the scheme of electrochromism membrane lifetime.CN85202443U provides a kind of liquid crystal electron shading eyeglasses.Similarly invention has a lot, at this, does not enumerate.Electrochromism subject matter is that power consumption is large, can't, as battery powered automatic anti-glare glasses, be difficult to application in automatic anti-glare glasses scheme.
Photochromic glasses are well known, and glasses obtain application widely in daily life.Although its light intensity can change along with light intensity, its subject matter is:, under certain light intensity, variable color intensity is fixed (1); (2) insensitive to some wavelength; (3) variable color needs a threshold light flux.
In sum, these inventions all can't solve surround lighting generation acute variation, as sunshine direct projection on daytime, under the night street lighting, under the service condition of thousands of times of variations of light intensity, how to realize the abblendbar problem.Photochromic lens can solve the requirement of shelter of high light to glasses, but to a little less than the dazzling light protective action.Because dazzling light is the visual experience that relative light intensity changes, the dazzling light absolute light flux under dim environment is smaller, is not enough to make fast the photochromic lens variable color.Liquid crystal automatic anti-glare glasses, two kinds of minute polarisation class and non-polarisation classes, the automatic anti-glare glasses of polarisation class relatively are applicable to the high light environment on daytime, and dark state is darker, and bright state is darker, and non-polarisation class is applicable to wearing night, and dark state is not dark, and bright state is brighter.Polaroid glasses, owing to filtering an optical component, easily produce spinning sensation.
Summary of the invention
According to the technical matters of above-mentioned proposition, and provide a kind of automatic anti-glare glasses and manufacture method thereof.Mainly there is huge room for improvement in the present invention in view of above-mentioned existing automatic anti-glare glasses, the multi-field practical experience manufactured and designed based on being engaged in relevant this series products and the professional knowledge of physicochemical optics, and cooperation manufacturing practice, expectation can be improved many limitation of existing of automatic anti-glare glasses, make the wearer there is more convenient and more comfortable impression.And by new method, inherit the advantage of existing automatic anti-glare glasses, manufacture can be when surround lighting generation acute variation, realize anti-glare under bright especially and dark especially state, really solve same secondary automatic anti-glare glasses, strong sunshine by day and the car bulb at night can be realized the effect of automatic anti-glare, it is strong that the automatic anti-glare glasses have anti-drop ability simultaneously, long service life, safe, light intensity sees through the characteristics such as the continuous variation in zone.By photochromic material, the ultraviolet ray in environment and short wavelength are absorbed the chemical characteristic of variable color, utilize the physical characteristics of vertical orientation dye liquid crystal electrooptical effect of active adjustment light transmission rate under extra electric field is controlled simultaneously, make glasses and build visual environment controlled, differentiation.
The technological means that the present invention adopts is as follows:
A kind of automatic anti-glare glasses is characterized in that: the order from the front surface to glasses is formed by stacking by photochromatic layer, anti-ultraviolet layer I, substrate I, the transparent electrode layer I, vertical alignment layer I, dye solution crystal layer, vertical alignment layer II, transparent electrode layer II, substrate II and the anti-ultraviolet layer II that are attached on described substrate I successively; Be provided with two or more interval insulant in described dye solution crystal layer, the laminating that is complementary of pattern on the plane of described substrate I and described substrate II and described transparent electrode layer I and described transparent electrode layer II, described substrate I and described substrate II form liquid crystal cell with the sealing that is arranged on described dye solution crystal layer surrounding and O-ring seal.
The laminating that is complementary of pattern on above-mentioned substrate I and the plane of substrate II and described transparent electrode layer I and described transparent electrode layer II, refer to fit with different interval according to the pattern of transparent electrode layer in the plane of substrate, realizes slitless connection, sealing; Use the dye solution crystal layer of different-thickness between two substrates, the zone that produces different transmitances, under single voltage effect, forming required contrast can regulate continuously.
Above-mentioned vertical alignment layer I and vertical alignment layer II are separated on the transparent electrode layer I and transparent electrode layer II be attached to respectively on substrate I and substrate II by the dye solution crystal layer.
As preferably, described photochromatic layer is made by the inorganic material with redox reaction or high-molecular organic material, and its effect is light modulation under bright state condition, under dark state condition, does not change.Available inorganic material has a variety of, as tungsten oxide, molybdena, titanium dioxide, calcium iodide and mercuric iodixde mixed crystal, cupric chloride, silver chloride, silver bromide etc.Available high-molecular organic material also has a variety of, as spiro-pyrans, fulgide, diarylethene, hexa-aryl bi-imidazole etc.
As preferably, the size of described interval insulant is controlled by the zone colour developing depth; The regional shallow interval insulant size that develops the color of the interval insulant size ratio that zone is developed the color dark is large.
As preferably, described substrate I and described substrate II are the glass substrate that plastic base or thickness are less than 0.1mm.
The invention also discloses a kind of manufacture method of above-mentioned automatic anti-glare glasses, it is characterized in that: the interval insulant arranged in described dye solution crystal layer is that gradation or repeatedly spray forms or exposure imaging forms;
Described gradation or repeatedly spray to form comprises the steps:
1. select the hollow out figure that scavenging material is made and described interval insulant is complementary of any surface finish, when the hollow out graphics shape is different, the interval insulant of every kind of size is made a figure;
2. the hollow out figure of different size will have the above overlapping region of 0.1mm;
3. the spraying density of the hollow out figure of different size and the diameter of described interval insulant are directly proportional;
4. after O-ring seal and sealing and described dye liquid crystal laminating being closed, by the pressurization of air bag limit or UV-irradiation or be heating and curing and get final product;
Described gradation or multiexposure, multiple exposure develop to form and comprise the steps:
1. make two or multiple masks;
2. apply the photoetching interval insulant;
3. expose, develop, solidify;
4. repeating step 2., 3. after, after O-ring seal and sealing and described dye liquid crystal laminating are closed, by the pressurization of air bag limit or UV-irradiation or be heating and curing and get final product.
As preferably, in gradation or in repeatedly spraying forming process, it is white steel or acrylic that step is selected the material of making the hollow out figure in 1..
As preferably, in gradation or in repeatedly spraying forming process, the spraying density of step in 3. is 100/mm
2above, in this step, need to change the hollow out figure also repeatedly.
Add man-hour, the technological process of the manufacture method between substrate I and substrate II and common TN and stn liquid crystal display is basic identical, the key distinction just is to increase the manufacture process of zones of different different-thickness dyeing liquor crystal layer, improve the adaptive faculty of automatic anti-glare glasses to surround lighting, adjust visual effect.
Than prior art, compare, the photochromatic layer of automatic anti-glare glasses of the present invention and dye solution crystal layer are respectively photochromic light modulation effect and electric-controlled light-regulating effect to light, have expanded the dimming scope of automatic anti-glare glasses.In addition, in the manufacture method of automatic anti-glare glasses, use the dye solution crystal layer of different-thickness between two substrates, the zone that produces different transmitances, under single voltage effect, forming required contrast can regulate continuously.No matter the automatic anti-glare glasses of this kind of structure, adopt ultra-thin glass substrate or flexible plastic substrates can realize the glasses of anti-drop impact, light weight.
The present invention is by the optimal combination design of photochromic and dye liquid crystal, expanded the dimming scope of automatic anti-glare glasses, and by the processing of different-thickness liquid crystal layer, obtained under single voltage, contrast and brightness change continuously, while wearing under high light and the multiple environment of half-light at night by day, visual experience obtains significantly and promotes.Under the environment of light, the light intensity setting range of 2.5%-25%, under the environment of half-light, the light intensity setting range of 10%-70%.Meet when surround lighting generation acute variation, incandescent and extremely dark state, realize automatic anti-glare.
The present invention has long service life and safe characteristics, under strong sunshine by day of same secondary automatic anti-glare glasses or the car bulb at night, can realize automatic anti-glare.
The accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation.
Fig. 1 is structural principle schematic diagram of the present invention.
Fig. 2 is the schematic diagram of the dye solution crystal layer that in the middle of a kind of color, dark edge is light.
In figure: 1, photochromatic layer 2, anti-ultraviolet layer I 3, substrate I 4, transparent electrode layer I 5, vertical alignment layer I 6, dye solution crystal layer 7, interval insulant I 8, interval insulant II 9, vertical alignment layer II 10, transparent electrode layer II 11, substrate II 12, anti-ultraviolet layer II 13, seal 14, O-ring seal.
Embodiment
A kind of automatic anti-glare glasses (as shown in Figure 1), the order from the front surface to glasses is formed by stacking by photochromatic layer 1, anti-ultraviolet layer I 2, substrate I 3, the transparent electrode layer I 4, vertical alignment layer I 5, dye solution crystal layer 6, vertical alignment layer II 9, transparent electrode layer II 10, substrate II 11 and the anti-ultraviolet layer II 12 that are attached on described substrate I 3 successively; Be provided with two kinds of interval insulants (as shown in Figure 2) in described dye solution crystal layer 6, be respectively interval insulant I 7 and interval insulant II 8, the laminating that is complementary of pattern on the plane of described substrate I 3 and described substrate II 11 and described transparent electrode layer I 4 and described transparent electrode layer II 10, described substrate I 3 and described substrate II 11 form liquid crystal cells with the sealing 13 that is arranged on described dye solution crystal layer 6 surroundings and O-ring seal 14.Wherein, described photochromatic layer 1 is selected the organic photochromic material hexa-aryl bi-imidazole; Described vertical alignment layer I 5 and described vertical alignment layer II 9 are used the chemical SE4811 of daily output; Described interval insulant I 7 is used long-pending hydrochemical SP2060, and described interval insulant II 8 is used long-pending hydrochemical SP2040; Described substrate I 3 and described substrate II 11 are selected the glass substrate that the thickness of Asahi Glass is 0.1mm.
Add man-hour, dye solution crystal layer 6 is used the dye liquid crystal of vertical orientations, and dyestuff is the positivity dyestuff, and liquid crystal is negative liquid crystal, and other kind liquid crystal phase ratio, its have higher contrast and zero point field transmitance.The technological process of the manufacture method between described substrate I 3 and described substrate II 11 and common TN and stn liquid crystal display is basic identical, the key distinction is to increase the manufacture process of the dye solution crystal layer 6 of zones of different different-thickness, dye solution crystal layer 6 improves the adaptive faculty of automatic anti-glare glasses to surround lighting, adjusts visual effect.
The interval insulant arranged in described dye solution crystal layer 6 is gradation or repeatedly sprays formation or exposure imaging formation; With gradation or repeatedly spray and form example, mainly comprise the steps:
Select the white steel of scavenging material of any surface finish, annular and circular hollow out figure that making and described interval insulant are complementary, interval insulant I 7 is used annular hollow out graph shealtering, is sprayed; Interval insulant II 8 is used circular pattern to block, and is sprayed.More than two kinds of overlapping 0.1mm of dimension of picture, overlapping region is by the spraying determining positions of interval insulant.The spraying density of the hollow out figure of different size and the diameter of described interval insulant are directly proportional; Spraying density is 100/mm
2above, in this step, need to change the hollow out figure also repeatedly.By after O-ring seal 14 and sealing 13 and described dye solution crystal layer 6 laminatings, by the pressurization of air bag limit or UV-irradiation or be heating and curing and get final product;
The molding process process of the manufacture method between described substrate I 3 and described substrate II 11 and common TN and stn liquid crystal display is basic identical, for better understanding the present invention, now is summarized as follows:
Vertical alignment layer I 5 and vertical alignment layer II 9 be through 220 ± 10 ℃ of pyroprocessing, the even rete that the thickness after pyroprocessing is 1000 dusts.
Described O-ring seal 14 frame portion heat-curable glue, the diameter of the interval insulant adulterated in the O-ring seal frame is the rigid interval insulant of 4 μ m.Use the method for serigraphy, form pattern.
The manufacture method of the liquid crystal cell be comprised of substrate I 3 to substrate II 11 and sealing and O-ring seal is as follows: the cleaning of substrate I 3 and substrate II 11 with dry, substrate I 3 and the surperficial resist coating of substrate II 11 and be heating and curing, utilize mask exposure, through developing liquid developing, the post bake of heating, etching solution etching, stripper after peeling off development remaining photoresist, prerinse, vertical orientated material coating materials apply, according to the O-ring seal sprocket bit of design, use the method for serigraphy to form O-ring seal 14.Epoxide-resin glue used is XN-5A.After above operation completes, through scratching the operations such as sheet, Liquid crystal pour, ultraviolet sealing, liquid crystal cleaning, proceed to pasting of anti-ultraviolet layer I 2, anti-ultraviolet layer II 12 and photochromatic layer 1.
The liquid crystal cell that the principal feature of method for making of the present invention the has dropping shock power structure of light acute variation automatic anti-glare glasses that can conform, and the dye solution crystal layer of vertically joining that uses different-thickness is to the absorption intensity that changes light.Use the dimming scope that significantly improves the automatic anti-glare glasses in the time of due to photochromatic layer and electrochromic layer.Simultaneously, by using the liquid crystal layer of different-thickness, can continuously change the color of automatic anti-glare glasses.Under the environment of light, the light intensity setting range of 2.5%-25%, under the environment of half-light, the light intensity setting range of 10%-70%.Meet when surround lighting generation acute variation, incandescent and extremely dark state, realize automatic anti-glare.Same secondary automatic anti-glare glasses, strong sunshine, the car bulb at night on daytime can be realized automatic anti-glare.
The above; it is only preferably embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to replacement or changed according to technical scheme of the present invention and inventive concept thereof, within all should being encompassed in protection scope of the present invention.
Claims (7)
1. automatic anti-glare glasses is characterized in that: the order from the front surface to glasses is formed by stacking by photochromatic layer (1), anti-ultraviolet layer I (2), substrate I (3), the transparent electrode layer I (4), vertical alignment layer I (5), dye solution crystal layer (6), vertical alignment layer II (9), transparent electrode layer II (10), substrate II (11) and the anti-ultraviolet layer II (12) that are attached on described substrate I (3) successively; Be provided with two or more interval insulant in described dye solution crystal layer (6), the laminating that is complementary of pattern on the plane of described substrate I (3) and described substrate II (11) and described transparent electrode layer I (4) and described transparent electrode layer II (10), described substrate I (3) and described substrate II (11) and the sealing (13) that is arranged on described dye solution crystal layer (6) surrounding and O-ring seal (14) composition liquid crystal cell.
2. automatic anti-glare glasses according to claim 1, it is characterized in that: described photochromatic layer (1) is made by the inorganic material with redox reaction or high-molecular organic material.
3. automatic anti-glare glasses according to claim 1 is characterized in that: the size of described interval insulant is controlled by the zone colour developing depth; The regional shallow interval insulant size that develops the color of the interval insulant size ratio that zone is developed the color dark is large.
4. automatic anti-glare glasses according to claim 1 is characterized in that: described substrate I (3) and described substrate II (11) are less than the glass substrate of 0.1mm for plastic base or thickness.
5. the manufacture method of automatic anti-glare glasses as claimed in claim 1 is characterized in that: the interval insulant arranged in described dye solution crystal layer (6) is that gradation or repeatedly spray forms or exposure imaging forms;
Described gradation or repeatedly spray to form comprises the steps:
1. select the hollow out figure that scavenging material is made and described interval insulant is complementary of any surface finish, when the hollow out graphics shape is different, the interval insulant of every kind of size is made a figure;
2. the hollow out figure of different size will have the above overlapping region of 0.1mm;
3. the spraying density of the hollow out figure of different size and the diameter of described interval insulant are directly proportional;
4. by after O-ring seal (14) and the laminating of sealing (13) and described dye solution crystal layer (6), by the pressurization of air bag limit or UV-irradiation or be heating and curing and get final product;
Described gradation or multiexposure, multiple exposure develop to form and comprise the steps:
1. make two or multiple masks;
2. apply the photoetching interval insulant;
3. expose, develop, solidify;
4. repeating step 2., 3. after, by after O-ring seal (14) and the laminating of sealing (13) and described dye solution crystal layer (6), by the pressurization of air bag limit or UV-irradiation or be heating and curing and get final product.
6. manufacture method according to claim 5 is characterized in that: in gradation or in repeatedly spraying forming process, it is white steel or acrylic that step is selected the material of making the hollow out figure in 1..
7. manufacture method according to claim 5 is characterized in that: in gradation or in repeatedly spraying forming process, the spraying density of step in 3. is 100/mm
2above, in this step, need to change the hollow out figure also repeatedly.
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| CN201310482674.5A CN103499889B (en) | 2013-10-15 | 2013-10-15 | A kind of automatic anti-glare glasses and manufacture method thereof |
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| CN201310482674.5A CN103499889B (en) | 2013-10-15 | 2013-10-15 | A kind of automatic anti-glare glasses and manufacture method thereof |
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| CN103499889B CN103499889B (en) | 2016-01-13 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104267532A (en) * | 2014-10-21 | 2015-01-07 | 京东方科技集团股份有限公司 | Display panel, manufacturing method thereof and display device |
| CN104586571A (en) * | 2014-06-26 | 2015-05-06 | 宁波吉欧光电科技有限公司 | Processing technology for electric welding helmet capable of adjusting angle of LCD incident rays in intelligent sensing mode |
| CN104586572A (en) * | 2014-06-26 | 2015-05-06 | 宁波吉欧光电科技有限公司 | Method for treating liquid crystal display light changing welding mask with incident light angle capable of being manually selected |
| CN104586573A (en) * | 2014-06-26 | 2015-05-06 | 宁波吉欧光电科技有限公司 | Machining method of automatic changing-light welding mask with adjustable incident ray angle |
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| CN109324427A (en) * | 2018-11-14 | 2019-02-12 | 江西合力泰科技有限公司 | A kind of production method of anti-blue light automatic light-adjusting glasses |
| CN110128937A (en) * | 2019-04-23 | 2019-08-16 | 安徽五岳松纳米技术有限公司 | A kind of efficiency light mutagenesis color protective coating |
| CN111587396A (en) * | 2018-02-09 | 2020-08-25 | 三井化学株式会社 | Lens and method for manufacturing lens |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1112686A (en) * | 1993-12-06 | 1995-11-29 | 卡西欧计算机公司 | Liquid crystal display device and process for producing same |
| CN1271108A (en) * | 1999-04-21 | 2000-10-25 | 株式会社日本触媒 | Spacer of liquid crystal displayer and its producing method and liquid crystal displayer |
| CN101446693A (en) * | 2008-10-31 | 2009-06-03 | 镇江万新光学眼镜有限公司 | Gradual change photochromic and electrochromic polarized spectacle lens and production method thereof |
| CN101738777A (en) * | 2010-01-11 | 2010-06-16 | 大连东方科脉电子有限公司 | Dye liquid crystal anti-glare vehicle rearview mirror |
| CN101957521A (en) * | 2010-08-12 | 2011-01-26 | 大连东方科脉电子有限公司 | High-contrast liquid crystal electronic paper displayer and manufacturing method thereof |
| CN102331643A (en) * | 2011-06-14 | 2012-01-25 | 大连东方科脉电子有限公司 | Single-polarizer liquid crystal dimming automotive rearview mirror |
| CN102897093A (en) * | 2012-10-13 | 2013-01-30 | 江苏和成显示科技股份有限公司 | Adjustable dye liquid crystal automobile rearview mirror |
| CN203480145U (en) * | 2013-10-15 | 2014-03-12 | 大连东方科脉电子有限公司 | Automatic anti-dazzling glasses |
-
2013
- 2013-10-15 CN CN201310482674.5A patent/CN103499889B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1112686A (en) * | 1993-12-06 | 1995-11-29 | 卡西欧计算机公司 | Liquid crystal display device and process for producing same |
| CN1271108A (en) * | 1999-04-21 | 2000-10-25 | 株式会社日本触媒 | Spacer of liquid crystal displayer and its producing method and liquid crystal displayer |
| CN101446693A (en) * | 2008-10-31 | 2009-06-03 | 镇江万新光学眼镜有限公司 | Gradual change photochromic and electrochromic polarized spectacle lens and production method thereof |
| CN101738777A (en) * | 2010-01-11 | 2010-06-16 | 大连东方科脉电子有限公司 | Dye liquid crystal anti-glare vehicle rearview mirror |
| CN101957521A (en) * | 2010-08-12 | 2011-01-26 | 大连东方科脉电子有限公司 | High-contrast liquid crystal electronic paper displayer and manufacturing method thereof |
| CN102331643A (en) * | 2011-06-14 | 2012-01-25 | 大连东方科脉电子有限公司 | Single-polarizer liquid crystal dimming automotive rearview mirror |
| CN102897093A (en) * | 2012-10-13 | 2013-01-30 | 江苏和成显示科技股份有限公司 | Adjustable dye liquid crystal automobile rearview mirror |
| CN203480145U (en) * | 2013-10-15 | 2014-03-12 | 大连东方科脉电子有限公司 | Automatic anti-dazzling glasses |
Cited By (13)
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|---|---|---|---|---|
| CN104586572B (en) * | 2014-06-26 | 2016-03-16 | 宁波吉欧光电科技有限公司 | Manual selection angle of incident light liquid crystal display screen becomes the processing method of photocoagulation face shield |
| CN104586571A (en) * | 2014-06-26 | 2015-05-06 | 宁波吉欧光电科技有限公司 | Processing technology for electric welding helmet capable of adjusting angle of LCD incident rays in intelligent sensing mode |
| CN104586572A (en) * | 2014-06-26 | 2015-05-06 | 宁波吉欧光电科技有限公司 | Method for treating liquid crystal display light changing welding mask with incident light angle capable of being manually selected |
| CN104586573A (en) * | 2014-06-26 | 2015-05-06 | 宁波吉欧光电科技有限公司 | Machining method of automatic changing-light welding mask with adjustable incident ray angle |
| CN104586571B (en) * | 2014-06-26 | 2016-03-16 | 宁波吉欧光电科技有限公司 | The processing method of intelligent sensing adjustable liquid crystal display screen angle of incident light electric welder's helmet |
| CN104267532A (en) * | 2014-10-21 | 2015-01-07 | 京东方科技集团股份有限公司 | Display panel, manufacturing method thereof and display device |
| CN105204180A (en) * | 2015-09-23 | 2015-12-30 | 江苏视客光学眼镜有限公司 | Manufacturing method and device of compound eye lens |
| CN105204180B (en) * | 2015-09-23 | 2018-01-26 | 江苏视客光学眼镜有限公司 | The manufacture method and device of compound spectacle glass |
| CN106773126A (en) * | 2017-03-08 | 2017-05-31 | 黄世杰 | A kind of Electrocontrolled color change glasses |
| CN111587396A (en) * | 2018-02-09 | 2020-08-25 | 三井化学株式会社 | Lens and method for manufacturing lens |
| TWI826419B (en) * | 2018-02-09 | 2023-12-21 | 日商三井化學股份有限公司 | Lenses and methods of manufacturing lenses |
| CN109324427A (en) * | 2018-11-14 | 2019-02-12 | 江西合力泰科技有限公司 | A kind of production method of anti-blue light automatic light-adjusting glasses |
| CN110128937A (en) * | 2019-04-23 | 2019-08-16 | 安徽五岳松纳米技术有限公司 | A kind of efficiency light mutagenesis color protective coating |
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