CN103445984A - Mild shampoo containing alkyl glycoside-hydroxypropyl sodium phosphate copolymer - Google Patents
Mild shampoo containing alkyl glycoside-hydroxypropyl sodium phosphate copolymer Download PDFInfo
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- CN103445984A CN103445984A CN2013103774033A CN201310377403A CN103445984A CN 103445984 A CN103445984 A CN 103445984A CN 2013103774033 A CN2013103774033 A CN 2013103774033A CN 201310377403 A CN201310377403 A CN 201310377403A CN 103445984 A CN103445984 A CN 103445984A
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Abstract
The invention relates to a mild shampoo containing a glycoside-hydroxypropyl sodium phosphate copolymer. Except water, the shampoo contains the following raw materials: (A) a main surfactant occupying 5-40% of the weight of the mild shampoo, which is the composition of the alkyl glycoside-hydroxypropyl sodium phosphate copolymer and lauryl polyoxyethylene ether sodium sulphate in a weight ratio of (10:1)-(2:1), (B) cationic guar gum occupying 0.05-0.5% of the weight of the mild shampoo, and (C) cocamide monoethanolamide occupying 1.0-3.0% of the weight of the mild shampoo; and the pH value of the shampoo is 4.5-5.5. In the mild shampoo disclosed by the invention, the alkyl glycoside-hydroxypropyl sodium phosphate copolymer is used as the main surfactant, thus the dosage of sulphate surfactants is greatly reduced; moreover, the mild shampoo is rich in foam, good in mild property, and suitable for preparing shampoos for children.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of mild shampoo compositions that contains alkyl polyglucoside hydroxypropyl sodium phosphate copolymer.
Background technology
Along with improving constantly of living standard, people are also more and more higher to demand and the requirement of hair washing product, this has proposed more and more higher requirement also to the formula engineers of technical field: foam is abundant, cleaning capacity is good, mildness is high, do not contain or contain a small amount of sulfate, do not contain or also arise at the historic moment containing technology demands such as a small amount of silicone oil.At present, aspect the shampoo formula technique, the main formula system of shampoo namely be take by the first type surface activating agent anion surfactant that sulfate is representative and is formed as lauryl alcohol sulfate and sulfated lauryl alcohol etc., in addition, also must add and use zwitterionic surfactant as cocamido propyl betaine in order to improve lather quickness and mildness, lauryl betaine or cocos nucifera oil both sexes sodium acetate, and nonionic foam stabilizer, coconut monoethanol amide, cocos nucifera oil diglycollic amides etc., for the dry wet conditioning property that increases hair also must be used silicone oil.
Along with new formula technique, the invention of new raw material and use, the formula of traditional shampoo is change quietly also.
The surfactant that for example the shampoo formula is used the surfactant from traditional sulfate type anion surfactant to the various performances made from the APG deriving technology as alkyl polyglucoside (APG) and some row with green surfactant shifts.The derivative surfactant of APG and APG has out of gentle characteristic, and has good hair conditioning.
The APG deriving technology is exactly the novel product out of the APG functional character that has that other functional group of bonding obtains natural origin on alkyl-glucoside or glycan molecule.In the present invention, the APG deriving technology be exactly on alkyl-glucoside or glycan molecule bonding hydroxypropyl sodium phosphate and the novel product that obtains, it is good that this novel product has with the anion surfactant compatibility, to eyes and skin as mild as a dove, do not contain silicone oil and there is conditioning, can hang down the pH value shampoo in order to produce, and foam being abundant, be easy to thickening, can greatly reduce the consumption of sulfate type anion surfactant etc. in the shampoo formula.
Summary of the invention
The present invention relates to a kind of mild shampoo containing alkyl polyglucoside hydroxypropyl sodium phosphate copolymer, outside dewatering, in this shampoo, contain: the first type surface activating agent that (A) accounts for mild shampoo weight 5% to 40% is, the compositions that this first type surface activating agent is alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and polyoxyethylene lauryl ether sodium sulfate, and both weight ratios are 10:1 to 2:1; (B) account for the cation guar gum of mild shampoo weight 0.05% to 0.5%; (C) account for the coconut monoethanol amide of mild shampoo weight 1.0% to 3.0%; This shampoo pH value is 4.5-5.5; Alkyl polyglucoside hydroxypropyl sodium phosphate copolymer is used as the first type surface activating agent in the present invention, almost can substitute the sulfate type anion surfactant fully, has conditioning property well and the mildness high.
Shampoo of the present invention, alkyl polyglucoside hydroxypropyl sodium phosphate copolymer wherein is Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and cocoyl glucosides hydroxypropyl sodium phosphate copolymer, preferably Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer.
Shampoo of the present invention, the first type surface activating agent adopts Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and polyoxyethylene lauryl ether sodium sulfate, and both part by weight 10:1-2:1.
Shampoo composite of the present invention, wherein said cationic polymer is selected from: cationic cellulose polymer, cation melon xanthan polymer, preferred cationic guar polymer of the present invention.
Shampoo composite of the present invention, also contain the pearlescent flake that accounts for composition weight 0.05% to 3.0%.
A kind of mild shampoo containing alkyl polyglucoside hydroxypropyl sodium phosphate copolymer, its component and content are:
| Component | The content % by weight |
| Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer (40%) | 28.4 |
| Polyoxyethylene lauryl ether sodium sulfate (70%) | 1.8 |
| Cation guar gum | 0.3 |
| Coconut monoethanol amide | 1.5 |
| Pearlescent flake | 1.5 |
| Disodiumedetate | 0.1 |
| Citric acid, antiseptic, coloring agent, spice, sodium chloride | In right amount |
| Water | Add to 100% |
Compared with prior art, the present invention has the following advantages:
It is that the first type surface activating agent is used that the large outstanding feature of mild shampoo one of the present invention has adopted a kind of alkyl polyglucoside hydroxypropyl sodium phosphate copolymer exactly, this first type surface activating agent for based on the APG deriving technology on alkyl-glucoside or glycan molecule bonding a kind of new nonionic surfactant of obtaining of hydroxypropyl phosphoric acid, this new nonionic surfactant will have gentle characteristic and the good capillary ability of reduction of anion surfactant with foam of traditional alkyl-glucoside (APG) concurrently.Can use separately or be used in conjunction with traditional sulfate type anion surfactant as the first type surface activating agent in the shampoo formula, greatly reduce the consumption of the sulfate type anion surfactant of tradition use, make the cleaning capacity of shampoo, spumescence and mildness all are improved.In addition, the polyglycoside surfactant activating agent of macromole polyphosphate structure also has the effect of protection scalp and hair in the clean hair of gentleness, pH faintly acid formula, the exploitation of more suitable configuration child adacrya hair washing formula.
The specific embodiment
Below will be elaborated to compositional selecting of the present invention and effect.
Containing the first type surface activating agent that accounts for mild shampoo weight 5.0% to 40% in mild shampoo of the present invention is, the compositions that this first type surface activating agent is alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and alkyl polyoxyethylene ether sodium sulfate, or the compositions of alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and alkyl sodium sulfate, or the compositions of alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and alkyl polyoxyethylene ether ammonium sulfate, or the compositions of alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and alkylsurfuric acid ammonium, in the present invention, a preferred scheme is, alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and alkyl polyoxyethylene ether sodium sulfate are used in combination.Sodium alkylether sulphate of the present invention is that alkylpolyoxyethylene sodium sulfate is called for short AES, and its structural formula is RO (CH
2cH
2o)
nsO
3na, R=C
12-C
18alkyl, n is 2-4, preferably average ethoxyquin degree is n=3.The active matter content of described alkylpolyoxyethylene sodium sulfate commercially available prod has 25% and 70% two kind, the alkylpolyoxyethylene sodium sulfate of 25% active matter content is the water white transparency thick liquid, the alkylpolyoxyethylene sodium sulfate of 70% active matter content is white or faint yellow pastel, the alkylpolyoxyethylene sodium sulfate that preferably active matter content is 70%.Described alkylpolyoxyethylene sodium sulfate also has the characteristic of non-ionic surface active agent, still has dirt-removing power preferably in hard water.
Contain a plurality of identical hydrophobic groups and a plurality of identical hydrophilic group in alkyl polyglucoside hydroxypropyl sodium phosphate copolymer surfactants structure in the present invention, can form micelle and show the capillary ability of good reduction under low concentration, this material is based on the anion surfactant of poly alkyl-glucoside structure, there is good biological degradability, and zest is low, to skin, eyes are gentle especially, can be used as the first type surface activating agent in shampoo uses, also can with the composite use of sulfate type anion surfactant as lauryl alcohol polyoxy ether sodium sulfate, can produce good cooperative effect, can be used as child or the baby cleaning product of having one's hair wash uses.
In the present invention, alkyl polyglucoside hydroxypropyl sodium phosphate copolymer comprises and is selected from Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer or cocoyl glucosides hydroxypropyl sodium phosphate copolymer, its molecular structural formula following (1):
In the molecular structure formula I, R represents alkyl, and its carbon number is 8 to 22; N is the integer between 4-6.In the present invention, R is selected from respectively C
12lauryl or C
8-C
18cocoyl, the preferred C of R of the present invention
12lauryl.
In the present invention, alkyl polyglucoside hydroxypropyl sodium phosphate copolymer comprises and is selected from Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and cocoyl glucosides hydroxypropyl sodium phosphate copolymer.Pass through great many of experiments, the inventor finds, being selected from the alkyl polyglucoside hydroxypropyl sodium phosphate copolymer of lauryl glucoside can be separately use as the first type surface activating agent of shampoo, can also with the composite use of sulfate type anion surfactant, there is splendid gentle characteristic, and can greatly reduce the consumption of sulfate type anion surfactant.In the present invention, Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and alkylpolyoxyethylene sodium sulfate have best synergy while according to the ratio of weight ratio 10:1 to 2:1, arranging in pairs or groups use.
Shampoo of the present invention, the preferred Plantacare APG 1200G hydroxypropyl of alkyl polyglucoside hydroxypropyl sodium phosphate copolymer sodium phosphate copolymer.The Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer that the present invention uses, come from poly alkyl glucose (APG for short non-ionic surface active agent), and by the chemically derived natural derivative with anionic ion attribute that produced to alkyglycosides APG skeleton.With respect to non-ionic APG precursor, there is the alkyglycosides polymer of anion attribute not only to hair and scalp gentleness, also there is the ability at low concentration decline low surface tension, therefore, the first type surface activating agent that can be used as shampoo is used separately, and use and also there is synergy with the collocation of sulfate type anion surfactant, and greatly reduce the use amount of sulfate type anion surfactant, glycan molecule in structure and phosphate molecule can reduce the direct zest of traditional sulfate type anion surfactant, being specially adapted to configure shampoo for children uses.
Alkyl polyglucoside hydroxypropyl sodium phosphate copolymer physicochemical property of the present invention: active quantities (solid content): 40%, pH(10% solution) 7.8, color Gardner≤1, Roche foam height (1% active matter) mm150;
Mild shampoo of the present invention also comprises a kind of steady foam, is selected from carbon 10 to carbon 181,2-alkyl 2 alcohol, or fatty alkanolamide comprises fatty monoethanolamine and fatty diethanol amide.The present invention preferably uses coconut monoethanol amide as foam stabilizer, and it is percent 0.5 to percent 5 that coconut monoethanol amide accounts for composition weight percentage ratio, further is optimized for percent 1 to percent 3.
The cationic polymer of the present invention are selected from quaternary ammonium derivatives of cellulose ethers, cationic cellulose, also known as Dow JR-400, LR400, cationic cellulose polymer is hydroxyethyl cellulose reacted with alkyl trimethylammonium chloride copolymers according to the degree of cationic substitution can be divided into: a high degree of cationic substitution JR, LR, and the low degree of cationic substitution degree of cationic substitution LK three models, high cationic degree of substitution is preferably cationic cellulose Su polymers, i.e., Polyquaternium-10; 2 and diallyl ammonium chloride homopolymer and methyl bis allyl 2 methyl ammonium chloride and acrylamide copolymers, such as Merck the Merquat100 poly and Merquat550 poly ammonium salts -6 -7, BASF diallyl dimethyl ammonium chloride / acrylamide copolymer (SALCARE? Super7), BASF acrylamide trimethylammonium chloride ammonium / acrylamide copolymer (? SALCARE SC60); cationized polysaccharide and cationized guar gum, cationic selected from 2,3 - epoxypropyl trimethyl ammonium chloride.Cation guar gum, Jaguar C13S as inferior as sieve ground, Jaguar C14S, or selective crosslinking homopolymer and the copolymer of (methyl) acryloyl ethyoxyl trimethyl ammonium chloride, Salcare SC92 as national starch, a kind of cationic solution (cross-linked copolymer of methacryl ethyoxyl trimethyl ammonium chloride and acrylamide) that is dispersed in content in mineral oil percent 50, and Salcare SC95 (cross-linked homopolymer of methacryl ethyoxyl trimethyl ammonium chloride).Cation melon glue of the present invention is the product obtained after melon glue is quaternized, its key component is melon glue oxypropyl trimethyl ammonium chloride, can obtain a series of cation melon glue product according to the difference of substitution value, preferably substitution value is 0.1 to 0.2, for cation melon glue of the present invention, under 25 ℃ of conditions, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s.
According to the present invention, it is 0.005 percent to percent 1 that preferred cationic melon xanthan polymer of the present invention accounts for composition weight percentage ratio, further is optimized for 0.05 percent to percent 0.3.
Mild shampoo of the present invention also contains the pearlescent flake that accounts for composition weight 0.05% to 3.0%, and described pearlescent flake is ethylene glycol monostearate and Ethylene Glycol Distearate.Adding of described pearlescent flake, can give the pearl effect that shampoo is beautiful.
Mild shampoo of the present invention can also comprise other optional components, comprises viscosity-controlling agent, chelating agen, pH adjusting agent, antiseptic, pigment and spice etc.Described viscosity-controlling agent accounts for 0.1% to 5.0% of composition weight, and the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, cellulose derivative, acrylic copolymer etc.Described chelating agen accounts for 0.01% to 0.30% of composition weight, the non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferably disodiumedetate; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., and optimization citric acid, the pH of regulation system is 4.0 to 6.0, and preferably 4.5 to 5.5; Choosing of described antiseptic, essence, pigment, meet the regulation of hygienic standards for cosmetics, selects safe raw material.
In mild shampoo of the present invention, except the above component, water is mended to aequum.
Preparation method
Shampoo of the present invention can by any known or other effectively be applicable to provide the technology preparation of shampoo composite, the method for preparing shampoo composite of the present invention comprises conventional preparation and hybrid technology.
Using method
Mild shampoo of the present invention is used in clean and mode conditioning hair of routine, mainly comprises following step:
(A) water is by the hair moistening;
(B) use the shampoo composite of the aforementioned any one claim of effective dose on described hair, the scope of described effective dose is generally 1 gram to 50 gram, preferably 2 to 20 grams;
(C) with the shampoo composite on the described hair of water rinse.
These steps can be as required repeatedly, to reach the effect of look for clean, conditioning, moisturizing and water retention.
Embodiment
It is below the non-limiting example of shampoo composite of the present invention.Providing of these embodiment is only for illustrative purposes, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.Term used " a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, pigment etc., the selection of these a small amount of materials will be along with selected changing in order to the physics and chemistry characteristic for preparing special component of the present invention.
Preparation Example I-X V
Described in suitable Preparation Example I-X V, the method for shampoo composite is as follows: suitable quantity of water is joined in retort, add the cation melon and glue is disperseed under slowly stirring, slowly be stirred and heated to 60 ℃ to 80 ℃, then according to formula, need to add respectively alkyl polyglucoside hydroxypropyl sodium phosphate copolymer, lauryl sulfate, Sodium dodecylpolyoxyethylene sulfate, pearlescent flake, disodiumedetate (if using these materials), make these materials disperse rear cooling fully.When temperature is down to 45 ℃ of left and right, add sodium chloride, citric acid, antiseptic, pigment, essence etc. to continue to stir, guarantee to obtain uniform mixture.After adding all components, can add as required viscosity modifier and pH adjusting agent, regulate the viscosity of product, finally pH is adjusted to 4.5-5.5.Optionally finally can add a small amount of water to supply.
Embodiment I-V
Embodiment VI-X
The foam height method of testing: adopt the method for testing of Roche (Ross--Miles) foamer meter to be tested, test respectively initial foam height, after 1 minute, foam height and foam height after 5 minutes, then average.From the embodiment of the present invention, can find out: in the situation that shampoo formula, the condition such as main and auxiliary surfactant activity content and cationic polymer is approximate, shampoo of the present invention adopts take foam height that Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and lauryl alcohol sulfate is the formula of first type surface activating agent and all is greater than and take the foam height that traditional aliphatic alcohol sulfate and fatty alcohol ether sulphate compositions be the first type surface active agent formulation, in Table 1.
H
50value mildness method of testing: adopt erythrocyte hemolysis experiment (Red blood cell test RBC) method, the method is one of Draize experiment alternative method, ultimate principle is to measure the damage of chemicals cell membrane and the change of the cell membrane permeability therefore caused, estimate the degree of injury of cell membrane by the amount of measuring the hemoglobin spilt from erythrocyte, this degree of injury has directly related property with the zest of product.The mainly eye irritation research for chemicals such as cosmetic product and raw materials by the RBC experiment in the world.Therefore the present invention passes through the mildness with erythrocyte hemolysis determination of experimental method formula, and forms contrast, test products mildness.Concrete grammar is: the absorbance of the red cell suspension after the effect of use spectrophotometry chemicals can calculate hemolysis rate and H
50value (even concentration value of the tested material of 50% erythrocyte generation haemolysis).H
50be worth littlely, add the sample of small amount just obvious haemolysis can occur, show that sample stimulus is large, mildness is poor.H
50value is large, shows that sample stimulus is little, and mildness increases.In the present invention, along with the increase of Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer percentage by weight in formula, H
50value also increases thereupon, shows that mildness increases, in Table 1.
Eyes comfortableness clinical trial method:
Eyes Comfort Evaluation method is: Preparation Example 1-10 is issued respectively to 60 testers and use.When using the shampoo sample, the tester washes hair according to identical method, every kind of shampoo is used one week (washing once at interval of two days), the tester according to oneself feel marked, standards of grading adopt 7 minutes systems, (eyes are shed tears or be red and swollen) representative in 1 minute is the poorest, 7 minutes (eyes comfortable, without any reaction) represent best, and the higher effect of mark is more good.Show that by above eyes Comfort Evaluation the more traditional shampoo of mild shampoo of the present invention has obvious superiority.Evaluation result is in Table 2.
Table 1 foam height and H
50value (mildness)
Table 2 eyes comfort evaluation statistics
Claims (6)
1. the mild shampoo containing alkyl polyglucoside hydroxypropyl sodium phosphate copolymer, can accept component except containing shampoo, and this shampoo also contains:
(A) account for the first type surface activating agent of mild shampoo weight 5.0% to 40%, the compositions that this first type surface activating agent is alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and polyoxyethylene lauryl ether sodium sulfate, and the weight ratio of alkyl polyglucoside hydroxypropyl sodium phosphate copolymer and polyoxyethylene lauryl ether sodium sulfate is 10:1 to 2:1;
(B) account for the cation guar gum of mild shampoo weight 0.05% to 0.5%;
(C) account for the coconut monoethanol amide of mild shampoo weight 1.0% to 3.0%;
Wherein, alkyl polyglucoside hydroxypropyl sodium phosphate copolymer, its molecular structural formula following (1):
In the molecular structure formula I, R represents alkyl, and its carbon number is 8 to 22; N is the integer between 4-6.
2. shampoo according to claim 1, in alkyl polyglucoside hydroxypropyl sodium phosphate copolymer wherein, R is selected from respectively C
12lauryl or C
8-C
18cocoyl.
3. shampoo according to claim 1, the preferred Plantacare APG 1200G hydroxypropyl of alkyl polyglucoside hydroxypropyl sodium phosphate copolymer sodium phosphate copolymer wherein.
4. shampoo according to claim 3, the part by weight 10:1-2:1 of wherein said Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and polyoxyethylene lauryl ether sodium sulfate.
5. shampoo according to claim 1, its pH value is 4.5-5.5.
6. the mild shampoo containing alkyl polyglucoside hydroxypropyl sodium phosphate copolymer, its component and content are:
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