CN103450773A - Epoxy acrylate modified high anticorrosion heat insulation paint containing porous ceramic addictive and production method thereof - Google Patents
Epoxy acrylate modified high anticorrosion heat insulation paint containing porous ceramic addictive and production method thereof Download PDFInfo
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- CN103450773A CN103450773A CN2012101723545A CN201210172354A CN103450773A CN 103450773 A CN103450773 A CN 103450773A CN 2012101723545 A CN2012101723545 A CN 2012101723545A CN 201210172354 A CN201210172354 A CN 201210172354A CN 103450773 A CN103450773 A CN 103450773A
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Abstract
The invention relates to a kind of heat insulation paint with a high anticorrosion performance and a preparation method thereof. The anticorrosion heat insulation paint is composed of following components in percentage by weight: 35 to 60% of deionized water, 20 to 40% of modified epoxy resin, 5 to 30% of modified acrylic resin, 1 to 8% of amino resin, 10 to 25% of heat insulation materials, 0 to 8% of strengthening materials, and 1 to 10% of auxiliary agent. The preparation method comprises following steps: orderly adding deionized water, modified epoxy resin, modified acrylic resin, and amino resin into a reactor, starting the stirrer, evenly mixing the materials, adjusting the pH value of the system to a range of 7 to 9, then orderly adding the auxiliary agent, the heat insulation materials, and the strengthening materials, stirring for 1 to 3 hours in a high speed, and evenly mixing so as to obtain the anticorrosion heat insulation paint. The preparation method has the advantages of simple technology, high production efficiency, and low energy consumption. The prepared paint does not contain any organic solvent, so no solvent will volatilize during the coating solidification process, so no pollution is generated to the environment. The paint has the advantages of excellent mechanical properties of bonding strength, hardness, scratch resistance, wear resistance, and water resistance, and good properties of anticorrosion, salt smog resistance, forming ability, heat resistance, and deflection resistance.
Description
Technical field
The invention belongs to the coatings chemistry technical field, particularly a kind of corrosion-resistant thermal insulation composition of insulating mold coating and preparation method thereof.
Background technology
World industry is day by day flourishing, the destruction of the increasing and mankind of population to the Nature, earth surface temperature is also raise day by day, earth resources is day by day exhausted, the mankind's life and existence are subject to increasing impact and threat, and therefore, energy-saving and cost-reducing work has caused concern and the attention of countries in the world, each energy-saving material has also become one of the scientific research in the world and elementary object of technological development, and energy-saving material also will more and more be subject to people's favor.
Existing insulating mold coating, the silicate materials such as asbestos, aluminum silicate fiber, pearlstone filler of generally take are main body, take water as dispersion agent, add tackiness agent, through loose, stir and the paste slurry made.During use, select as the case may be suitable method to be coated on the working face surface, play the effect of heat-insulation and heat-preservation.But asbestos are as filler, when making and use the coating of the type, the asbestos dust of formation and the particle of volatilization are easily absorbed by people, and are difficult for excreting.This situation easily causes human body to produce the major diseases such as lung cancer and skin carcinoma, and therefore, country has forbidden using asbestos to do filler in lagging material.Also have in the market a kind ofly without asbestos environment-friendly type thermal insulating coating, its main heat insulation aggregate is vacuum ceramic microballoon and aerosol, and its thermal insulation and the feature of environmental protection are promoted.But, with cheap inorganic mineral, compare, the high cost of vacuum ceramic microballoon, this makes the development of such coating be very restricted.
The Chinese patent that publication number is CN1035514C, adopt the cheap chemical assistant penetrant m aqueous solution, according to specific ratio, add chrysotile and polygorskite to make slurry as base-material, silicate fiber or rock wool fibers are made the auxiliary material that strengthens, pearlstone, float pearl and diatomite is made filler, carboxymethyl cellulose, water glass and polyvinyl alcohol water solution are made binding agent, and wilkinite is made suspension stabilizer, become at normal temperatures insulating mold coating through fully stirring.This coating has good heat-insulating property, and easy construction, few without dust, consumption, reduce engineering cost.But unit cost is high, without Corrosion Protection, not ageing-resistant, use range is limited to.
The Chinese patent that publication number is CN1583895A, though be to reach effect of heat insulation by adding the hollow ceramic pearl to reduce thermal conductivity, this coating has adopted dimethylbenzene, harmful to environment.
The Chinese patent that publication number is CN1485381A, the Water-based thermal insulation coating of use benzene emulsion, both do not had elastic effect, and good weathering resistance and ageing resistance can not be provided again.
The Chinese patent that publication number is CN1271747A, disclosed exterior coating be take pure-acrylic emulsion as base-material, and take titanium dioxide, light calcium carbonate etc. is filler, and ageing-resistant, thermotolerance and the heat-proof quality of such product are poor.
Summary of the invention
Technical problem to be solved by this invention is: the deficiency that overcomes existing insulating mold coating, a kind of have high preservative property, high salt fog resistance are provided, mechanical property, plasticity, thermotolerance, excellent in bent-resistant performance, sticking power is good, the compound insulating mold coating its preparation method of lightweight, inexpensive, environmental protection.
Solving the technical scheme that its technical problem adopts is:
A kind of corrosion-resistant thermal insulation thermal insulating coating is characterised in that the component that it contains following weight percent content: deionized water 35-60%, modified epoxy 20-40%, acrylic resin modified 5-30%, aminoresin 1-8%, lagging material 10-25%, strongthener 0-8%, auxiliary agent 1-10%;
Described modified epoxy is one or more the composition in acrylic modified epoxy resin, butyl acrylate epoxy resin, trimethyl cyclohexyl methacrylate epoxy resins, polyurethane modified epoxy resin, bi-maleimide modified epoxy resin, polyamic acid modified epoxy, bisphenol A epoxide resin;
Described acrylic resin modified be acrylic or methacrylic acid and the multipolymer of esters of acrylic acid or acrylic acid hydroxy alkyl ester or vinylformic acid amido alkyl ester;
Described aminoresin comprises one or more the composition in methyl-etherified aminoresin, butylated amino resin;
Described auxiliary agent is one or more the composition in sterilant, mould inhibitor, wetting dispersing agent, flow agent, defoamer, pH adjusting agent, frostproofer, film coalescence aid, pigment, thickening material, catalyzer;
Wherein, sterilant can be inorganic fungicide, as SULPHUR POWDER, lime sulfur mixture, copper sulfate, mercuric chloride, lime Bordeaux mixture, copper hydroxide, Red copper oxide etc.; Organosulfureous fungicide, as amobam, sodium paminobenzensulfonate, ziram, zineb, zinc manganese ethylenebisdithiocarbamate, thiram etc.; Organophosphorus, arsenic sterilant, as Kitazine, Hinosan, phosethyl Al, tolclofosmethyl, Tuzet, mazn etc.; Substituted beneze-group fungicides, as thiophanate methyl, m-tetrachlorophthalodinitrile, fenaminosulf, quintozene etc.; Azoles fungicide, as triadimefon, derosal, the mould spirit of evil, F-1991, thiabendazole etc.; The Antibiotics sterilant, as jingganmycin, polyoxin, kasugamycin, agricultural streptomycin, antimycoin 120 etc.; Composite bactericide, as the disease prestige of going out, " shuang xiao ling ", anthrax good fortune U.S., Sandofan M8, first frost copper, DT sterilant, metalaxyl-mn-zn, amicarthiazol MnZn, thiophanate_methyl MnZn, wide sterilizing milk powder, metaxanin-thiram wettable powder etc.; Other sterilant, as metaxanin, dichlozolin, procymidone, iprodione, Phaltan, Vancide 89, Te Fuling, anilazine, auspicious withered mould, formalin, high fat film, octicin solution, Propamocarb, oxolinic acide, dimethomorph MnZn etc.;
Mould inhibitor can be phenols, as phenol; Chlorophenols, as Pentachlorophenol; Organic mercury salt, as phenyl mercury oleate; Organic copper salt, as copper 8-quinolinolate; Organic tin salt, as chlorination three second or tributyl tin; Inorganic salt, as copper sulfate, mercury chloride, Sodium Fluoride etc., also can be used the commercially available sanitas AMP-95 in market;
Wetting dispersing agent can be that natural polymer subclass (as Yelkin TTS), synthetic high score subclass (as acid and the polyamino salt of long-chain polyester), polyvalent carboxylic acid's salt, silicon system and titanium are coupling agent etc.; Matting agent can be metallic soap (as aluminum stearate, zinc, calcium salt etc.), modified oil (as tung oil), macromolecule wax (as polyethylene wax, Poly Propylene Wax, tetrafluoroethylene wax), functional filler (as diatomite, gas phase sio2) etc.;
Flow agent can be polyacrylic ester, silicone resin and fluorine surfactant etc.;
Defoamer can be lower alcohol (as ethanol, propyl carbinol), organically-modified compound (as tributyl phosphate, metallic soap), mineral oil, organic polymer (as polyethers, polyacrylic ester), silicone resin (as polydimethyl siloxane fluid, modified polyorganosiloxane) etc., as polyether silicone;
PH adjusting agent can be 2-amino-2-methyl-1-propanol, N, N-dimethylethanolamine etc.;
Frostproofer can be propylene glycol, ethylene glycol etc.;
Film coalescence aid can be 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, Yi Shiman lauryl alcohol ester etc.;
Thickening material can be associative thickener, polyurethane thickener etc.;
Catalyzer can be cobalt naphthenate, zinc naphthenate, T31 etc.;
Pigment adds according to actual needs in right amount.
As preferably, described aminoresin is one or more the composition in melamine-type, benzene guanamine type, glycoluril type, urea aldehyde type resin; Melamine-type resins comprises methyl-etherified trimeric cyanamide, butyl ether trimeric cyanamide etc., preferably Cyme1300, Cymel 303, Cyme130, Cymel 32, Cyme1370, Cymel l156, Cymel l158, Cyme 1325 or the Ineos 747 etc. of the special company of cyanogen; Benzene birds droppings amine type resin comprises the single polymers of the first and second base etherified resins, butyl ether resin and methoxylation etc., preferably Cymel l123, Cymel l125, Cymel 1170, the Cymel 1172 etc. of the special company of cyanogen; Urea aldehyde type resin comprises methyl-etherified and butyl ether resin, preferably Beetl 55, Beetl 60, Beetl 65, the Beetl 80 etc. of Beetl company.
Described lagging material is hollow glass micropearl, hollow haydite, expanded vermiculite, pearlstone, sepiolite, diatomite, wilkinite, float one or more the composition in pearl, tin-antiomony oxide, tin indium oxide, titanium dioxide.
Described strongthener is one or more the composition in hollow aramid fiber, sepiolite fibre, aluminum silicate fiber.
Described acrylic acid hydroxy alkyl ester is one or more the composition in Hydroxyethyl acrylate, Propylene glycol monoacrylate, vinylformic acid hydroxy butyl ester or hydroxyethyl methylacrylate, Rocryl 410, methacrylic acid hydroxy butyl ester.
The preparation method of described corrosion-resistant thermal insulation thermal insulating coating is characterized in that preparation process is as follows:
By the 35-60% deionized water, the 20-40% modified epoxy, 5-30% is acrylic resin modified, and 1-8% aminoresin adds in reactor, starts agitator, mixes; The pH value of regulation system is between 7-9; Then add successively 1-10% auxiliary agent, 10-25% lagging material, 0-8% strongthener, high-speed stirring 1-3 hour, mix and obtain the invention product.
Relative prior art the invention has the beneficial effects as follows:
Production technique is simple, and production efficiency is high and energy consumption is low; , containing organic solvent, solvent-free volatilization during coating curing, can be to environment; The mechanical property excellences such as coating adhesion, hardness, scratch resistance, wear resistance, water tolerance; Simultaneously non-corrosibility, salt fog resistance, plasticity, thermotolerance, bending resistance are better.
Embodiment
According to client's actual needs, invent formula by adjustment, can obtain needed product effect, below by embodiment, the invention will be further described, but and do not mean that limiting the scope of the present invention.
Accurately take each component by formula, successively deionized water, modified epoxy, acrylic resin modified, aminoresin are added in reactor, start agitator, mix; The pH value of regulation system is between 7-9; Then add successively auxiliary agent, lagging material, strongthener, high-speed stirring 1-3 hour, mix and obtain the invention product.Composite formula is as shown in table 1:
Table 1 Coating material composition composition formula
Above embodiment, the performance test results is as shown in table 2:
Table 2 the performance test results
From the performance comparison of test-results, can find out, embodiment has excellent over-all properties.
Above-described embodiment is preferably embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and principle, substitutes, combination or simplify; all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (6)
1. a corrosion-resistant thermal insulation thermal insulating coating, be characterised in that it comprises the component with following weight percent content: deionized water 35-60%, modified epoxy 20-40%, acrylic resin modified 5-30%, aminoresin 1-8%, lagging material 10-25%, strongthener 0-8%, auxiliary agent 1-10%;
Described modified epoxy is one or more the composition in acrylic modified epoxy resin, butyl acrylate epoxy resin, trimethyl cyclohexyl methacrylate epoxy resins, polyurethane modified epoxy resin, bi-maleimide modified epoxy resin, polyamic acid modified epoxy, bisphenol A epoxide resin;
Described acrylic resin modified be acrylic or methacrylic acid and the multipolymer of esters of acrylic acid or acrylic acid hydroxy alkyl ester or vinylformic acid amido alkyl ester;
Described auxiliary agent is one or more the composition in sterilant, mould inhibitor, wetting dispersing agent, flow agent, defoamer, pH adjusting agent, frostproofer, film coalescence aid, pigment, thickening material, catalyzer.
2. corrosion-resistant thermal insulation thermal insulating coating according to claim 1, is characterized in that described aminoresin is one or more the composition in melamine-type, benzene guanamine type, glycoluril type, urea aldehyde type resin.
3. corrosion-resistant thermal insulation thermal insulating coating according to claim 1, is characterized in that described lagging material is hollow glass micropearl, hollow haydite, expanded vermiculite, pearlstone, sepiolite, diatomite, wilkinite, floats one or more the composition in pearl, tin-antiomony oxide, tin indium oxide, titanium dioxide.
4. corrosion-resistant thermal insulation thermal insulating coating according to claim 1, is characterized in that described strongthener is one or more the composition in hollow aramid fiber, sepiolite fibre, aluminum silicate fiber.
5. corrosion-resistant thermal insulation thermal insulating coating according to claim 1, is characterized in that described acrylic acid hydroxy alkyl ester is one or more the composition in Hydroxyethyl acrylate, Propylene glycol monoacrylate, vinylformic acid hydroxy butyl ester or hydroxyethyl methylacrylate, Rocryl 410, methacrylic acid hydroxy butyl ester.
6. according to the preparation method of the described corrosion-resistant thermal insulation thermal insulating coating of any one in claim 1 to 5, it is characterized in that preparation process is as follows:
By the 35-60% deionized water, the 20-40% modified epoxy, 5-30% is acrylic resin modified, and 1-8% aminoresin adds in reactor, starts agitator, mixes; The pH value of regulation system is between 7-9; Then add successively 1-10% auxiliary agent, 10-25% lagging material, 0-8% strongthener, high-speed stirring 1-3 hour, mix and obtain described corrosion-resistant thermal insulation thermal insulating coating.
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| CN103787649A (en) * | 2013-12-23 | 2014-05-14 | 苏州宏泉高压电容器有限公司 | Anti-corrosion ceramic material and preparation method thereof |
| CN104277638A (en) * | 2014-10-29 | 2015-01-14 | 安徽朗凯奇建材有限公司 | Anti-oil-pollution anti-bacterial self-cleaning type water-based paint and preparation method thereof |
| CN104277671A (en) * | 2014-10-29 | 2015-01-14 | 安徽朗凯奇建材有限公司 | Water-based thermal insulating coating with good wear resistance weather resistance and preparation method of water-based thermal insulating coating |
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