CN103436155B - 一种耐光性水性聚氨酯涂料的制备方法 - Google Patents
一种耐光性水性聚氨酯涂料的制备方法 Download PDFInfo
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- CN103436155B CN103436155B CN201310407835.4A CN201310407835A CN103436155B CN 103436155 B CN103436155 B CN 103436155B CN 201310407835 A CN201310407835 A CN 201310407835A CN 103436155 B CN103436155 B CN 103436155B
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- Prior art keywords
- stirring reaction
- light
- waterborne polyurethane
- resistant waterborne
- polyurethane coating
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011527 polyurethane coating Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 32
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 11
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004970 Chain extender Substances 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000012975 dibutyltin dilaurate Substances 0.000 claims abstract description 7
- 238000004945 emulsification Methods 0.000 claims abstract description 7
- 230000035484 reaction time Effects 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims abstract description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 15
- -1 isocyanic acid tri-methyl hexamethylene esters Chemical class 0.000 claims description 4
- KJTLQQUUPVSXIM-ZCFIWIBFSA-N (R)-mevalonic acid Chemical group OCC[C@](O)(C)CC(O)=O KJTLQQUUPVSXIM-ZCFIWIBFSA-N 0.000 claims description 3
- KJTLQQUUPVSXIM-UHFFFAOYSA-N DL-mevalonic acid Natural products OCCC(O)(C)CC(O)=O KJTLQQUUPVSXIM-UHFFFAOYSA-N 0.000 claims description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 claims description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 abstract description 11
- 229920002635 polyurethane Polymers 0.000 abstract description 11
- 230000007613 environmental effect Effects 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 11
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 230000000176 photostabilization Effects 0.000 description 7
- 238000009835 boiling Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229920006264 polyurethane film Polymers 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical class OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 239000007998 bicine buffer Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
时间/min | PODESENG 513MS | D | F | G | H |
90 | 0.7 | 0.3 | 0.4 | 0.2 | 0.1 |
150 | 0.9 | 0.4 | 0.6 | 0.2 | 0.1 |
270 | 1.0 | 0.5 | 0.7 | 0.3 | 0.3 |
330 | 1.1 | 0.5 | 0.7 | 0.4 | 0.4 |
390 | 1.3 | 0.7 | 0.8 | 0.5 | 0.6 |
450 | 1.5 | 0.8 | 0.8 | 0.6 | 0.7 |
510 | 1.8 | 0.9 | 0.9 | 0.7 | 0.9 |
540 | 2.1 | 1.0 | 1.1 | 0.7 | 0.9 |
600 | 2.3 | 1.1 | 1.1 | 1.0 | 1.0 |
类别 | PODESENG 513MS | D | F | G | H |
断裂伸长率/% | 188.26 | 227.67 | 222.52 | 221.80 | 223.54 |
Claims (2)
Priority Applications (1)
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CN201310407835.4A CN103436155B (zh) | 2013-09-09 | 2013-09-09 | 一种耐光性水性聚氨酯涂料的制备方法 |
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CN201310407835.4A CN103436155B (zh) | 2013-09-09 | 2013-09-09 | 一种耐光性水性聚氨酯涂料的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN103436155A CN103436155A (zh) | 2013-12-11 |
CN103436155B true CN103436155B (zh) | 2015-12-23 |
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CN201310407835.4A Expired - Fee Related CN103436155B (zh) | 2013-09-09 | 2013-09-09 | 一种耐光性水性聚氨酯涂料的制备方法 |
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CN (1) | CN103436155B (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104004449B (zh) * | 2014-06-15 | 2016-04-20 | 段宝荣 | 一种耐光与阻燃性水性聚氨酯涂料的制备方法 |
CN104087149B (zh) * | 2014-07-21 | 2016-04-27 | 段宝荣 | 一种耐光性水性聚氨酯涂料的制备方法 |
CN104098995B (zh) * | 2014-07-21 | 2016-05-04 | 广州市盛邦康体场地材料有限公司 | 一种阻燃与防水性水性聚氨酯涂料的制备方法 |
CN104073145B (zh) * | 2014-07-21 | 2016-08-24 | 常州市天安特种涂料有限公司 | 一种耐光性水性聚氨酯涂料的制备方法 |
CN104356330B (zh) * | 2014-09-28 | 2017-02-08 | 陕西科技大学 | 一种羧酸型水性聚氨酯扩链剂及其制备方法 |
CA2975276C (en) * | 2015-03-06 | 2023-04-18 | H.B. Fuller Company | Water based primer composition |
CN109354681A (zh) * | 2018-11-19 | 2019-02-19 | 中国科学院青岛生物能源与过程研究所 | 一种非异氰酸酯聚氨酯的制备方法 |
CN111662633B (zh) * | 2020-06-24 | 2021-11-30 | 广东达尔新型材料有限公司 | 一种防静电耐磨聚氨酯地坪涂料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1333791A (zh) * | 1998-12-11 | 2002-01-30 | 陶氏化学公司 | 由多环氧化物和多异氰酸酯制得的聚噁唑烷酮粘合剂树脂组合物 |
CN1405253A (zh) * | 2001-08-07 | 2003-03-26 | 拜尔公司 | 亲水性聚氨酯树脂的水分散体 |
CN103073696A (zh) * | 2013-01-30 | 2013-05-01 | 段宝荣 | 一种耐光性水性聚氨酯的制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101497698A (zh) * | 2009-01-22 | 2009-08-05 | 南京大学 | 壳聚糖-聚氨酯离子复合物弹性体材料的制备方法 |
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2013
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1333791A (zh) * | 1998-12-11 | 2002-01-30 | 陶氏化学公司 | 由多环氧化物和多异氰酸酯制得的聚噁唑烷酮粘合剂树脂组合物 |
CN1405253A (zh) * | 2001-08-07 | 2003-03-26 | 拜尔公司 | 亲水性聚氨酯树脂的水分散体 |
CN103073696A (zh) * | 2013-01-30 | 2013-05-01 | 段宝荣 | 一种耐光性水性聚氨酯的制备方法 |
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Address after: 264000 16-2, Fu Qing Street, Zhifu District, Shandong, Yantai Applicant after: Duan Baorong Address before: 264005 Shandong Province, Yantai city Laishan District Road No. 30 spring Applicant before: Duan Baorong |
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CB03 | Change of inventor or designer information |
Inventor after: Tan Zhigang Inventor before: Duan Baorong Inventor before: Gao Long Inventor before: Song Yu |
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TR01 | Transfer of patent right |
Effective date of registration: 20170215 Address after: 529738 Guangdong city of Jiangmen province Heshan City, the ancient town of labor three Road Industrial Area Patentee after: Heshan Yixin Chemical Co., Ltd. Address before: 264000 16-2, Fu Qing Street, Zhifu District, Shandong, Yantai Patentee before: Duan Baorong |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151223 Termination date: 20200909 |
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CF01 | Termination of patent right due to non-payment of annual fee |