CN103483649A - Bulletproof tire and manufacturing method thereof - Google Patents
Bulletproof tire and manufacturing method thereof Download PDFInfo
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- CN103483649A CN103483649A CN201310423465.3A CN201310423465A CN103483649A CN 103483649 A CN103483649 A CN 103483649A CN 201310423465 A CN201310423465 A CN 201310423465A CN 103483649 A CN103483649 A CN 103483649A
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Abstract
The invention belongs to the field of tires, and particularly relates to a bulletproof tire and a manufacturing method of the bulletproof tire. The bulletproof tire is composed of butadiene styrene rubber, natural rubber, white carbon black, carbon nano tube fibers, ultrafine spring steel wires, nano silicon dioxide, a vulcanizing agent, a vulcanization accelerator, an antioxidant, process oil, zinc oxide and stearic acid. The bulletproof tire produced from the component formula has the advantages of being good in abrasive resistance, puncture resistance, aging resistance and controllability and high in fade resistance, even being punctured by bullets or sharp objects, the tire can still normally operate, and a vehicle can be normally driven.
Description
Technical field
The invention belongs to the tire field, be specifically related to a kind of shoot proof tyre, also relate to the preparation method of above-mentioned shoot proof tyre.
background technology
No matter shoot proof tyre, due to its excellent safety performance, is in military domain or at civil area, all has application very widely.In military domain, concerning military vehicle, due to the region of the travelling battlefield surroundings in the hail of bullets in intricate and wartime, easily suffer nature and artificial destruction, so the safety traffic performance after tire prevent breakage and breakage there is vital impact to the battlefield survival of vehicle.At civil area, although can meeting with bullet hardly, vehicle tyre punctures, but the sharp objects such as iron nail still have significant threat to tire safety, and the damage resistant and piercing through hardly of the various tires on market, this has major hidden danger to driver individual and public safety.
The shoot proof tyre of present stage exploitation, owing to having added a large amount of high density materials such as steel wire, so the tire oeverall quality is larger, not only affects the flexible manipulation of vehicle but also waste energy, therefore, develop a kind of light weight, shoot proof tyre that intensity is high has very important meaning.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of shoot proof tyre composition, and the tire prepared based on this composition can prevent from being punctured by sharp objects such as bullet or iron nails or stinging the gas leakage thoroughly caused.
The present invention also provides the preparation method of above-mentioned tire.
The present invention realizes by following technical scheme:
A kind of shoot proof tyre, tire comprises the component of following portions by weight:
Styrene-butadiene rubber(SBR) 30～60 natural rubbers 20～40
White carbon black 0.5～2 carbon nano-tube fibre 2～12
Ultra-fine spring wire 3～13 nano silicons 1～10
Vulcanizing agent 1～2 vulcanization accelerator 0.5～2
Antioxidant 0.5～2 process oil 2～15
Zinc oxide 1～6 stearic acid 1～2;
Ultra-fine spring wire is the spring wire skeleton of diameter 0.05～0.5mm and the processing of process plucking.
Preferably, shoot proof tyre comprises the component of following parts by weight:
Styrene-butadiene rubber(SBR) 35～50 natural rubbers 25～35
White carbon black 0.8～1.8 carbon nano-tube fibre 2～10
Ultra-fine spring wire 4～12 nano silicons 1～9
Vulcanizing agent 1～2 vulcanization accelerator 0.5～1.8
Antioxidant 0.5～1.8 process oil 2～12
Zinc oxide 1～5 stearic acid 1～1.8.
Shoot proof tyre comprises the component of following parts by weight:
Styrene-butadiene rubber(SBR) 40 natural rubbers 30
White carbon black 1 carbon nano-tube fibre 8
Ultra-fine spring wire 6 nano silicons 6
Vulcanizing agent 1.5 vulcanization accelerators 1.2
Antioxidant 1.2 process oils 8
Zinc oxide 3 stearic acid 1.5.
Above-mentioned shoot proof tyre, carbon nano-tube fibre, adopt the multi-walled carbon nano-tubes fiber;
Vulcanizing agent comprises sulphur, organo-peroxide, at least one in metal oxide;
Vulcanization accelerator comprises Ammonia, amine, Thiourea, Sulfonates, at least one in aldehydes;
Antioxidant comprises amine, imidazoles, at least one in the amine ketone;
Process oil comprises, the fragrant same clan, naphthenic, at least one in paraffin class.
Above-mentioned shoot proof tyre, vulcanizing agent is: sulphur, two-(γ-tri-ethoxy silylpropyl)-tetrasulfide, 1, two (the lemon imide methyl) benzene of 3-, zinc dialkyl dithiophosphate, N, N '-meta-phenylene bismaleimide, two hydration hexa-methylenes-1,6-dithio sulfuric acid disodium salt;
Vulcanization accelerator is: any in accelerator M, vulcanization accelerator TT, accelerator H, accelerator ZDMC, accelerator ZBX, accelerator NA-22, accelerator CZ;
Antioxidant is: hydroquinone type, phosphorous acid ester, paraffin, dibutyl dithiocaarbamate salt, 6,6-oxyethyl group-2,2, the 4-3 methyl isophthalic acid, any in the Resorcinol of 2-dihydroquinoline, replacement, Ursol D class, secondary amine class, phenols, phosphorous acid ester, mantoquita, triazines;
Process oil is: any in aromatic hydrocarbon oil, paraffin oil, naphthene base crude oil.
Above-mentioned shoot proof tyre, vulcanizing agent is: sulphur;
Vulcanization accelerator is: accelerator NA-22;
Antioxidant is: dibutyl dithiocaarbamate salt;
Process oil is: paraffin oil.
The shoot proof tyre its preparation method comprises following step:
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.05～0.5mm and process plucking are processed with diameter;
30～60 parts of styrene-butadiene rubber(SBR), 20～40 parts of natural rubbers, 0.5～2 part of white carbon black, 1～10 part of nano silicon, 1～2 part of vulcanizing agent, 0.5～2 part of vulcanization accelerator, 0.5～2 part of antioxidant, 2～15 parts of process oils, 1～6 part of zinc oxide, 1～2 part of stearic acid are added in kneader by above-mentioned quality proportioning, material is mediated evenly;
Material face refining 5～10min by after mediating, then add 5-20 part pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 2～12 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 1～4mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃～175 ℃, and curing time is 15～30min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 150 ℃～160 ℃, and shaping time is 5～10min, and the shoot proof tyre after heat treatment is finished product after pruning.
Preferably, above-mentioned shoot proof tyre its preparation method comprises following step:
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.1mm and process plucking are processed with diameter;
40 parts of styrene-butadiene rubber(SBR), 30 parts of natural rubbers, 1 part of white carbon black, 5 parts of nano silicons, 1.5 parts of vulcanizing agents, 0.8 part of vulcanization accelerator, 0.8 part of antioxidant, 10 parts of process oils, 3 parts of zinc oxide, 1.5 parts of stearic acid are added in kneader by above-mentioned quality proportioning, material is mediated evenly;
Material face refining 8min by after mediating, then add 10 parts of pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 8 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 3mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃, and curing time is 20min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 155 ℃, and shaping time is 7min, and the shoot proof tyre after heat treatment is finished product after pruning.
Beneficial effect of the present invention is, the advantage such as utilize the shoot proof tyre of above-mentioned composite formula production to there is good wear resistance, anti-ly puncture, ageing-resistant, easily handling and anti-discoloration is strong, even punctured by bullet or sharp objects, tire also can turn round as usual, and vehicle can travel as usual.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
Shoot proof tyre comprises the component of following parts by weight:
Styrene-butadiene rubber(SBR) 40 natural rubbers 30
White carbon black 1 carbon nano-tube fibre 8
Ultra-fine spring wire 6 nano silicons 6
Vulcanizing agent 1.5 vulcanization accelerators 1.2
Antioxidant 1.2 process oils 8
Zinc oxide 3 stearic acid 1.5;
Ultra-fine spring wire is the spring wire skeleton of diameter 0.1 mm and the processing of process plucking.
Embodiment 2
Shoot proof tyre comprises the component of following parts by weight:
Styrene-butadiene rubber(SBR) 30 natural rubbers 20
White carbon black 0.5 carbon nano-tube fibre 2
Ultra-fine spring wire 3 nano silicons 1
Vulcanizing agent 1 vulcanization accelerator 0.5
Antioxidant 0.5 process oil 2
Zinc oxide 1 stearic acid 1;
Ultra-fine spring wire is the spring wire skeleton of diameter 0.05mm and the processing of process plucking.
Embodiment 3
Shoot proof tyre comprises the component of following parts by weight:
Styrene-butadiene rubber(SBR) 60 natural rubbers 40
White carbon black 2 carbon nano-tube fibres 12
Ultra-fine spring wire 13 nano silicons 10
Vulcanizing agent 2 vulcanization accelerators 2
Antioxidant 2 process oils 15
Zinc oxide 6 stearic acid 2;
Ultra-fine spring wire is the spring wire skeleton of diameter 0.15mm and the processing of process plucking.
Embodiment 4
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.1mm and process plucking are processed with diameter;
By 40 parts of styrene-butadiene rubber(SBR), 30 parts of natural rubbers, 1 part of white carbon black, 5 parts of nano silicons, 1.5 parts of vulcanizing agents two-(γ-tri-ethoxy silylpropyl)-tetrasulfide, 0.8 part of vulcanization accelerator TT, 0.8 portion of antioxidant dibutyl dithiocaarbamate salt, 10 parts of aromatic hydrocarbon oil, 3 parts of zinc oxide, 1.5 parts of stearic acid add in kneader by above-mentioned quality proportioning, material mediated evenly;
Material face refining 8min by after mediating, then add 10 parts of pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 8 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 3mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃, and curing time is 20min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 155 ℃, and shaping time is 7min, and the shoot proof tyre after heat treatment is finished product after pruning.
Embodiment 5
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.15mm and process plucking are processed with diameter;
By 35 parts of styrene-butadiene rubber(SBR), 35 parts of natural rubbers, 1.5 parts of white carbon blacks, 5 parts of nano silicons, 1.5 parts of vulcanizing agent N, N '-meta-phenylene bismaleimide, 0.8 part of accelerator H, 0.8 portion of antioxidant dibutyl dithiocaarbamate salt, 10 parts of paraffin oils, 3 parts of zinc oxide, 1.5 parts of stearic acid add in kneader by above-mentioned quality proportioning, and material is mediated evenly;
Material face refining 8min by after mediating, then add 10 parts of pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 7 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 3mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃, and curing time is 20min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 150 ℃, and shaping time is 6min, and the shoot proof tyre after heat treatment is finished product after pruning.
Embodiment 6
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.15mm and process plucking are processed with diameter;
By 50 parts of styrene-butadiene rubber(SBR), 40 parts of natural rubbers, 1.5 parts of white carbon blacks, 10 parts of nano silicons, 2 parts of vulcanizing agent zinc dialkyl dithiophosphates, 2 parts of accelerator ZDMCs, 2 parts of antioxidants 6,6-oxyethyl group-2,2, the 4-3 methyl isophthalic acid, 2-dihydroquinoline, 15 parts of paraffin oils, 6 parts of zinc oxide, 2 parts of stearic acid add in kneader by above-mentioned quality proportioning, and material is mediated evenly;
Material face refining 8min by after mediating, then add 10 parts of pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 7 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 3mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃, and curing time is 20min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 150 ℃, and shaping time is 6min, and the shoot proof tyre after heat treatment is finished product after pruning.
Embodiment 7
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.15mm and process plucking are processed with diameter;
By 30 parts of styrene-butadiene rubber(SBR), 20 parts of natural rubbers, 0.5 part of white carbon black, 2 parts of nano silicons, 1 part of vulcanizing agent zinc dialkyl dithiophosphate, 0.5 part of accelerator ZDMC, 0.5 part of antioxidant 6,6-oxyethyl group-2,2, the 4-3 methyl isophthalic acid, 2-dihydroquinoline, 2 parts of paraffin oils, 1 part of zinc oxide, 1 part of stearic acid add in kneader by above-mentioned quality proportioning, and material is mediated evenly;
Material face refining 8min by after mediating, then add 10 parts of pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 7 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 3mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃, and curing time is 20min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 150 ℃, and shaping time is 6min, and the shoot proof tyre after heat treatment is finished product after pruning.
Claims (8)
1. a shoot proof tyre, is characterized in that, described tire comprises the component of following portions by weight:
Styrene-butadiene rubber(SBR) 30～60 natural rubbers 20～40
White carbon black 0.5～2 carbon nano-tube fibre 2～12
Ultra-fine spring wire 3～13 nano silicons 1～10
Vulcanizing agent 1～2 vulcanization accelerator 0.5～2
Antioxidant 0.5～2 process oil 2～15
Zinc oxide 1～6 stearic acid 1～2;
Described ultra-fine spring wire is the spring wire skeleton of diameter 0.05～0.5mm and the processing of process plucking.
2. shoot proof tyre as claimed in claim 1 comprises the component of following parts by weight:
Styrene-butadiene rubber(SBR) 35～50 natural rubbers 25～35
White carbon black 0.8～1.8 carbon nano-tube fibre 2～10
Ultra-fine spring wire 4～12 nano silicons 1～9
Vulcanizing agent 1～2 vulcanization accelerator 0.5～1.8
Antioxidant 0.5～1.8 process oil 2～12
Zinc oxide 1～5 stearic acid 1～1.8.
3. shoot proof tyre as claimed in claim 1 comprises the component of following parts by weight:
Styrene-butadiene rubber(SBR) 40 natural rubbers 30
White carbon black 1 carbon nano-tube fibre 8
Ultra-fine spring wire 6 nano silicons 6
Vulcanizing agent 1.5 vulcanization accelerators 1.2
Antioxidant 1.2 process oils 8
Zinc oxide 3 stearic acid 1.5.
4. shoot proof tyre as claimed in claim 1, is characterized in that,
Described carbon nano-tube fibre, adopt the multi-walled carbon nano-tubes fiber;
Vulcanizing agent comprises sulphur, organo-peroxide, at least one in metal oxide;
Vulcanization accelerator comprises Ammonia, amine, Thiourea, Sulfonates, at least one in aldehydes;
Antioxidant comprises amine, imidazoles, at least one in the amine ketone;
Process oil comprises, the fragrant same clan, naphthenic, at least one in paraffin class.
5. shoot proof tyre as claimed in claim 1, is characterized in that,
Described vulcanizing agent is: sulphur, two-(γ-tri-ethoxy silylpropyl)-tetrasulfide, 1, two (the lemon imide methyl) benzene of 3-, zinc dialkyl dithiophosphate, N, N '-meta-phenylene bismaleimide, two hydration hexa-methylenes-1,6-dithio sulfuric acid disodium salt;
Vulcanization accelerator is: any in accelerator M, vulcanization accelerator TT, accelerator H, accelerator ZDMC, accelerator ZBX, accelerator NA-22, accelerator CZ;
Antioxidant is: hydroquinone type, phosphorous acid ester, paraffin, dibutyl dithiocaarbamate salt, 6,6-oxyethyl group-2,2, the 4-3 methyl isophthalic acid, any in the Resorcinol of 2-dihydroquinoline, replacement, Ursol D class, secondary amine class, phenols, phosphorous acid ester, mantoquita, triazines;
Process oil is: any in aromatic hydrocarbon oil, paraffin oil, naphthene base crude oil.
6. shoot proof tyre as claimed in claim 1, is characterized in that,
Described vulcanizing agent is: sulphur;
Vulcanization accelerator is: accelerator NA-22;
Antioxidant is: dibutyl dithiocaarbamate salt;
Process oil is: paraffin oil.
7. shoot proof tyre its preparation method as claimed in claim 1 comprises following step:
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.05～0.5mm and process plucking are processed with diameter;
30～60 parts of styrene-butadiene rubber(SBR), 20～40 parts of natural rubbers, 0.5～2 part of white carbon black, 1～10 part of nano silicon, 1～2 part of vulcanizing agent, 0.5～2 part of vulcanization accelerator, 0.5～2 part of antioxidant, 2～15 parts of process oils, 1～6 part of zinc oxide, 1～2 part of stearic acid are added in kneader by above-mentioned quality proportioning, material is mediated evenly;
Material face refining 5～10min by after mediating, then add 5-20 part pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 2～12 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 1～4mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃～175 ℃, and curing time is 15～30min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 150 ℃～160 ℃, and shaping time is 5～10min, and the shoot proof tyre after heat treatment is finished product after pruning.
8. shoot proof tyre its preparation method as claimed in claim 1 comprises following step:
Open each pair of shoot proof tyre curing forming mold processed and heat treatment mould;
Prepare the shoot proof tyre steel-wire carcass: be the spring wire skeleton that 0.1mm and process plucking are processed with diameter;
40 parts of styrene-butadiene rubber(SBR), 30 parts of natural rubbers, 1 part of white carbon black, 5 parts of nano silicons, 1.5 parts of vulcanizing agents, 0.8 part of vulcanization accelerator, 0.8 part of antioxidant, 10 parts of process oils, 3 parts of zinc oxide, 1.5 parts of stearic acid are added in kneader by above-mentioned quality proportioning, material is mediated evenly;
Material face refining 8min by after mediating, then add 10 parts of pentamethylene in the rubber material of face refining machine, standby after continuation face refining 8min;
The rubber size that face is refined is put into rubber sheet press, Yi Bian open rubber sheet press, Yi Bian send into 8 parts of carbon nano-tube fibres in tabletting machine, rubber size is pressed into to the thin slice that contains carbon fibre web that thickness is 3mm;
The steel wheel hub of shoot proof tyre is put into to the mould of vulcanization forming machine;
Woven shoot proof tyre steel-wire carcass is put into to the mould of vulcanization forming machine;
Rubber ring is put into to the mould of vulcanization forming machine, the temperature of controlling the vulcanization forming machine moulding is 170 ℃, and curing time is 20min;
Shoot proof tyre after sulfidization molding is taken out, put into the heat treatment mould of another vulcanization forming machine and do heat treatment, the heat treatment temperature is 155 ℃, and shaping time is 7min, and the shoot proof tyre after heat treatment is finished product after pruning.
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| CN201310423465.3A CN103483649A (en) | 2013-09-17 | 2013-09-17 | Bulletproof tire and manufacturing method thereof |
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| CN201310423465.3A CN103483649A (en) | 2013-09-17 | 2013-09-17 | Bulletproof tire and manufacturing method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104086821A (en) * | 2014-07-02 | 2014-10-08 | 安徽宁国尚鼎橡塑制品有限公司 | High-performance rubber composition for automobiles |
| CN104177667A (en) * | 2014-07-21 | 2014-12-03 | 安徽中马橡塑制品有限公司 | Modified natural rubber composite material for tire treads |
| CN105037828A (en) * | 2015-08-28 | 2015-11-11 | 苏州国泰科技发展有限公司 | Stretch-proof tire rubber material and preparation method thereof |
| CN105667213A (en) * | 2016-02-18 | 2016-06-15 | 山东丰源轮胎制造股份有限公司 | Ultra-safe tire with bursting resistance, air leakage resistance and static electricity resistance |
| CN105778167A (en) * | 2014-12-23 | 2016-07-20 | 王明江 | Production process for bulletproof and fireproof tyre |
| US10000623B2 (en) | 2013-11-12 | 2018-06-19 | Robinson Brothers Limited | Accelerator compositions and methods |
| CN111499945A (en) * | 2020-05-28 | 2020-08-07 | 江苏通用科技股份有限公司 | Two-dimensional directional arrangement filling rubber composite material and preparation method thereof |
| CN114591549A (en) * | 2022-03-07 | 2022-06-07 | 中策橡胶集团股份有限公司 | Low rolling resistance tread rubber composition, mixing process method thereof and tire |
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| CN102174218A (en) * | 2011-02-22 | 2011-09-07 | 王崇庆 | Bullet-proof tire |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102174218A (en) * | 2011-02-22 | 2011-09-07 | 王崇庆 | Bullet-proof tire |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10000623B2 (en) | 2013-11-12 | 2018-06-19 | Robinson Brothers Limited | Accelerator compositions and methods |
| CN104086821A (en) * | 2014-07-02 | 2014-10-08 | 安徽宁国尚鼎橡塑制品有限公司 | High-performance rubber composition for automobiles |
| CN104177667A (en) * | 2014-07-21 | 2014-12-03 | 安徽中马橡塑制品有限公司 | Modified natural rubber composite material for tire treads |
| CN105778167A (en) * | 2014-12-23 | 2016-07-20 | 王明江 | Production process for bulletproof and fireproof tyre |
| CN105037828A (en) * | 2015-08-28 | 2015-11-11 | 苏州国泰科技发展有限公司 | Stretch-proof tire rubber material and preparation method thereof |
| CN105667213A (en) * | 2016-02-18 | 2016-06-15 | 山东丰源轮胎制造股份有限公司 | Ultra-safe tire with bursting resistance, air leakage resistance and static electricity resistance |
| CN105667213B (en) * | 2016-02-18 | 2019-04-02 | 山东丰源轮胎制造股份有限公司 | Anti- explosion, anti-gas-leak, antistatic wheel tyre |
| CN111499945A (en) * | 2020-05-28 | 2020-08-07 | 江苏通用科技股份有限公司 | Two-dimensional directional arrangement filling rubber composite material and preparation method thereof |
| CN114591549A (en) * | 2022-03-07 | 2022-06-07 | 中策橡胶集团股份有限公司 | Low rolling resistance tread rubber composition, mixing process method thereof and tire |
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