CN103469643B - Inkjet printing method of ultra-thin thin fabric and inkjet printing combination layer thereof - Google Patents
Inkjet printing method of ultra-thin thin fabric and inkjet printing combination layer thereof Download PDFInfo
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- CN103469643B CN103469643B CN201310450452.5A CN201310450452A CN103469643B CN 103469643 B CN103469643 B CN 103469643B CN 201310450452 A CN201310450452 A CN 201310450452A CN 103469643 B CN103469643 B CN 103469643B
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Abstract
The invention discloses an inkjet printing method of ultra-thin thin fabric. The method includes the steps that printing assistant is dissolved in solvent, pasting material is added and stirred, and a sizing agent is prepared; the sizing agent is pressed on the ultra-thin thin fabric in a soaked mode, or the ultra-thin thin fabric is coated with the sizing agent, and the ultra-thin thin fabric with the sizing agent is dried and coiled for use; a carrier is coated with adhesive to serve as a cushion layer carrier, and the carrier coated with the adhesive is dried for use; the ultra-thin thin fabric processed in the coating or soaking pressing mode is attached to the adhesive side of the cushion layer carrier, pressurizing is performed, the ultra-thin thin fabric and the cushion layer carrier are combined together to form an inkjet printing combination layer, and the inkjet printing combination layer is coiled for use; the inkjet printing combination layer is installed on the inkjet printing machine, inkjet printing is performed on one side, where the sizing agent is distributed, of the ultra-thin thin fabric, and meanwhile drying and coiling are performed; the ultra-thin thin fabric is processed in an after-finish fixation mode and then is washed by water, forming or stentering is performed, and the ultra-thin thin fabric with inkjet printed patterns is formed.
Description
Technical field
The invention belongs to textile printing and dyeing field, particularly a kind of ink-jet printing method of ultrathin shell fabric and ink-jet printed combination layer thereof.
Background technology
Ink-jet printed, having another name called digit printing, is the stamp undertaken by digital technology.Ink-jet printed technology is a kind of new high-tech product integrating machinery, computer electronic information technology formed gradually along with computer technology development, it comes across the mid-90 in 20th century the earliest, the appearance of this technology is with constantly perfect, a completely new concept is brought to textile printing and dyeing industry, the production principle of its advanced person and means, bring a unprecedented opportunity to develop to textile printing and dyeing.
Ink-jet printed production process be exactly briefly by various digitlization means as: scanning, digital photo, the various digitlization pattern input computers that image or computing mechanism deal with, again by after the process of computer color splitting printing system, by special RIP software by various dedicated dye is (active to its sprayed printed system, dispersion, acid main coating) directly spray printing is on various fabric or other medium, again after processing, various weaving face fabric obtains required various high-precision Printing, the advantage of the following aspects is had compared with traditional dyeing and finishing technique:
1. ink-jet printed production process makes original process route greatly shorten, and order speed is fast, and cost of drawing a design reduces greatly.
Due to the ink-jet printed technological process of production broken away from Conventional decal in process of production color separation retouch original text, film-making, network process processed, thus production time greatly shortened.Accept the mode of style, can pass through the various advanced means such as CD, E-mail, generally the time of drawing a design is no more than a working day, and the cycle that tradition is drawn a design is generally at about one week.
In addition because the simplification of the technique cost that makes to draw a design also reduces greatly.Draw a design the shortening in cycle and the reduction of cost of drawing a design, this is in current Time is money, under the market competition rule that efficiency is most important, brings the more market opportunity undoubtedly to enterprise.
2. the principle of ink-jet printed technology makes its product break the chromatography of traditional mode of production and spend back the restriction of length, and weaving face fabric can be made to realize the printing effect of high-grade printing.
Because ink-jet printed technology can adopt digital pattern, colour measuring & colour matching, spray printing is carried out through computer, thus make the color of digit printing product can reach 1,670 ten thousand kinds in theory, breach the chromatography restriction of traditional textile printing and dyeing style, particularly in the printing to the patterns of high precision such as color gradient, moire, ink-jet printed have unrivaled advantage technically especially.In addition, the pattern of Conventional decal is often subject to the restriction of " spending back " length, and can not there is the concept of " spending back " in ink-jet printed technical process, thus has greatly expanded the space of Textile Pattern Design, improves the class of product.
3. ink-jet printed production really achieves the production process of small lot, fast response, and production lot is unrestricted.
Because ink-jet printed production process all realizes computerized digital production, thus production chains is improved greatly, some products even can realize delivery on the same day, immediate delivery.In addition, due to the application of computer technology, print the serial pattern of the different tone of same pattern, and in process of production designers to pattern being constantly modified as in order to ink-jet printed production is different from the large technical advantage that Conventional decal produces color.
4. high-precision jet printing process to make in jet printing process without water without mill base.
In jet printing process, the use of dyestuff is by computer " distribution according to need ", make in jet printing process, do not contaminate the waste of material, emit no waste water, by computer-controlled jet printing process, do not produce noise, make not produce pollution in jet printing process, achieve Green production process, thus the production process of the production of textile printing is broken away from the past high energy consumption, high pollution, high noisy, achieve low energy consumption, free of contamination production process, bring a technological revolution to the production of textile printing and dyeing.
Along with the speed issue of one of the progress and ink-jet printed bottleneck of technology is resolved substantially, the ink-jet printed proportion occupied in printing in textiles is increasing at present, in printing in textiles, and polyester fabric, silk fabric, in cotton fabric etc. shared must in continue to increase.Only before the several years, ink-jet printed also only rest on draw a design on, even if there is order, be also only confined to tens of rice, the little order of hundreds of meters; At present, the ink-jet printed order of thousands of meters is very common, tens thousand of rice, and even the ink-jet printed order of 10 myriametres is not rarely seen yet.Along with the continuation of ink-jet printed speed improves, the continuation of cost declines, and the real ink-jet printed epoch will arrive, and this time can not too late, also with regard within 2-3.
But the ink-jet printed ultrathin shell fabric being less than or equal to 60 grams/m for general grammes per square metre has very large difficulty in the prior art, such as real silk paj, Nylon Taffeta etc.The grammes per square metre of this kind fabric own is light, blotting amount is just not enough, spy in such as ink-jet printed is dark, quantity of ink needs to reach the color depth demand that 30 ~ 50 grams/m of ability meet client, this quantity of ink has has met or exceeded the grammes per square metre of fabric, the Saturated Moisture Content of superfluorescent fiber far away itself, causes ink trickle or permeate in fabric reverse side, cause and drag look, form substandard products.
So in the prior art, ultrathin shell fabric is difficult to carry out ink-jet printed, ink-jet printedly carries out stamp processing, also have the deficiency that the percentage of A-class goods is low even if use.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of ink-jet printing method of ultrathin shell fabric and ink-jet printed combination layer thereof, is difficult to carry out ink-jet printed or to carry out ink-jet printed cost high, the deficiency that the percentage of A-class goods is low to solve ultrathin shell fabric in prior art.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows:
An ink-jet printing method for ultrathin shell fabric, the method comprises the steps:
(1) starching of ultrathin shell fabric: be dissolved in by printing assistant in solvent, add thickener, stirs, is made into slurry; Described slurry be coated with or pad on ultrathin shell fabric, drying, clot, for subsequent use;
(2) preparation of bed course carrier: adhesive is coated on as bed course carrier on carrier, dry for standby;
(3) bed course carrier and ultrathin shell fabric compound: fit in the side that the bed course carrier that the ultrathin shell fabric after step (1) being processed and step (2) obtain has adhesive, and ensure that the side that ultrathin shell fabric is not fitted with bed course carrier is distributed with slurry, pressurization, ultrathin shell fabric and bed course carrier are combined with each other and form ink-jet printed combination layer, clot, for subsequent use;
(4) ink-jet printed: to be loaded on ink-jet decorating machine by above-mentioned ink-jet printed combination layer, side ultrathin shell fabric being distributed with to slurry is carried out ink-jet printed, and dries, clot simultaneously;
(5) Final finishing: the ultrathin shell fabric after step (4) process and bed course carrier are peeled off, ultrathin shell fabric through Final finishing fixation treatment, then is washed, and sizing or tentering, become ink-jet printed ultrathin shell fabric.
In the present invention, described ultrathin shell fabric is the fabric that grammes per square metre is less than or equal to 60 grams/m.
In step (1), described printing assistant is water absorbing agent, sour agent or alkaline agent.
Described alkaline agent is to ionize the material generating hydroxide ion in the solution, and it is generally a few class of inorganic base, organic base, basic salt or strong base-weak acid salt.Wherein, described inorganic base is generally NaOH, calcium hydroxide or potassium hydroxide etc., described organic base is generally ethylenediamine or triethanolamine etc., described basic salt is generally alkali formula calcium chloride etc., described strong base-weak acid salt is generally sodium bicarbonate, saleratus, potash, sodium trichloroacetate, tertiary sodium phosphate or soda ash etc., and using maximum in cellulose fibre printing with reactive dye is exactly strong base-weak acid salt.
Described water absorbing agent is in atmosphere can the material of deliquescence water suction, and general conventional in textile printing is urea, glycerine.
Described sour agent produces hydrionic material for ionizing in the solution, it comprises organic acid, inorganic acid, a few class such as acid salt or strong acid weak base salt, wherein organic acid is generally formic acid, acetic acid, oxalic acid, citric acid, malic acid or trichloroacetic acid etc., and inorganic acid is generally hydrochloric acid, sulfuric acid, phosphoric acid or nitric acid etc.Acid salt is generally niter cake or sodium dihydrogen phosphate etc., and strong acid weak base salt is generally ammonium sulfate etc., and when fibre digital stamps such as nylon, wool, real silks, conventional acid is generally ammonium sulfate, citric acid, malic acid or trichloroacetic acid etc.
Those skilled in the art can according to the use kind of the classification choose reasonable printing assistant of fabric, dyestuff and use amount, and this is technology well known in the art.
In step (1), described solvent is water, organic solvent, or the mixture of water and organic solvent, described organic solvent can select alcohols, amide-type, glycol ethers or methyl-sulfoxide, wherein alcohols particular methanol, ethanol, isopropyl alcohol, isobutanol etc., the preferred dimethyl formamide of amide-type, dimethylacetylamide etc., glycol ethers has glycol monoethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol monobutyl ether etc., in the present invention, consider cost and Environmental Factors, organic solvent most preferred ethanol.
In step (1), the kind of described thickener is a lot, every can be water-soluble, form thick liquid material and the polymer do not reacted with dyestuff can be used as printing gum, it is divided into natural materials and synthetic; Wherein, described natural materials has sodium alginate, starch, glucidtemns, imperial glue or bentonite etc., and described synthetic is etherified cellulose, etherification starch, etherificate seed glue, polysaccharide material or acrylic thickener.The service property (quality) of thickener is 1 ~ 40% of printing assistant, solvent and thickener gross mass.Vary in size widely different according to the viscosity of thickener itself, such as the sodium carboxymethylcellulose in the etherified cellulose of high molecular, as long as the effect that 1% just has a well fixing ink-jet ink, and for molecular weight glucidtemns yellow starch gum to reach 40% and just have good fixation to ink-jet ink.Those skilled in the art can for concrete fabric and dye class, finds out the optimum quantum of utilization of thickener by simple experiment.When the solvent used is for organic solvent, thickener will be selected to dissolve in organic solvent, the thickener that can dissolve in water again, as hydroxypropyl cellulose, polyvinylpyrrolidone or pulullan polysaccharide etc.
The kind of above printing assistant, solvent, thickener and character are all well known to those skilled in the art, those skilled in the art can according to different fabric varieties and dyeing and printing process, select different printing gums, water absorbing agent, sour agent or alkaline agent kind, and their consumption; Such as when fabric is cellulose fibre, dyestuff can only select REACTIVE DYES ink-jet ink, at this moment pH value needs at alkaline range, generally be adjusted to 8.5 ~ 11, water absorbing agent generally selects urea, consumption is generally between 5 ~ 15wt%, and thickener needs to select the thickener do not reacted with REACTIVE DYES in the basic conditions, as the etherification starch of sodium alginate, high substituted degree, the etherified cellulose of high substituted degree etc.; When fabric is nylon, wool, cocoon fiber, dyestuff can select REACTIVE DYES ink-jet ink, also ACID DYES ink-jet ink can be selected, its pH value needs to adjust to acid range, generally be adjusted to 2.5 ~ 5.5, water absorbing agent uses urea or glycerine usually, and the range of choice of thickener is comparatively large, and substantially all printing gums can use; When face liber is polyster fibre, pH value does not generally have particular/special requirement, because the pH value of thickener own is about 7, so generally do not need deliberately acid adding agent or alkaline agent adjust ph; Water absorbing agent can not add; The selection of thickener it is noted that because terylene ink-jet printed after be with about 200 DEG C high temperature fixation, thickener needs the thickener that decomposition does not occur when high temperature, and such as sodium alginate, etherification starch, etherified cellulose all can as its thickener.
In step (2), described adhesive is the adhesive of two component, pressure sensitive adhesive or thermoplastic adhesives.The adhesive of described two components is two component polyamide binder, polyurethane binder of two component or polyacrylic binder of two component; Described pressure sensitive adhesive can be divided into rubber-type and resin type two class according to matrix resin composition, and rubber pressure-sensitive adhesive can be divided into again natural rubber class pressure sensitive adhesive or synthetic rubber class pressure sensitive adhesive; Resin type mainly comprises acrylic pressure-sensitive adhesivee, silicone based pressure sensitive adhesive or polyurethanes pressure sensitive adhesive; Described thermoplastic adhesives, thermoplastic is a lot, in general, as long as be solid at normal temperatures, at high temperature become fluid, and fluid has powerful adhesion, become solid again after cooling, and the material that chemical property does not change in whole process is all thermoplastic; It comprises thermoplasticity lower-molecular substance or thermal plastic high polymer material, and thermoplasticity lower-molecular substance has monosaccharide and disaccharide or polyethylene glycol etc. usually; And thermal plastic high polymer material is generally thermoplastic resin, it of a great variety, as polyurethane thermal-plastic's resin, polyamide thermoplastic resin, polyester thermoplastic's resin, polypropylene thermoplastic resin or abietic resin etc.
In step (2), described carrier is paper, plastic film or metal forming.Wherein, plastic film generally uses polyester film or polypropylene screen; Metal forming uses aluminium foil usually.
In step (3), for thermoplastic adhesives at compound tense, need heating while pressurization, the temperature of its heating is different with the melt temperature difference of thermoplastic cements, can select different heating-up temperatures according to different thermoplastic cements for those skilled in the art, be conventional means.
In step (4), different fabric varieties selects corresponding ink-jet dye ink, and such as wool fabric, real silk fabric, nylon fabrics can select acid dye ink or reactive dye ink; And the cotton of cellulose fibre, viscose glue etc. can only select reactive dye ink; Terylene ultrathin shell fabric can only select disperse dye ink; These are all technology well known to those skilled in the art.
In step (5), the fabric of different dyestuffs, different fiber species, color fixing process is different, these are also technology well known to those skilled in the art, such as, when fabric is cellulose fibre, use REACTIVE DYES ink-jet ink, fixation can bake three kinds of fixation modes by decatize, cold dome, heat; When fabric is nylon, wool, real silk, dye ink can select REACTIVE DYES or ACID DYES, and fixation mode adopts decatize; When fabric during polyster fibre, decatize or heat can be adopted to bake, but in ink-jet printed, in order to reduce investment and reduce costs, polyster fibre take heat to bake mode fixation usually.
An ink-jet printed combination layer for ultrathin shell fabric, it comprises the ink-jet ink absorbed layer, ultrathin shell fabric, ink-jet ink absorbed layer, adhesive layer and the carrier layer (Fig. 1) that bond successively from top to bottom; Or it comprises the ink-jet ink absorbed layer, ultrathin shell fabric, adhesive layer and the carrier layer (Fig. 2) that bond successively from top to bottom.If by ultrathin shell fabric by padding ink receptive layer slurry, then rolling additional size by padding machine, drying, just obtaining the ultrathin shell fabric of two sides all containing ink receptive layer (i.e. first kind of way Fig. 1); If adopted by ultrathin shell fabric one side blade coating, one side intaglio plate roller coat, garden net roller coating, silk screen blade coating etc. ink receptive layer slurry to be coated on the surface of ultrathin shell fabric, drying the ultrathin shell fabric (i.e. second way Fig. 2) just obtaining one side and contain ink receptive layer.
Wherein, described ink-jet ink absorbed layer is the mixture of thickener and printing assistant.
Described printing assistant is water absorbing agent, sour agent or alkaline agent.
Described alkaline agent is to ionize the material generating hydroxide ion in the solution, and it is generally a few class of inorganic base, organic base, basic salt or strong base-weak acid salt.Wherein, described inorganic base is generally NaOH, calcium hydroxide or potassium hydroxide etc., described organic base is generally ethylenediamine or triethanolamine etc., described basic salt is generally alkali formula calcium chloride etc., described strong base-weak acid salt is generally sodium bicarbonate, saleratus, potash, sodium trichloroacetate, tertiary sodium phosphate or soda ash etc., and using maximum in cellulose fibre printing with reactive dye is exactly strong base-weak acid salt.
Described water absorbing agent is in atmosphere can the material of deliquescence water suction, and general conventional in textile printing is urea, glycerine.
Described sour agent produces hydrionic material for ionizing in the solution, it comprises organic acid, inorganic acid, a few class such as acid salt or strong acid weak base salt, wherein organic acid is generally formic acid, acetic acid, oxalic acid, citric acid, malic acid or trichloroacetic acid etc., and inorganic acid is generally hydrochloric acid, sulfuric acid, phosphoric acid or nitric acid etc.Acid salt is generally niter cake or sodium dihydrogen phosphate etc., and strong acid weak base salt is generally ammonium sulfate etc., and when fibre digital stamps such as nylon, wool, real silks, conventional acid is generally ammonium sulfate, citric acid, malic acid or trichloroacetic acid etc.
Those skilled in the art can according to the use kind of the classification choose reasonable printing assistant of fabric, dyestuff and use amount, and this is technology well known in the art.
The kind of described thickener is a lot, every can be water-soluble, form thick liquid material and the polymer do not reacted with dyestuff can be used as printing gum, it is divided into natural materials and synthetic; Wherein, described natural materials has sodium alginate, starch, glucidtemns, imperial glue or bentonite etc., and described synthetic is etherified cellulose, etherification starch, etherificate seed glue, polysaccharide material or acrylic thickener.The service property (quality) of thickener is 1 ~ 40% of printing assistant, solvent and thickener gross mass.Vary in size widely different according to the viscosity of thickener itself, such as the sodium carboxymethylcellulose in the etherified cellulose of high molecular, as long as the effect that 1% just has a well fixing ink-jet ink, and for molecular weight glucidtemns yellow starch gum to reach 40% and just have good fixation to ink-jet ink.Those skilled in the art can for concrete fabric and dye class, finds out the optimum quantum of utilization of thickener by simple experiment.When the solvent used is for organic solvent, thickener will be selected to dissolve in organic solvent, the thickener that can dissolve in water again, as hydroxypropyl cellulose, polyvinylpyrrolidone or pulullan polysaccharide etc.Those skilled in the art know, and different ultrathin shell fabric kind printing gum kinds is different, and as wool fabric, nylon facing material is almost applicable to all printing gums; And must consider that printing gum can not react with REACTIVE DYES during cotton fabric use REACTIVE DYES.
Wherein, described adhesive layer is the adhesive of two component, pressure sensitive adhesive or thermoplastic adhesives.Its Main Function is temporarily adhered to each other by the ultrathin shell fabric of carrier and first-class ink-jet ink absorbed layer, after ink-jet terminates, ultrathin shell fabric can be torn with carrier and be separated.The adhesive of described two components is two component polyamide binder, polyurethane binder of two component or polyacrylic binder of two component; Described pressure sensitive adhesive can be divided into rubber-type and resin type two class according to matrix resin composition, and rubber pressure-sensitive adhesive can be divided into again natural rubber class pressure sensitive adhesive or synthetic rubber class pressure sensitive adhesive; Resin type mainly comprises acrylic pressure-sensitive adhesivee, silicone based pressure sensitive adhesive or polyurethanes pressure sensitive adhesive; Described thermoplastic adhesives, thermoplastic is a lot, in general, as long as be solid at normal temperatures, at high temperature become fluid, and fluid has powerful adhesion, become solid again after cooling, and the material that chemical property does not change in whole process is all thermoplastic; It comprises thermoplasticity lower-molecular substance or thermal plastic high polymer material, and thermoplasticity lower-molecular substance has monosaccharide and disaccharide or polyethylene glycol etc. usually; And thermal plastic high polymer material is generally thermoplastic resin, it of a great variety, as polyurethane thermal-plastic's resin, polyamide thermoplastic resin, polyester thermoplastic's resin, polypropylene thermoplastic resin or abietic resin etc.
Wherein, described carrier layer is paper, plastic film or metal forming, and wherein, plastic film is generally polyester film, polypropylene screen; Metal forming is generally aluminium foil.
To those skilled in the art, weaving face fabric for dress ornament purposes is network structure, so be coated with in the layer excessively of ink receptive layer on ultrathin shell fabric, when use is padded, after drying, ink receptive layer slurry is actual is that to infiltrate ultrathin shell fabric inner, and that is, at this moment the two sides of ultrathin shell fabric and inside are all containing ink receptive layer, ultrathin shell fabric inside, because of for ease of expressing, does not also show containing ink receptive layer by Fig. 1; Equally, when using one side blade coating, one side intaglio plate roller coat, garden net roller coating, silk screen blade coating etc. ink receptive layer slurry to be coated on ultrathin shell fabric surperficial, the slurry of ink receptive layer also can infiltrate ultrathin shell fabric inside, that is, at this moment the one side of ultrathin shell fabric and inside are all containing ink receptive layer, ultrathin shell fabric inside, for the ease of expressing, does not show containing ink receptive layer by Fig. 2.
Principle of the present invention is, when ink-jet printed, the ink-jet ink of air brushing in ultrathin shell fabric surface is adsorbed by ink receptive layer, and ink receptive layer spreading is also dissolved by ink, and ink and ink receptive layer are combined together, and ink becomes thickness; At this time, because the network structure of ultrathin shell fabric, ultrathin shell fabric grammes per square metre is too light in addition, and can not absorb ink completely, ink can permeate the reverse side in ultrathin shell fabric, causes the fuzzy and reverse side of flower pattern to drag look; Because reverse side of the present invention posts one deck carrier layer, stopped the reverse side infiltration of ink, make ink remain at ultrathin shell fabric front, under the drive of carrier, fabric enters drying unit below, is dried by ink, completes ink-jet printed emboss portions; Tear carrier layer off afterwards, then to evaporate or heat bakes or cold dome through conventional, washing, the Final finishing such as sizing, just obtain ink-jet printed ultrathin shell fabric.
Beneficial effect: the inventive method, with low cost, stopped ultrathin shell fabric ink-jet printed time ink reverse side infiltration, the ink-jet printed of ultrathin shell fabric can be realized smoothly, add the ink-jet printed scope of application, for ink-jet printed realization on ultrathin shell fabric provides possibility.
Accompanying drawing explanation
Fig. 1 is the ink-jet printed combination layer schematic diagram of a kind of ultrathin shell fabric of the present invention.
Fig. 2 is the ink-jet printed combination layer schematic diagram of another kind of ultrathin shell fabric of the present invention.
Wherein, 1 is carrier layer, and 2 is adhesive layer, and 3 is ink-jet ink absorbed layer, and 4 is ultrathin shell fabric.
Fig. 3 is present invention process and existing technique printing quality comparison diagram.
Detailed description of the invention
According to following embodiment, the present invention may be better understood.But those skilled in the art will readily understand, the content described by embodiment only for illustration of the present invention, and should can not limit the present invention described in detail in claims yet.
Embodiment 1:
By the printing gum sodium alginate of 5 kilograms, the urea of 10 kilograms, the sodium bicarbonate of 2 kilograms mixes, and puts into 83 kg of water and stirs, be dissolved into ink receptive layer slurry; Get real silk paj fabric (grammes per square metre is 30 grams/m) some, fabric is immersed in above-mentioned slurry, then rolls additional size with padding machine, dry.
The paper getting 100 grams/m is again some, painting polypropylene pressure sensitive adhesive, dries; Above-mentioned real silk paj and paper are fitted, through padding machine, real silk paj and paper are bonded together, and clot is stand-by, becomes structure shown in Fig. 1.
The combination of the ink-jet ink absorbed layer of structure shown in Fig. 1, real silk paj, ink-jet ink absorbed layer, adhesive layer and carrier layer is put on Japanese MIMAKI TS-34 digital decorating machine, REACTIVE DYES ink-jet ink is used to carry out ink-jet printed, ink receptive layer fixes ink, carrier layer stops ink to permeate to fabric backing, pattern profile is made to keep clear, again under the drive of carrier, fabric enters the oven dry part of digital decorating machine, moisture in ink is dried, tear carrier paper off, complete ink-jet printed part; Eventually pass and evaporate, wash, shape, obtain ink-jet printed real silk paj fabric.
Embodiment 2:
By the sodium carboxymethyl starch in the printing gum etherification starch of 10 kilograms, the urea of 2 kilograms, the ammonium sulfate of 2 kilograms mixes, and puts into 86 kg of water and stirs, be dissolved into ink receptive layer slurry; Get 400T, 15D nylon fabric (grammes per square metre is 35 grams/m) is some, by above-mentioned slurry scraper blade coating on Nylon Taffeta surface, dries.
The polyester film getting 20 micron thickness is again some, coated polyester thermoplastic resin solution, dries; Above-mentioned Nylon Taffeta and polyester film are fitted, through padding machine, heating, make Nylon Taffeta together with polyester film adhesive, and clot is stand-by, becomes structure shown in Fig. 2.
The combination of the ink-jet ink absorbed layer of structure shown in Fig. 2, Nylon Taffeta, adhesive layer, carrier layer is put on Japanese military rattan 1638 digital decorating machine, ACID DYES ink-jet ink is used to carry out ink-jet printed, ink receptive layer fixes ink, carrier layer stops ink to permeate to fabric backing, makes pattern profile keep clear, then under the drive of carrier, fabric enters the oven dry part of digital decorating machine, moisture in ink is dried, tears Carrier polyester film off, complete ink-jet printed part; Eventually pass and evaporate, wash, shape, obtain ink-jet printed nylon fabric.
Embodiment 3:
By the sodium carboxymethylcellulose of 3 kilograms, put into 97 kg of water and stir, be dissolved into ink receptive layer slurry; Get ultra-thin terylene thread screen cloth (grammes per square metre is 20 grams/m) some, terylene thread screen cloth is immersed in above-mentioned slurry, then rolls additional size with padding machine, and dry stand-by.
The biaxially oriented polypropylene film getting 40 micron thickness is some, the two-component polyurethane adhesive intaglio press mixed is applied to the surface of polypropylene screen, and dry, the printing surface of above-mentioned terylene thread screen cloth and polypropylene screen is fitted, pressurization, slaking a few hours, the ink-jet printed combination layer of the ultrathin shell fabric shown in Fig. 1.
By above combination layer clot, be contained on Italian MS-JPK ink-jet decorating machine, select DISPERSE DYES ink-jet printing ink, by design air brushing in combinations thereof, then enter oven for drying, tear polypropylene screen off, terylene mesh is entered baker, temperature 180 DEG C, fixation under 1 minute time condition, eventually pass washing, the ultra-thin terylene thread screen cloth of digit printing.
Embodiment 4:
By 30 kg of starch hydrolysate yellow starch gums, 5 kilograms of urea, 5 kg of glycerin, 2 kilograms of malic acid add in 58 kg of water, stir, make it to become pulpous state.
Get the ultra-thin scarf fabrics of cashmere (grammes per square metre is 55 grams/m) some, used by above-mentioned slurry intaglio press roller coat on cashmere fabric surface, dry.
Get 30 micron aluminum foils more some, by acrylate pressure sensitive adhesive solution coat at aluminium foil surface, dry; Fitted by the coated face of the uncoated surface of above-mentioned cashmere fabric and aluminium foil, pressurization, makes cashmere fabric and aluminium foil be bonded together, becomes the ink-jet printed combination of ultrathin shell fabric shown in Fig. 2.
Clot will be combined above, be contained on Japanese MIMAKI TS500 ink-jet decorating machine, select ACID DYES ink-jet printing ink, by design air brushing in combinations thereof, then enter oven for drying, tear aluminium foil off, being entered by cashmere fabric in steaming box, is 105 DEG C in temperature, and the time is steaming and color fixing under 40 minutes conditions, eventually pass washing, the ultra-thin cashmere fabric of digit printing.
Embodiment 5:
Get 10 kilograms of hydroxypropyl celluloses, 5 kg of glycerin, 3 kilograms of oxalic acid, add in 82 kg ethanol mixed liquors, stir, dissolve, make it to become slurry.
Get ultra-thin nylon net cloth (grammes per square metre is 25 grams/m) some, above-mentioned slurry is placed in evenness calender, makes nylon net cloth by evenness calender, evenness calender roll rolls additional size, dries nylon net cloth.
Get 100 grams/m of blank sheet of paper some, sucrose is heated to 170 DEG C, makes it melting, then be applied on blank sheet of paper, cooling, fits the coated face of above-mentioned nylon net cloth and blank sheet of paper, pressurization, heating, makes nylon net cloth and blank sheet of paper fit together, becomes the ink-jet printed combination of ultrathin shell fabric shown in Fig. 1.
Clot will be combined above, be contained on Japanese military rattan 1604 ink-jet decorating machine, select ACID DYES ink-jet ink, by design air brushing on the ink receptive layer of combinations thereof, dry, tear blank sheet of paper off, nylon net cloth enters steam box, vapour steaming colour fixing, finally washes, sizing, namely obtains ink-jet printed nylon net cloth.
Embodiment 6:
Get 6 kilograms of hydroxypropyl celluloses, 4 kilograms of imperial glue, 3 kg of glycerin, 3 kilograms of urea, 2 kilograms of citric acids, 1 kilogram of niter cake, add in the mixed solution of 5 kilograms of ethylene glycol and 76 kg of water, stir, dissolve, make it to become slurry.
Get ultra-thin habotai (48 grams/m) some, above-mentioned slurry is placed in evenness calender, and make habotai by evenness calender, rolling removes additional size, dries habotai.
The biaxially oriented polypropylene film getting 30 micron thickness is some, two component polyamide binder intaglio press is applied to the surface of polypropylene screen, and dry, the printing surface of above-mentioned habotai and polypropylene screen is fitted, pressurization, slaking a few hours, the ink-jet printed combination layer of the ultrathin shell fabric shown in Fig. 1.
Clot will be combined above, be contained on Japanese military rattan 1604 ink-jet decorating machine, select ACID DYES ink-jet ink, by design air brushing on the ink receptive layer of combinations thereof, dry, tear polypropylene screen off, habotai enters steam box, and 110 DEG C of vapour steaming colour fixings 30 minutes, finally wash, sizing, namely obtains ink-jet printed ultra-thin habotai.
Embodiment 7:
By 5 kilograms of sodium carboxymethylcelluloses, 3 kilograms of bentonites, 12 kilograms of acrylic acid, 5 kilograms of urea, 5 kg of glycerin, 2 kilograms of trichloroacetic acids, 3 kg of phosphoric acid sodium dihydrogens, add in 65 kg of water, stir, make it to become pulpous state.
Get the ultra-thin garment material of polyamide fibre (45 grams/m) some, used by above-mentioned slurry intaglio press roller coat on polyamide fibre ultrathin shell fabric surface, dry.
Get 30 micron aluminum foils more some, polyurethanes pressure sensitive adhesive is coated on aluminium foil surface, dry; The uncoated surface of above-mentioned polyamide fibre ultrathin shell fabric and the coated face of aluminium foil are fitted, pressurization, makes fabric and aluminium foil be bonded together, becomes the ink-jet printed combination of ultrathin shell fabric shown in Fig. 2.
Clot will be combined above, be contained on Japanese MIMAKI TS500 ink-jet decorating machine, select ACID DYES ink-jet printing ink, by design air brushing in combinations thereof, then enter oven for drying, tear aluminium foil off, entering in steaming box by polyamide fibre ultrathin shell fabric, is 102 DEG C in temperature, and the time is steaming and color fixing under 35 minutes conditions, eventually pass washing, the ultra-thin garment material of digit printing polyamide fibre.
Embodiment 8:
By the polyvinylpyrrolidone of 2 kilograms, 2 kilograms of pulullan polysaccharides, put into the stirring of 96 kilograms of N-N dimethyl formamides (DMF), are dissolved into ink receptive layer slurry.
Get ultra-thin terylene thread screen cloth (grammes per square metre is 27 grams/m) some, ultra-thin terylene thread screen cloth is immersed in above-mentioned slurry, then rolls additional size with padding machine, and dry stand-by.
The biaxial stretching polyester film getting 40 micron thickness is some, two component polyacrylic binder intaglio press is applied to the surface of polyester film, and dry, the printing surface of above-mentioned ultra-thin terylene thread screen cloth and polyester film is fitted, pressurization, slaking a few hours, the ink-jet printed combination layer of the ultrathin shell fabric shown in Fig. 1.
By above combination layer clot, be contained on Italian MS-JPK ink-jet decorating machine, select DISPERSE DYES ink-jet printing ink, by design air brushing in combinations thereof, then enter oven for drying, tear polyester film off, terylene mesh is entered baker, temperature 200 DEG C, fixation under 50 seconds time condition, eventually pass washing, the ultra-thin terylene thread screen cloth of digit printing.
Embodiment 9:
By the hydroxyethylcellulose of 8 kilograms, 10 kilograms of sodium alginates, put into and stir with 82 kg of water, be dissolved into ink receptive layer slurry;
Get ultra-thin terylene skin clothing fabric (grammes per square metre is 32 grams/m) some, used by above-mentioned slurry intaglio press roller coat on ultra-thin polyester fabric surface, dry.
Get 100 grams/m of blank sheet of paper some, the mixture (mass percent 2:1) of sucrose and polyester thermoplastic's resin is heated to 170 DEG C, make it melting, be applied to again on blank sheet of paper, cooling, fits the coated face of above-mentioned ultra-thin polyester fabric and blank sheet of paper, pressurization, heating, becomes the ink-jet printed combination of ultrathin shell fabric shown in Fig. 2.
By above combination layer clot, be contained on Italian MS-JPK ink-jet decorating machine, select DISPERSE DYES ink-jet printing ink, by design air brushing in combinations thereof, then enter oven for drying, tear blank sheet of paper off, ultra-thin polyester fabric is entered baker, temperature 180 DEG C, fixation under 1 minute time condition, eventually pass washing, digit printing ultra-thin terylene skin clothing fabric.
Embodiment 10:
By the printing gum sodium alginate of 3 kilograms, 2 kilograms of sodium carboxymethylcelluloses, the urea of 10 kilograms, the saleratus of 2 kilograms, 1 kg of phosphoric acid trisodium mixes, and puts into 82 kg of water and stirs, be dissolved into ink receptive layer slurry;
Get real silk paj ultrathin shell fabric (grammes per square metre is 30 grams/m) some, fabric is immersed in above-mentioned slurry, then rolls additional size with padding machine, dry.
The paper getting 100 grams/m is again some, and coating polyurethane thermal-plastic resin solution, dries; Above-mentioned real silk paj ultrathin shell fabric and paper are fitted, through padding machine, fabric and paper are bonded together, and clot is stand-by, becomes structure shown in Fig. 1.
The combination of the ink-jet ink absorbed layer of structure shown in Fig. 1, real silk paj, ink-jet ink absorbed layer, adhesive layer and carrier layer is put on Japanese MIMAKI TS-34 digital decorating machine, REACTIVE DYES ink-jet ink is used to carry out ink-jet printed, ink receptive layer fixes ink, carrier layer stops ink to permeate to fabric backing, pattern profile is made to keep clear, again under the drive of carrier, fabric enters the oven dry part of digital decorating machine, moisture in ink is dried, tear carrier paper off, complete ink-jet printed part; Eventually pass 102 DEG C evaporate 30 minutes, washing, sizing, obtain ink-jet printed real silk paj ultrathin shell fabric.
Embodiment 11:
By the sodium carboxymethylcellulose of 3 kilograms, 2 kilograms of carboxymethyl starch, the urea of 10 kilograms, the sodium trichloroacetate of 4 kilograms, 2 kilograms of sodium bicarbonate mix, and put into 79 kg of water and stir, be dissolved into ink receptive layer slurry;
Get wool/bamboo pulp blending ultrathin shell fabric (grammes per square metre is 60 grams/m) some, used by above-mentioned slurry intaglio press roller coat on wool/bamboo pulp blending ultrathin shell fabric surface, dry.
The polyester film getting 20 micron thickness is again some, and coating polyamide thermoplastic resin solution, dries; Above-mentioned wool/bamboo pulp blending ultrathin shell fabric and polyester film are fitted, through padding machine, heating, make wool/bamboo pulp blending ultrathin shell fabric together with polyester film adhesive, and clot is stand-by, becomes structure shown in Fig. 2.
Clot will be combined above, be contained on Italian MS-JPK ink-jet decorating machine, select active dye ink-jet printing ink, by design air brushing in combinations thereof, then enter oven for drying, tear polyester film off, by wool/bamboo pulp blending ultrathin shell fabric enters in steaming box, be 105 DEG C in temperature, the time is steaming and color fixing under 40 minutes conditions, eventually pass washing, digit printing wool/bamboo pulp blending ultrathin shell fabric.
Embodiment 12:
By the hydroxypropyl cellulose of 2 kilograms, 3 kilograms of sodium alginates, the urea of 12 kilograms, the sodium trichloroacetate of 3 kilograms, 2 kilograms of soda ash mix, and put into 78 kg of water and stir, be dissolved into ink receptive layer slurry;
Get viscose glue/cotton ultra-thin interwoven fabric (grammes per square metre is 55 grams/m) some, fabric is immersed in above-mentioned slurry, then rolls additional size with padding machine, dry.
Get 30 micron aluminum foils more some, polypropylene type pressure sensitive adhesive is coated on aluminium foil surface, dry; Fitted by the coated face of above-mentioned viscose glue/cotton ultra-thin interwoven fabric and aluminium foil, pressurization, makes fabric and aluminium foil be bonded together, becomes the ink-jet printed combination of ultrathin shell fabric shown in Fig. 1.
Clot will be combined above, be contained on Japanese MIMAKI TS-34 ink-jet decorating machine, select active dye ink-jet printing ink, by design air brushing in combinations thereof, then enter oven for drying, tear aluminium foil off, by viscose glue/cotton ultra-thin interwoven fabric enters in steaming box, be 105 DEG C in temperature, the time is steaming and color fixing under 15 minutes conditions, eventually pass washing, digit printing viscose glue/cotton ultra-thin interwoven fabric.
Embodiment 13:
Get 0588 polyvinyl alcohol 20 kilograms, 4 kilograms, ammonium sulfate, 3 kilograms, urea, add in 73 kg of water, stir, dissolve and become ink receptive layer slurry; Get 20D, 380T Nylon Taffeta is some, and (grammes per square metre is 40 grams/m), by with spreading mass, rolls additional size with padding machine, dries, clot, for subsequent use; Get the above-mentioned nylon fabric part containing ink receptive layer, be contained in stamp on Japanese MIMAKI TS34 digital decorating machine, print flower pattern A, B, C, D, E respectively; Again at 102 DEG C, saturated vapor evaporates 30 minutes, washing, dries, obtains digit printing Nylon Taffeta printed fabric A1, B1, C1, D1, E1.
Equally, get the above-mentioned nylon fabric containing ink receptive layer, fit with the polyester film being coated with polyester thermoplastic's resin, pressurization, make it to be combined with each other, the fabric that compound is good is contained in stamp on Japanese MIMAKI TS34 digital decorating machine, print flower pattern A, B respectively, C, D, E; Tear the polyester film of carrier again off, then by nylon fabric at 102 DEG C, saturated vapor evaporates 30 minutes, washing, dry, obtain digit printing Nylon Taffeta printed fabric A2, B2, C2, D2, E2.
Can obviously find out, digit printing nylon fabric A2, B2, C2, D2, E2 are than the thick in color of A1, B1, C1, D1, E1, and clear-cut, contrast is strong, and vividness is good.
Because the reason of photographic resolution, in the sample of reality, the imbibition of A1, B1, C1, D1, E1 reverse side is serious, and profile is coarse, loses the use value on dress ornament.
Claims (5)
1. an ink-jet printing method for ultrathin shell fabric, is characterized in that, the method comprises the steps:
(1) starching of ultrathin shell fabric: be dissolved in by printing assistant in solvent, add thickener, stirs, is made into slurry; Described slurry be coated with or pad on ultrathin shell fabric, drying, clot, for subsequent use;
(2) preparation of bed course carrier: adhesive is coated on as bed course carrier on carrier, dry for standby;
(3) bed course carrier and ultrathin shell fabric compound: fit in the side that the bed course carrier that the ultrathin shell fabric after step (1) being processed and step (2) obtain has adhesive, and ensure that the side that ultrathin shell fabric is not fitted with bed course carrier is distributed with slurry, pressurization, ultrathin shell fabric and bed course carrier are combined with each other and form ink-jet printed combination layer, clot, for subsequent use;
(4) ink-jet printed: to be loaded on ink-jet decorating machine by above-mentioned ink-jet printed combination layer, side ultrathin shell fabric being distributed with to slurry is carried out ink-jet printed, and dries, clot simultaneously;
(5) Final finishing: the ultrathin shell fabric after step (4) process and bed course carrier are peeled off, ultrathin shell fabric through Final finishing fixation treatment, then is washed, and sizing or tentering, become ink-jet printed ultrathin shell fabric.
2. the ink-jet printing method of ultrathin shell fabric according to claim 1, is characterized in that, in step (1), described printing assistant is water absorbing agent, sour agent or alkaline agent; Described solvent is the mixture of water, organic solvent or water and organic solvent.
3. the ink-jet printing method of ultrathin shell fabric according to claim 1, it is characterized in that, in step (1), described thickener is can the thick liquid material of water-soluble formation and the polymer substance do not reacted with dyestuff, and it is divided into natural materials and synthetic; Wherein, described natural materials is sodium alginate, starch, glucidtemns, imperial glue or bentonite, and described synthetic is etherified cellulose, etherification starch, etherificate seed glue, polysaccharide material or acrylic thickener; The service property (quality) of thickener is 1 ~ 40% of printing assistant, solvent and thickener gross mass.
4. the ink-jet printing method of ultrathin shell fabric according to claim 1, is characterized in that, in step (2), described adhesive is the adhesive of two component, pressure sensitive adhesive or thermoplastic adhesives.
5. the ink-jet printing method of ultrathin shell fabric according to claim 1, is characterized in that, in step (2), described carrier is paper, plastic film or metal forming.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103952929A (en) * | 2014-04-25 | 2014-07-30 | 何炽斌 | Method of printing cloth by printer |
| CN104278563A (en) * | 2014-09-27 | 2015-01-14 | 无锡市东北塘宏良染色厂 | Special printing paste for terylene |
| CN104278562A (en) * | 2014-09-27 | 2015-01-14 | 无锡市东北塘宏良染色厂 | Printing paste |
| CN106592257A (en) * | 2016-11-28 | 2017-04-26 | 江苏格美高科技发展有限公司 | Silk cloth suitable for ink-jet printing output and manufacturing method of silk cloth |
| CN109577023A (en) * | 2018-10-25 | 2019-04-05 | 苏州维宁斯化工有限公司 | A kind of multi-functional Non-water washing direct printing technique of novel environment-friendly |
| CN110565419A (en) * | 2019-09-23 | 2019-12-13 | 刘静 | Fabric double-side accurate alignment printing method |
| CN110685176A (en) * | 2019-10-14 | 2020-01-14 | 刘静 | Positioning gold stamping method for ink-jet wet transfer printing fabric |
| CN110667292A (en) * | 2019-10-22 | 2020-01-10 | 刘静 | Positioning gold stamping method for digital ink-jet wet transfer printing fabric |
| CN110667293A (en) * | 2019-10-22 | 2020-01-10 | 刘静 | Positioning gold stamping method for digital ink-jet heat transfer printing fabric |
| CN114030197A (en) * | 2021-09-24 | 2022-02-11 | 湖南省醇龙箱包股份有限公司 | Shell processing production line and processing method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101381934A (en) * | 2008-10-21 | 2009-03-11 | 东华大学 | Fixation method and apparatus for inking and printing on cotton with active ink |
| CN102642361A (en) * | 2011-02-22 | 2012-08-22 | 聚纺股份有限公司 | Print fabric and color fabric preparation method |
| CN102677492A (en) * | 2011-09-08 | 2012-09-19 | 沈翰宇 | Heat transfer digital printing method for natural fibers and regenerated cellulose fibers |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030077961A1 (en) * | 2001-10-22 | 2003-04-24 | Elizbeth Cates | Textile substrate having coating containing organic cationic material and sorbant polymer thereon for image printing |
-
2013
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101381934A (en) * | 2008-10-21 | 2009-03-11 | 东华大学 | Fixation method and apparatus for inking and printing on cotton with active ink |
| CN102642361A (en) * | 2011-02-22 | 2012-08-22 | 聚纺股份有限公司 | Print fabric and color fabric preparation method |
| CN102677492A (en) * | 2011-09-08 | 2012-09-19 | 沈翰宇 | Heat transfer digital printing method for natural fibers and regenerated cellulose fibers |
Non-Patent Citations (1)
| Title |
|---|
| 超薄型织物的设计与开发;王国和等;《丝绸》;20061231(第12期);第13-15页 * |
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