CN103476391A - Oxidative hair dye or bleaching agent composition - Google Patents
Oxidative hair dye or bleaching agent composition Download PDFInfo
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- CN103476391A CN103476391A CN2012800168995A CN201280016899A CN103476391A CN 103476391 A CN103476391 A CN 103476391A CN 2012800168995 A CN2012800168995 A CN 2012800168995A CN 201280016899 A CN201280016899 A CN 201280016899A CN 103476391 A CN103476391 A CN 103476391A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/43—Guanidines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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Abstract
The present invention relates to an oxidative hair dye composition or a bleaching agent composition. The oxidative hair dye composition or the bleaching agent composition is used by mixing a first agent containing an alkaline agent with a second agent containing hydrogen peroxide. A mixture contains a guanidinium salt in an amount exceeding 0.5 mass% and an aromatic alcohol that is liquid at ordinary temperature in an amount exceeding 2.0 mass%, and if the content of the guanidinium salt is regarded as mass% a, and the content of the aromatic alcohol that is liquid at ordinary temperature is regarded as mass% b, (a-0.5)*(b-2.0)>=1.0 is satisfied, and the pH of the mixture is 8.0 to 11.5.
Description
Technical field
The present invention relates to hair dye or the depigmenting agent compositions of oxidized form.
Background technology
In the decolouring of hair or hair dyeing, be widely used under the coexisting of the oxidant that contains in the alkaline agent that contains in the 1st dose, the 2nd dose etc. hair dye or the depigmenting agent compositions by the oxidized form of hair decolouring or dyeing by oxidation reaction.
But the hair dye of such oxidized form or depigmenting agent compositions easily cause hair damages, in the inner cavity that produces of hair, the diffuse-reflectance that its result has due to light produces dimness, becomes the problem that completes effect tarnished.So, as the oxidative hair dyes of the damage that has suppressed hair, propose to have the technology of the hair dye (patent documentation 1～2) that used specific organic solvent etc.Yet, in these oxidative hair dyes and depigmenting agent compositions, can not repair the damage produced and obtain gloss good complete effect.
In addition, known guanidinesalt is used as the alkaline agent in oxidative hair dyes or depigmenting agent all the time, but about by with specific concentration range and with hair damages repairing effect or gloss that specific organic solvent and guanidinesalt produced, giving also the unknown of effect.
On the other hand, in patent documentation 3 and 4, disclose and will there is the low molecular compound of amino, hydroxyl, carbonyl or carboxyl in molecule as giving the technology of hair with the effective ingredient of third dimension, transparent feel or depth perception, as described effective ingredient, can also enumerate guanidine derivatives or aromatic alcohols.But, do not put down in writing the example that has used guanidinesalt in the embodiment of these documents, certainly do not put down in writing the formula of guanidinesalt and specific organic solvent use yet.In addition, the concrete dosage form of putting down in writing as these embodiment, only shampoo, hair conditioner, agent for permanent hair waving the 1st dose, the 2nd dose, and for the hair dye by oxidized form or depigmenting agent compositions by the hair decolouring or dye and obtain the hair damages repairing effect not record do not provide technology yet and enlighten.
The prior art document
Patent documentation
Patent documentation 1: Japanese kokai publication hei 11-029443 communique
Patent documentation 2: TOHKEMY 2002-193770 communique
Patent documentation 3: TOHKEMY 2001-220321 communique
Patent documentation 4: TOHKEMY 2001-220322 communique
Summary of the invention
The invention provides a kind of oxidative hair dyes or depigmenting agent compositions, described hair dye or depigmenting agent compositions the 2nd dose of hair coloring preparation composition or the depigmenting agent compositions of mixing use for containing the 1st dose of alkaline agent and contain hydrogen peroxide, containing the guanidinesalt of the amount that surpasses 0.5 quality % and surpass under the room temperature of amount of 2.0 quality % in mixture is the aromatic alcohols of liquid, content at guanidinesalt is a quality %, when under room temperature, for the content of the aromatic alcohols of liquid, being b quality %, meet (a-0.5) * (b-2.0) >=1.0, and the pH of mixture is 8.0～11.5.
The specific embodiment
Although the present invention relates to is hair dye or the depigmenting agent compositions that easily causes under normal conditions the oxidized form of hair damages, also can repair the hair dye of oxidized form or depigmenting agent compositions and the cavity of the hair that the sustains damage effect that completes that obtains having good gloss as healthy hair by other, and make also excellent oxidative hair dyes or depigmenting agent compositions of the bright ability of color development as the key property of the hair dye of oxidized form or depigmenting agent compositions.
The present inventors find: by also use guanidinesalt and the aromatic alcohols of the amount that surpasses certain concentration in oxidative hair dyes or depigmenting agent compositions, and its content is met some requirements, can solve the problems of the technologies described above simultaneously.
In this manual, " in the mixture " relevant to the content of each composition is in the situation that double-formulation refers to " in the mixture of the 1st dose and the 2nd dose ", in the situation that three dosage forms refer to " in the 1st dose～the 3rd dose mixture formed ".
[guanidinesalt]
As the guanidinesalt used in the present invention, can enumerate guanidine hydrochloride, guanidine sulfate, Guanidine nitrate (1:1), guanidine carbonate, bicarbonate guanidine, phosphoguanidine, guanidine thiocyanate, boric acid guanidine, Guanidine Sulfamate 99, organic acid guanidinesalt etc., wherein preferred guanidine carbonate and bicarbonate guanidine.These guanidinesalts can be used singly or in combination of two or more thereof.Guanidinesalt preferably is matched with in the 1st dose, and the viewpoint of the good gloss completed from dyeing contains the amount that surpasses 0.5 quality % in mixture, preferably contains 1～10 quality %, is more preferably and contains 2～8 quality %.
[aromatic alcohols]
As being the aromatic alcohols of liquid (being designated hereinafter simply as " aromatic alcohols ") under the room temperature used in the present invention, can enumerate benzylalcohol, cinnamyl alcohol, phenethanol, to anise alcohol, to methylbenzyl alcohol, phenyl phenol, 2-BOE etc., wherein preferably benzylalcohol, 2-BOE.In addition, " room temperature " in the application refers to 25 ℃.These aromatic alcohols can contain in preparation arbitrarily, also can be used as with described the 1st dose～the 3rd dose other preparation and use.Aromatic alcohols can be used singly or in combination of two or more thereof.The viewpoint of the good gloss that aromatic alcohols completes from dyeing contains the amount that surpasses 2.0 quality % in mixture, preferably contains 2.5～20.0 quality %, further preferably contains 3.0～10.0 quality %.
Oxidative hair dyes of the present invention or depigmenting agent compositions, content at guanidinesalt is a quality %, when under room temperature, for the content of the aromatic alcohols of liquid, being b quality %, the viewpoint of the good gloss completed from dyeing, need to meet (a-0.5) * (b-2.0) >=1.0, preferably meet (a-0.5) * (b-2.0) >=2.0, further preferably meet (a-0.5) * (b-2.0) >=2.5, be more preferably satisfied (a-0.5) * (b-2.0) >=3.0, be more preferably satisfied (a-0.5) * (b-2.0) >=3.5, be more preferably satisfied (a-0.5) * (b-2.0) >=4.0.In addition, from the viewpoint of good hair dyeing, preferably meet 40 >=(a-0.5) * (b-2.0), further preferably meet 35 >=(a-0.5) * (b-2.0), be more preferably and meet 30 >=(a-0.5) * (b-2.0).
[oxidation dye]
In the situation that compositions of the present invention is hair coloring preparation composition, contain oxidation dye.As oxidation dye, can use known precursor and colour coupler for common hair dye.As precursor, for example can enumerate p-phenylenediamine (PPD), Toluene-2,4-diisocyanate, the 5-diamidogen, the chloro-p-phenylenediamine (PPD) of 2-, N-methoxy ethyl-p-phenylenediamine (PPD), N, two (2-the ethoxy)-p-phenylenediamine (PPD) of N-, 2-(2-ethoxy)-p-phenylenediamine (PPD), 2, 6-dimethyl-p-phenylenediamine (PPD), 4, 4 '-diamino-diphenyl amine, 1, two (N-(2-ethoxy)-N-(4-aminophenyl) amino)-2-propanol of 3-, PEG-3, 3, 2 '-p-phenylenediamine (PPD), para-aminophenol, p-methylaminophenol, 3-methyl-PAP, 2-amino methyl-PAP, 2-(2-hydroxyethylamino methyl)-PAP, o-aminophenol, the 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-acetaminophenol, 3, the 4-diaminobenzoic acid, 5-aminosalicylic acid, 2, 4, 5, the 6-tetraminopyrimidine, 2, 5, 6-triamido-4-hydroxy pyrimidine, 4, 5-diaminostilbene-(4 '-chlorobenzyl) pyrazoles, 4, 5-diaminostilbene-hydroxyethyl pyrazole and their salt etc.
In addition, as colour coupler, for example can enumerate m-diaminobenzene., 2,4-diamino phenoxy ethanol, 2-amino-4-(2-hydroxyethylamino) methyl phenyl ethers anisole, 2,4-diaminourea-5-tolyl ethyl ether, 2,4-diaminourea-5-(2-hydroxy ethoxy) toluene, 2,4-dimethoxy-1, the 3-diaminobenzene, two (2-hydroxyethylamino) toluene of 2,6-, 2,4-diaminourea-5-toluene fluoride, two (2, the 4-diamino phenoxy) propane of 1,3-, m-aminophenol, 2-methyl-5-amino-phenol, 2-methyl-5-(2-hydroxyethylamino) phenol, the chloro-3-amino-phenol of 2,4-bis-, the chloro-3-amino of 2--6-methylphenol, the chloro-5-amino-phenol of 2-methyl-4-, N-cyclopenta-m-aminophenol, 2-methyl-4-methoxyl group-5-(2-hydroxyethylamino) phenol, the fluoro-5-amino-phenol of 2-methyl-4-, resorcinol, the 2-methylresorcinol, the 4-chloro resorcinol, the 1-naphthols, 1,5-dihydroxy naphthlene, 1,7-dihydroxy naphthlene, 2,7-dihydroxy naphthlene, 2-isopropyl-5-methylphenol, the 4-oxyindole, 5-OHi, the 6-oxyindole, the 7-oxyindole, 6-hydroxy benzo morpholine, 3,4-methylenedioxyphenyl phenol, 2-is bromo-4,5-methylenedioxyphenyl phenol, 3,4-methylenedioxyphenyl amine, 1-(2-ethoxy) amino-3, the 4-methylenedioxyphenyl, 2,6-dihydroxy-3, the 4-lutidines, 2,6-dimethoxy-3, the 5-diamino-pyridine, 2,3-diaminourea-6-methoxypyridine, 2-methylamino-3-amino-6-methoxypyridine, 2-amino-3-pyridone, DAP and their salt etc.
Precursor and colour coupler can be distinguished and use two or more, and its content is preferably respectively 0.01～5.0 quality % in mixture, more preferably 0.1～4.0 quality %.
[other dyestuff]
Hair coloring preparation composition of the present invention, as the dyestuff beyond oxidation dye, can further and use direct dyes.As direct dyes, can enumerate nitro dye, disperse dyes, basic stain, acid stain etc.As nitro dye, can enumerate 2-nitro p-phenylenediamine, the chloro-4-nitrophenol of 2-amino-6-, 3-nitro to hydroxyethylamino phenol, NPD, 4-amino-3-nitro phenol, 4-hydroxypropyl amino-3-nitro phenol, No. 2, HC indigo plant, No. 1, HC orange, yellow No. 2 of red No. 1 of HC, HC, yellow No. 4 of HC, HC yellow No. 5, red No. 3 of HC, N, N-couple-(2-ethoxy)-2-nitro p-phenylenediamine etc.; As disperse dyes, can enumerate disperse violet 1, disperse blue 1, dispersion black 9 etc.; As basic stain, can enumerate that alkali blue 99, bismarck brown 16, bismarck brown 17, alkalescence are red 76, alkalescence is red 51, basic yellow 57, basic yellow 87, Basic Orange 31 etc.As acid stain, can enumerate orange No. 205, red No. 106 etc.
Also two or more kinds may be used for direct dyes.In addition, its content is preferably 0.001～5.0 quality % in mixture, more preferably 0.01～3.0 quality %.
[alkaline agent]
Hair dye of the present invention or depigmenting agent compositions contain alkaline agent in the 1st dose.As alkaline agent, can enumerate ammonia and salt thereof; Sodium hydroxide, potassium hydroxide; Alkanolamine and the salt thereof of monoethanolamine, isopropanolamine, 2-amino-2-methyl propanol, 2-amino butanol etc.; Alkane diamidogen and the salt thereof of 1,3-propane diamine etc.; The carbonate of sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate etc. etc.
Two or more kinds may be used for alkaline agent, content in mixture, from the viewpoint of sufficient hair dyeing effect and the viewpoint that reduces hair damages or scalp irritation, be preferably 0.05～15.0 quality %, more preferably 0.1～10.0 quality %, be more preferably 0.2～5.0 quality %.In addition, do not comprise described guanidinesalt in the content of this said alkaline agent.
[hydrogen peroxide]
Hair dye of the present invention or depigmenting agent compositions contain hydrogen peroxide in the 2nd dose.The content of the hydrogen peroxide in mixture, the viewpoint from sufficient hair dyeing effect and reduction hair damages or scalp irritation, be preferably 0.1～12.0 quality %, and more preferably 0.5～9.0 quality %, be more preferably 1.0～6.0 quality %.
[surfactant]
In hair dye of the present invention or depigmenting agent compositions, can in any preparation more than a kind, contain surfactant.As surfactant, also can use any of anion surfactant, non-ionic surface active agent, cationic surfactant, amphoteric surfactant.
As anion surfactant, such as enumerating the sulfuric acid ester anion surfactants such as alkyl sulfate, alkyl ether sulfate; The carboxylic acids anion surfactants such as salt of N-acyl amino hydrochlorate, N-acyl group-N-alkylaminoacid salts, acid amide type N-acyl amino hydrochlorate, ether carboxylate, soap, succinic acid Arrcostab or succinic acid alkenyl esters; The sulfonic acid analog anion surfactants of sulfosuccinate type, isethionate type, taurate type, alkylbenzenesulfonate type, alpha-alkene sulfonate type, alkane sulfonic acid type etc.; The phosphoric acid ester such as alkylphosphonic, alkyl ether phosphate anion surfactant.Wherein, optimization acid's class, sulfuric acid ester, wherein optimization acid's class.Preferred N-acyl amino hydrochlorate, ether carboxylate in the carboxylic acids anion surfactant, wherein, preferably the carbon number of acyl group is 10～18, is preferably 10～16, is more preferably 10～14 N-acyl glutamate; The carbon number of alkyl is 10～18, is preferably 10～16, and more preferably the average addition molal quantity of 10～14 oxyethylene group is 3～15, is preferably 3～12, is more preferably 4～10 polyxyethylated carboxylate.
As non-ionic surface active agent, can enumerate alkyl poly glucoside, polyoxyalkylene alkyl, alkyl glycerol base ether etc.As alkyl poly glucoside, the carbon number of preferred alkyl is 8～18, is more preferably 8～14,9～11 alkyl poly glucoside more preferably, and in addition, preferably this alkyl is straight chained alkyl.The average degree of polymerization of glucosides is preferably 1～5, and more preferably 1～2.As polyoxyalkylene alkyl, the carbon number that is preferably alkyl is 10～22,12～18 polyoxyalkylene alkyl more preferably, and in addition, preferably this alkyl is straight chained alkyl.In addition, be more preferably polyoxyethylene alkyl ether, wherein the average addition molal quantity of preferential oxidation vinyl is 1～50, is more preferably 2～40 polyoxyethylene alkyl ether.As alkyl glycerol base ether, the carbon number of preferred alkyl is 8～18, is more preferably 8～12 alkyl glycerol base ether, and in addition, preferably this alkyl is branched alkyl.
As cationic surfactant, be preferably the single-long-chain alkyl quaternary ammonium salt, two long chain alkyl ammonium salts, particularly, can enumerate hexadecyltrimethylammonium chloride, the stearyl trimethyl ammonium chloride, mountain Yu base trimethyl ammonium chloride, oronain (stearalkonium chloride) draws in department, benzalkonium chloride, stearic oxygen base oxypropyl trimethyl ammonium chloride, dialkyl group (C12-18) alkyl dimethyl ammonium chloride etc., stearyl trimethyl ammonium chloride more preferably, mountain Yu base trimethyl ammonium chloride, stearic oxygen base oxypropyl trimethyl ammonium chloride, dialkyl group (C12-18) alkyl dimethyl ammonium chloride.As the commercially available product of cationic surfactant, can enumerate that QUARTAMIN86W, QUARTAMIN 86P CONC, QUARTAMIN60W, QUARTAMIN E-80K, QUARTAMIND2345P(are above to be manufactured for KAO. Corp. SA), NIKKOL CA-2580(Nihon SurfactantKogyo K.K. manufacture).
As amphoteric surfactant; can enumerate the surfactant of carboxybetaine class with alkyl, thiazolinyl or acyl group that carbon number is 8～24, amide betaine class, sulfobetaines class, hydroxy sulfo lycine class, amide sulfo betaine class, phosphate ester betaines, imidazolines, wherein preferably carboxybetaine class surfactant, sulfobetaines class surfactant.As preferred amphoteric surfactant, can enumerate lauric amide CAB, fatty acid distribution of coconut oil amido propyl betaine, lauryl dimethyl aminoacetic acid betanin, lauryl hydroxy sulfo lycine etc.
Two or more kinds may be used for surfactant, the content in mixture, and the viewpoint from the stability of mixture, be preferably 2.0～8.0 % by weight, and more preferably 2.5～7.0 quality %, be more preferably 3.0～6.0 quality %.
[higher alcohol]
In oxidative hair dyes of the present invention or depigmenting agent compositions, from sense of touch improve, the viewpoint of stability, preferably at any one of the 1st dose, the 2nd dose and the 3rd dose, take the upper carbon number that contains as the higher alcohol more than 12.These form structure with surfactant and prevent from separating, and have the effect of improving the sense of touch while rinsing.
As higher alcohol, be preferably carbon number and be 12～30, more preferably 16～22 higher alcohol, particularly, can enumerate myristyl alcohol, spermol, stearyl alcohol, arachidic alcohol, behenyl alcohol, isooctadecanol, 2-octyldodecanol, oleyl alcohol etc., and their mixture.
Two or more kinds may be used for higher alcohol, and in addition, its content, from the viscosity of mixture and the viewpoint of stability, be preferably 3.0～11.0 % by weight in mixture, is more preferably 4.0～9.0 % by weight.
[polyhydric alcohol]
Hair dye of the present invention or depigmenting agent compositions, further preferably contain polyhydric alcohol.As polyhydric alcohol, it is the polyhydric alcohol that carbon number is 2～20, particularly, can enumerate ethylene glycol, diethylene glycol, triethylene glycol, Polyethylene Glycol, propylene glycol, dipropylene glycol, polypropylene glycol, 1, the aklylene glycol class of 2-butanediol, 1,3 butylene glycol, pentanediol, hexanediol etc.; The glycerols of glycerol, two glycerol, polyglycereol etc.; The sugar alcohols of xylitol, mannitol, galactitol (galactitol), Sorbitol etc.; Other trimethylolethane, trimethylolpropane, tetramethylolmethane etc.
Also two or more kinds may be used for polyhydric alcohol.In addition, the content in mixture, moistening from giving to hair, as to suppress the withered effect excellence of hair viewpoint, be preferably 0.1～20.0 quality %, is more preferably 0.5～15.0 quality %, more preferably 1.0～10.0 quality %.
[medium]
In compositions of the present invention, as medium, can make water and organic solvent as required.As organic solvent, except above-mentioned aromatic alcohols, can enumerate the carbitol class of the cellosolve class, ethyl carbitol, BC etc. of the polyalcohols, ethyl cellosolve, butyl cellosolve, benzyl cellusolve etc. of the lower alcohols, propylene glycol, 1,3 butylene glycol, diethylene glycol, glycerol etc. of ethanol, 2-propanol etc.
[dosage form etc.]
Compositions of the present invention, can with the oxide hair dye extensively utilized now or depigmenting agent similarly, as providing with the 2nd dose of double-formulation formed that contains hydrogen peroxide by the 1st dose that contains alkaline agent, the Powdered oxidant perhaps formed as the granules that further combines persulfate (Ammonium persulfate., potassium peroxydisulfate, sodium peroxydisulfate etc.) etc. in order to improve decoloring ability provides as the 3rd dose of three dosage forms that form, and the form that is further used as other preparations of combination in above-mentioned two dosage forms or three dosage forms provides.The dosage form of the 1st dose and the 2nd dose is aqueous such as making, emulsion form, white shape, gel, paste, cystose etc., is being in foamed situation, also can make any of aerosol shape, non-aerosol form.
[pH]
The pH(25 ℃ of compositions of the present invention) preferably the 1st dose be 8.0～12.0, the 2nd dose is 2.0～5.0, from the viewpoint of decolouring hair dyeing effect and skin irritation, whole compositionss during mixing are preferably 8.0～11.5, more preferably 9.0～11.0.As pH adjusting agent, except above-mentioned alkaline agent, can enumerate the phosphate etc. of the hydrochlorate, potassium dihydrogen phosphate, sodium hydrogen phosphate etc. of the organic acid, hydrochloric acid monoethanolamine etc. of the mineral acid, citric acid, glycolic, lactic acid etc. of hydrochloric acid, phosphoric acid etc.
[other any composition]
In compositions of the present invention, can add other composition as cosmetic material is used usually except mentioned component.As so any composition, can enumerate hydro carbons, animal and plant fat, higher fatty acids class, natural or synthetic macromolecule, silicone, ethers, protein derivatives, hydrolyzed protein, amino acids, antiseptic, chelating agen, stabilizing agent, antioxidant, botanical extract, Chinese herbal medicine extract, vitamins, spice, UV absorbent.
[facture]
When using compositions of the present invention by coloring hairs or decolouring processing, for example need only before being about to use the 1st dose of compositions of the present invention and the 2nd dose of (in the situation that three dosage forms, add the 3rd dose) mix, then be applied on hair, after placing official hour, rinse dry getting final product.The temperature be applied on hair is preferably 15～45 ℃, and time of application is preferably 3～60 minutes, is more preferably 5～45 minutes, is more preferably 10～30 minutes.
About the above embodiments of the present invention, below summarize and show.
<1 > a kind of oxidative hair dyes or depigmenting agent compositions, wherein, described hair dye or depigmenting agent compositions the 2nd dose of hair coloring preparation composition or the depigmenting agent compositions of mixing use for containing the 1st dose of alkaline agent and contain hydrogen peroxide, containing the guanidinesalt of the amount that surpasses 0.5 quality % and surpass under the room temperature of amount of 2.0 quality % in mixture is the aromatic alcohols of liquid, content at guanidinesalt is a quality %, when under room temperature, for the content of the aromatic alcohols of liquid, being b quality %, meet (a-0.5) * (b-2.0) >=1.0, and the pH of mixture is 8.0～11.5.
<2 > as<1 > described oxidative hair dyes or depigmenting agent compositions, wherein, guanidinesalt is selected from guanidine hydrochloride, guanidine sulfate, Guanidine nitrate (1:1), guanidine carbonate, bicarbonate guanidine, phosphoguanidine, guanidine thiocyanate, boric acid guanidine, Guanidine Sulfamate 99 and organic acid guanidinesalt.
<3 > as<1 > or<2 > described oxidative hair dyes or the depigmenting agent compositions, wherein, in mixture, the content of guanidinesalt is 1～10 quality %, more preferably 2～8 quality %.
<4 > as<1 >～<3 > the middle described oxidative hair dyes of any one or depigmenting agent compositions, wherein, under room temperature for the aromatic alcohols of liquid be selected from benzylalcohol, cinnamyl alcohol, phenethanol, to anise alcohol, to methylbenzyl alcohol, phenyl phenol and 2-BOE.
<5 > as<1 >～<4 in the described oxidative hair dyes of any one or depigmenting agent compositions, wherein, in mixture under room temperature the content for the aromatic alcohols of liquid be 2.5～20.0 quality %, 3.0～10.0 quality % more preferably.
<6 > as<1 >～<5 > the middle described oxidative hair dyes of any one or depigmenting agent compositions, wherein, further contain surfactant in mixture.
<7 > as<6 > described oxidative hair dyes or depigmenting agent compositions, wherein, surfactant is at least one be selected from anion surfactant, non-ionic surface active agent, cationic surfactant and amphoteric surfactant.
<8 > as<6 > or<7 > described oxidative hair dyes or the depigmenting agent compositions, wherein, in mixture, the content of surfactant is 2.0～8.0 quality %, more preferably 2.5～7.0 quality %, be more preferably 3.0～6.0 quality %.
<9 > as<1 >～<8 > the middle described oxidative hair dyes of any one or depigmenting agent compositions, wherein, further containing carbon number in mixture is the higher alcohol more than 12.
<10 > as<9 > described oxidative hair dyes or depigmenting agent compositions, wherein, carbon number is that the higher alcohol more than 12 is at least one be selected from myristyl alcohol, spermol, stearyl alcohol, arachidic alcohol, behenyl alcohol, isooctadecanol, 2-octyldodecanol and oleyl alcohol.
<11 > as<9 > or<10 > described oxidative hair dyes or the depigmenting agent compositions, wherein, the content that in mixture, carbon number is the higher alcohol more than 12 is 3.0～11.0 quality %, more preferably 4.0～9.0 quality %.
<12 > as<1 >～<11 > the middle described oxidative hair dyes of any one or depigmenting agent compositions, wherein, further contain polyhydric alcohol in mixture.
<13 > as<12 > described oxidative hair dyes or depigmenting agent compositions, wherein, in mixture, the content of polyhydric alcohol is 0.1～20.0 quality %, more preferably 0.5～15.0 quality %, be more preferably 1.0～10.0 quality %.
<14 > as<1 >～<13 > the middle described oxidative hair dyes of any one or depigmenting agent compositions, wherein, meet (a-0.5) * (b-2.0) >=2.0, further preferably meet (a-0.5) * (b-2.0) >=2.5, be more preferably satisfied (a-0.5) * (b-2.0) >=3.0, be more preferably satisfied (a-0.5) * (b-2.0) >=3.5, be more preferably satisfied (a-0.5) * (b-2.0) >=4.0.
<15 > as<1 >～<14 > the middle described oxidative hair dyes of any one or depigmenting agent compositions, wherein, meet 40 >=(a-0.5) * (b-2.0), further preferably meet 35 >=(a-0.5) * (b-2.0), be more preferably and meet 30 >=(a-0.5) * (b-2.0).
<16 > as<1 >～<15 > the middle described oxidative hair dyes of any one or depigmenting agent compositions, wherein, the pH of mixture is 9.0～11.0.
<17 > a kind of hair dyeing or discoloration method, wherein, will<1 before be about to using >～<16 in the 1st dose and the 2nd dose of mixing of the described oxidative hair dyes of any one or depigmenting agent compositions, then be applied on hair, under 15～45 ℃, place 3～60 minutes, more preferably place 5～45 minutes, after being more preferably and placing 10～30 minutes, rinse dry.
Embodiment
Embodiment 1～14, comparative example 1～6
(estimating the making with hair)
After Chinese's poliosis is repeated to following 1 and 2 operation 2 times, after further once decolouring again and processing, with hair-dryer, within dry 15 minutes, make the damage hair.From damage hair visual select hair inside spread all over length integrally the hair of cavityization as the evaluation hair.
1. carry out decolouring in 20 minutes under 30 ℃ processes with destaining solution (table 1);
2. carry out 15 circulations of circulation pattern of following daily hair care behavior.
The circulation pattern of daily hair care behavior: hair is immersed in the water of 40 ℃ after 1 minute, with dry 15 minutes (warm braw) of hair-dryer.
| Destaining solution | (quality %) |
| Ammonium bicarbonate | 0.50 |
| Sequestrene Na4 two water salt | 0.05 |
| Strong ammonia (28 quality %) | 3.00 |
| The aqueous hydrogen peroxide solution of 35 quality % | 8.15 |
| Purified Water | Surplus |
(evaluation of empty repairing effect)
After above-mentioned processing, after confirm estimating the cavity with the inside of hair, dipping 40 root evaluation hairs in the inorganic agent formed by the formula shown in table 2～4 at 11g, under 30 ℃ standing 60 minutes.With the warm water washings of 40 ℃ 15 seconds, after natural drying, again observe the cavity at same position.The cavity of the hair inside before and after comparison process, calculate empty repairing rate by following formula.Repairing rate=(x-y)/x * 100
X: preparation has the radical of empty hair before processing
Y: preparation has the radical of empty hair after processing
(inorganic agent)
Mass ratio by following the 1st dose (table 2) and the 2nd dose (table 3) with 1:1 mixes, and makes inorganic agent.
Table 2:
*: use guanidine carbonate in embodiment 1～13, comparative example 1～6, in embodiment 14, use guanidine hydrochloride.
[table 3]
[table 4]
Embodiment 15～16, comparative example 7
On Japanese's topknot of about 2.8g hair, the destaining solution of coating 3g table 1 is under 30 ℃ standing 30 minutes, with the warm water washings of 40 ℃ 15 seconds, with shampoo, washes flushing in 15 seconds 15 seconds.After making hair conditioner infiltration 15 seconds, rinse 15 seconds, use the hair-dryer drying.To carry out the topknot of 10 these processing as the evaluation topknot.
By estimate with topknot impregnated in 28g by the 2nd dose of inorganic agent be mixed to get with mass ratio 1:1 shown in the 1st dose shown in table 5 and table 6, under 30 ℃ standing 20 minutes.By the warm water washing of 40 ℃ 15 seconds for topknot, make about 3g hair conditioner infiltrate through topknot 15 seconds, after the warm water washings of 40 ℃ 15 seconds, make it dry.
[table 5]
[table 6]
| The 2nd dose (embodiment, comparative example identical) | (quality %) |
| Aqueous hydrogen peroxide solution (35 quality %) | 16.3 |
| Purified Water | Surplus |
Gloss is estimated: allow 3 special evaluation group members that are engaged in the hair dye exploitation more than 5 years carry out visual valuation.Be evaluated as the paired comparison evaluation of comparative example 7 and embodiment 15 and comparative example 7 and embodiment 16, estimated according to following standard.The results are shown in table 7.
Embodiment is more glossy: 2
Embodiment is more glossy a little: 1
Embodiment and comparative example are equal: 0
Comparative example is more glossy a little :-1
Comparative example is more glossy :-2
[table 7]
Claims (15)
1. an oxidative hair dyes or depigmenting agent compositions, wherein,
Described hair dye or depigmenting agent compositions the 2nd dose of hair coloring preparation composition or the depigmenting agent compositions of mixing use for containing the 1st dose of alkaline agent and contain hydrogen peroxide, containing the guanidinesalt of the amount that surpasses 0.5 quality % and surpass under the room temperature of amount of 2.0 quality % in mixture is the aromatic alcohols of liquid, when the content of guanidinesalt is to be b quality % for the content of the aromatic alcohols of liquid under a quality %, room temperature, meet (a-0.5) * (b-2.0) >=1.0, and the pH of mixture is 8.0～11.5.
2. oxidative hair dyes as claimed in claim 1 or depigmenting agent compositions, wherein,
Guanidinesalt is selected from guanidine hydrochloride, guanidine sulfate, Guanidine nitrate (1:1), guanidine carbonate, bicarbonate guanidine, phosphoguanidine, guanidine thiocyanate, boric acid guanidine, Guanidine Sulfamate 99 and organic acid guanidinesalt.
3. oxidative hair dyes as claimed in claim 1 or 2 or depigmenting agent compositions, wherein,
In mixture, the content of guanidinesalt is 1～10 quality %.
4. oxidative hair dyes as claimed in claim 1 or 2 or depigmenting agent compositions, wherein,
In mixture, the content of guanidinesalt is 2～8 quality %.
5. oxidative hair dyes as described as any one in claim 1～4 or depigmenting agent compositions, wherein,
Under room temperature for the aromatic alcohols of liquid be selected from benzylalcohol, cinnamyl alcohol, phenethanol, to anise alcohol, to methylbenzyl alcohol, phenyl phenol and 2-BOE.
6. oxidative hair dyes as described as any one in claim 1～5 or depigmenting agent compositions, wherein,
The content that in mixture under room temperature, is the aromatic alcohols of liquid is 2.5～20.0 quality %.
7. oxidative hair dyes as described as any one in claim 1～5 or depigmenting agent compositions, wherein,
The content that in mixture under room temperature, is the aromatic alcohols of liquid is 3.0～10.0 quality %.
8. oxidative hair dyes as described as any one in claim 1～7 or depigmenting agent compositions, wherein,
Further contain surfactant in mixture.
9. oxidative hair dyes as claimed in claim 8 or depigmenting agent compositions, wherein,
Surfactant is at least one be selected from anion surfactant, non-ionic surface active agent, cationic surfactant and amphoteric surfactant.
10. oxidative hair dyes or depigmenting agent compositions as claimed in claim 8 or 9, wherein,
In mixture, the content of surfactant is 2.0～8.0 quality %.
11. oxidative hair dyes as described as any one in claim 1～10 or depigmenting agent compositions, wherein,
Further containing carbon number in mixture is higher alcohol 3.0～11.0 quality % more than 12.
12. oxidative hair dyes as described as any one in claim 1～11 or depigmenting agent compositions, wherein,
Further contain polyhydric alcohol in mixture.
13. oxidative hair dyes as claimed in claim 12 or depigmenting agent compositions, wherein,
In mixture, the content of polyhydric alcohol is 0.1～20.0 quality %.
14. oxidative hair dyes as described as any one in claim 1～13 or depigmenting agent compositions, wherein,
（a-0.5）*（b-2.0）≥3.5。
15. oxidative hair dyes as described as any one in claim 1～14 or depigmenting agent compositions, wherein,
（a-0.5）*（b-2.0）≥4.0。
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| JP2011-085434 | 2011-04-07 | ||
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| PCT/JP2012/059390 WO2012137877A1 (en) | 2011-04-07 | 2012-04-05 | Oxidative hair dye or bleaching agent composition |
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| JP (1) | JP5956807B2 (en) |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109199892A (en) * | 2017-06-30 | 2019-01-15 | 朋友株式会社 | Composition and its application method containing oxidant |
| CN111050743A (en) * | 2017-09-20 | 2020-04-21 | 花王株式会社 | Liquid hair dye composition |
| CN111093596A (en) * | 2017-09-20 | 2020-05-01 | 花王株式会社 | Powdered composition |
| CN111107830A (en) * | 2017-09-20 | 2020-05-05 | 花王株式会社 | Liquid hair dye composition |
| CN111132736A (en) * | 2017-09-20 | 2020-05-08 | 花王株式会社 | Hair dyeing method |
| CN113613732A (en) * | 2019-03-19 | 2021-11-05 | 花王株式会社 | Liquid hair dye composition |
| CN114727930A (en) * | 2019-11-26 | 2022-07-08 | 汉高股份有限及两合公司 | Method for decolouring keratin materials which have been coloured by application of pigments |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2015022361A1 (en) * | 2013-08-15 | 2015-02-19 | Kao Corporation | Aqueous composition for treating hair |
| JP6158041B2 (en) * | 2013-10-30 | 2017-07-05 | ヘンケルジャパン株式会社 | Second agent composition for dyeing or decoloring hair |
| EP2883570A1 (en) * | 2013-12-13 | 2015-06-17 | Kao Corporation | Powder hair lightening/bleaching composition |
| FR3015240B1 (en) * | 2013-12-19 | 2019-08-02 | L'oreal | HAIR COLORING COMPOSITION COMPRISING A SALT OF GUANIDINE |
| FR3015241B1 (en) * | 2013-12-19 | 2019-08-02 | L'oreal | CAPILLARY CLARIFICATION COMPOSITION COMPRISING A GUANIDINE SALT |
| CN113456017A (en) | 2020-03-30 | 2021-10-01 | 尼德克株式会社 | Ophthalmic device |
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| JP2002068976A (en) * | 2000-08-30 | 2002-03-08 | Chuo Aerosol Kagaku Kk | Composition for human body, formulated with alkaline guanidine |
| JP2002193770A (en) * | 2000-12-28 | 2002-07-10 | Kao Corp | Hair dye composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP3563569B2 (en) * | 1997-07-09 | 2004-09-08 | 花王株式会社 | Hair treatment composition |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002068976A (en) * | 2000-08-30 | 2002-03-08 | Chuo Aerosol Kagaku Kk | Composition for human body, formulated with alkaline guanidine |
| JP2002193770A (en) * | 2000-12-28 | 2002-07-10 | Kao Corp | Hair dye composition |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109199892A (en) * | 2017-06-30 | 2019-01-15 | 朋友株式会社 | Composition and its application method containing oxidant |
| CN111050743A (en) * | 2017-09-20 | 2020-04-21 | 花王株式会社 | Liquid hair dye composition |
| CN111093596A (en) * | 2017-09-20 | 2020-05-01 | 花王株式会社 | Powdered composition |
| CN111107830A (en) * | 2017-09-20 | 2020-05-05 | 花王株式会社 | Liquid hair dye composition |
| CN111132736A (en) * | 2017-09-20 | 2020-05-08 | 花王株式会社 | Hair dyeing method |
| CN111107830B (en) * | 2017-09-20 | 2022-11-29 | 花王株式会社 | Liquid hair dye composition |
| CN111132736B (en) * | 2017-09-20 | 2022-11-29 | 花王株式会社 | Hair dyeing method |
| CN113613732A (en) * | 2019-03-19 | 2021-11-05 | 花王株式会社 | Liquid hair dye composition |
| CN114727930A (en) * | 2019-11-26 | 2022-07-08 | 汉高股份有限及两合公司 | Method for decolouring keratin materials which have been coloured by application of pigments |
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| JP2012224621A (en) | 2012-11-15 |
| JP5956807B2 (en) | 2016-07-27 |
| WO2012137877A1 (en) | 2012-10-11 |
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