CN103478124A - Thiamethoxam oil suspension - Google Patents
Thiamethoxam oil suspension Download PDFInfo
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- CN103478124A CN103478124A CN201310444663.8A CN201310444663A CN103478124A CN 103478124 A CN103478124 A CN 103478124A CN 201310444663 A CN201310444663 A CN 201310444663A CN 103478124 A CN103478124 A CN 103478124A
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- diacloden
- suspending agent
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Abstract
The invention relates to the field of pesticide formulations and discloses a dispersible thiamethoxam oil suspension. The thiamethoxam oil suspension comprises the following raw materials in percentage by weight: 1-25% of thiamethoxam, 5-25% of a surfactant, 0.1-10% of a functional additive and 50-94% of one or combination of two of plant oil or mineral oil and ester thereof. The thiamethoxam oil suspension mainly has the advantages as follows: (1) a synergistic effect is achieved as the mineral oil or the plant oil has a remarkable synergistic effect for prevention and control of pesticides on pest and disease damage; (2) the pollution degree is low as the raw materials used in the suspension are all non-destructive and lowly-destructive to the environment; (3) the plant resistance is improved as the plant growth is improved while the pest damage is prevented and controlled after the suspension is applied; (4) the hidden trouble in stability of the suspension is improved.
Description
Technical field
The present invention relates to formulations of pesticide field, but particularly Diacloden dispersed oil suspending agent.
Background technology
Diacloden, its mechanism of action is similar to Imidacloprid, alternative inhibition insect central nervous system nicotinic acid nAChR ligands, and then the normal conduction of blocking-up insect central nervous system, death while causing insect the paralysis machine to occur.Not only have tag, stomach toxicity, systemic activity, and there is higher activity, better safety, wider insecticidal spectrum and the characteristics such as speed of action is fast, the lasting period is long, be the better kind that replaces those are high to mammalian toxicity, residual and environmental problem are arranged organic phosphor, carbamate, organochlorine insecticides.To coleoptera, diptera, Lepidoptera, especially homoptera pest has high activity, can effectively prevent and treat the insect that the insect such as various aphids, leafhopper, plant hopper, aleyrodid, chafer larva, colorado potato beetle, nematode, ground beetle, leaf miner and knot polytype chemical pesticide produce resistance.With Imidacloprid, Acetamiprid, Nitenpyram without cross resistance.Both can be used for cauline leaf processing, seed treatment, also can be used for soil treatment.Suitable crop is rice class crop, beet, rape, potato, cotton, Kidney bean, fruit tree, peanut, sunflower, soybean, tobacco and citrus etc.Under recommended dose, use to crop safety, without poisoning.
The formulation that Diacloden is used as insecticide at present mainly contains suspending agent, water dispersible granules.The present invention has solved the livering problem with respect to suspending agent, with respect to water dispersible granules, has reduced production cost, and different synergistic effects is all arranged.
Summary of the invention
In view of this, but the invention provides a kind of Diacloden dispersed oil suspending agent.Form the percentage composition that reaches a component as follows: Diacloden 1～25%, surfactant 5～25%, functional aid 0.1～10%, one or both combinations 50～94% of vegetable oil or mineral oil and carboxylate thereof.Described emulsifier is selected from compound, anion and the non-ionic surface active agent of anion and non-ionic surface active agent and compound, calcium dodecyl benzene sulfonate, the styryl phenol formaldehyde resin polyoxyethylene of solvent, one or more in polyoxypropylene block type polyethers, polyoxyethylene nonylphenol ether phosphate or OPEO phosphate.
In order to realize the foregoing invention purpose, the invention provides following technical scheme.
But a kind of Diacloden dispersed oil suspending agent forms the percentage composition that reaches a component as follows: Diacloden 1～25%, surfactant 5～25%, functional aid 0.1～10%, one or both combinations 50～94% of vegetable oil or mineral oil and carboxylate thereof.Described emulsifier is selected from compound, anion and the non-ionic surface active agent of anion and non-ionic surface active agent and compound, calcium dodecyl benzene sulfonate, the styryl phenol formaldehyde resin polyoxyethylene of solvent, one or more in polyoxypropylene block type polyethers, polyoxyethylene nonylphenol ether phosphate or OPEO phosphate.
As preferably, but Diacloden dispersed oil suspending agent provided by the invention, and the mass ratio of one or both combinations of the former medicine of Diacloden, surfactant, functional aid, vegetable oil or mineral oil and carboxylate thereof is 1～25:5～25:0.1～10:50～94.
As preferably, but Diacloden dispersed oil suspending agent provided by the invention, and the mass ratio of one or both combinations of the former medicine of Diacloden, surfactant, functional aid, vegetable oil or mineral oil and carboxylate thereof is 5～10:5～25:0.1～10:50～94.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is agriculture breast 500#.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is polyoxypropylene block type polyethers.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is styryl phenol formaldehyde resin polyoxyethylene.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is the OPEO phosphate.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises antifreezing agent.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 5% antifreezing agent.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises thickener.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 0.1% thickener.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises defoamer.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 0.1% defoamer.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises preservative.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 0.1% preservative.
Embodiment
But the invention discloses a kind of Diacloden dispersed oil suspending agent, those skilled in the art can use for reference this paper content, suitably improve technological parameter and realize.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they all are deemed to be included in the present invention.Method of the present invention and application are described by preferred embodiment, the related personnel obviously can be changed methods and applications as herein described or suitably change and combination within not breaking away from content of the present invention, spirit and scope, realizes and apply the technology of the present invention.
But a kind of Diacloden dispersed oil suspending agent forms the percentage composition that reaches a component as follows: Diacloden 1～25%, surfactant 5～25%, functional aid 0.1～10%, one or both combinations 50～94% of vegetable oil or mineral oil and carboxylate thereof.Described surfactant is selected from compound, anion and the non-ionic surface active agent of anion and non-ionic surface active agent and compound, calcium dodecyl benzene sulfonate, the styryl phenol formaldehyde resin polyoxyethylene of solvent, one or more in polyoxypropylene block type polyethers, polyoxyethylene nonylphenol ether phosphate or OPEO phosphate.
As preferably, but Diacloden dispersed oil suspending agent provided by the invention, and the mass ratio of one or both combinations of the former medicine of Diacloden, surfactant, functional aid, vegetable oil or mineral oil and carboxylate thereof is 1～25:5～25:0.1～10:50～94.
As preferably, but Diacloden dispersed oil suspending agent provided by the invention, and the mass ratio of one or both combinations of the former medicine of Diacloden, surfactant, functional aid, vegetable oil or mineral oil and carboxylate thereof is 5～10:5～25:0.1～10:50～94.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is agriculture breast 500#.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is polyoxypropylene block type polyethers.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is styryl phenol formaldehyde resin polyoxyethylene.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, and described surfactant is the OPEO phosphate.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises antifreezing agent.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 5% antifreezing agent.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises thickener.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 0.1% thickener.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises defoamer.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 0.1% defoamer.
As preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention also comprises preservative.
Preferably, but a kind of Diacloden dispersed oil suspending agent provided by the invention, in mass fraction, also comprises 0.1% preservative.
Surfactant (surfactant), have fixing hydrophilic and oleophilic group, on the surface of solution, can align, and the material that can make solution surface tension significantly descend.The molecular structure of surfactant has amphipathic: an end is hydrophilic radical, and the other end is hydrophobic grouping; Hydrophilic radical is often the group of polarity, as carboxylic acid, sulfonic acid, sulfuric acid, amino or amido and salt thereof, and also hydroxyl, amide groups, ehter bond etc.; And hydrophobic grouping is often nonpolar hydrocarbon chain, as 8 above hydrocarbon chains of carbon atom, as straight chain, side chain, fragrant chain, fluorine-containing long-chain etc.Based on the said structure characteristics, that surfactant has is wetting or anti-stick, the effect of emulsification or breakdown of emulsion, foaming or froth breaking and solubilising, dispersion.
No. 500, agriculture breast, chemical name is calcium dodecyl benzene sulfonate, belong to anion surfactant, outward appearance is the brown color thick liquid, the pH value is 6～8, be mainly used in farm chemical emulgent, the farm chemical emulgent be made into as lipophilic surfactant component and non-ionic hydrophilic surfacant, be applicable to various types of agricultural chemicals.Also can be used for textile finish oil, ceramic tile detergent, grind finish, cement dispersants etc.
Agricultural emulsifier NO．600, chemical name is styrylphenol polyoxyethylene ether, is light yellow or orange-yellow oily liquid, be half mobile state after cooling, soluble in water and various organic solvents, not electrolysis in water, stable in acid-base solution, contact easy cracking during high temperature with oxidant; Agricultural emulsifier NO．600 belongs to nonionic surface active agent, and performance is identical with emulsifier BP, after can acting as styryl phenol by phenol and styrene, then obtains with ethylene oxide polymerization.Outward appearance is light yellow or orange-yellow oily liquid, and the pH value is 5～7.
Polyoxypropylene block type polyethers toxicity is very little, is used as emulsifier, excipients in food industry, also as boiling sugared auxiliary agent; Be used as low bubble emulsifier in textile industry; Be used as emulsifier and thickener in cosmetics industry; In detergent industry for preparing dish washing detergent, metal cleaner; Can be used as corrosion inhibitor, demulsifier, additive in the industry such as plastics, coating.
A kind of function admirable of OPEO phosphate, in the industries such as weaving, medicine, food, cosmetics widely used surfactant.Be the new nonionic surfactant obtained through Phosphation by ether type non-ionic surface active agent, thereby have the characteristic of nonionic and anion concurrently.It has the performances such as good antistatic behaviour, wetability, emulsibility, dispersiveness, especially there is heat endurance high, can use in than large-temperature range, good stability in soda acid and electrolyte solution, not stratified, do not precipitate and the advantage such as toxicity is low, excitant is little.
but embodiment 1 preparation Diacloden dispersed oil suspending agent provided by the invention
Diacloden 1Kg, agriculture breast 500#2Kg, polyoxypropylene block type polyethers 3Kg, OPEO phosphate 5Kg, corn oil 85.7Kg, antifreezing agent 3kg, thickener 0.1kg, defoamer 0.1kg, preservative 0.1kg, but make Diacloden dispersed oil suspending agent after mixing sand milling.
but embodiment 2 preparation Diacloden dispersed oil suspending agent provided by the invention
Diacloden 10Kg, agriculture breast 500#1Kg, polyoxypropylene block type polyethers 5Kg, OPEO phosphate 10Kg, methyl oleate 70.7Kg, antifreezing agent 3kg, thickener 0.1kg, defoamer 0.1kg, preservative 0.1kg, but make Diacloden dispersed oil suspending agent after mixing sand milling.
but embodiment 3 preparation Diacloden dispersed oil suspending agent provided by the invention
Diacloden 15Kg, agriculture breast 500#5Kg, polyoxypropylene block type polyethers 5Kg, OPEO phosphate 10Kg, corn oil 41.7Kg, mineral oil 20Kg, antifreezing agent 3kg, thickener 0.1kg, defoamer 0.1kg, preservative 0.1kg, but make Diacloden dispersed oil suspending agent after mixing sand milling.
but embodiment 4 preparation Diacloden dispersed oil suspending agent provided by the invention
Diacloden 20Kg, agriculture breast 500#5Kg, polyoxypropylene block type polyethers 3Kg, OPEO phosphate 15Kg, mineral oil 53.7Kg, antifreezing agent 3kg, thickener 0.1kg, defoamer 0.1kg, preservative 0.1kg, but make Diacloden dispersed oil suspending agent after mixing sand milling.
but embodiment 5 preparation Diacloden dispersed oil suspending agent provided by the invention
Diacloden 25Kg, agriculture breast 500#4Kg, polyoxypropylene block type polyethers 5Kg, OPEO phosphate 11Kg, methyl oleate 20Kg, mineral oil 31.7Kg, antifreezing agent 3kg, thickener 0.1kg, defoamer 0.1kg, preservative 0.1kg, but make Diacloden dispersed oil suspending agent after mixing sand milling.
but embodiment 6 Diacloden dispersed oil provided by the invention suspending agent field efficacy experiment
The dispenser place: Feixi County San He town Feng Lenongization is given birth to test and is tested base.The control rice fulgorid carries out in middle rice field, and front stubble is idle field.Fertility uniformity experimental field, physical features is smooth.The inclined to one side sand mold of soil, middle fertility.Before whole ground, paddy rice-dedicated fertilizer 40kg/667 ㎡ is executed in each experimental field.Semilate rice is in heading stage, and growing way is better, and rice fulgorid is heavier.
Spraying time: in rice ear sprouting period, the concrete time is dispenser in afternoon on August 23 in 2011.
Dispenser condition: dispenser fine day on the same day, 25 ℃～33 ℃ of temperature.
Dispenser dosage and mode: spraying volume 0.06kg/m
2, liquid adopts two step dilution method preparations.Medical instruments adopt workers and peasants-16 knapsack sprayer, dress fan type shower nozzle, artificial even spraying.
Experimental group: but dispersed oil suspending agent experimental group, water dispersion granule experimental group and suspending agent experimental group be divided into; Wherein, but in dispersed oil suspending agent experimental group according to 0.0048g/m
2but dosage spray in the embodiment of the present invention 3, make containing 15% Diacloden dispersed oil suspending agent, the water dispersion granule experimental group is according to 0.0048mL/m
2dosage spray containing 15% Diacloden water dispersion granule (self-control), the suspending agent experimental group is according to 0.0048mL/m
2dosage spray containing 15% Diacloden suspending agent (self-control).
Blank group: according to 0.0048mL/m
2dosage spray clear water.
Test method: each experimental group and blank group all repeat 4 times, and each experimental group and blank group take respectively community, experimental field area 30m
2, the community randomized arrangement.Before dispenser, in each experimental group and blank Zu community, get at random 4 single single fillings in ，，Ge community, rich water quality management and other cultivation conditions are identical.
In 14 days, observe each treatment region rice hoppers insect population situation after dispenser, record without the poisoning phenomenon.Investigate each community insect population number when within after dispenser 14 days, the rice fulgorid insect pest is stablized, calculate control efficiency.Investigation adopts five point sampling ，Mei communities to get 5 points, looks into 4 clumps of ，Ji Mei communities at every and looks into 20 clumps.
Insect population radix before insect population radix after insect population radix before control efficiency=processing-processing/processing * 100%
Each formulation control rice fulgorid effect of table 1 Diacloden
As shown in Table 1, but after dispenser 3d in dispersed oil suspending agent experimental group according to 0.0048g/m
2but dosage spray in the embodiment of the present invention 5, make containing 25% Diacloden dispersed oil suspending agent preventive effect 51.1%, the water dispersion granule experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden water dispersion granule (self-control) preventive effect 48.9%, the suspending agent experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden suspending agent (self-control) preventive effect 45.7%.But after dispenser 14d in dispersed oil suspending agent experimental group according to 0.0048g/m
2but dosage spray in the embodiment of the present invention 5, make containing 25% Diacloden dispersed oil suspending agent preventive effect 95.7%, the water dispersion granule experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden water dispersion granule (self-control) preventive effect 88.9%, the suspending agent experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden suspending agent (self-control) preventive effect 91.3%.
but embodiment 7 Diacloden dispersed oil provided by the invention suspending agent field efficacy experiment
The dispenser place: Feixi County San He town Feng Lenongization is given birth to test and is tested base.The control rice fulgorid carries out in middle rice field, and front stubble is idle field.Fertility uniformity experimental field, physical features is smooth.The inclined to one side sand mold of soil, middle fertility.Before whole ground, paddy rice-dedicated fertilizer 40kg/667 ㎡ is executed in each experimental field.Semilate rice is in heading stage, and growing way is better, and rice fulgorid is heavier.
Spraying time: in rice ear sprouting period, the concrete time is dispenser in afternoon on August 23 in 2011.
Dispenser condition: dispenser fine day on the same day, 25 ℃～33 ℃ of temperature.
Dispenser dosage and mode: spraying volume 0.06kg/m
2, liquid adopts two step dilution method preparations.Medical instruments adopt workers and peasants-16 knapsack sprayer, dress fan type shower nozzle, artificial even spraying.
Experimental group: but dispersed oil suspending agent experimental group, water dispersion granule experimental group and suspending agent experimental group be divided into; Wherein, but in dispersed oil suspending agent experimental group according to 0.0048g/m
2but dosage spray in the embodiment of the present invention 5, make containing 25% Diacloden dispersed oil suspending agent, the water dispersion granule experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden water dispersion granule (self-control), the suspending agent experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden suspending agent (self-control).
Blank group: according to 0.0048mL/m
2dosage spray clear water.
Test method: each experimental group and blank group all repeat 4 times, and each experimental group and blank group take respectively community, experimental field area 30m
2, the community randomized arrangement.Before dispenser, in each experimental group and blank Zu community, get at random single single filling the in 4 Dian，Ge communities, rich water quality management and other cultivation conditions are identical.
In 14 days, observe each treatment region rice hoppers insect population situation after dispenser, record without the poisoning phenomenon.Investigate each community insect population number when within after dispenser 14 days, the rice fulgorid insect pest is stablized, calculate control efficiency.Investigation adopts five point sampling ，Mei communities to get 5 points, looks into 4 clumps of ，Ji Mei communities at every and looks into 20 clumps.
Control efficiency=(insect population radix after insect population radix before processing-processing)/insect population radix * 100% before processing
each formulation control rice fulgorid effect of table 2 Diacloden
As shown in Table 2, but after dispenser 3d in dispersed oil suspending agent experimental group according to 0.0048g/m
2but dosage spray in the embodiment of the present invention 5, make containing 25% Diacloden dispersed oil suspending agent preventive effect 54.5%, the water dispersion granule experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden water dispersion granule (self-control) preventive effect 33.3%, the suspending agent experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden suspending agent (self-control) preventive effect 42.6%.But after dispenser 14d in dispersed oil suspending agent experimental group according to 0.0048g/m
2but dosage spray in the embodiment of the present invention 5, make containing 25% Diacloden dispersed oil suspending agent preventive effect 100%, the water dispersion granule experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden water dispersion granule (self-control) preventive effect 87.5%, the suspending agent experimental group is according to 0.0048mL/m
2dosage spray containing 25% Diacloden suspending agent (self-control) preventive effect 93.6%.
Claims (7)
1. but a Diacloden dispersed oil suspending agent is characterized in that: by one or both of Diacloden, surfactant, functional aid, vegetable oil or mineral oil and carboxylate thereof, constituted.
2. but Diacloden dispersed oil suspending agent as claimed in claim 1, it is characterized in that: the percentage composition ratio of Diacloden is 1～25%.
3. but Diacloden dispersed oil suspending agent as claimed in claim 1, it is characterized in that: the percentage composition ratio of surfactant is 5～25%.
4. but Diacloden dispersed oil suspending agent as claimed in claim 1, described surfactant is characterized in that: be selected from compound, anion and the non-ionic surface active agent of anion and non-ionic surface active agent and compound, calcium dodecyl benzene sulfonate, the styryl phenol formaldehyde resin polyoxyethylene of solvent, one or more in polyoxypropylene block type polyethers, polyoxyethylene nonylphenol ether phosphate or OPEO phosphate.
5. but Diacloden dispersed oil suspending agent as claimed in claim 1, it is characterized in that: the percentage composition ratio of functional aid is 0.1～10%.
6. but Diacloden dispersed oil suspending agent as claimed in claim 1, it is characterized in that: the percentage composition ratio of one or both combinations of vegetable oil or mineral oil and carboxylate thereof is 50～94%.
7. but Diacloden dispersed oil suspending agent as claimed in claim 1, described functional aid is characterized in that: be one or more of antifreezing agent, thickener, preservative, defoamer.
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| CN201310444663.8A CN103478124A (en) | 2013-09-26 | 2013-09-26 | Thiamethoxam oil suspension |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310444663.8A CN103478124A (en) | 2013-09-26 | 2013-09-26 | Thiamethoxam oil suspension |
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| CN201310444663.8A Pending CN103478124A (en) | 2013-09-26 | 2013-09-26 | Thiamethoxam oil suspension |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104430578A (en) * | 2014-12-24 | 2015-03-25 | 青岛锐志农业技术服务有限公司 | Pesticide composite containing thiamethoxam and nicosulfuron |
| CN107439563A (en) * | 2017-09-21 | 2017-12-08 | 海门臻凯工业设计有限公司 | A kind of new herbicides |
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Application publication date: 20140101 |