The recycle device of waste heat and dust in reclaimed copper refining flue gas
Technical field
The present invention is the recycle device of waste heat and dust in a kind of reclaimed copper refining flue gas.The method that belongs to UTILIZATION OF VESIDUAL HEAT IN and exhaust-gas treatment.
Background technology
The reclaimed copper refining is that to take blister copper, useless composition brass be raw material, prepares the smart copper of copper content >=99.3% through the processing refining, and the process of copper ingot or positive plate is made in then cast molding.
Regeneration Rotary Anode Furnace in Copper operation be divided into feed intake, oxidation, reduction and casting four-stage.Wherein the flue-gas temperature of oxidation stage discharge is at 1200~1300 ℃, and flue gas contains a large amount of dust, and carries the metallic particles of semi-molten state; At reduction phase, adopt heavy oil as reducing agent, its utilization rate is lower than 30%, and remaining is 70% with fume emission, and the flue-gas temperature of reduction phase is up to 1400 ℃.In the reclaimed copper refining process, the heat that flue gas is taken away accounts for the over half of metal smelt total energy consumption.Therefore, in reclaimed copper refinery practice process, the waste heat carried in the flue gas of discharge is valuable heat resource.By it, recycle for saving the energy significant.The recycling of the heat energy that simultaneously, the flue gas of reclaimed copper refinery practice discharge carries is the important step that reclaimed copper refining enterprise reduces energy consumption and production costs.
Contain copper metal and various valuable element in a large amount of exhaust gas dusts that the reclaimed copper refining produces.In order to improve smelting recovery, and reclaim valuable element, the while environmental contamination reduction, the recovery of exhaust gas dust has Important Economic benefit and environmental benefit.
In prior art, the recycling of reclaimed copper refining fume afterheat, mostly adopt waste heat boiler, only the high-temperature flue gas waste heat recycled, and middle-low temperature heat is not also recycled fully, and the heat exchange efficiency of traditional waste heat boiler is low.Therefore, exist the residual heat resources rate of recovery lower.Still have part of waste heat to enter atmosphere with tail gas.Both wasted energy, again contaminated environment.
In reclaimed copper refining flue gas of the prior art, the recovery method of dust, have dry method to gather dust and wet dust collector.Dry method is gathered dust and is reclaimed dust and use morely, exists process control unstable, burns out the cloth bag recover, or the fault that cloth bag stops up happens occasionally, and causes stopping.Have a strong impact on steady production, and energy consumption is higher, dust reclaims not exclusively.Tail gas enters atmosphere, causes environmental pollution.
A kind of high-temperature residual heat that not only reclaims, and reclaim middle-low temperature heat, waste heat recovery efficiency is high, and dust reclaims fully, and the recycle device of waste heat and dust in the lower desirable reclaimed copper refining flue gas of cost recovery, is that people expect.
Summary of the invention
The object of the invention is to avoid above-mentioned weak point of the prior art, and a kind of high-temperature residual heat that not only reclaims is provided, and reclaim middle-low temperature heat, waste heat recovery efficiency is high, dust reclaims fully, and the recycle device of waste heat and dust in the lower reclaimed copper refining flue gas of cost recovery.
Purpose of the present invention can reach by following measure:
In refining flue gas of the present invention, the recycle device of waste heat and dust, is characterized in that comprising waste-heat recovery device and device for recovering powder;
Described waste-heat recovery device is comprised of countercurrent flow waste heat boiler A1, countercurrent flow waste heat boiler B2 and countercurrent flow waste heat boiler working medium preheater 3;
Described device for recovering powder is washed tower 4, liquid film washer 5, mist catcher 6, air-introduced machine 7, settlement filter A8, settlement filter B9 by water wash and is formed;
Waste-heat recovery device and device for recovering powder are linked in sequence and form by pipeline or pipe fitting, and in flue gas, the recoverying and utilizing method of waste heat and dust comprises the steps:
1.. the waste heat one-level reclaims
High-temperature flue gas from the reclaimed copper refining furnace enters countercurrent flow waste heat boiler A1, and with working medium countercurrent flow in boiler, the high temperature heat that it is carried passes to boiler working substance; Flue gas self temperature is reduced to≤700 ℃ realize that the waste heat one-level reclaims;
2.. the waste heat secondary recovery
Through step 1. the flue gas of waste heat after once reclaiming enter countercurrent flow waste heat boiler B2, with the boiler working substance countercurrent flow, warmly during it is carried can pass to boiler working substance; Flue gas self temperature is reduced to≤450 ℃ realize the waste heat secondary recovery;
3.. three grades of recovery of waste heat
Through step 2. the flue gas after the waste heat secondary recovery enter countercurrent flow waste heat boiler working medium preheater 3, with the working medium countercurrent flow of waste heat boiler working medium preheater 4, the low temperature heat energy that it is carried passes to the working medium of boiler working substance preheater; Flue gas self temperature is reduced to≤120 ℃ realize three grades of recovery of waste heat;
4.. water smoke drip washing dust reclaims
Enter water wash from the flue gas of countercurrent flow waste heat boiler working medium preheater 3 and wash tower 4 bottoms, in uphill process with the water droplet counter current contacting of tower top spray atomizing, dust enters settlement filter A8 with washing water, Separation of Solid and Liquid is filtered in sedimentation, washing water is sent to water wash and washs tower 4 tower tops, continue to recycle, filter residue is recycled; Flue gas after washing is washed tower 4 tower tops from water wash and is flowed out;
5.. the liquid film dust reclaims
Through step, 4. after water smoke drip washing, the flue gas of washing tower 4 from water wash enters liquid film absorber 5, after continuing to reclaim dust, enters deposition filter B9, and Separation of Solid and Liquid is filtered in sedimentation, and water is sent to water wash and washs tower 4 tower tops, continues to recycle, and filter residue is recycled;
6.. mist is removed
Through step 5. the flue gas of liquid film dust after reclaiming enter mist catcher 6, remove mist;
7.. exhaust emissions
Through the 6. dustless tail gas of mist after removing of step, after reaching discharge standard, through air-introduced machine 7 discharges.
From thermodynamic (al) theory, the most rational heat exchange mode is countercurrent flow, and under same heat transfer boundary condition, countercurrent flow can be realized the uniform temperature difference, and the irreversible loss that makes heat transfer process produce is little, therefore changes efficiency high.The technical scheme that the waste heat carried in the flue gas that the present inventor adopts countercurrent heat exchange method to discharge for the reclaimed copper refinery practice is recycled, for solving the technical problem to be solved in the present invention, made outstanding contribution.
Water smoke drip washing dust reclaims, and the liquid film dust reclaims, to the recovering effect of dust all significantly better than prior art.The tail gas of discharge reaches the discharge standard of national regulation.
Purpose of the present invention can also reach by following measure:
The recycle device of waste heat and dust in reclaimed copper refining flue gas of the present invention, it is characterized in that step 1., 2., waste-heat recovery device countercurrent flow waste heat boiler A1, the countercurrent flow waste heat boiler B2 and countercurrent flow waste heat boiler working medium preheater 3 flue gases that adopt in 3. adopt pair bushing type countercurrent heat exchange methods with the heat exchange that boiler afterheat reclaims between working medium, or three bushing type countercurrent heat exchange methods; Wherein:
Described pair of bushing type countercurrent heat exchange method, the heat-exchanger rig two straight tube suit configurations different by several diameters constitute, and flue gas is walked central tube, and waste heat recovery working medium is walked the annular space pipe, and the two flow direction is contrary, realizes countercurrent flow;
Described three bushing type countercurrent heat exchange methods, the heat-exchanger rig three straight tube suit configurations different by diameter form, and flue gas is walked central tube and outer annular space, and waste heat recovery working medium is walked interior annular space pipe, and the two flow direction is contrary, realizes countercurrent flow.
It is preferred scheme in time.
The recycle device of waste heat and dust in reclaimed copper refining flue gas of the present invention, it is characterized in that step 1., 2., waste-heat recovery device countercurrent flow waste heat boiler A1, the countercurrent flow waste heat boiler B2 and countercurrent flow waste heat boiler working medium preheater 3 flue gases that adopt in 3. all adopt two bushing type countercurrent heat exchange methods with the heat exchange that boiler afterheat reclaims between working medium. the heat-exchanger rig two straight tubes suits different by several diameters configure and constitute, flue gas is walked central tube, waste heat recovery working medium is walked the annular space pipe, the two flow direction is contrary, realizes countercurrent flow.
It is a preferred technical scheme.
The recycle device of waste heat and dust in reclaimed copper refining flue gas of the present invention, it is characterized in that step 1., 2., the waste-heat recovery device countercurrent flow waste heat boiler A1, the countercurrent flow waste heat boiler B2 that adopt in 3. and the heat exchange between countercurrent flow waste heat boiler working medium preheater 3 flue gases and boiler working substance all adopt three bushing type countercurrent heat exchange methods, the heat-exchanger rig three straight tube suit configurations different by diameter form, flue gas is walked central tube and outer annular space, waste heat recovery working medium is walked interior annular space pipe, the two flow direction is contrary, realizes countercurrent flow.
It is most preferred technical scheme.
The recycle device of waste heat and dust in reclaimed copper refining flue gas of the present invention, it is characterized in that step 1., 2., 3. in the waste-heat recovery device countercurrent flow waste heat boiler A1 flue gas adopted and the heat exchange that boiler afterheat reclaims between working medium all adopt pair bushing type countercurrent heat exchange methods; Heat exchange between countercurrent flow waste heat boiler B2 and countercurrent flow waste heat boiler working medium preheater 3 flue gases and boiler working substance adopts three bushing type countercurrent heat exchange methods.
It is a preferred technical scheme.
The recycle device of waste heat and dust in reclaimed copper refining flue gas of the present invention, is characterized in that waste heat that the flue gas during smelting of flue-gas temperature≤1000 ℃ carries and the recoverying and utilizing method of dust, and described step is the waste heat secondary recovery 2., and saving need not.Be one and save the preferred technical scheme of equipment investment.
The recycle device of waste heat and dust in reclaimed copper refining flue gas of the present invention, the working medium that it is characterized in that described waste heat boiler working medium or waste heat boiler working medium preheater is water or low boiling organic working medium.
The heat energy that in reclaimed copper refining flue gas of the present invention, the recycle device of waste heat and dust reclaims utilize method, it is characterized in that directly using with the form of heat energy, or change the heat energy of recovery into electric energy or mechanical energy.
The recycle device of waste heat and dust in reclaimed copper refining flue gas of the present invention has following good effect compared to existing technology:
1.. a kind of high-temperature residual heat that not only reclaims is provided, and has reclaimed middle-low temperature heat, waste heat recovery efficiency is high, and dust reclaims fully, and the waste heat carried in the flue gas of the lower reclaimed copper refining discharge of cost recovery and the recycle device of dust.
2.. contain copper metal and various valuable element in exhaust gas dust and recycle, improved blister copper and smelted productive rate, and reclaimed valuable element, obtain obvious economic benefit; The tail gas of discharge reaches the discharge standard of national regulation, the spontaneous combustion environmental protection of having protected the mankind to depend on for existence.
3.. avoided dry method to gather dust and reclaimed in dust technique, the process control of existence is unstable, burns out the cloth bag recover, or the fault of cloth bag obstruction.
. 4.. adopt countercurrent flow, improved the heat recovery rate.Waste heat recovery rate >=90%.
5.. reduce water consumption, reduced energy consumption.
The accompanying drawing explanation
Fig. 1 is the receipts use device schematic flow sheet that in reclaimed copper refining flue gas of the present invention, waste heat and dust return.Wherein:
1. countercurrent flow waste heat boiler A
2. countercurrent flow waste heat boiler B
3. countercurrent flow waste heat boiler working medium preheater
4. water wash is washed tower
5. liquid film washer
6. mist catcher
7. air-introduced machine
8. settlement filter A
9. settlement filter B
The specific embodiment
The present invention will now be further detailed embodiment:
Embodiment 1
In a kind of reclaimed copper refining flue gas, the recycle device of waste heat and dust, comprise waste-heat recovery device and device for recovering powder;
Described waste-heat recovery device is comprised of countercurrent flow waste heat boiler A1, countercurrent flow waste heat boiler B2 and countercurrent flow waste heat boiler working medium preheater 3;
Described device for recovering powder is washed tower 4, liquid film washer 5, mist catcher 6 air-introduced machines 7, settlement filter A8, settlement filter B9 by water wash and is formed;
Waste-heat recovery device and device for recovering powder are linked in sequence and form by pipeline or pipe fitting, and in flue gas, the recoverying and utilizing method of waste heat and dust comprises the steps:
1.. the waste heat one-level reclaims
The flue gas of 1350 ℃ from the reclaimed copper refining furnace enters countercurrent flow waste heat boiler A1, adopt two bushing type countercurrent heat exchange methods, the heat-exchanger rig two straight tube suit configurations different by several diameters constitute, flue gas is walked central tube, waste heat recovery working medium is walked the annular space pipe, the two flow direction is contrary, realizes countercurrent flow; With working medium countercurrent flow in boiler, the high temperature heat that flue gas carries it passes to boiler evaporating working medium; Flue gas self temperature is reduced to≤700 ℃ realize that the waste heat one-level reclaims;
2.. the waste heat secondary recovery
Through step 1. the flue gas of waste heat after once reclaiming enter countercurrent flow waste heat boiler B2, adopt two bushing type countercurrent heat exchange methods, the heat-exchanger rig two straight tube suit configurations different by several diameters constitute, flue gas is walked central tube, waste heat recovery working medium is walked the annular space pipe, the two flow direction is contrary, realizes countercurrent flow, and the high temperature heat that flue gas carries it passes to boiler evaporating working medium; Flue gas self temperature is reduced to≤450 ℃ realize the waste heat secondary recovery;
3.. three grades of recovery of waste heat
Through step 2. the flue gas after the waste heat secondary recovery enter countercurrent flow waste heat boiler working medium preheater 3, adopt two bushing type countercurrent heat exchange methods, the heat-exchanger rig two straight tube suit configurations different by several diameters constitute, flue gas is walked central tube, waste heat recovery working medium is walked the annular space pipe, the two flow direction is contrary, realizes countercurrent flow; The working medium countercurrent flow of flue gas and waste heat boiler working medium preheater 4, the low temperature heat energy that it is carried passes to the working medium of boiler working substance preheater; Flue gas self temperature is reduced to≤120 ℃ realize three grades of recovery of waste heat;
4.. water smoke drip washing dust reclaims
Enter water wash from the flue gas of countercurrent flow waste heat boiler working medium preheater 3 and wash tower 4 bottoms, in uphill process with the water droplet counter current contacting of tower top spray atomizing, most of dust enters settlement filter A8 with washing water, Separation of Solid and Liquid is filtered in sedimentation, washing water is sent to water wash and washs the use of tower top continuation circulation cleaning, and filter residue is recycled; Flue gas after washing flows out from tower top, continues to reclaim dust;
5.. the liquid film dust reclaims
Through step, flue gas 4. enters liquid film absorber 5, after continuing to reclaim dust, enters deposition filter B9, and Separation of Solid and Liquid is filtered in sedimentation, and water is sent to water wash and washs tower top and continue circulation cleaning and use, and filter residue is recycled;
6.. mist is removed
Through step 5. the flue gas of liquid film dust after reclaiming enter mist catcher 7, remove mist;
7.. exhaust emissions
Through the 6. dustless tail gas of mist after removing of step, after reaching discharge standard, through air-introduced machine (7), discharge.
Waste heat recovery rate >=90%.The tail gas of discharge reaches the discharge standard of national regulation.
Embodiment 2
According to the recycle device of waste heat and dust in the reclaimed copper refining flue gas of embodiment 1, difference is:
Step 1., 2., waste-heat recovery device countercurrent flow waste heat boiler A1, the countercurrent flow waste heat boiler B2 and the countercurrent flow waste heat boiler working medium preheater 3 that adopt in 3., heat exchange between flue gas and boiler working substance all adopts three bushing type countercurrent heat exchange methods, the heat-exchanger rig three straight tube suit configurations different by diameter form, flue gas is walked central tube and outer annular space, waste heat recovery working medium is walked interior annular space pipe, the two flow direction is contrary, realizes countercurrent flow.
Waste heat recovery rate >=95%.The tail gas of discharge reaches the discharge standard of national regulation.
Embodiment 3
According to the recycle device of waste heat and dust in the reclaimed copper refining flue gas of embodiment 1, difference is:
Step is the middle waste-heat recovery device countercurrent flow waste heat boiler A1 adopted 1., flue gas all adopts two bushing type countercurrent heat exchange methods from the heat exchange that boiler afterheat reclaims between working medium. and the heat-exchanger rig two straight tube suit configurations different by several diameters constitute, flue gas is walked central tube, waste heat recovery working medium is walked the annular space pipe, the two flow direction is contrary, realizes countercurrent flow.
Step 2., the waste-heat recovery device countercurrent flow waste heat boiler B2 that adopts in 3. and the heat exchange between countercurrent flow waste heat boiler working medium preheater 3 flue gases and boiler working substance all adopt three bushing type countercurrent heat exchange methods, the heat-exchanger rig three straight tube suit configurations different by diameter form, flue gas is walked central tube and outer annular space, waste heat recovery working medium is walked interior annular space pipe, the two flow direction is contrary, realizes countercurrent flow.
Waste heat recovery rate >=93%.The tail gas of discharge reaches the discharge standard of national regulation.