CN103416399B - Sex attractant of carposina coreana and attracting agent comprising the same - Google Patents
Sex attractant of carposina coreana and attracting agent comprising the same Download PDFInfo
- Publication number
- CN103416399B CN103416399B CN201310188650.9A CN201310188650A CN103416399B CN 103416399 B CN103416399 B CN 103416399B CN 201310188650 A CN201310188650 A CN 201310188650A CN 103416399 B CN103416399 B CN 103416399B
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- China
- Prior art keywords
- carposina
- coreana
- sex attractant
- attractant
- sex
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Food Science & Technology (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
The invention provides a sex attractant of carposina coreana which is expectable to be used for occurrence prediction, mass trap and mating disruption, and an attracting agent with the same as a main component. Specifically, the invention provides a sex attractant of carposina coreana at least comprising at least (Z)-7-tricosene and (Z)-13-eicosene-10-one, and a sex attracting agent of carposina coreana with the same as a main component.
Description
Technical field
The present invention relates to the sex attractant substance of fruit tree pest insect Carposina coreana (Carposina coreana) and contain which
Sex attractant.
Background technology
Carposina coreana is China, the important pests of the Fructus Corni of Korea.In recent years, from foodsafety, to environment
From the viewpoint of burden, in the use of insecticide, it is desirable to controlled in necessary bottom line.Therefore, replace sprinkling
The exploitation of the new control technology of insecticide is important.
Instead the control technology of spraying insecticide, can enumerate the insect-pest exterminating mode that make use of sex attractant substance.
For example, in the Occurrence forecast of lepidoptera pest, extensively using sex attractant trap.Sex attractant substance is referred to male insect
Show the material of species specificity attracting action.By being used as attractant, effective Occurrence forecast can be carried out.By sending out
Raw prediction and can in due course the phase prevent and kill off, therefore can expect to prevent the effect of insecticide overspray.Further, by using
The sex attractant substance traps and kills the copulation interference (Disrupting of a large amount of trapping methods of a large amount of male worms, interference male and female mating behavior
Sex Pheromone Communication) method, it is also possible to carry out preventing and kill off for insect.
So far, as the sex attractant substance of Carposina coreana is unclear, therefore unavailability attractant is lured
Catch device.Therefore, the strong sex attractant for expecting to develop this kind.
The content of the invention
The present invention is made in view of the foregoing, it is therefore intended that offer can expect for Occurrence forecast, a large amount of trapping,
The sex attractant substance and the sex attractant with which as effective ingredient of the Carposina coreana in copulation interference.
The present inventor has found (Z) -7- tricosenes and 20 carbon of (Z) -13- when field trapping experiment is implemented
The mixture of alkene -10- ketone shows epigamic to Carposina coreana, so as to complete the present invention.
Therefore, the present invention provides a kind of sex attractant substance and the Fructus Corni moth with which as effective ingredient of Carposina coreana
The sex attractant of fruit moth, above-mentioned sex attractant substance at least containing (Z) -7- tricosenes and (Z) -13- eicosylenes -
10- ketone.
In accordance with the invention it is possible to specifically be lured the male insect of Carposina coreana, shape is occurred for understanding
The effective sex attractant of condition.Additionally, by for a large amount of trappings, copulation interference etc., it is also possible to directly prevent and kill off the species.
Therefore, the present invention provides a kind of Occurrence forecast method of Carposina coreana, a large amount of trapping methods or copulation interference
Method, which uses the Carposina coreana at least containing (Z) -7- tricosenes and (Z) -13- eicosylene -10- ketone
Sex attractant substance luring Carposina coreana.
The present invention also provides a kind of (Z) -7- tricosenes and (Z) -13- eicosylene -10- ketone in preparative
Purposes in attractant, wherein sex attractant of the sex attractant for Carposina coreana.
Description of the drawings
Fig. 1 shows white adhesive type trapper.
Specific embodiment
With regard to (Z) -7- tricosenes, the intersection idol of Grignard reagent and known 1- bromo-decanes for example, can be passed through
Connection reacts and synthesizes, wherein, Grignard reagent is to make known chloroalkene (Z) -7- chloro tridecylenes in tetrahydrofuran
With obtained by metal reactive magnesium.
With regard to (Z) -13- eicosylene -10- ketone, can be by known method (for example, Japanese Unexamined Patent Application 55-
No. 59129 publications) synthesis.I.e., for example, can be by making the chloro- 3- decene of 1- and Grignard reagent, the last of the ten Heavenly stems obtained by metal reactive magnesium
The anhydride reaction of thiazolinyl magnesium chloride and capric acid and synthesize.
For the Fructus Corni moth fruit at least containing (Z) -7- tricosenes and (Z) -13- eicosylene -10- ketone
The sex attractant substance of moth, its (Z) -7- tricosene and (Z) are as long as the mixed proportion of -13- eicosylene -10- ketone
It is that male insect shows the scope reacted, is not particularly limited, e.g. 10：100 to 10000：100 (mass ratioes), it is excellent
Elect 100 as：100 to 1000：100 (mass ratioes), more preferably 200：100 to 800：100 (mass ratioes).
In the sex attractant of the sex attractant substance containing Carposina coreana of the present invention, butylhydroxy first can also be added
The antioxidants such as benzene, Butylated hydroxyanisole, hydroquinone, Vitamin E, 2- hydroxyl -4- octyloxybenzophenones, 2- (2 ' -
Hydroxyl-the 3 '-tert-butyl group -5 '-aminomethyl phenyl) UV absorbent such as -5- chlorobenzotriazoles, relative to (Z) -7- two
The total amount of tridecylene and (Z) -13- eicosylene -10- ketone, for example, antioxidant is 1～5 mass %, and ultraviolet is inhaled
Receipts agent is 1～5 mass %.
As long as the sex attractant of the present invention can not especially be limited long lasting for a certain amount of effective ingredient is discharged
It is fixed, be filled in rubber, polyethylene, polypropylene, ethylene-vinyl acetate copolymer, polrvinyl chloride etc. work(is controlled with burst size
Can material formed cover (cap), pipe, be laminated made by use in the container such as bag, capsule, ampoule.
As long as the quality sex attractant of the sex lure carried in container shows the scope of attractive activity, do not have
It is particularly limited to, for example the preferred scope of 10 μ g～100mg.
In the case of for Occurrence forecast, preferably always exist within 6 periods in May to the October for producing adult
1 or 2 trappers are set in 1 hectare.As the amount (bearing capacity) of the sex attractant substance in each container now, it can be preferred to make
It is monitored with 10 μ g～10mg.When bearing capacity is increased, trapping number becomes many, but investigation sometimes becomes complicated.On the other hand, exist
In the case of for a large amount of trapping methods, preferably during the generation 6 months of period of above-mentioned adult in the always setting in 1 hectare
More than 10 trappers.The borer population of capture more at most preventive effect is higher, therefore the amount of the sex attractant substance in each container (is carried
Amount) it is desired for 1mg～100mg.
The trapper of the sex attractant carried in dispensing containers is not particularly limited, and for example, can enumerate white stickup
Type trapper.
Fig. 1 shows an example of white adhesive type trapper.The white adhesive type trapper of Fig. 1 includes lid and bottom plate,
The intrusion mouth of worm is made to narrow.Also, stickup material is pasted with plate upper surface, attractant is directly placed on sticking veneer
A and use.That is, it is the structure that only captures the insect near attractant, and is that flying into for the insect outside object is excluded as far as possible
Outer structure.
Embodiment
Embodiments of the invention described further below, but the present invention do not limited by these embodiments.
[embodiment 1, comparative example 1]
With 432：(Z) -7- tricosenes and (Z) -13- eicosylene -10- ketone are mixed by 100 quality ratio
Close, and both compositions of 5mg are carried on the device of the rubber cover being made up of isoprene, as drawing for embodiment 1
Lure.Additionally, only being carried the rubber cover of (Z) -13- eicosylene -10- ketone this composition of 5mg as comparative example 1
Attractant.Attractant place an evening after be installed on white adhesive type trapper (SANKEI CHEMICAL CO.,
LTD. the SE trappers that (サ Application ケ イ chemistry society) manufactures, 29cm × 32.5cm).
(1 hectare of the fruit tree institute that Carposina coreana is lived：100m × 100m) two deciles are used and are compared for embodiment 1
Example 1, installs 1 trapper for being configured with each attractant at respective center.Every 15～18 days, determine each trapper and trapped and killed
Male insect number.By the trapping number of the Carposina coreana of the attractant of embodiment 1 interior during investigation and drawing for comparative example 1
The result of total trapping number of lure is shown in table 1.
Table 1
Confirm that the attractant of embodiment 1 has trapped and killed 4 Carposina coreanas, and the attractant of comparative example 1 is during investigating
1 does not all have trapping.Understand that (Z) -7- tricosenes are this kind with the mixture of (Z) -13- eicosylene -10- ketone
The sex attractant substance of category.
Claims (2)
1. the Occurrence forecast method of Carposina coreana, a large amount of trapping method or copulation interference method, which is with least containing quality
Than for 200：100 to 800：100 (Z) -7- tricosenes and the Fructus Corni of (Z) -13- eicosylene -10- ketone are eaten into
The sex attractant substance of fruit moth is luring Carposina coreana.
2. the mixture of (Z) -7- tricosenes and (Z) -13- eicosylene -10- ketone is in sex attractant is prepared
Purposes, wherein sex attractant of the sex attractant for Carposina coreana, and the mixture contains mass ratio for 200：
100 to 800：100 (Z) -7- tricosenes and (Z) -13- eicosylene -10- ketone.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-116463 | 2012-05-22 | ||
| JP2012116463A JP5914161B2 (en) | 2012-05-22 | 2012-05-22 | Sexual attractant of Sanshu Yushinui and attractant containing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103416399A CN103416399A (en) | 2013-12-04 |
| CN103416399B true CN103416399B (en) | 2017-04-12 |
Family
ID=49642206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310188650.9A Active CN103416399B (en) | 2012-05-22 | 2013-05-21 | Sex attractant of carposina coreana and attracting agent comprising the same |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5914161B2 (en) |
| KR (1) | KR20130130651A (en) |
| CN (1) | CN103416399B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102823590A (en) * | 2011-06-17 | 2012-12-19 | 信越化学工业株式会社 | Sex pheromone composition of peach fruit moth and attractant comprising the same |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5377004A (en) * | 1976-12-17 | 1978-07-08 | Nourinshiyou Nougiyou Gijiyuts | 77alkenee111one compound and insect attraction agent containing same as effective component |
| LU78277A1 (en) * | 1977-10-10 | 1979-06-01 | Airwick Ag | ATTRACTIVE BATS FOR USE IN THE CONTROL OF SYNANTHROPIC FLIES |
| LU78276A1 (en) * | 1977-10-10 | 1979-06-01 | Airwick Ag | REDUCED TOXICIDE INSECTICIDES |
| JPS57139005A (en) * | 1981-02-19 | 1982-08-27 | Otsuka Pharmaceut Co Ltd | Composition disturbing communication between insect pests |
| JPS6242903A (en) * | 1985-08-16 | 1987-02-24 | Earth Chem Corp Ltd | Fly attractant |
| JP2002142640A (en) * | 2000-11-13 | 2002-05-21 | Shin Etsu Chem Co Ltd | Method for predicting breeding of pest using pheromone trap in field treated with communication disruptor |
-
2012
- 2012-05-22 JP JP2012116463A patent/JP5914161B2/en active Active
-
2013
- 2013-05-21 KR KR1020130057318A patent/KR20130130651A/en not_active Application Discontinuation
- 2013-05-21 CN CN201310188650.9A patent/CN103416399B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102823590A (en) * | 2011-06-17 | 2012-12-19 | 信越化学工业株式会社 | Sex pheromone composition of peach fruit moth and attractant comprising the same |
Non-Patent Citations (1)
| Title |
|---|
| Sex pheromone of the peach fruit moth，Carposina niponensis walsingham(Lepidoptera:Carposinidae):isolation，identification and synthesis;Yoshio Tamaki et al.;《Appl. Ent. Zool.》;19771231;第12卷(第1期);60-68 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5914161B2 (en) | 2016-05-11 |
| CN103416399A (en) | 2013-12-04 |
| JP2013241377A (en) | 2013-12-05 |
| KR20130130651A (en) | 2013-12-02 |
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